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NASA NTRS2012

The Multiple Altimeter Beam Experimental Lidar (MABEL), an Airborne Simulator for the ICESat-2 Mission

The Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) mission is currently under development by NASA. The primary mission of ICESat-2 will be to measure elevation changes of the Greenland and Antarctic ice sheets, document changes in sea ice thickness distribution, and derive important information about the current state of the global ice coverage. To make this important measurement, NASA is implementing a new type of satellite-based surface altimetry based on sensing of laser pulses transmitted to, and reflected from, the surface. Because the ICESat-2 measurement approach is different from that used for previous altimeter missions, a high-fidelity aircraft instrument, the Multiple Altimeter Beam Experimental Lidar (MABEL), was developed to demonstrate the measurement concept and provide verification of the ICESat-2 methodology. The MABEL instrument will serve as a prototype for the ICESat-2 mission and also provides a science tool for studies of land surface topography. This paper outlines the science objectives for the ICESat-2 mission, the current measurement concept for ICESat-2, and the instrument concept and preliminary data from MABEL.

McGill, Matthew↗

NASA NTRS2012

First Assessments of Predicted ICESat-2 Performance Using Aircraft Data

The Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) is a next-generation laser altimeter designed to continue key observations of ice sheet elevation change, sea ice freeboard, vegetation canopy height, earth surface elevation, and sea surface height. Scheduled for launch in mid-2016, ICESat-2 will use a high repetition rate (10 kHz), small footprint (10 m nominal ground diameter) laser, and a single-photon-sensitive detection strategy (photon counting) to measure precise range to the earth's surface. Using green light (532 nm), the six beams of ICESat-2 will provide improved spatial coverage compared with the single beam of ICESat, while the differences in transmit energy among the beams provide a large dynamic range. The six beams are arranged into three pairs of beams which allow slopes to measured on an orbit-by-orbit basis. In order to evaluate models of predicted ICESat-2 performance and provide ICESat-2-like data for algorithm development, an airborne ICESat-2 simulator was developed and first flown in 2010. This simulator, the Multiple Altimeter Beam Experimental Lidar (MABEL) was most recently deployed to Iceland in April 2012 and collected approx 85 hours of science data over land ice, sea ice, and calibration targets. MABEL uses a similar photon-counting measurement strategy to what will be used on ICESat-2. MABEL collects data in 16 green channels and an additional 8 channels in the infrared aligned across the direction of flight. By using NASA's ER-2 aircraft flying at 20km altitude, MABEL flies as close to space as is practical, and collects data through approx 95% of the atmosphere. We present background on the MABEL instrument, and data from the April 2012 deployment to Iceland. Among the 13 MABEL flights, we collected data over the Greenland ice sheet interior and outlet glaciers in the southwest and western Greenland, sea ice data over the Nares Strait and Greenland Sea, and a number of small glaciers and ice caps in Iceland and Svalbard. Several of the flights were coincident in time and space with NASA's Operation IceBridge, which provides an independent data set for validation. MABEL also collected data along CryoSat track 10482 in north central Greenland approximately one month after CryoSat passed overhead.

Neumann, Thomas↗

NASA NTRS2015

Development of Double and Triple-Pulsed 2-micron IPDA Lidars for Column CO2 Measurements

Carbon dioxide (CO2) is an important greenhouse gas that significantly contributes to the carbon cycle and globalradiation budget on Earth. CO2 role on Earth’s climate is complicated due to different interactions with various climatecomponents that include the atmosphere, the biosphere and the hydrosphere. Although extensive worldwide efforts formonitoring atmospheric CO2 through various techniques, including in-situ and passive sensors, are taking place highuncertainties exist in quantifying CO2 sources and sinks. These uncertainties are mainly due to insufficient spatial andtemporal mapping of the gas. Therefore it is required to have more rapid and accurate CO2 monitoring with higheruniform coverage and higher resolution. CO2 DIAL operating in the 2-μm band offer better near-surface CO2measurement sensitivity due to the intrinsically stronger absorption lines. For more than 15 years, NASA LangleyResearch Center (LaRC) contributed in developing several 2-m CO2 DIAL systems and technologies. This paperfocuses on the current development of the airborne double-pulsed and triple-pulsed 2-m CO2 integrated pathdifferential absorption (IPDA) lidar system at NASA LaRC. This includes the IPDA system development andintegration. Results from ground and airborne CO2 IPDA testing will be presented. The potential of scaling suchtechnology to a space mission will be addressed.

