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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55

Onset of the Efficiency Droop in GaInN Quantum Well Light-Emitting Diodes under Photoluminescence and Electroluminescence Excitation

The efficiency of Ga0.87In0.13N/GaN single and multiple quantum well (QW) light-emitting diodes is investigated under photoluminescence (PL) and electroluminescence (EL) excitation. By measuring the laser spot area (knife-edge method) and the absorbance of the GaInN QW (transmittance/reflectance measurements), the PL excitation density can be converted to an equivalent EL excitation density. The EL efficiency droop-onset occurs at an excitation density of 2.08 × 1026 cm–3 s–1 (J = 10 A/cm2), whereas no PL efficiency droop is found for excitation densities as high as 3.11 × 1027 cm–3 s–1 (J = 149 A/cm2). Considering Shockley–Read–Hall, radiative, and Auger recombination and including carrier leakage shows that the EL efficiency droop is consistent with a reduction of injection efficiency.

36 MATERIALS SCIENCE↗

Stable, High Efficiency White Electrophosphorescent Organic Light Emitting Devices (OLED) by Reduced Molecular Dissociation (Final Report)

We shall pursue radically new strategies for increasing the lifetime of blue phosphorescent light emitting devices (PHOLEDs). Systematically seek robust dopant and host molecular pairs whose energy gaps allow both to participate in charge conduction in the PHOLED Emissive Layer (EML). By tailoring the host/dopant grading profile and extending the emission zone, it is anticipated that these approaches may significantly increase device lifetime while simultaneously increasing its efficiency.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Rebound effects for lighting

Explore the source record for details and available documents.

solar (photovoltaic), solid state lighting, phonon↗

High performance blue-emitting organic light-emitting diodes from thermally activated delayed fluorescence: A guest/host ratio study

Emitters displaying thermally activated delayed fluorescence (TADF) can drive highly efficient organic light-emitting diodes (OLEDs). Such emitters are usually incorporated into the emissive layer (EML) at a relatively low concentration (<20 wt. %) with respect to a host material, a guest-host method inherited from conventional fluorescent or phosphorescent OLEDs. In this work, detailed studies on OLEDs, in which the concentration of oBFCzTrz (a blue-emitter displaying TADF) in a DPEPO host was varied from 8 to 100 wt. %, reveals that oBFCzTrz displays ambipolar transport and limited fluorescence-quenching due to aggregation. For instance, a neat film of oBFCzTrz maintains a photoluminescence quantum yield of 82%. We determine that OLEDs with an EML having an oBFCzTrz concentration of 50 wt. % in DPEPO yield a maximum external quantum efficiency (EQE) of 25.5% with an EQE roll-off of 10% in the range from 10 to 1000 cd/m 2 and Commission Internationale de l'Eclairage color coordinates of (0.20, 0.44). OLEDs with smaller or larger oBFCzTrz concentrations display smaller maximum EQE values. OLEDs with a neat oBFCzTrz EML display a maximum EQE of 14.0%. Finally, time-resolved electroluminescent decay studies, and analysis using a simple model, reveal significant differences in transport, trapping, and recombination in these devices.

36 MATERIALS SCIENCE↗

Dimming LEDs with Phase-Cut Dimmers: The Specifier's Process for Maximizing Success

This report reviews how phase-cut dimmers work, how LEDs differ from the incandescent lamps that the dimmers were historically designed to control, and how these differences can lead to complications when trying to dim LEDs. Compatibility between a specific LED source and a specific phase-cut dimmer is often unknown and difficult to assess, and ensuring compatibility adds complexity to the design, specification, bidding, and construction observation phases for new buildings and major remodel projects. To maximize project success, this report provides both general guidance and step-by-step procedures for designing phase-controlled LED dimming on both new and existing projects, as well as real-world examples of how to use those procedures.

0-10V↗

Evidence of trap-assisted Auger recombination in low radiative efficiency MBE-grown III-nitride LEDs

By studying low radiative efficiency blue III-nitride light emitting diodes (LEDs), we find that the ABC model of recombination commonly used for understanding efficiency behavior in LEDs is insufficient and that additional effects should be taken into account. We propose a modification to the standard recombination model by incorporating a bimolecular nonradiative term. The modified model is shown to be in much better agreement with the radiative efficiency data and to be more consistent than the conventional model with very short carrier lifetimes measured by time-resolved photoluminescence in similar, low radiative efficiency material. Here, we present experimental evidence that a hot carrier-generating process is occurring within these devices, in the form of measurements of forward photocurrent under forward bias. The forward photocurrent, due to hot carrier generation in the active region, is present despite the lack of any "efficiency droop"-the usual signature of band-to-band Auger recombination in high-quality III-nitride LEDs. Hot carrier generation in the absence of band-to-band Auger recombination implies that some other source of hot carriers exists within these low radiative efficiency devices, such as trap-assisted Auger recombination.

36 MATERIALS SCIENCE↗

Connected Lighting Systems Efficiency Study: PoE Cable Energy Losses, Part 2

DOE published a report in November 2017 (herein referred to as “Part 1”) summarizing the results of an exploratory study investigating power losses in Ethernet cables used between PoE switches and luminaires in PoE connected lighting systems. Testing was conducted at the Pacific Northwest National Laboratory (PNNL) Connected Lighting Test Bed (CLTB) in September 2017. The results were analyzed to explore the impact of cable selection on PoE lighting system energy efficiency, as well as the effectiveness of guidelines published by the American National Standards Institute (ANSI) C137 Lighting Systems Committee in 2017. The guidance offered in ANSI C137.3-2017 was found to be effective in limiting cable energy losses to 5% in PoE lighting applications, provided that the average cable length on a project does not exceed 50 m. This Part 2 report summarizes the results of a continued investigation of the power losses in Ethernet cables used between PoE switches and luminaires in PoE connected lighting systems. Testing was conducted at the PNNL CLTB in July-August 2018. A test setup comprising a PoE switch, a set of luminaires, and a reference meter was again used to test multiple cable models of varying design. The results were analyzed to explore the impact of cable selection and installation practices (e.g., cable bending, cable bundling, and installation in conduit) on PoE lighting system energy efficiency, as well as the effectiveness of the ANSI C137.3 guidelines. Notably, three cables—two of which were shielded—were previously excluded from the Part 1 study due to compatibility issues. All three cables were included in this Part 2 study, along with a fourth model cable introduced in Part 2. In addition, whereas no patch cords were used in Part 1, patch cords were used in some Part 2 testing. The ANSI C137.3 guidance was again shown to effectively limit power losses to less than 5% in the cables tested (varying in AWG, Category, shielding, fire rating, and manufacturer), and AWG again proved to be the most important cable design variable for energy performance, as expected. However, these findings should not be construed as being representative of all cable models and installation practices. For example, energy losses would be greater when cables are connected to patch cords, bundled in conduit, and loaded with powered devices (PDs) approaching 100 W input power. The other key finding was that with 44 W luminaires as PDs and room ambient temperatures below 30°C, cable energy losses were not substantially increased by cable bending or bundling in uninsulated conduit. However, environments with higher ambient temperatures will have greater energy losses due to increased conductor DCR. In addition, product selection and installation practices will have increased importance as PDs approaching 100 W input power—conveyed by a single Ethernet cable—are introduced following publication of the forthcoming Institute of Electrical and Electronics Engineers (IEEE) Standard 802.3bt. The report also provides recommendations and next steps, which include plans for additional PoE cable energy losses testing with higher-power PDs to more fully explore the potential of PoE lighting systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