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NASA NTRS1982

The prebiological paleoatmosphere - Stability and composition

In the past, it was generally assumed that the early atmosphere of the earth contained appreciable quantities of methane (CH4) and ammonia (NH3). This was the type of atmosphere believed to be the most suitable environment for chemical evolution, the nonbiological formation of complex organic molecules, the precursors of living systems. Photochemical considerations suggest that a CH4-NH3 dominated early atmosphere was probably very short-lived, if it ever existed at all. Instead, an early atmosphere of carbon dioxide (CO2) and nitrogen (N2) is favored by photochemical as well as geological and geochemical considerations. Photochemical calculations also indicate that the total oxygen column density of the prebiological paleoatmosphere did not exceed 10 to the -7th of the present atmospheric level.

Levine, J. S.↗

NASA NTRS1983

Epitaxial growth of Hg/1-x/Cd/x/Te by chemical vapor transport

The chemical vapor transport technique was applied for the first time to the growth of Hg(1-x)Cd(x)Te epitaxial layers on CdTe substrates using a preannealed source material of Hg(0.8)Cd(0.2)Te. The experiment took place in a pretreated ampoule loaded with source material, HgI2 transport agent, and substrate and sealed under a residual pressure of about 10 to the -5th torr. The temperature of the source region was 590 C and that of the deposition zone 535 C with a nearly sigmoidal shaped profile between the end temperatures. The change in appearance of the substrate surface during the experiment is described, and the structures of the surface of the Hg(1-x)Cd(x)Te layer and of the layer itself as revealed by Nomarski contrast illumination and Laue X-ray diffraction, respectively, are discussed.

Wiedemeier, H.↗

NASA NTRS1982

Observations of a gamma-ray burst and other sources with a large-area, balloon-borne detector

Observations of a weak cosmic gamma ray burst of integrated intensity 2 x 10 to the -6th erg/sq cm, two solar flare events, and pulsed emission profiles of A0535+26 and NP0532 are reported for several energy intervals in the energy range from 45 to 520 keV. The measurements were made with a NaI(Tl) detector array flown on a balloon to 4 g/sq cm residual atmosphere from Palestine, Texas, on October 6-8, 1980, for 28 hours. The detector is a prototype of the Burst and Transient Source Experiment (BATSE) to be flown on the Gamma-Ray Observatory (GRO).

Wilson, R. B.↗

NASA NTRS1982

A numerical simulation of the magnetospheric gate model for the X-ray bursters

A Lagrangian, stellar interior computer code which assumes radiation transport by diffusion is used to numerically simulate an X-ray burst occurring on a rapidly rotating, 1 solar mass neutron star accreting material from a companion in noncontinuous, episodic fashion. The blob of gas from the companion extends from the surface of the neutron star to a radius of 185 km, is optically thick, has mass of 10 to the -11th solar masses, and is initially at rest with respect to the surface. The gas initially has a temperature of about 10 million K and a surface luminosity of 0.1 that of the sun. The infall results in a burst which lasts about 0.1 second and reaches a peak luminosity and effective temperature of 240,000 suns and nine million K. The burst is followed by a phase of oscillations with a period of 0.2 second. It is found that the burst is too cool and rapid to resemble normal bursts, although the time scale is in agreement with some observations.

Starrfield, S.↗

NASA NTRS1982

Maxwell currents under thunderstorms

Time variations observed in thunderstorm electric fields may be interpreted in terms of a total Maxwell current density, varying slowly with time in the intervals between lightning discharges, which can be used to estimate and map thunderstorms. Using the quasi-static behavior of the Maxwell current density, an expression is derived for the field-dependent current density under a thunderstorm during the field recovery following a lightning discharge. Values of air conductivity under the small storm which range from 2 to 6 x 10 to the -13th mho/m are inferred. Data are presented which indicate that the area-average Maxwell current is not usually affected by lightning, and instead varies slowly throughout the evolution of the storm. In light of this, it is suggested that cloud electrification processes probably do not depend on the cloud electric field as much as on the more slowly varying storm dynamics and meteorological structure.

Krider, E. P.↗

NASA NTRS1982

Comets produce submicron particles in the solar system

Observational evidence for the existence of submicron particles issuing from meteor streams and comets is examined. The MTS Explorer 46 carried a meteoroid detector which measured the rate of impact of particles with masses on the order of 10 to the -16th gram. Particle enhancements were observed in association with meteor streams, such as the Taurid and Orionids. The ratio of radiation pressure to gravity is employed to examine the effects of radiation pressure on the particles. When the ratio is higher than one, particles become smaller, unless they are dielectrics. Particles with radii less than 0.1 micron, having a potential of +3.3 V, are projected to have a lifetime of about 3 yr. Several thousands of tons of submicron particles are expected to be produced during a cometary perihelion passage. Launch of a long duration exposure facility with the Shuttle is recommended for studies of the decay of the particles over time.