Singh, Upendra N.↗

DOE OSTI2025

Ir(hkl) Surface Electrochemistry in a Nonadsorbing Acidic Medium

The fundamental properties of electrochemical materials depend on the multiple and often complex interactions between electrode surface sites and electrolyte species at the electrochemical interface. Despite Iridium use in electrolyzer systems, much of its surface electrochemistry remains underexplored. This study investigates the surface electrochemistry of Ir(111), Ir(100), and Ir(110) surfaces in acidic media. Using cyclic voltammetry and CO charge displacement experiments, we establish the charge states and adsorbate coverages as a function of the electrode potential, revealing the presence of hydrogen and hydroxyl co-adsorption at low potentials on (111), and almost no coverage of H ad on (110) facet. In situ Shell Isolated Nanoparticle Enhanced Raman Spectroscopy experiments provide direct evidence of the formation of key adsorbate species, such as hydrogen, hydroxyl, and oxygen, but most importantly, their interactions with interfacial water, confirmed by Density Functional Theory calculations. Our findings highlight the role of co-adsorption and interspecies interactions, with microkinetic adsorption voltammetry simulations corroborating the influence of lateral interactions on adsorption dynamics, particularly for Ir(100) where the OHad formation occurs as a sharp adsorption/desorption current. Our results underscores the importance of interfacial water and hydrogen bonding networks in shaping the electrochemical behavior on Ir surfaces, refining our baseline understanding of the Ir surface electrochemistry necessary for the development of advanced Ir-based electrochemical materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Influence of near-surface oxide layers on TiFe hydrogenation: mechanistic insights and implications for hydrogen storage applications

The inevitable formation of passivating oxide films on the surface of the TiFe intermetallic compound limits its performance as a stationary hydrogen storage material. Extensive experimental efforts have been dedicated to the activation of TiFe, i.e. oxide layer removal prior to utilization for hydrogen storage. However, development of an efficient activation protocol necessitates a fundamental understanding of the composition and structure of the air-exposed surface and its interaction with hydrogen, which is currently absent. Therefore, in this study we explored the growth and nature of oxide films on the most exposed TiFe surface (110) in depth using static and dynamic first-principles methods. We identified the lowest energy structures for six oxygen coverages up to approximately 1.12 nm of thickness with a global optimization method and studied the temperature effects and structural evolution of the oxide phases in detail via ab initio molecular dynamics (AIMD). Based on structural similarity and coordination analysis, motifs for TiO 2 and TiFeO 3 as well as Ti(FeO 2 ) x (x = 2, 3 or 5) phases were identified. On evaluating the interaction of the oxidized surface with hydrogen, a minimal energy barrier of 0.172 eV was predicted for H 2 dissociation while H migration from the top of the oxidized surface to the bulk TiFe was limited by several high-lying energy barriers above 1.4 eV. Our mechanistic insights will prove themselves valuable for informed designs towards new activation methods of TiFe and related systems as hydrogen storage materials.

08 HYDROGEN↗

DOE OSTI2023

Elucidating the Influence of Metal Surface Composition on Organic Adsorbate Binding Using Active Particle Dynamics

