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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 991 records · Page 55

Territorial Economic Impact Index: Measuring the ongoing effects of long-term disruptions to Pacific Island Territories

The Territorial Economic Impact Index (TEII) estimates the change in overall territory-level economic activity during the COVID-19 pandemic relative to January 2020. It shows which Pacific Island Territories may be more susceptible to large reductions in economic activity compared to normal conditions by looking at which industries make up each territory’s economy and then tracking monthly changes in industry employment at the U.S. national level. Economic activity in the TEII is measured by the total value added of all industries within the territory. Territories with economic activities dominated by industries experiencing rising unemployment can expect larger direct impacts to their local economies, particularly if the industries account for a large portion of the economic output of that county. Results are available for all three Pacific Island Territories: American Samoa, Guam, and the Commonwealth of the Northern Mariana Islands.

99 GENERAL AND MISCELLANEOUS↗

Predicting Switchgrass Biomass Yields Using a Spectral Vegetation Index Derived from Multispectral Satellite Imagery

Successful scaling of perennial bioenergy crop production requires a landscape design that optimizes the benefits of finite lands for people, communities, and environments. Utilizing marginal areas is the key to sustainable bioenergy crop production (Ssegane et al., 2015, 2016). Marginal areas are often small-sized lands and unevenly distributed across the agricultural landscape (Ssegane et al., 2016); thus, a systematic, semi-automated remote sensing method is needed as an effective means of estimating bioenergy crop yields across landscapes. Argonne National Laboratory (Argonne) is currently developing a tool, Scaling Up Perennial Bioenergy Economics and Ecosystem Services Tool (SUPERBEEST), to identify marginal agricultural lands and quantify environmental and economic effects of perennial bioenergy crop production systems. The tool aims to provide users a path to foster the sustainable and productive integration of bioenergy crops in the Midwestern agricultural landscape. Reliable, cost-effective, and timely estimation of bioenergy crop yields using remote sensing would help calculate and track the success of integrated bioenergy crops in the landscape for those communities. Argonne previously conducted feasibility studies for estimating biomass yields for bioenergy feedstock, corn and perennial grass using spectral vegetation indices (SVIs)1 derived from optical imagery (Hamada et al., 2015, 2021). In both studies, SVIs, more specifically those sensitive to plant chlorophyll or nitrogen contents, showed potential for estimating or predicting biomass yields with a correlation of determination (R2) ranging from 0.54 to 0.96, indicating a value for further investigation as a viable means of quantifying bioenergy feedstock production across large landscapes. Thus, the goal of this study is to evaluate the feasibility of use of SVIs as a means of estimating or predicting switchgrass biomass yields at harvest using publicly available multispectral satellite imagery. The feasibility analysis was performed using four study areas of mature switchgrass located in Virginia. Objectives are to (1) examine the SVIs and establish their relationships with switchgrass biomass yields at harvest, (2) develop a parsimonious image processing model for predicting at-harvest yields by applying the relationships with the most promising spectral index and (3) map switchgrass yields predicted by the image processing model across the study sites. The calibration to field data will rely on switchgrass biomass yields determined by the baling method, representing a potential challenge to the analysis but an important practical aspect for future applications. With this research design, the study aimed to gain insights into enabling remote sensing-based estimation of bioenergy crop yields in a reliable, cost- effective, and timely manner across large, heterogeneous landscapes.

09 BIOMASS FUELS↗

Temperature dependent index of refraction compensation and radiation resistance in monolithic optical systems

Monolithic catadioptric optical systems are susceptible to defocus errors caused by inhomogeneous temperature within the glass material due to temperature dependent index of refraction. This invention discloses methods to mitigate these errors using tuned materials in its optical design coupled with active optical radiative heating to provide optimal performance and includes methods to enhance radiation resistance.

36 MATERIALS SCIENCE↗

Computational Determination of the Refractive Index of TATB, LLM-105, β-HMX, & α-RDX

In this study, we use Materials Studio CASTEP, an ab initio quantum mechanical (QM) program employing density functional theory (DFT), to compute the refractive index (RI) of solid energetic materials, specifically, PETN (tetragonal phase), TATB, LLM-105, β-HMX, and α-RDX. The use of quantum mechanical DFT methods affords the investigation of the optical mate rial properties of a system without the need for any experimental input. The RI values of PETN and TATB have been experimentally determined previously and are compared here to the QM derived RI values as validation of the theoretical approach in determining material optical proper ties. To date, experimental measurements to determine the RI values for LLM-105 have yet to be determined. This fact obviates the need to determine LLM-105 RI values using quantum mechanical means.

