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At least 991 records · Page 55

Custom surface reflectance, shade mask, and equivalent water thickness maps for the Colorado Headwaters Ecological Spectroscopy Study (2025)

This dataset contains land surface reflectance estimates and additional derived products generated from NEON Imaging Spectrometer (NIS) data collected in the Upper Gunnison river basin during June and July of 2025. Data was collected over three domains: the Upper East River (CRBU), Almont Triangle (ALMO), and the Upper Taylor Basin (UPTA). These products were derived from radiance and LiDAR data collected by the NEON Airborne Observation Platform (AOP) campaign funded by the Colorado Headwaters Ecological Spectroscopy Study (CHESS) (doi:10.15485/3017965). Products include per-pixel surface reflectance (rfl) and reflectance uncertainty (rfl_unc), observational data (obs), canopy equivalent water thickness (ewt), and shade masks. Atmospheric correction was performed per flightline using the ISOFIT (Imaging Spectrometer Optimal FITting) optimal estimation framework to estimate surface reflectance and the associated per-band reflectance uncertainty. Reflectance retrievals achieved a mean absolute error of 1.5% across diverse validation surfaces (see validation report.pdf). Equivalent water thickness was calculated from surface reflectance using the Beer–Lambert absorption of liquid water. Shade masks were generated based on the geometry between the sun angle, ground surface, and sensor at the time of flight. Data products are provided per-flightline and as mosaics for each domain. Flightline data products are provided as ENVI-formatted binary files (rfl, rfl_unc, ewt) and GeoTIFFs (shade). Reflectance and uncertainty mosaics are provided as tiled NetCDFs, while all other mosaicked products are provided as cloud-optimized GeoTIFFs. These formats are supported by common geospatial software (e.g., QGIS, ArcGIS, ENVI) and programmatic libraries in Python (e.g., rasterio, xarray, spectral, netCDF4) and R (e.g., terra, ncdf4). Processing workflows were designed to be equivalent to those used to generate the 2018 CHESS campaign airborne imaging spectroscopy data products (doi:10.15485/3013527). All outputs were co-registered to a common spatial grid to support time series analyses. CHESS Project Description: The Colorado Headwaters Ecological Spectroscopy Study (CHESS) comprised a multi-week airborne remote sensing and field observation campaign in the Upper Gunnison Basin, Colorado, conducted in June and July of 2025. Airborne remote sensing was conducted by the National Ecological Observatory Network Airborne Observation Platform (NEON AOP), concurrent with a field campaign run by the Rocky Mountain Biological Laboratory (RMBL), the Lawrence Berkeley National Laboratory (LBNL) and SLAC National Accelerator Laboratory Watershed Function Science Focus Area (SFA), and NASA-JPL (Jet Propulsion Laboratory) Earth Surface Mineral Dust Source Investigation (EMIT) program. Between June 10 and July 18, 2025, the NEON AOP flight team collected high-resolution aerial imaging spectroscopy and Light Detection and Ranging (LiDAR) data over three domains: the Upper East River (CRBU), Almont Triangle (ALMO), and the Upper Taylor Basin (UPTA). In coordination with the flights, a field campaign acquired ground-truth observations, including observations of vegetation composition, foliar traits, forest demography, and subsurface properties in 18 core sampling areas within the domains. Additional surface water observations were taken at over 380 point locations. All CHESS campaign datasets can be found within the CHESS ESS-DIVE data portal: https://data.ess-dive.lbl.gov/portals/chess. Funding Acknowledgment: Data acquisition was performed under a grant from the National Aeronautics and Space Administration (80NSSC24K1005). Computational research was carried out at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (80NM0018D0004) and was funded by EMIT Extended Mission Phase E Science.

