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At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Kinetics of the reactions of ClO with O and with NO

The rate constants k1, k2, and k3 for the reactions Cl + O3 yields ClO + O2 (1), ClO + O yields Cl + O2 (2), and ClO + NO yields Cl + NO2 (3), respectively, were measured by the discharge-flow technique, in which chlorine atoms are added to a flow of O3 and either O or NO in a helium carrier gas. The conditions of the experiment were such that the steady-state concentration ratios of Cl to ClO are simply interpretable in terms of the rate constant ratios k2/k3 or k3/k1. These rate constant ratios were measured over the range 220 to 298 K and combined with the directly determined k1 value to yield k2 and k3. The results are: k1 = 2.12 x 10 to the -11th exp(-157/T); k2 = 3.38 x 10 to -11th exp(75 plus or minus 40/T); and k3 = 1.13 x 10 to the -11th exp(200 plus or minus 30/T) cu cm/sec.

Zahniser, M. S.↗
NASA NTRS1977

Principles of equivalence, Eotvos experiments, and gravitational red-shift experiments - The free fall of electromagnetic systems to post-post-Coulombian order

Free fall in an external static gravitational field of a composite test body consisting of electromagnetically interacting charged particles is analyzed using the TH-epsilon-mu formalism developed by Lightman and Lee (1973). The Lightman and Lee calculation that was carried out to 'post-Coulombian' order is extended to 'post-post-Coulombian' order, and violations of the weak equivalence principle are found which result from the magnetostatic self-energy of the test body. The current generation of Eotvos experiments is shown to test the cited formalism at first order in the external gravitational potential to an accuracy of 4 by 10 to the -10th power for electrostatic energies and 6 by 10 to the -6th power for magnetostatic energies. It is concluded that although the formalism can be tested to an accuracy of 0.04 for electrostatic energies at second order in the gravitational potential, a significant second-order test for magnetostatic energies would require Eotvos experiments accurate to better than one part in 10 to the 15th power.

Haugan, M. P.↗
NASA NTRS1977

Differentiation of the matter of the moon

The following facts were uncovered in comparing the basaltic surface rocks of the moon with terrestrial tholeiitic basalts and ordinary chondrites: (1) there is an excess of the so-called refractory chemical elements, including the group of truly refractory elements, the rare earths, U, and Th, in comparison with their content in primitive terrestrial basalts and chondrites; (2) the so-called siderophilic elements have lower contents in the lunar surface rocks than in terrestrial rocks; (3) the low alkali content (Na, K, Rb) in lunar rocks is established; (4) there is a low content of H2O and the ordinary gases CO2, halides, etc.; (5) the low content of metals with high vapor pressure, (In, Tl, etc.) has been established. It is proposed that U and Th were carried from the internal areas to the peripheral rocks of the moon during magmatic activity, i.e., up to 3 billion years ago. This redistribution of U and Th lead to their concentration in surface layers of the moon, and the heat which they generated was lost into surrounding space. The conclusion is then reached that in order to understand processes on the moon, the chondritic model cannot be used.

Vinogradov, A. P.↗
NASA NTRS1977

Design and performance of an actively collimated phoswich system for X-ray astronomy

The design and performance of a phoswich type scintillation detector system having 34 sq cm effective collecting area and a sensitivity of 3 x 10 to the -5th power photons/sq cm/s/keV for balloon-borne cosmic X-ray source observations are discussed. The various shield anticoincidence systems are evaluated for effectiveness in reduction of the system background. The total background of nominally 4 x 10 to the -4th power counts/sq cm/s/keV is analyzed and found to consist of aperture flux, K-escape X-rays from the shielding, leakage, and degradation of gamma-rays through the shielding, and several particle induced effects. The background analysis suggests an ultimate practical upper limit of about 8 x 10 to the -5th power counts/sq cm/s/keV might be attainable beyond which further sensitivity improvements will require increased collecting area or a basically differing design approach.

Matteson, J. L.↗
NASA NTRS1978

Upper bound and probable value of the rate constant of the reaction OH + HO2 yields H2O + O2

Discharge-flow experiments at 295 K of the OH + HO2 reaction are described in which excess O3 is added to OH through a movable injector; OH concentration is measured downstream by resonance fluorescence with and without addition of excess NO just upstream of the detector so that both OH concentration and OH concentration + HO2 concentration are determined independently. The data are compared with a computer model involving 12 reaction steps. A simple sensitivity analysis is carried out to establish how errors in the other 'known' rate constants affect the data fit. Best agreement is obtained between computer calculations and experiments when k1 for the OH + HO2 reaction is in the range 2-3 x 10 to the -11th cu cm/s. Values above about 5 x 10 to the -11th are very unlikely whereas those below about 1 x 10 to the -11th are less strongly excluded.