Singer, S. F.↗

NASA NTRS1982

Modifying a silicone potting compound for space flight applications

RTV-615 has been devolatilized by subjecting the uncatalyzed resin to a temperature of between 125 and 150 C for 24 hours in a vacuum of about 10 to the -6th torr. The resultant resin can be catalyzed and after a room temperature cure the outgassing of the resin is sufficiently low when tested according to ASTM E-595 that it is suitable for space flight use. Tests of physical properties of the cured devolatilized resin were compared with those of the as received silicone. The devolatilized silicones are slightly harder, have a higher tear resistance and higher tensile strengths.

Park, J. J.↗

NASA NTRS1983

Fluorescence yield from photodissociation of CH4 at 1060-1420 A

The photoabsorption and fluorescence cross sections of CH4 were measured using synchrotron radiation at 1060-1420 A. The fluorescence starts to appear at 1330 A, and its cross section increases with decreasing photon wavelengths. The fluorescence cross section at 1060 A is 0.38 x 10 to the -18th sq cm, which is much smaller than the theoretical expectation. It is unlikely that the CH2 production from CH4 photodissociation will have a population inversion in the singlet system. A vibrational structure observed at 1060-1120 A is probably the 1t2-3p Rydberg transition of CH4.

Lee, L. C.↗

NASA NTRS1983

NASA multipurpose airborne DIAL system and measurements of ozone and aerosol profiles

The hardware, operational characteristics, data processing system, and applications of the NASA airborne differential absorption lidar (DIAL) system are described. DIAL functions by assessing the average gas concentration over a specified range interval by analyzing the difference in lidar backscatter signals for laser wavelengths tuned on and off of the molecular absorption line of a gas under investigation. The system comprises two frequency-doubled Nd:YAG lasers pumping two high conversion efficiency tunable dye lasers emitting pulses separated by 100 microsec or less. The return signals are digitized and stored on magnetic tape. The signal collector consists of photomultiplier tubes implanted in a cassegrain telescope. Flight tests of the system involved on-measurements at 285.95 nm and off-measurements at 299.40 nm, which yielded a differential cross section of 1.74 x 10 to the -16th sq cm. In situ measurements with another plane at a nominal altitude of 3.2 km for comparison purposes showed accuracy to within 10% in and above the boundary layer. The system is considered as a test apparatus for more developed versions to be flown on the Shuttle

Browell, E. V.↗

NASA NTRS1982

The abundance of CH3D in the atmosphere of Titan, derived from 8- to 14-micron thermal emission

The 8.6-micron emission feature of Titan's infrared spectrum was analyzed using the Voyager temperature-pressure profile. Although both C3H8 and CH3D have bands at that wavelength, it is shown that CH3D dominates the observed emission on Titan. A CH3D/CH4 mixing ratio is derived using this band and the strong CH4 band at 7.7 microns. The corresponding D/H ratio is 4.2(+2 -1.5) x 10 to the -4th, neglecting deuterium fractionation with other molecules. The main uncertainty in this value comes from the continuum emission characteristics. The D/H ratio is apparently significantly enhanced on Titan with respect to published values for Saturn.

Kim, S. J.↗

NASA NTRS1983

Density drift instabilities and weak collisions

A model is developed which describes the effects of weak collisions on the linear kinetic theory of electrostatic density drift instabilities. A dispersion equation valid at all frequencies and wave numbers is derived using the assumptions of a weak, uniform density gradient; a uniform magnetic field; and the BGK collision operator with a modification of the local approximation. The properties of the universal and collisional density drift instabilities at maximum growth rates are examined in detail. The thresholds of the instabilities are examined for an ionospheric model which includes ion-neutral, electron-neutral, and electron-ion collisions, and are compared with the threshold of the lower hybrid density drift instability. It is concluded that the k to the -5th short wavelength density power spectra observed above 280 km in the PLUMEX experiment are due to the effects of the universal density drift instability.

Gary, S. P.↗

NASA NTRS1983

Rapid rotation and stellar activity in the triple system HD 165590

X-ray and ultraviolet observations of the spectroscopic and visual binary HD 165590 are presented. Results show that the spectroscopic binary component has a period of 0.88 day and a near-solar spectral type. A substantial soft X-ray flux for HD 165590 is also found with an X-ray luminosity of 10 to the 30.6th ergs/sec for the system. No obvious periodicities of less than 0.5 days are detected in the X-ray data, although stochastic variability is present. Observations of the transition region emission lines using the International Ultraviolet Explorer satellites are shown to be consistent with the X-ray data and reveal an approximately 50% variability on the time scale of days. It is concluded that comparisons of the results for HD 165590 with X-ray observations of other late F and G stars demonstrate that rotation-activity scaling relations are useful as gross predictors of X-ray emission.