The adsorption strengths of organic compounds on metal surfaces are sensitive to the metal composition, and they play a central role in many catalytic reactions, helping to control the coverage of the reactant and altering the overall reaction rate. While adsorption energies are straightforward to measure and calculate in vacuum and gas-phase environments, adsorption energetics can be dramatically altered by the presence of solvent in liquid-phase reactions. However, the effects of metal composition on binding strengths in a liquid environment are less well understood, primarily due to the difficulty of accurate in situ measurements of organic binding on metal surfaces in the liquid phase. Here, we utilize the motion of active particles in water to probe the adsorption energies of an organic adsorbate (furfural) on a range of metal surfaces (pure Pd, pure Pt, and four PdAu alloy compositions) to elucidate the effect of metal composition. Janus particles with catalytic caps of particular metal compositions all exhibited active motion resulting from consumption of H 2 O 2 ; adsorbate binding was inferred through the decrease in the velocity of active motion and was modeled by a Langmuir adsorption isotherm. The measured adsorption affinities were used to extract the adsorption enthalpy of furfural on the different metals. The Pd surface was found to bind furfural more strongly than the Pt surface by some 10 kJ/mol. Furthermore, the adsorption of furfural on the alloys was found to increase monotonically in magnitude with Pd content. As a result, the data reported herein aid the development of accurate understanding of organic adsorption in the presence of solvent and the role of the metal surface in tuning adsorption strengths to optimize catalytic processes in the liquid phase.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Ab Initio Molecular Dynamics Study of Pd Nucleation on a γ-Al 2 O 3 Surface

We perform ab initio molecular dynamics (AIMD) free energy simulations to investigate the stability and dynamics of dispersed Pd atoms and subnanometer clusters on γ-Al 2 O 3 . We consider nucleation for varying Pd loadings on dry γ-Al 2 O 3 (100), dry γ-Al 2 O 3 (110) and wet γ-Al 2 O 3 (110) and examine temperature, entropy and water coverage effects on the stability and dynamics of Pd clusters. At low Pd loading (1.07 Pd atoms/nm 2 on the (100) and 0.75 Pd/nm 2 on the (110)), association of the Pd atoms is thermodynamically unfavorable on the dry surfaces and almost thermoneutral on the wet (110) owing to water blocking of the AlIII defect sites. In agreement with past studies, the Pd atoms are quite mobile but the diffusion free energy barriers do not increase with the water coverage, as previously suggested, but rather remain similar in magnitude owing to translational entropy at finite temperatures. At these Pd loadings, oxidized Pd(II) atoms on the wet (110) surface are dispersed and immobile. At higher Pd loading (1.12 and 1.5 Pd atoms/nm 2 ) on the (110) surface, Pd 3 and Pd 4 clusters are thermodynamically very stable and form fast. At the 1.12 Pd atoms/nm 2 loading, the formation of the Pd 3 cluster is two orders of magnitude slower when the surface is hydroxylated as the system becomes somewhat trapped before the dinuclear cluster Pd 2 collides with a Pd atom.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1993

Earth observing scanning polarimeter

Climate forcing by tropospheric aerosols is receiving increased attention because of the realization that the climate effects may be large, while our knowledge of global aerosol characteristics and temporal changes is very poor. Tropospheric aerosols cause a direct radiative forcing due simply to their scattering and absorption of solar radiation, as well as an indirect effect as cloud condensation nuclei which can modify the shortwave reflectivity of clouds. Sulfate aerosols tend to increase planetary albedo through both the direct and indirect effects; a cooling due to anthropogenic sulfate aerosols has been estimated of order 1 W/sq m, noting that this is similar in magnitude to the present anthropogenic greenhouse gas warming. Other aerosols, including those from biomass burning and wind-blown desert dust are also of potential climatic importance. At present, the only global monitoring of tropospheric aerosols is a NOAA operational product, aerosol optical thickness, obtained using channel-1 (0.58-0.68 mu m) radiances from the AVHRR. With this single channel radiance data, one must use an approach which is based on the inferred excess of reflected radiance owing to scattering by the aerosols over that expected from theoretical calculations. This approach is suited only for situations where the surface has a low albedo that is well known a priori. Thus, the NOAA operational product is restricted to coverage over the ocean at AVHRR scan angles well away from sun glint, and aerosol changes are subject to confusion with changes caused by either optically thin or subpixel clouds. Because optically thin aerosols have only a small effect on the radiance, accurate measurements for optical thickness less than 0.1 (which is a typical background level) are precluded. Moreover, some of the largest and most important aerosol changes are expected over land. The Earth Observing Scanning Polarimeter (EOSP) instrument, based upon design heritage and analysis techniques developed for planetary missions, will retrieve tropospheric aerosol characteristics from measurements of multispectral radiance and polarization. Moreover, the same radiance and polarization measurements will also provide very precise information on cloud properties and maps of surface characteristics for cloud-free regions. These capabilities also give EOSP the unique ability to discriminate aerosol from clouds and surface.

