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At least 991 records · Page 55

The influence of cobalt, tantalum, and tungsten on the elevated temperature mechanical properties of single crystal nickel-base superalloys

The influence of composition on the tensile and creep strength of 001-line oriented nickel-base superalloy single crystals at temperatures near 1000 C was investigated. Cobalt, tantalum, and tungsten concentrations were varied according to a matrix of compositions based on the single crystal version of MAR-M247. For alloys with the baseline refractory metal level of 3 wt pct Ta and 10 wt pct W, decreases in Co level from 10 to 0 wt pct resulted in increased tensile and creep strength. Substitution of 2 wt pct W for 3 wt pct Ta resulted in decreased creep life at high stresses, but improved life at low stresses. Substitution of Ni for Ta caused large reductions in tensile strength and creep resistance, and corresponding increases in ductility. For these alloys with low Ta-plus-W totals, strength was independent of Co level. The effects of composition on properties were related to the microstructural features of the alloys. In general, high creep strength was associated with high levels of gamma-prime volume fraction, gamma-gamma-prime lattice mismatch, and solid solution hardening.

Nathal, M. V.↗

New algorithms for microwave measurements of ocean winds Applications to Seasat and the special sensor microwave imager

Improved second generation wind algorithms are used to process the three month Seasat SMMR and SASS data sets. The new algorithms are derived without using in situ anemometer measurements. All known biases in the sensors prime measurements are removed, and the algorithms prime model functions are internally self-consistent. The computed SMMR and SASS winds are collocated and compared on a 10 km cell-by-cell basis, giving a total of 115444 wind comparisons. The comparisons are done using three different sets of SMMR channels. When the 6.6H SMMR channel is used for wind retrieval, the SMMR and SASS winds agree to within 1.3 m/s over the SASS primary swath. At nadir where the radar cross section is less sensitive to wind, the agreement degrades to 1.9 m/s. The agreement is very good for winds from 0 to 15 m/s. Above 15 m/s, the off-nadir SASS winds are consistently lower than the SMMR winds, while at nadir the high SASS winds are greater than SMMR's. When 10.7H is used for the SMMR wind channel, the SMMR/SASS wind comparisons are not quite as good. When the frequency of the wind channel is increased to 18 GHz, the SMMR/SASS agreement substantially degrades to about 5 m/S.

Wentz, F. J.↗

A geographic information system for resource managers based on multi-level remote sensing data

Procedures followed in developing a test case geographic information system derived primarily from remotely sensed data for the North Cache Soil Conservation District (SCD) in northern Utah are outlined. The North Cache SCD faces serious problems regarding water allocation, flood and geologic hazards, urban encroachment into prime farmland, soil erosion, and wildlife habitat. Four fundamental data planes were initially entered into the geo-referenced data base: (1) land use/land cover information for the agricultural and built-up areas of the valley obtained from various forms of aerial photography; (2) vegetation/land cover in mountains classified digitally from Landsat; (3) geomorphic terrain units derived from aerial photography and soil maps; and (4) digital terrain maps obtained from DMA digital data. The land use/vegetation/land cover information from manual photographic and Landsat interpretation were joined digitally into a single data plane with an integrated legend, and segmented into quadrangle units. These were merged with the digitized geomorphic units and the digital terrain data using a Prime 400 minicomputer. All data planes were geo-referenced to a UTM coordinate grid.

Wheeler, D. J.↗

Microstructure/mechanical property relationships for various thermal treatments of Al-Cu-Mg-X PM aluminum alloys

The thermal response and aging behavior of three 2XXX-series powder metallurgy aluminum alloys have been investigated, using Rockwell B hardness measurements, optical and electron microscopy, and energy-dispersive chemical analysis, in order to correlate microstructure with measured mechanical properties. Results of the thermal response study indicated that an increased solution heat treatment temperature was effective in resolutionizing large primary constituents in the alloy bearing more copper but had no apparent effect on the microconstituents of the other two. Aging studies conducted at room temperature and at 120, 150, and 180 C for times ranging up to 60 days indicated that classic aging response curves, as determined by hardness measurements, occurred at lower aging temperatures than were previously studied for these alloys, as well as at lower aging temperatures than are commonly used for ingot metallurgy alloys of similar compositions. Microstructural examination and fracture surface analysis of peak-aged tension specimens indicated that the highest tensile strengths are associated with extremely fine and homogeneous distributions of theta-prime or S-prime phases combined with low levels of both large constituent particles and dispersoids. Examination of the results suggest that refined solution heat treatments and lower aging temperatures may be necessary to achieve optimum mechanical properties for these 2XXX series alloys.