2018 NEON and 2025 CHESS Campaigns↗

Thick Concrete Specimen Construction, Testing, and Preliminary Analysis

The purpose of the U.S. Department of Energy Office of Nuclear Energy’s Light Water Reactor Sustainability (LWRS) Program is to develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the operating lifetimes of nuclear power plants (NPPs) beyond 60 years. Since many important safety structures in an NPP are constructed of concrete, inspection techniques must be developed and tested to evaluate the internal condition. In-service containment structures generally do not allow for the destructive measures necessary to validate the accuracy of these inspection techniques. This creates a need for comparative testing of the various nondestructive evaluation (NDE) measurement techniques on concrete specimens with known material properties, voids, internal microstructure flaws, and reinforcement locations. A preliminary report detailed some of the challenges associated with thick reinforced concrete sections and prioritized conceptual designs of specimens that could be fabricated to represent NPP concrete structures for using in NDE evaluation comparisons. This led to the construction of the concrete specimen presented in this report, which has sufficient reinforcement density and cross-sectional size to represent an NPP containment wall. Details on how a suitably thick concrete specimen was constructed are presented, including the construction materials, final nominal design schematic, as well as formwork and rigging required to safely meet the desired dimensions of the concrete structure. The report also details the type and methods of forming the concrete specimen as well as information on how the rebar and simulated defects were embedded. Details on how the resulting specimen was transported, safely anchored, and marked to allow access for systematic comparative NDE testing of defects in a representative NPP containment wall concrete specimen are also given. Data collection using the MIRA Ultrasonic NDE equipment and initial results are also presented along with a discussion of the preliminary findings. Comparative NDE of various defects in reinforced concrete specimens is a key component in identifying the most promising techniques and directing the research and development efforts needed to characterize concrete degradation in commercial NPPs. This requires access to the specimens for data collection using state-of-the-art technology. The construction of the specimen detailed in this report allows for an evaluation of how different NDE techniques may interact with the size and complexities of NPP concrete structures. These factors were taken into account when determining specimen size and features to ensure a realistic design. The lateral dimensions of the specimen were also chosen to mitigate unrealistic boundary effects that would not affect the results of field NPP concrete testing. Preliminary results show that, while the current methods are able to identify some of the deeper defects, improvements in data processing or hardware are necessary to be able to achieve the precision and reliability achieved in evaluating thinner and less heavily reinforced concrete structures.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A Prototype Thick-Target Bremsstrahlung Model with Angularly-Dependent Emission in the MCNP6 ® Code

This document summarizes the current thick-target bremsstrahlung (TTB) model in MCNP and provides test results for an alternative implementation to improve the accuracy with reduced cost compared to full electron transport. It has been observed that the current TTB model produces inaccurate results in problems where the medium is thick with respect to electrons, but the photon distribution in the problem has a strong directionality. An example of such a simulation is detectors surrounding a metal target irradiated with a radiographic beam of high energy photons. The primary cause of this discrepancy is the current TTB method emits all bremsstrahlung photons in the same direction as the primary electron produced from each (γ, e ± ) interaction, leading to artificially forward peaked photon distributions for intermediate to high-energy incident photons. To improve the TTB model, we have implemented an angularly-dependent TTB model in a developer version of the MCNP6 ® code; for developers, this was done on the branch prototype/angular_ttb in the mcnp6 repo on bitbucket. The angularly-dependent TTB model accounts for the energy and scattering of electrons as they slow down in the current material, but does not sample the computationally expensive energy straggling, secondary electron events, and tracking electrons; this approach is significantly less computationally expensive than full electron transport and can be comparable to the original TTB method for problems with sufficiently complex materials and geometry. To evaluate the method, we have modeled a simple problem of a beam of 5 MeV photons incident on a sphere of plutonium surrounded by detectors at different deflection angles. For this problem, the angularly-dependent TTB produces a photon flux within 8.0% for a 90 degree deflection angle and 0.8% along the beam axis, as compared to the electron transport solution. This is an improvement compared to a 43% and 81% discrepancy with the original TTB method, respectively. The rest of this work includes the following: the first section details the current TTB treatment in MCNP, which has not been well documented elsewhere. Then, the modified TTB algorithm is detailed and the approximations compared to the condensed history algorithm are compared. Results are given comparing the two TTB methods to the condensed history transport algorithm. The appendix includes details for code developers on relevant electron transport implementation details and potential code improvements for future work.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Influence of Diffusional Surface Alloying on the Hardened-Layer Thickness for Gray-Iron Machine Parts

In diffusional surface alloying, gray-iron components of vehicles and machines are heated in contact with oxides of the alloying elements (chromium, titanium, vanadium, and molybdenum). The influence of the sample temperature and holding time in diffusional surface alloying on the thickness of the hardened layer is investigated, on the basis of experiment planning. The models obtained may be used to ensure specified thickness of the hardened layer in diffusional surface alloying, with maximum productivity in both production and repair processes.