Travis, Larry↗

NASA NTRS1990

Oxidation of the Si(100) surface promoted by Sr overlayer - An X-ray photoemission study

The interaction of strontium films with the underlaying Si (100) surface and the Sr-promoted low-temperature oxidation of Si were investigated, using XPS, at three different Sr coverages (theta): theta = 0.55 monolayer (ML), theta = 1 ML, and theta = 1.85 ML. Oxygen adsorption was studied both at room temperature and at 500 C, and at oxygen exposures up to 2 x 10 to the 6th L (1 L = 10 to the -6th torr) and 2 x 10 to the 5th L, respectively. The XPS spectra of the Si2p, O1s, and Sr3d core levels were measured for the atomically clean Si, the Sr-covered Si, and for the Sr-covered Si after each oxygen exposure. Results indicate that Sr interacts with the Si(100) surface forming a strong ionic bond, and that Sr promotes the oxidation of the Si (100) surface.

Mesarwi, A.↗

NASA NTRS1994

Ice surface temperature retrieval from AVHRR, ATSR, and passive microwave satellite data: Algorithm development and application

During the first half of our second project year we have accomplished the following: (1) acquired a new AVHRR data set for the Beaufort Sea area spanning an entire year; (2) acquired additional ATSR data for the Arctic and Antarctic now totaling over seven months; (3) refined our AVHRR Arctic and Antarctic ice surface temperature (IST) retrieval algorithm, including work specific to Greenland; (4) developed ATSR retrieval algorithms for the Arctic and Antarctic, including work specific to Greenland; (5) investigated the effects of clouds and the atmosphere on passive microwave 'surface' temperature retrieval algorithms; (6) generated surface temperatures for the Beaufort Sea data set, both from AVHRR and SSM/I; and (7) continued work on compositing GAC data for coverage of the entire Arctic and Antarctic. During the second half of the year we will continue along these same lines, and will undertake a detailed validation study of the AVHRR and ATSR retrievals using LEADEX and the Beaufort Sea year-long data. Cloud masking methods used for the AVHRR will be modified for use with the ATSR. Methods of blending in situ and satellite-derived surface temperature data sets will be investigated.

Key, Jeff↗

NASA NTRSDate not supplied

Satellite-Assisted Particulate Matter (SAPM) for the Models, In situ, and Remote Sensing of Aerosols (MIRA) Working Group