Blackburn, L. B.↗

FUSE/Lyman grant

A variety of options for a short wavelength spectrometer for the Lyman telescope has been studied, and the optimum configuration for this instrument identified. In this spectrometer option study it is assumed (consistent with performance goals outlined by the project) that the instrument, whose prime spectral domain is 900-12000A, will incorporate a grazing incidence telescope which will maintain good collecting efficiency down to 100A. In particular it is assumed that the telescope will have an effective focal length of 10 meters, an image quality of 1.5", and will provide a diverging f/10 beam. Designs compatible with this telescope are analyzed, and it is determined that a two-element grazing incidence spectrometer using as its first optic an ellipsoid to re-focus the beam and a varied line-space plane diffraction grating to disperse the light is the best overall design. This spectrometer could be fed by a small pick-off mirror located just behind the prime focus of the telescope and would clear the light path when not in use. A test of the diffraction efficiency of a low blaze angle grating is undertaken, which is the only technical uncertainty in the spectrometer design.

Hurwitz, M.↗

The effect of nonlinearities on the dynamic response of a large shuttle payload

The STS Centaur was designed to be a high energy upper stage for use with the Space Shuttle. Two versions were designed under development when the program was cancelled. The first version, designated G-prime, was for planetary missions. The second version, designated G, was to place spacecraft in geosynchronous orbit. As a part of the STS Centaur finite-element model verification effort, test articles of both versions were subjected to a series of static tests. In addition the Centaur G-prime test article was subjected to a series of dynamic tests including a modal survey. Both the static and dynamic tests showed that nonlinearities existed in the Centaur and its support system. The support system included flight-like latches. The nonlinearities were particularly apparent in tests that loaded the forward support structure of the Centaur. These test results were used to aid in the development of two improved finite-element models. The first was a linear model, while the second contained nonlinear elements at the boundaries. Results from both models were compared with the transient response obtained from a step-relaxation or twang test. The linear model was able to accurately match the low frequency response found in the test data. However, only the nonlinear model was able to match higher frequency response that was present in some of the test data. In addition the nonlinear model was able to predict other nonlinear behavior such as the dynamic jump that occurs in systems with nonlinear stiffness.

Sullivan, Timothy L.↗

The effect of heat treatment on microfissuring in alloy 718

Changes in the microfissuring susceptibility of alloy 718 due to solution annealing and age hardening are studied. The effects of Ni3Nb (delta) precipitation during solution annealing and gamma-prime + gamma-double-prime precipitation during age hardening on microfissuring are investigated. It is observed that solution annealing reduces microfissuring and age hardening increases it, and the two precipitates do not affect microfissuring susceptibility. Potential causes for the detected intergranular segregation of the alloy are discussed.

Thompson, R. G.↗

The effects of tantalum on the microstructure of two polycrystalline nickel-base superalloys - B-1900 + Hf and MAR-M247

The effect of changing the content of Ta on the gamma/gamma-prime carbide microstructure was investigated in two crystalline nickel-base superalloys: conventionally cast B-1900 + Hf, and both conventionally cast and directionally solidified MAR-M247. The changes occurring in the microstructure effects were similar in both alloys. The gamma-prime and carbide volume fractions increased linearly with Ta additions, while the gamma-prime phase compositions did not change. Bulk Ta additions increased the levels of Cr and Co (in addition to that of Ta) of the gamma phase, a result of the approximately constant partitioning ratios for these two elements. The addition of Ta led to a partial replacement of Hf in the MC carbides. In addition, Cr-rich M(23)C(6) carbides formed as a result of MC carbide decomposition during heat treatment.