36 MATERIALS SCIENCE↗

Influences and Interactions of Inundation, Peat, and Snow on Active Layer Thickness: Modeling Archive

The Advanced Terrestrial Simulator was used to simulate thermal hydrological conditions across varied environmental conditions for an ensemble of 1D models of Arctic permafrost. The thickness of organic soil is varied from 2 to 40cm, snow depth is varied from approximately 0 to 1.2 meters, water table depth was varied from -51cm below the soil surface to 31 cm above the soil surface. A total of 15,960 ensemble members are included. Data produced includes the third and fourth simulation year: active layer thickness, time of deepest thaw depth, temperature of the unfrozen soil, and unfrozen liquid saturation, for each ensemble member. Input files used to run the ensemble are also included. File formats in the data package: .py, .h5, .xml, .exo, .txt, and .pdf.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Improvements in the estimates of ice thickness and production in the Chukchi Sea polynyas derived from AMSR-E

For January-March 2003, we use 12.5-km resolution Advanced Microwave Scanning Radiometer (AMSR) data for the first time in a comparison with Synthetic Aperture Radar (SAR) and Special Sensor Microwave/Imager (SSM/I) data to study two Chukchi coast polynyas, one consisting of many, the other of only a few 25-km SSM/I pixels. Within these polynyas, the ice thicknesses are derived separately from the SMM/I 37-GHz and AMSR 36-GHz channels; the heat fluxes are derived by combining thicknesses with meteorological data. Comparison with ScanSAR data shows that for the large polynya, because AMSR provides better resolution of the surrounding coastline and first-year ice, the AMSR heat losses are greater than the SSM/I; for the small polynya, AMSR measures its variability even when its area is order of a single SSM/I pixel. This means that AMSR permits more accurate calculation of polynya heat losses, yielding the potential of improved estimates of Arctic polynya productivity.

ice thicknesses↗

Improvements in the estimates of ice thickness and production in the Chukchi Sea polynyas derived from AMSR-E

For January-March 2003, we use 12.5-km resolution Advanced Microwave Scanning Radiometer (AMSR) data for the first time in a comparison with Synthetic Aperture Radar (SAR) and Special Sensor Microwave/Imager (SSM/I) data to study two Chukchi coast polynyas, one consisting of many, the other of only a few 25-km SSM/I pixels. Within these polynyas, the ice thicknesses are derived separately from the SMM/I 37-GHz and AMSR 36-GHz channels; the heat fluxes are derived by combining thicknesses with meteorological data. Comparison with ScanSAR data shows that for the large polynya, because AMSR provides better resolution of the surrounding coastline and first-year ice, the AMSR heat losses are greater than the SSM/I; for the small polynya, AMSR measures its variability even when its area is order of a single SSM/I pixel. This means that AMSR permits more accurate calculation of polynya heat losses, yielding the potential of improved estimates of Arctic polynya productivity.

Chukchi coast polynyas↗

Improvements in the estimates of ice thickness and production in the Chukchi Sea polynyas derived from AMSR-E

For January-March 2003, we use 12.5-km resolution Advanced Microwave Scanning Radiometer (AMSR) data for the first time in a comparison with Synthetic Aperture Radar (SAR) and Special Sensor Microwave/Imager (SSM/I) data to study two Chukchi coast polynyas, one consisting of many, the other of only a few 25-km SSM/I pixels. Within these polynyas, the ice thicknesses are derived separately from the SMM/I 37-GHz and AMSR 36-GHz channels; the heat fluxes are derived by combining thicknesses with meteorological data. Comparison with ScanSAR data shows that for the large polynya, because AMSR provides better resolution of the surrounding coastline and first-year ice, the AMSR heat losses are greater than the SSM/I; for the small polynya, AMSR measures its variability even when its area is order of a single SSM/I pixel. This means that AMSR permits more accurate calculation of polynya heat losses, yielding the potential of improved estimates of Arctic polynya productivity.

