Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “N2”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Photolysis of methyl nitrite.

Study of the photolysis of CH3ONO, alone and in the presence of NO, NO-N2 mixtures, and NO-CO mixtures, between 25 and 150 F. The major products of this reaction are CH2O, N2O, and H2O. The steps responsible for these products are determined. The N2O yield is large at low pressures but approaches a high-pressure limiting value of 0.055 at all temperatures as the excited CH3O produced in the primary step is stabilized by collision. Nitrogen is also a product of the reaction and is produced from two sources. When pure CH3ONO is photolyzed, CO is produced and NO accumulates in the system. Both products are formed in related processes and result from CH3O attack on CH2O.

Wiebe, H. A.↗
NASA NTRS1973

Twilight airglow. I - Photoelectrons and forbidden O I 5577-angstrom radiation.

A payload consisting of a number of experiments to study the earth's atmosphere was launched from White Sands on Feb. 8, 1971. The differential photoelectron flux spectrum was measured as a function of altitude. The energy distribution revealed the N2 vibrational structure appearing at 2.8 V, rising to a maximum at 4 eV, decreasing to an 8-volt-wide plateau at 20 V, and then further decreasing. The ion and electron density distributions were measured simultaneously. An optical measurement of forbidden O I 5577-A radiation was made. Both electron impact on atomic oxygen and dissociative recombination of O2(+) were found to produce this emission above 150 km. The recombination rate for the O(1 S) found from a reported nightglow profile is 2.5 plus or minus 1.5 x 10 to the minus 9th cu cm/sec. Between 140 and 120 km, photodissociation is a source of 5577 radiation. Chapman three-body recombination is dominant below 120 km.

Hays, P. B.↗
NASA NTRS1973

Magnetic control of the near equatorial neutral thermosphere.

Neutral density data between 400 and 500 km obtained with the Ogo 6 neutral mass spectrometer indicate that at all longitudes the daytime N2 and O densities have latitudinal minimums at the magnetic equator that are about 20 and 10%, respectively, below maximums observed between plus and minus 20 deg magnetic latitude. Our calculations suggest that this anomaly could result from latitudinal variations in ion drag associated with the 'equatorial anomaly' in F region ionization. At latitudes of enhanced electron density the energy flow from the dayside to the nightside of the earth is damped, and thus the amplitude of the temperature and density variations is enhanced, and the time of maximum is shifted to later local times.

Hedin, A. E.↗
NASA NTRS1973

Carbon chemistry of Luna 16 and Luna 20 samples.

Luna 16 and Luna 20 samples were analyzed for volatilizable species using vacuum pyrolysis to 1400 C. The major gaseous products evolved (ranging from 10-650 micrograms/g) were H2O, CO, CO2, N2 and CH4. Minor components (all less than 10 micrograms/g) included NH3, HCN, NO, SO2, H2S, C2H2, C2H4, C2H6, C3H6 and higher hydrocarbons, benzene, toluene, and the polymeric contaminants Teflon and silicone oil. The total carbon and nitrogen contents (micrograms/g) for these sieved samples were: Luna 16 - C 418, N 134 and Luna 20 - C 380, N 80.

Simoneit, B. R.↗
NASA NTRS1973

Rocket observations of the extreme ultraviolet dayglow.

The ultraviolet dayglow in the wavelength region 750-1050 A was investigated over the altitude range 100-800 km using a thin film filter photometer. From the airglow spectrum obtained by Carruthers and Page, one of the dominant features in this wavelength range is OII 834 A. It is pointed out that the major excitation mechanism for this transition is photoionization excitation of atomic oxygen. Solution of the radiative transfer problem for this excitation process shows good agreement with the observed dayglow in the 300-800 km region. At lower altitudes additional componets are present and are interpreted as the N2, OI and possibly HI emissions observed by Carruthers and Page.

Carlson, R. W.↗
NASA NTRS1973

Nonequilibrium effects on shock-layer radiometry during earth entry.

Radiative enhancement factors for the CN violet and N2(+) first negative band systems caused by nonequilibrium thermochemistry in the shock layer of a blunt-nosed vehicle during earth entry are reported. The results are based on radiometric measurements obtained with the aid of a combustion-driven shock tube. The technique of converting the shock-tube measurements into predictions of the enhancement factors for the blunt-body case is described, showing it to be useful for similar applications of other shock-tube measurements.

Arnold, J. O.↗
NASA NTRS1973

A contaminant monitor for submarine atmospheres.