Models, In situ, and Remote sensing of Aerosols (MIRA) is an international working group that provides a forum for collaborations amongst these three atmospheric aerosol communities. MIRA consists of a collection of interdisciplinary and independently funded Topic/Project groups with clear goals and generally characterized by requests for additional scientific data. The Satellite-Assisted Particulate Matter (SAPM) Topic group focuses on the study of fine particulate matter (PM2.5), as it is a major contributor to air pollution and negatively impacts human health. Our group aims to provide intercomparisons of various methods and techniques for estimating surface PM2.5 assisted by satellite remote sensors (passive and active), global aerosol models, and in situ aerosol measurements. The overall motivation of our work is to enhance PM2.5 coverage beyond in situ ground stations, which can be limited. In this presentation, we provide an overview of various PM2.5 estimation approaches by current SAPM team members, as each approach has its own strengths and limitations. One approach uses near-surface aerosol extinction retrievals from the spaceborne Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and an assumed value of mass extinction efficiency to derive PM2.5 concentrations (Toth et al 2019). A study using this method found a promising agreement (R=0.60; slope=0.89) with U.S. Environmental Protection Agency (EPA) in situ PM2.5 measurements over the contiguous United States (CONUS) for a 12-year (2007-2018) period (Toth et al 2022). In a different approach combining spaceborne lidar and a model, the Cloud Aerosol Transport System (CATS) lidar and Goddard Earth Observing System (GEOS) model are blended in an ensemble variational assimilation scheme to retrieve aerosol extinction and convert speciated mass concentrations to total PM2.5. A recent study (Matus et al in prep.) found agreement within 2 μg/m3 over the CONUS on the 2016 annual mean when compared to EPA ground-based measurements. Another study explored trends in city aerosol optical depth (AOD) from a spaceborne passive remote sensor, Moderate Resolution Imaging Spectroradiometer (MODIS), and found that these trends agree well with trends in city surface PM2.5, which provides confidence in the use of city AOD for city PM2.5 trend studies (Vohra et al 2021). In a follow-on study, steep and significant trends (~2.5 to 7.8% a-1) in AOD are found for several South Asian cities (e.g., Bangalore and Hyderabad), suggesting rapid growth in PM2.5 (Vohra et al 2022). Also in this presentation, we report results on our current collective SAPM study of India, a country that exhibits high levels of PM2.5 pollution. We show the temporal (i.e., seasonal) and spatial variability of PM2.5 over India using the CALIOP and CATS+model approaches, comparisons between the estimated PM2.5 from the retrieval schemes, and validation with in situ PM2.5 ground-based observations from the Central Pollution Control Board in India. This region provides us with an excellent case study to test our PM2.5 retrievals in heavily polluted scenes and over a complex and varying topography. The SAPM Topic group actively seeks international participants/collaborators in our group, including those working with in situ aerosol measurements (e.g., ACTRIS). We are interested in aerosol datasets in order to either improve our PM2.5 estimates from various approaches (e.g., using in situ mass scattering/absorption coefficient and aerosol hygroscopic properties for various aerosol species) and/or validate the PM2.5 estimates (e.g., using in situ ground-based PM2.5 concentrations).

Travis D Toth↗

NASA NTRSDate not supplied

Satellite-Assisted Particulate Matter (SAPM) for the Models, In situ, and Remote sensing of Aerosols (MIRA) Working Group

Models, In situ, and Remote sensing of Aerosols (MIRA) is an international working group that aims to foster collaborations amongst these three major aerosol specialties. It consists of a collection of interdisciplinary and independently funded projects/topics with clearly-defined goals. Currently there are four MIRA topic areas, including Satellite-Assisted Particulate Matter (SAPM), which is focused specifically on fine particulate matter (PM2.5). The study of PM2.5 is important due to its significant contribution to air pollution and resultant, adverse human health effects. The goal of the SAPM topic group is to conduct and provide intercomparisons of various methods and techniques to obtain surface PM2.5 estimates assisted by satellite remote sensors, global aerosol models, and in situ aerosol measurements. Some benefits of space-based/model-assisted PM2.5 retrievals include providing PM2.5 approximations in regions with poor in situ ground station coverage and a means for assessing spatial/temporal PM2.5 variations on regional and/or global scales. Furthermore, benefits of spaceborne lidar/model-assisted PM2.5 retrievals include providing nighttime PM2.5 estimates and characterization of near-surface aerosol vertical structure. SAPM is seeking international datasets of mass scattering/absorption coefficient and aerosol hygroscopic properties for different aerosol species, as well as ground-based in situ PM2.5 measurements. In this poster presentation, we give an overview of SAPM, and show results from three recent/ongoing PM2.5 studies. These efforts involve deriving surface PM2.5 concentrations from two spaceborne lidars, the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) and Cloud-Aerosol Transport System (CATS), and investigating key variables that impact the estimation of PM2.5 from model simulated aerosol optical depth (AOD) using the Goddard Earth Observing System (GEOS) model.

Travis D. Toth↗

NASA NTRS1971

Importance of combining convection with film cooling

The interaction of film and convection cooling and its effect on wall cooling efficiency is investigated analytically for two cooling schemes for advanced gas turbine applications. The two schemes are full coverage- and counterflow-film cooling. In full coverage film cooling, the cooling air issues from a large number of small discrete holes in the surface. Counterflow film cooling is a film-convection scheme with film injection from a slot geometry. The results indicate that it is beneficial to utilize as much of the cooling air heat sink as possible for convection cooling prior to ejecting it as a film.