Advanced Microwave Scanning Radiometer (AMSR)↗

Arctic Snow Depth and Sea Ice Thickness From ICESat‐2 and CryoSat‐2 Freeboards: A First Examination

We present a first examination of Arctic sea ice snow depth estimates from differencing satellite lidar (ICESat‐2) and radar (CryoSat‐2) freeboards. These estimates cover the period between 14 October 2018 and the end of April 2019. Snow depth is related to freeboard differences by the refractive index/bulk density of the snow layer—the only free parameter in the approach. Area‐averaged snow depth ranges from 9 cm (on first‐year ice: 5 cm, multiyear ice: 14 cm) in late October to 19 cm (first‐year ice: 17 cm, multiyear ice: 27 cm) in April; on average, this snow is thinner over FYI. Spatial patterns and gradients of snow depth estimates compare well with reconstructions using snowfall from ERA‐Interim and ERA5, although snowfall from ERA5 is systematically higher. For all months, the results suggest that ~50% of the total freeboard is comprised of snow. Retrievals are within a few centimeters of snow depth data acquired by Operation IceBridge in April 2019. Sources of uncertainties associated with this freeboard‐differencing approach are discussed. Further, sea ice thicknesses calculated using the retrieved snow depth and a modified climatology are contrasted. Comparatively, the snow depth and calculated ice thickness using a modified climatology are higher by ~5 cm and 0.33 m, although these differences are not uniform throughout the season. Snow accumulation was slower between October and December but increased between December and January, unlike the modified climatology, which exhibited a monotonic accumulation for all months. Future opportunities for assessment and improvement of these estimates are discussed.

Arctic Ocean↗

On the Representation of Through-The-Thickness Reinforcements in Finite Element Analysis of Stitched, Blade Stiffened Panels

Modern aircraft employ laminated composites for their tailorable in-plane properties, high specific strengths, and high specific stiffnesses. However, laminated composites exhibit relatively poor interlaminar properties without through-the-thickness reinforcements. Quantifying the necessary amount of through-the-thickness reinforcements is necessary to reduce cost and meet damage tolerance certification requirements. In this study, a discrete superposed cohesive element (DSCE) approach is applied to represent the mixed-mode delamination behavior of stitched stiffened panels subjected to seven-point bending. This approach is compared to a one-dimensional embedded spring element (ESE) method. The DSCE approach uses two superposed bilinear traction-separation laws to obtain a representative load-displacement response determined from interlaminar tensile and shear tests. Additionally, several stitch configurations (unstitched, stitched, and overstitched) are evaluated in terms of their load-displacement response and crack-arrestment capability. Results indicate that the DSCE and ESE approaches show good agreement with respect to the predicted load-displacement response, but the ESE method tends to overpredict the crack growth behavior by approximately 13%. Stitches were not observed to fail during skin-stringer separation. Using an overstitched laminate with stitches near the flange edge provides the greatest crack-arrestment capability. Furthermore, the skin retains 92% of its stiffness after skin-stringer separation occurs.

composites↗

On the Representation of Through-The-Thickness Reinforcements in Finite Element Analysis of Stitched, Blade Stiffened Panels

Modern aircraft employ laminated composites for their tailorable in-plane properties, high specific strengths, and high specific stiffnesses. However, laminated composites exhibit relatively poor interlaminar properties without through-the-thickness reinforcements. Quantifying the necessary amount of through-the-thickness reinforcements is necessary to reduce cost and meet damage tolerance certification requirements. In this study, a discrete superposed cohesive element (DSCE) approach is applied to represent the mixed-mode delamination behavior of stitched stiffened panels subjected to seven-point bending. This approach is compared to a one-dimensional embedded spring element (ESE) method. The DSCE approach uses two superposed bilinear traction-separation laws to obtain a representative load-displacement response determined from interlaminar tensile and shear tests. Additionally, several stitch configurations (unstitched, stitched, and overstitched) are evaluated in terms of their load-displacement response and crack-arrestment capability. Results indicate that the DSCE and ESE approaches show good agreement with respect to the predicted load-displacement response, but the ESE method tends to overpredict the crack growth behavior by approximately 13%. Stitches were not observed to fail during skin-stringer separation. Using an overstitched laminate with stitches near the flange edge provides the greatest crack-arrestment capability. Furthermore, the skin retains 92% of its stiffness after skin-stringer separation occurs.