A requirement for monitoring selected atmospheric constituents on board nuclear powered submarines has been met by the development of the Central Atmosphere Monitoring System, Mark I. This system employs a mass spectrometer to monitor H2, H2O, N2, O2, CO2, Freon 11, Freon 12, and Freon 114, in addition to an infrared sensor for CO. The CAMS MKI development is discussed, including background, operating fundamentals, principal requirements, functional and physical descriptions, and summarized test results. Each of two prototype units has successfully completed over 9000 hr of operational sea trails, providing the necessary ground work for the manufacture of production units. At the same time, these units, which have benefited extensively from NASA hardware experience, may in turn provide useful data for the development of a new class of maintainable atmospheric monitoring instrumentation for manned spacecraft.

Ruecker, M. R.↗
NASA NTRS1973

Gasdynamic lasers and photon machines.

The basic operational highlights of CO2-N2 gasdynamic lasers (GDL's) are described. Features common to powerful gas lasers are indicated. A simplified model of the vibrational kinetics of the system is presented, and the importance of rapid expansion nozzles is shown from analytic solutions of the equations. A high-power pulsed GDL is described, along with estimations of power extraction. A closed-cycle laser is suggested, leading to a description of a photon generator/engine. Thermodynamic analysis of the closed-cycle laser illustrates in principle the possibility of direct conversion of laser energy to work.

Christiansen, W. H.↗
NASA NTRS1973

Study of neutral composition of lower thermosphere at Fort Churchill.

On Feb. 4 and 6, 1969, and May 11, 1970, Aerobee rockets carrying neutral mass spectrometers were flown at Fort Churchill, Canada during conditions of low geomagnetic activity. As in earlier flights at White Sands, New Mexico, each rocket carried both 'open' and 'closed' ion source instruments. Vertical profiles of N2, O2, O, Ar, and He were measured. Results obtained were essentially the same as those observed at White Sands except that for the winter flights helium appeared to be in diffusive equilibrium.

Nier, A. O.↗
NASA NTRS1973

Excitation of the CO fourth positive system by the dissociative recombination of CO2/+/ ions.

The fourth positive system of CO has been excited in a static afterglow experiment by the dissociative recombination of CO2(+) ions. From combined absolute optical and microwave measurements the specific recombination coefficient for exciting the CO system was found to be (2 plus 1 or minus 0.5) x 10 to the minus 8th cu cm/sec. This value represents approximately 5% of the total recombination coefficient (4.0 plus or minus 0.5) x 10 to the minus 7th cu cm/sec measured in this experiment, implying that CO2(+) dissociative recombination will contribute significantly to the excitation of the CO fourth positive system in the Martian airglow. Corroborative electron heating experiments showed that the magnitude of the specific recombination coefficient decreased as the electron temperature was increased. Evidence was also found for the presence of vibrationally excited ions in the CO2(+) plasma, a result which indicates that analogous laboratory studies on the dissociative recombination of O2(+), N2(+), and NO(+) ions may have also involved vibrationally hot plasmas.

Gutcheck, R. A.↗
NASA NTRS1973

Organic analysis of lunar samples and the Martian surface.

In addition to the organogenic elements (H, C, N, O, S, P) which are necessary for the synthesis of organic molecules, the lunar samples from Apollo 11, 12, 14, and 15 contain substantial amounts of CO, N2, and CO2 which are released at relatively high temperatures and smaller amounts of more complex organic compounds (e.g., benzene). The lunar surface provides one of the less favorable solar system models for the synthesis of organic compounds; yet small amounts of these compounds have been detected in the returned samples. It is reasonable to assume that the different physical and developmental features of the planet Mars (increased gravitational field, presence of an atmosphere with CO2, CO, and H2O, recent volcanic and tectonic activity, etc.) would favor an increased organic content of the surface of this planet relative to the moon. Therefore the organic molecules present in the Martian soil should be measurable by miniaturized mass spectrometers after fractional distillation or gas chromatographic separation of the volatiles released by moderate heating.

Oro, J.↗
NASA NTRS1973

High latitude minor ion enhancements: A clue for studies of magnetosphere-atmosphere coupling

Unexpectedly abrupt and pronounced distributions of the thermal molecular ions NO(+), O2(+) and N2(+) were observed at mid and high latitudes by the OGO-6 ion mass spectrometer. These minor ions may reach concentration levels exceeding 1000 ions/cu cm at altitudes as great as 1000 km, suggestive of scale heights well in excess of those inferred from low and mid-latitude measurements, under relatively undisturbed conditions. The high latitude ion enhancements were observed to be narrowly defined in time and space, with molecular ion concentrations changing by as much as an order of magnitude between successive orbits.