Colladay, R. S.↗

NASA NTRS1972

Importance of combining convection with film cooling.

Colladay, R. S.↗

NASA NTRS1977

The ESSA solution

ESSA (Electronic Switching Spherical Array) is a fixed truncated spherical antenna with its elements over the complete surface, conceived to satisfy many future antenna system requirements. Constant gain and beam shape throughout large volumetric coverage regions are the principle characteristics. In the present paper, the two existing types of ESSA are discussed. ESSA I is a simple nonphase correcting aperture approach characterized by light weight, low dc power consumption, gain between +7 and +14 dB, and 90% spherical coverage. ESSA II is a phase corrected aperture which would have very low sidelobe levels and improved gain over ESSA I (12 to 22 dB), but would be heavier and require more dc power.

Hockensmith, R. P.↗

NASA NTRS1983

Sensitive observations with the Spacelab 2 infrared telescope

The small helium-cooled infrared telescope (Spacelab IRT) is a multiband instrument capable of highly sensitive observations from space. The experiment consists of a cryogenically cooled, very well baffled telescope with a ten channel focal plane array. During the Spacelab 2 flight of the Space Shuttle, this instrument will make observations between 5 and 120 micron wavelength that will be background limited by the expected zodiacal emission. Design considerations necessitated by this level of performance are discussed in this paper. In particular, the operation of a very sensitive focal plane array in the space environment is described. The Spacelab IRT will be used to map the extended, low-surface brightness celestial emission. During the seven day length of the mission better than 70 percent sky coverage is expected. The instrument will also be used to measure the infrared contamination environment of the Space Shuttle. This information will be important in the development of the next generation of infrared astronomical instruments. The performance of the Spacelab IRT, in particular its sensitivity to the contamination environment is detailed.

Young, E. T.↗

NASA NTRS1984

The Venus radar mapper mission

The Venus Radar Mapper (VRM) Mission, in 1988, will be the next NASA mission to Venus. This paper describes the mission as it is currently planned, showing how the design of the science payload, the spacecraft, and the mission satisfies the science objectives and requirements as well as other programmatic constraints. The VRM mission is dedicated to obtaining Synthetic Aperture Radar (SAR) images of at least 70 percent of the surface of Venus at a resolution of 1 km per line pair or better (comparable to the coverage and resolution of the Mars Mariner 9 mission). Additional investigations will study the interior geophysical characteristics of the planet using altimetric data and gravity field measurements of the planet.

Dallas, S. S.↗

NASA NTRS1989

Radiometric calibration of Landsat Thematic Mapper Thermal Band

Radiometric calibration of satellite-acquired data is essential for quantitative scientific studies, as well as for a variety of image-processing applications. This paper describes a multiyear, on-orbit radiometric calibration of the Landsat Thematic Mapper (TM) Band 6 conducted at DOE's Pacific Northwest Laboratory. Numerous Landsat TM scenes acquired and analyzed included day and night coverages at several geographical locations over several seasons. Concurrent with Landsat overpasses, thermal field and local meteorological (surface and radiosonde) measurements were collected. At-satellite (uncorrected) radiances and temperatures for water and nonwater land cover were compared to ground truth (GT) measurements after making adjustments for atmospheric (using LOWTRAN), mixed-pixel, and emissivity effects. Results indicate that, for both water and nonwater features, TM Band 6 average corrected temperature determinations using local radiosonde data to adjust for atmospheric effects, and using appropriate emissivities, are within 1.0 C of GT temperature values. Temperatures of water pixels derived from uncorrected TM Band 6 data varied roughly between 1 and 3 C of ground truth values for water temperatures ranging between 4 and 24 C. Moreover, corrections using nonlocal and noncoincident radiosonde data resulted in errors as large as 12 C. Corrections using the U.S. Standard Atmosphere gave temperature values within 1 to 2 C of GT. The average uncertainty for field instruments was + or - 0.2 C; average uncertainty for Landsat TM corrected temperature determinations was + or - 0.4 C.

Wukelic, G. E.↗