composites↗

Metallurgical Factors that Govern ST Properties in Commercial 2219-T87 Thick Plate

This report is contained within a NASA Engineering & Safety Center (NESC) assessment of the variability in short-transverse (ST) mechanical properties of commercial lots of 12.7-cm-thick 2219-T87 plate. The document comprises a review of the potential metallurgical reasons for the variations in ST tensile ductility and fracture behavior observed. Preliminary data from through-thickness mechanical testing and microstructural analyses conducted early in the investigation are referenced. The report concludes with a summary of considerations for the NESC based on the key results of this literature survey.

Aluminum alloy↗

The dependence of the strength and thickness of field‐aligned currents on solar wind and ionospheric parameters

Abstract Sheared plasma flows at the low‐latitude boundary layer (LLBL) correlate well with early afternoon auroral arcs and upward field‐aligned currents. We present a simple analytic model that relates solar wind and ionospheric parameters to the strength and thickness of field‐aligned currents (Λ) in a region of sheared velocity, such as the LLBL. We compare the predictions of the model with DMSP observations and find remarkably good scaling of the upward region 1 currents with solar wind and ionospheric parameters in region located at the boundary layer or open field lines at 1100–1700 magnetic local time. We demonstrate that and Λ ∼ L when Λ/ L < 5 where L is the auroral electrostatic scale length. The sheared boundary layer thickness (Δ m ) is inferred to be around 3000 km, which appears to have weak dependence on V sw . J ∥ has dependencies on Δ m , Σ p , n sw , and V sw . The analytic model provides a simple way to organize data and to infer boundary layer structures from ionospheric data.

Johnson, Jay R.↗

Spray Pyrolysis-Aerosol Deposition for the Production of Thick Yttria-Stabilized Zirconia Coatings

Aerosol deposition (AD) is a coating technique wherein particles are impacted onto a target substrate at reduced pressures, and supersonic particle impact velocities lead to coating consolidation. The limiting step in AD application is often not supersonic deposition operation, but aerosolization of powder particles with the proper size distribution; the translational impact velocity is strongly size-dependent. It is demonstrated that by directly synthesizing particles in the gas phase, size-controlled ceramic particles can be injected into AD systems. This in situ formation step obviates the need for particle aerosolization. Ultrasonic spray pyrolysis (USP) is applied to produce yttria-stabilized zirconia (YSZ), and USP is directly coupled with AD to produce consolidated, thick, YSZ coatings on metal substrates. USP-AD yields YSZ coatings on stainless steel and aluminum substrates with porosities <0.20, which grow to thicknesses beyond 100 μm. Aerodynamic particle spectrometry and electron microscopy reveal that the depositing particles are 200 nm–1.2 μm in diameter, though each particle is composed of nanocrystalline YSZ. Supporting computational fluid dynamics calculations demonstrate that the YSZ particle impact speeds are above 300 m s -1 . Thermal conductivity measurements demonstrate that USP-AD coatings have conductivities consistent with those produced from high-temperature processes.

36 MATERIALS SCIENCE↗

Layer-by-Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium-Ion Battery Negative Electrodes

TiO 2 films of varying thicknesses (up to ≈1.0 µm) with vertically oriented, accessible 7–9 nm nanopores are synthesized using an evaporation-induced self-assembly layer-by-layer technique. The hypothesis behind the approach is that epitaxial alignment of hydrophobic blocks of surfactant templates induces a consistent, accessible mesophase orientation across a multilayer film, ultimately leading to continuous, vertically aligned pore channels. Characterization using grazing incidence X-ray scattering, scanning electron microscopy, and impedance spectroscopy indicates that the pores are oriented vertically even in relatively thick films (up to 1 µm). These films contain a combination of amorphous and nanocrystalline anatase titania of value for electrochemical energy storage. When applied as negative electrodes in lithium-ion batteries, a capacity of 254 mAh g -1 is obtained after 200 cycles for a single-layer TiO 2 film prepared on modified substrate, higher than on unmodified substrate or nonporous TiO 2 film, due to the high accessibility of the vertically oriented channels in the films. Thicker films on modified substrate have increased absolute capacity because of higher mass loading but a reduced specific capacity because of transport limitations. These results suggest that the multilayer epitaxial approach is a viable way to prepare high capacity TiO 2 films with vertically oriented continuous nanopores.