Chang, J. S.↗
NASA NTRS1975

The fission track record of Apennine Front KREEP basalts

Whitlockite grains in two Apennine Front KREEP soil fragments contain extremely high densities of fission tracks. A new method is described in which particle tracks are examined in an actinide-poor phase bordering an actinide-rich whitlockite phase. This method clearly distinguishes the fission track contributions from other track sources; e.g., Fe-group cosmic rays, spallation recoils, and dislocations. Observed track excesses, when corrected for U- and Th-related fission sources, are 4-20 times greater than the contribution from spontaneous fission of U-238 (based on an age of 4 b.y.), and probably represent a large and variable contribution from the fission of Pu-244. These fragments may have pre-Imbrium ages, underscoring the importance of KREEP as a constituent of the pre-mare lunar crust. Track excesses are not correlated with the U or Th contents of the whitlockite grains. This behavior suggests that Pu fractionates differently from U and Th in lunar igneous KREEP.

Haines, E. L.↗
NASA NTRS1978

Rate constants for the deactivation of O/1D/ by Xe, Kr, and Ar over the range 110-330 K

The rate constants for the deactivation of O(1D) by Xe, Kr, and Ar were measured over the range 110-330 K. Only Xe had a significant temperature dependence. Its Arrhenius expression is (8.5 + or - 1.7) times 10 to the -11th power exp(-103 + or - 52)/RT cu cm/molecule-sec. The rate constants for Kr and Ar are (6.4 + or - 1.3) times 10 to the -12th power and (5.0 + or - 1.5) times 10 to the -13th power cu cm/molecule-sec, respectively. The observed trend in deactivation efficiency, Xe (greatest), Kr, Ar (least), and the observed temperature effects support the results and the spin-orbit interaction mechanism for deactivation given by Husain and co-workers.

Davidson, J. A.↗
NASA NTRS1979

Interplanetary phase scintillation and the search for very low frequency gravitational radiation

Observations of radio-wave phase scintillation are reported which used the Viking spacecraft having an earth-spacecraft link very similar to that which will be used in very low-frequency (VLF) gravitational-wave searches. The phase power-spectrum level varies by seven orders of magnitude as the sun-earth-spacecraft (elongation) angle changes from 1 to 175 deg. It is noteworthy that a broad minimum in the S-band (2.3 GHz) phase fluctuation occurs in the antisolar direction; the corresponding fractional frequency stability (square root Allan variance) is about 3 x 10 to the -14th for 1000-s integration times. A simultaneous two-frequency two-station observation indicates that the contribution to the phase fluctuation from the ionosphere is significant but dominated by the contribution from the interplanetary medium. Nondispersive tropospheric scintillation was not detected (upper limit to fractional frequency stability about 5 x 10 to the -14th). Evidently, even observations in the antisolar direction will require higher radio frequencies, phase scintillation calibration, and correlation techniques in the data processing, for detection of gravitational bursts at the anticipated strain amplitude levels of no more than 10 to the -15th.

Armstrong, J. W.↗
NASA NTRS1979

Absolute rate constants for the reaction of atomic hydrogen with ketene from 298 to 500 K

Rate constants for the reaction of atomic hydrogen with ketene have been measured at room temperature by two techniques, flash photolysis-resonance fluorescence and discharge flow-resonance fluorescence. The measured values are (6.19 + or - 1.68) x 10 to the -14th and (7.3 + or - 1.3) x 10 to the -14th cu cm/molecule/s, respectively. In addition, rate constants as a function of temperature have been measured over the range 298-500 K using the FP-RF technique. The results are best represented by the Arrhenius expression k = (1.88 + or - 1.12) x 10 to the -11th exp(-1725 + or - 190/T) cu cm/molecule/s, where the indicated errors are at the two standard deviation level.

Michael, J. V.↗
NASA NTRS1979

Rate constants for the reactions of OH with ClO, Cl2, and Cl2O at 298K

Recent concern about the depletion of stratospheric ozone by chlorine species from the decomposition of chlorofluoromethanes has emphasized the need for laboratory studies of the first reaction steps involved, especially those which control the concentration of the OH and ClO radicals in the stratosphere. Rate constants for the reactions of OH with ClO, Cl2, and Cl2O at 298 K have been determined in a discharge flow system using resonance fluoresence detection. The results are (9.1 + or - 1.3) x 10 to the -12th, (5.5 + or - 0.3) x 10 to the -14th, and (6.5 + or - 0.5) x 10 to the -12th (all in units of cu cm/sec), respectively.

Leu, M. T.↗
NASA NTRS1979

Asymptotic effective potentials for electron-hydrogen scattering

The asymptotic effective potential for electron- or positron-hydrogen elastic scattering is derived, correct to order x to the -7th, where x is the positron projectile coordinate, using the Feshbach optical potential as a starting point in the manner of Kleinman et al (1968). To order x to the -6th the potential agrees with the close-coupling results of Seaton and Steenman-Clark (1977) but not to order x to the -7th, where the present calculation gives the result + or - 213/2(x to the 7th) for electron and positron respectively. This coefficient differs considerably from the approximate value of Seaton and Steenman-Clark, and the discrepancy is traced to the omission of d states in their calculation.