Stern, R. A.↗

NASA NTRS1983

Detection of sulfur in the galactic center

A strong detection at the S III forbidden 18.71 micron line is reported for the galactic center region, Sgr A West. A line flux of 1.7 + or - 0.2 x 10 to the -17th W/sq cm is found for a 20 inch beam size measurement centered on IRS 1. A preliminary analysis indicates that the S III abundance relative to hydrogen is consistent with the cosmic abundance of sulfur, 0.000016, if a filling factor of unity within the known clumps is assumed. However, the sulfur abundance in the galactic center may be as much as a factor of 3 overabundant if a filling factor of 0.03 is adopted, a value found to hold for some galactic H II regions.

Herter, T.↗

NASA NTRS1982

Performance characteristics of a microwave plasma disk ion source

The development, design, and preliminary performance characteristics of a microwave plasma disk ion source are presented. Several important design concepts indigenous to microwave plasmas have been utilized in the development of this ion source: generation of a resonantly sustained microwave discharge inside a microwave/plasma coupler, probe and length tuning of the microwave/plasma coupler, and minimization of plasma volume. The experimental results for a 2.45 GHz, eight cm ion source excited in the TE(211) and TM(011) modes are described. Results are presented for electromagnetic mode excitation, electron density, coupling efficiency and loaded cavity Q, and I-V characteristics and efficiencies. It is preliminarily shown that a microwave disk-like plasma can be sustained adjacent to the grids with either TE or TM cavity modes at pressures below 2 x 10 to the -4th torr. Over 80% of the power absorbed in the cavity is coupled into the plasma.

Asmussen, J.↗

NASA NTRS1983

Methane flux across the air-water interface - Air velocity effects

Methane loss to the atmosphere from flooded wetlands is influenced by the degree of supersaturation and wind stress at the water surface. Measurements in freshwater ponds in the St. Marks Wildlife Refuge, Florida, demonstrated that for the combined variability of CH4 concentrations in surface water and air velocity over the water surface, CH4 flux varied from 0.01 to 1.22 g/sq m/day. The liquid exchange coefficient for a two-layer model of the gas-liquid interface was calculated as 1.7 cm/h for CH4 at air velocity of zero and as 1.1 + 1.2 v to the 1.96th power cm/h for air velocities from 1.4 to 3.5 m/s and water temperatures of 20 C.

Sebacher, D. I.↗

NASA NTRS1982

Atomic clocks for astrophysical measurements

It is noted that recently developed atomic hydrogen masers have achieved stability well into the 10 to the -16th domain for averaging time intervals beyond 1000 sec and that further improvements are in prospect. These devices are highly adaptable for space use in very high precision measurements of angle through Very Long Baseline Interferometry (VLBI) and of range and range-rate through Doppler techniques. Space missions that will use these clocks for measuring the sun's gravity field distribution and for testing gravitation and relativity (a project that will include a search for pulsed low-frequency gravitational waves) are discussed. Estimates are made of system performance capability, and the accuracy capability of relativistic measurements is evaluated in terms of the results from the 1976 NASA/SAO spaceborne clock test of the Einstein Equivalence Principle.

Vessot, R. F. C.↗

NASA NTRS1983

Observations of unusual structures of high-latitude stratospheric electric fields

The observation, by means of balloon-borne sensors, of three cases of unusual stratospheric electric field structures at high latitudes is reported. In all three cases a region of downward directed electric field is flanked by regions with upward field. In two out of the three cases, the central downward field is much stronger than the average fair weather field. The vertical current densities involved are less than 5 x 10 to the -11th A/sq m. These field structures are observed only about 0.5 percent of the time.

Madsen, M. M.↗

NASA NTRS1982

Optimum shapes for lightweighted mirrors

Two types of monolithic lightweight mirrors with arched backs, the center-supported single arch and the ring-supported double arch, are discussed. It is shown that, assuming a maximum permissible rms tolerance of 6 x 10 to the -6th in, the single arch mirror weighs about 50 percent of an equivalent solid mirror up to a diameter of 24 in. The single arch is relatively simple to construct and uses a simple center support. Where a better figure is required, or for larger sizes, the double arch is superior in performance to the single arch. The weight of the double arch will vary from about 50 to under 40 percent of an equivalent conventional mirror as the diameter is increased from 20 to 144 in. Further weight reduction for the double arch is possible through the reduction of the size of the support.

Vukobratovich, D.↗