Heckel, R. W.↗

The dayglow of the O2 atmospheric band system

The dayglow of the O2 atmospheric O2(1Sigma) band system has been simulated by taking into account the three main production mechanisms of the O2(1Sigma) state resonance fluorescence, a photochemical term due to quenching of O(1D), and a pure chemical process. Values of the emission rate, which are involved in the resonant scattering of the O2 atmospheric bands (A, B, and gamma), have been obtained as a function of altitude (0-120 km) and solar zenith angle using a line-by-line calculation. The values of the emission rate, along with updated rate coefficients, have been used in the calculation of the production rate of O2(1Sigma) and the volume emission rate of the (O2 1Sigma, v prime = 0)-(O2 3Sigma, v double prime = 0) transition. The results of these calculations are compared to observational measurements and are found to be in excellent agreement.

Bucholtz, A.↗

Direct infrared imaging of VB 8

Near-infrared images of VB 8 taken at K (2.2 microns) and L-prime (3.75 microns) during a period of good seeing at the IRTF show no evidence of the brown dwarf companion reported by McCarthy et al. (1985). Any companion 1.0 arcsec away from the primary must be at least 4 mag fainter than the primary at K and 3 mag fainter at L-prime in order to escape detection. A faint nebula centered on the star with scattering properties similar to a nebula detected near another main-sequence M star, Lalande 21185 (reported by McCarthy in 1986), may account for the extended emission detected by speckle observations.

Skrutskie, M. F.↗

The effect of nonlinearities on the dynamic response of a large Shuttle payload

The STS Centaur was designed to be a high energy upper stage for use with the Space Shuttle. Two versions were designed and under development when the program was cancelled. The first version, designated G-prime, was designed for planetary missions. The second version, designated G, was designed to place spacecraft in geosynchronous orbit. As a part of the STS Centaur finite-element model verification effort, test articles of both versions were subjected to a series of static tests. In addition the Centaur G-prime test article was subjected to a series of dynamic tests including a modal survey. Both the static and dynamic tests showed that nonlinearities existed in the Centaur and its support system. The support system included flight-like latches. The nonlinearities were particularly apparent in tests that loaded the forward support structure of the Centaur. These test results were used to aid in the development of two improved finite-element models. The first was a linear model, while the second contained nonlinear elements at the boundaries. Results from both models were compared with the transient response obtained from a step-relaxation or twang test. The linear model was able to accurately match the low frequency response found in the test data. However, only the nonlinear model was able to match higher frequency response that was present in some of the test data. In addition the nonlinear model was able to predict other nonlinear behavior such as the dynamic 'jump' that occurs in systems with nonlinear stiffness.

Sullivan, Timothy L.↗

Vibrational excitation in O2(B1Sigma g+)

Excitation processes for O2(b1Sigma g+) in aurorae, in the nightglow, and in laboratory sources are discussed. It is shown that the observed vibrational distribution in aurorae is consistent with the O2(+) + NO charge-transfer mechanism. Arguments are presented for the case the quenching of O2(b) in vibrational levels above v-prime = 1 is rapid, and that therefore the auroral source is much larger than previously supposed. It is suggested that oxygen atoms are an efficient quencher for O2(b) levels above v-prime = 1.

Slanger, Tom G.↗

Mechanical and swelling behaviour of well characterized polybutadiene networks

Endlinking of hydroxyl-terminated polybutadiene with the appropriate isocyanate has been used to prepare well characterized networks. Two networks have been studied with molecular weights of the prepolymers being 6100 and 2400 g/mole by g.p.c. Cylindrical specimens were prepared and the derivatives of the stored energy function with respect to the stretch invariants were determined by torque and normal force measurements in torsion. From these data the Valanis-Landel (1967) stored energy function derivatives w-prime(lambda) were determined for both networks. The stored energy function for the junction constraint model of Flory (1953, 1977, 1979, 1985) which is a special form of the Valanis-Landel function, has been fitted to that determined from the experiments. The contributions to the stored energy function from the phantom network and from the junction constraints respectively do not agree with predictions from the topologies of the networks. In spite of this, the form of w-prime(lambda) for the junction constraint model gives an excellent 'curve fit' to the data. Comparison is also made with equilibrium swelling.