Drachman, R. J.↗
NASA NTRS1979

Thorium concentrations in the lunar surface. III - Deconvolution of the Apenninus region

A technique of deconvoluting orbital-gamma ray data which improves spatial resolution and contrast has been applied to Th concentrations in the Apenninus region of the moon. The highest concentration seen from orbit has been found along the northern edge of the data track at Archimedes, requiring a component more highly fractionated in KREEP than the Apollo 15 medium-K Fra Mauro basalt. The results show generally diminishing Th levels extending outward from the Imbrium Basin, and impact penetration of basalt flows in Mare Imbrium to eject sub-mare Th-rich material. The results reinforce the hypothesis that the highlands which border and underlie the western maria contain a pre-mare layer of volcanically-derived KREEP material.

Metzger, A. E.↗
NASA NTRS1980

Field-aligned currents in the magnetospheric boundary layer

A self-consistent magnetopause-boundary layer model is constructed which contains two current layers, one for the magnetopause and one for the magnetosphere-boundary layer transition region. Field-aligned sheet currents in the boundary layer are generated by the plasma flow along the boundary layer. The magnitude of these boundary layer field-aligned currents is about 10 to the -8th A/sq m, which can be scaled along field lines to about 5 x 10 to the -6th A/sq m near the ionosphere and therefore can be identified as a possible source for the auroral sheet currents. The cross-field current density in the model is also about 10 to the -8th A/sq m, which is sufficient to excite the lower-hybrid-drift waves to produce the observed electromagnetic fluctuations in the magnetopause-boundary layer region.

Lee, L. C.↗
NASA NTRS1980

Determination of the thermal rate coefficient, products, and branching ratios for the reaction of O/+/ /D-2/ with N2

Atmosphere Explorer-C satellite measurements are used to determine rate coefficients (RCs) for the following reactions: O(+)(D-2) + N2 yields N2(+) + O (reaction 1), O(+)(D-2) + N2 yields O(+)(S-4) + N2 (reaction 2), and O(+)(D-2) + N2 yields NO(+) + N (reaction 3). Results show the RC for reaction 1 to be 1 (plus 1 or minus 0.5) x 10 to the -10th cu cm per sec, for reaction 2 to be 3 (plus 1 or minus 2) x 10 to the -11th cu cm per sec, and 3 to be less than 5.5 x 10 to the -11th cu cm per sec. It is also found that the reaction of O(+)(D-2) with N2 does not constitute a detectable source of NO(+) ions in the thermosphere.

Torr, D. G.↗
NASA NTRS1980

Helium runaways in white dwarfs

The long-term evolution of a carbon-accreting white dwarf (M = 0.5 solar mass) has been studied from the onset of accretion to the ignition of helium. The variations in the details of the helium-shell flash have been examined with respect to variations in mass accretion rate. For intermediate rates (10 to the -9th to 10 to the -8th solar mass/yr) the helium flash is potentially explosive, whereas for high rates (5 x 10 to the -8th solar mass/yr) the shell flash is relatively weak. The results are discussed in the context of the long-term evolution of novae.

Taam, R. E.↗
NASA NTRS1980

Search for far-infrared emission from young supernova remnants

A search has been conducted for 80-350 micron emission from the Tycho, Kepler, and Cas A supernova remnants. The bolometric fluxes are less than 5 x 10 to the -11th, 4 x 10 to the -12th, and 9 x 10 to the -12th W/sq m, respectively, for the entire radio shell, corresponding to luminosities less than 25,000, 1100, and 1500 solar luminosities (within 2 standard deviations). The ratio of dust to gas in Cas A is at least 10 times less than the 'normal' ratio.

Wright, E. L.↗
NASA NTRS1981

Field-aligned currents in the earth's magnetotail

Direct measurements of the plasma velocity distributions and simultaneous observations of magnetic fields are used to examine the character of field-aligned currents in the earth's magnetotail during the recovery phase of a magnetic substorm. Three contiguous field-aligned current sheets are identified at the interface between the magnetotail lobe and plasma sheet. Average current densities within these three current sheets are, in order of decreasing distance to the plasma sheet, +3.3 x 10 to the -9th, -1.3 x 10 to the -8th, and +1.1 x 10 to the -8th A/sq m, respectively.

Frank, L. A.↗
NASA NTRS1981

Far-infrared emission line and continuum observations of NGC 7027

The first observation of a fine-structure transition in NGC 7027 at wavelengths greater than 30 microns is reported. The flux in the 63.2-micron line is found to be approximately 10 to the -16th W/sq cm. It is noted that if NGC 7027 lies at 1 kpc, this corresponds to a luminosity, in the line, approximately 30 times greater than the solar luminosity. The flux of the 88.35-micron line is less than 10 to the -17th W/sq cm, and the upper limit to the line flux at 51.8 microns is found to be 10 to the -16th W/sq cm. These upper limits imply an electron density that is less than 1.6 x 10 to the 5th/cu cm. It is noted that the continuum measurements obtained support a dust temperature of 90 K with an emissivity approximately equal to the reciprocal of the square of the wavelength. The data exclude grain materials whose wavelength-dependent emissivity (the reciprocal of the wavelength raised to nth power) requires n to be outside the range between 1.6 and 2, unless the temperature varies drastically across the dust cloud

Melnick, G.↗