Taylor, H. A., Jr.↗
NASA NTRS1973

Fundamental study of transpiration cooling

Isothermal and non-isothermal pressure drop data and heat transfer data generated on porous 304L stainless steel wire forms, sintered spherical stainless steel powder, and sintered spherical OFHC copper powder are reported and correlated. Pressure drop data was collected over a temperature range from 500 R to 2000 R and heat transfer data collected over a heat flux range from 5 to 15 BTU/in2/sec. It was found that flow data could be correlated independently of transpirant temperature and type (i.e., H2, N2). It was also found that no simple relation between heat transfer coefficient and specimen porosity was obtainable.

Koh, J. C. Y.↗
NASA NTRS1972

Computed linewidths of SO2

Self-broadened and foreign-gas (N2 and O2) broadened linewidths of sulfur dioxide, for both type A and type B bands, have been calculated using the Anderson-Tsao-Curnutte theory of line broadening. Computed values of these linewidths at 300 K are given for all the transitions with J or = 20 and K sub minus 1 or = 15. Air-broadened linewidths have also been calculated for SO2 at 250 K and 200 K for these transitions.

Tejwani, G. D. T.↗
NASA NTRS1973

Recombination in radar meteors

Recombinations in the ionized columns generated by faint radar meteors are observed as: (1) A rapid loss of returned signal in the first few milliseconds after formation of the column; (2) an apparent absence of bright, low meteors; and (3) anomalies in apparent diffusion rates. Recombination at rates characteristic of dissociative recombination of ionized atmospheric molecules N2(+) and O2(+) is completely consistent with the observations. It appears either that the molecules are ionized in the initial formation of the ionized column or that there is rapid charge exchange. Recombination is a sufficient cause for the differences between diffusion measures and other atmospheric studies.

Southworth, R. B.↗
NASA NTRS1973

Laboratory determination of the luminous efficiency of meteor constituents

A crossed beam apparatus has been used to measure the emission and ionization cross sections for the prominent spectral features of Na, Ca, Mg, and Fe in collisions with N2 and O2 over the velocity range of 30 to 120 km/s. From the emission and ionization cross sections, the absolute luminous efficiencies in air were determined over the range of meteor velocities. The maximum luminous efficiencies for the brightest features were: greater than 1 percent for the Na D-lines, 0.2 percent for the Ca I(2) singlet, 0.06 percent for the Mg I(2) and Mg I(3) triplets, and 0.4 percent for Fe over the visible spectral range. These luminous efficiencies are valid for free molecular flow conditions for velocities above about 30 km/s and are directly applicable to spectroscopic observations of faint meteors. In contrast to previous work, the luminous efficiency found for stone in the present investigation decreased with velocity above about 50 km/s.

Savage, H. F.↗
NASA NTRS1974

Blowoff and escape of H2

It is shown that a pure hydrogen atmosphere cannot be retained by Titan, but will blow off in a few hours. Addition of a heavier gas, such as CH4 or N2, in comparable abundance gives a great improvement, although the escape rate can still be large. Moreover, the actual flux can be predicted with confidence from the mixing ratio of H2 to heavy gas.

Hunten, D. M.↗
NASA NTRS1973

Time-resolved spectroscopic measurements behind incident and reflected shock waves in air and xenon

Time-resolved spectra have been obtained behind incident and reflected shock waves in air and xenon at initial pressures of 0.1 and 1.0 torr using a rotating drum spectrograph and the OSU (The Ohio State University) arc-driven shock tube. These spectra were used to determine the qualitative nature of the flow as well as for making estimates of the available test time. The (n+1,n) and (n,n) band spectra of N2(+) (1st negative) were observed in the test gas behind incident shock waves in air at p1=1.0 torr and Us=9-10 km/sec. Behind reflected shock waves in air, the continuum of spectra appeared to cover almost the entire wavelength of 2,500-7,000 A for the shock-heated test gas. For xenon, the spectra for the incident shock wave cases for p1=0.1 torr show an interesting structure in which two intensely bright regions are witnessed in the time direction. The spectra obtained behind reflected shock waves in xenon were also dominated by continuum radiation but included strong absorption spectra due to FeI and FeII from the moment the reflected shock passed and on.

Yoshinaga, T.↗