Mckenna, Gregory B.↗

Spectral determination of nitrogen vibrational temperatures

A technique for determining the vibrational temperature of nitrogen molecules is found from the emission of the N2 first positive spectrum. The technique involves calculating wavelength integrals of portions of the emission spectrum associated with transitions from the ststes B3Pi(g)(v-prime) to A3 Sigma(u +)(v-double prime) where Delta = 2, 3, etc. Ratios of the integrated intensities are then correlated with vibrational temperature. The dependence of the technique on rotational temperature is considered and less dependence is obtained if the overlap between Delta v-regions is accounted for. The technique is applied to the shock layer of a blunt body in an arc jet flow. The N2(1+) spectrum is measured in the shock layer to obtain the intensity integral ratios. From these ratios estimates of the vibrational temperature are found from the correlation which agree quite well with calculated temperatures in the shock layer flow.

Blackwell, Harvel E.↗

The evolution of nucleotides

Examples of chiral selection in nonenzymatic aminoacylation of internal 2-prime hydroxyl groups of oligo- and polynucleotides are discussed as an evidence for the early evolution of bionucleotides. Some factors that could influence the degree of this chiral selection and its direction are discussed. These include the structure of the aminoacyl component, the structure of the nucleoside component, and the reaction conditions. Investigation of the mechanism of this reaction was aided by the use of 3-prime inosine methyl phosphate (as a simplified model for a dinucleoside monophosphate) and proton NMR spectroscopy of t-butoxycarbonyl-alanyl esters of nucleosides as models for the transition state of the aminoacylation reaction itself.

Usher, D. A.↗

Thermal stability of the nickel-base superalloy B-1900 + Hf with tantalum variations

The microstructure of the solutionized and aged nickel-base superalloy B-1900 + Hf was examined after additional aging at 982 C for 72, 250, and 1000 hours. Alloy compositions that were examined contained the normal 1.34 at. pct (4.3 wt pct) Ta as well as 0.67 at. pct and zero Ta levels. The gamma-prime phase agglomerated, became platelike in morphology, and decreased in volume fraction for all three alloys throughout the aging treatments. Changes which occurred in the gamma and gamma-prime phase compositions were nearly complete after 72 hours of aging while changes in the MC carbide composition continued throughout the aging. Blocky M6C carbides precipitated along the grain boundaries of all three alloys in the first 72 hours of aging. In addition, an acicular form of this Mo/Cr/Ni-rich carbide developed in the intragranular regions of the Ta-containing alloys.

Harmon, B. S.↗

Theoretical determination of the radiative lifetime of the A 2Sigma(+) state of OH

The present theoretical potentials and transition moment-based computation of the radiative lifetime of the A 2Sigma(+)(v-prime = 0, N-prime = 1) state of OH yields a value of 673 ns, in excellent agreement with two of the experimental values obtained through laser excitation fluorescence. The theoretical radiative lifetimes, which are expected to be lower bounds and accurate to 2 percent, are accurate enough to preclude both the slightly lower value determined by Hanle effect studies and the higher values obtained by the high frequency deflection technique.

Bauschlicher, Charles W., Jr.↗

The effect of altered 5-hydroxytryptamine levels on beta-endorphin

The purpose of the present study was to examine the effect of altering the concentration of 5-hydroxytryptamine (5-HT) on beta-endorphin (beta-Ep) content in the hypothalamus, thalamus, and periaqueductal gray (PAG)-rostral pons regions of the rat brain. The selective 5-HT reuptake inhibitor, fluoxetine (10 mg/kg), significantly lowered beta-Ep content in the hypothalamus and the PAG. Parachlorophenylalanine, which inhibits 5-HT synthesis, significantly elevated beta-Ep in all brain parts studied. Intracisternal injections of the neurotoxin 5-prime, 7-prime-dihydroxytryptamine with desmethylimipramine pretreatment significantly increased beta-Ep content in the hypothalamus and the PAG. In adrenalectomized rats, fluoxetine significantly decreased beta-Ep levels in the hypothalamus and increased the levels in the PAG. The results indicate that 5-HT may modulate the levels of brain beta-Ep.

Soliman, Karam F. A.↗