25 ENERGY STORAGE↗

Si Complies with GaN to Overcome Thermal Mismatches for the Heteroepitaxy of Thick GaN on Si

Heteroepitaxial growth of lattice mismatched materials has advanced through the epitaxy of thin coherently strained layers, the strain sharing in virtual and nanoscale substrates, and the growth of thick films with intermediate strain‐relaxed buffer layers. However, the thermal mismatch is not completely resolved in highly mismatched systems such as in GaN‐on‐Si. Here, geometrical effects and surface faceting to dilate thermal stresses at the surface of selectively grown epitaxial GaN layers on Si are exploited. The growth of thick (19 µm), crack‐free, and pure GaN layers on Si with the lowest threading dislocation density of 1.1 × 10 7 cm −2 achieved to date in GaN‐on‐Si is demonstrated. With these advances, the first vertical GaN metal–insulator–semiconductor field‐effect transistors on Si substrates with low leakage currents and high on/off ratios paving the way for a cost‐effective high power device paradigm on an Si CMOS platform are demonstrated

Tanaka, Atsunori↗

Tailoring the Thickness‐Dependent Optical Properties of Conducting Nitrides and Oxides for Epsilon‐Near‐Zero‐Enhanced Photonic Applications

Abstract The unique properties of the emerging photonic materials, conducting nitrides and oxides, especially their tailorability, large damage thresholds, and, importantly, the so‐called epsilon‐near‐zero (ENZ) behavior, have enabled novel photonic phenomena spanning optical circuitry, tunable metasurfaces, and nonlinear optical devices. This work explores direct control of the optical properties of polycrystalline titanium nitride (TiN) and aluminum‐doped zinc oxide (AZO) by tailoring the film thickness, and their potential for ENZ‐enhanced photonic applications. This study demonstrates that TiN–AZO bilayers support Ferrell–Berreman modes using the thickness‐dependent ENZ resonances in the AZO films operating in the telecom wavelengths spanning from 1470 to 1750 nm. The bilayer stacks also act as strong light absorbers in the ultraviolet regime using the radiative ENZ modes and the Fabry–Perot modes in the constituent TiN films. The studied Berreman resonators exhibit optically induced reflectance modulation of 15% with picosecond response time. Together with the optical response tailorability of conducting oxides and nitrides, using the field enhancement near the tunable ENZ regime can enable a wide range of nonlinear optical phenomena, including all‐optical switching, time refraction, and high‐harmonic generation.

Saha, Soham↗

Scalable Synthesis of 2D Mo 2 C and Thickness‐Dependent Hydrogen Evolution on Its Basal Plane and Edges

Abstract 2D transition metal carbides (2D TMCs and MXenes) are promising candidates for applications of energy storage and catalysis. However, producing high‐quality, large 2D flakes of Mo2C MXene has been challenging. Here, a new salt‐assisted templating approach is reported that enables the direct synthesis of 2D Mo 2 C with low defect concentrations. KCl acts as a template to form an intermediate 2D product, facilitating Mo 2 C formation without coarsening upon melting. The thickness of the flakes produced can range from monolayer (0.36 nm) to 10 layers (4.55 nm), and the electrocatalytical hydrogen evolution reaction (HER) activity of 2D Mo 2 C is inversely proportional to its thickness. The monolayer Mo 2 C shows remarkable HER performance with a current density of ≈6800 mA cm − 2 at 470 mV versus reversible hydrogen electrode and an ultrahigh turnover frequency of ≈17 500 s − 1 . This salt‐assisted synthesis approach can also produce WC and V 8 C 7 nanosheets, expanding the family of 2D carbides. The new pathway eliminates the need for layered ceramic precursors, making it a versatile approach to direct synthesis of MXene‐like 2D carbides.

Chemistry↗