36 MATERIALS SCIENCE↗

Predicting Selective Laser Printing Print Quality of Polymer Powders through Melt Flow Index

Selective Laser Sintering (SLS) uses a precisely controlled laser to fuse polymer powder to build complex 3D shapes. While SLS covers a wide application space, the processing knowledge of polymer powder is limited, restricting the number of commercial powders available. This study serves to expand the processing knowledge of polypropylene and polyethylene in parallel with a “mature” SLS feedstock, nylon, through melt flow index (MFI) characterization. Differential Scanning Calorimetry (DSC) was used to explore the sintering window of the polymers. Polyethylene and polypropylene exhibited a relatively narrow sintering window between 4 – 5 °C, whereas the sintering window of nylon was much wider, between 23 – 24 °C. This suggests that the print quality between polyethylene and polypropylene would be similar; however, X-ray computed tomography revealed a higher volume of print defects, voids, and de lamination in polyethylene than in polypropylene. MFI analysis provided additional insight into the difference in print quality, as the MFI of polyethylene was 7.16 g/10 min, 9.95 g/10 min for polypropylene, and 17.23 g/10 min for nylon. MFI is inversely correlated to melt viscosity, and a low melt viscosity is desired for proper coalescing between the layers and particles. These results suggest that MFI is a promising tool, in conjunction with traditional thermal analysis, for screening candidate powder feedstocks for SLS and optimization of print parameters for novel powders.

36 MATERIALS SCIENCE↗

National Park Air Quality Index Dataset

The National Park Air Quality Index dataset (NPS-AQI) consists of webcam images taken from the National Park Service's publicly available air quality web cameras and associated measurements for air pollutants, AQI, and meteorological data obtained via the publicly available NPS Gaseous Pollutant Monitoring Program. The full dataset is a collection of 146,822 images paired with air quality measurements. The specific measurements reported are: ozone ppm, 8-hour running average ozone ppm, so2 ppm, AQI (derived from ozone), temperature, and humidity. The images are 1500X1000 pixel PNG files arranged into folders by NPS site and named according to the time and date the image was taken. There are three CSV files (representing "training", "validation", and "testing" images splits) containing image names and associated NPS site names, air pollutant measurements, and meteorlogical data.

Svinth, Christian N↗

Simulated Changes in Tropical Cyclone Size, Accumulated Cyclone Energy and Power Dissipation Index in a Warmer Climate

Detection, attribution and projection of changes in tropical cyclone intensity statistics are made difficult from the potentially decreasing overall storm frequency combined with increases in the peak winds of the most intense storms as the climate warms. Multi-decadal simulations of stabilized climate scenarios from a high-resolution tropical cyclone permitting atmospheric general circulation model are used to examine simulated global changes from warmer temperatures, if any, in estimates of tropical cyclone size, accumulated cyclonic energy and power dissipation index. Changes in these metrics are found to be complicated functions of storm categorization and global averages of them are unlikely to easily reveal the impact of climate change on future tropical cyclone intensity statistics.

Wehner, Michael (ORCID:0000000159910082)↗

Liquid Chromatography Coupled to Refractive Index or Mass Spectrometric Detection for Metabolite Profiling in Lysate-based Cell-free Systems

Engineering cellular metabolism for targeted biosynthesis can require extensive design-build-test-learn (DBTL) cycles as the engineer works around the cell's survival requirements. Alternatively, carrying out DBTL cycles in cell-free environments can accelerate this process and alleviate concerns with host compatibility. A promising approach to cell-free metabolic engineering (CFME) leverages metabolically active crude cell extracts as platforms for biomanufacturing and for rapidly discovering and prototyping modified proteins and pathways. Realizing these capabilities and optimizing CFME performance requires methods to characterize the metabolome of lysate-based cell-free platforms. That is, analytical tools are necessary for monitoring improvements in targeted metabolite conversions and in elucidating alterations to metabolite flux when manipulating lysate metabolism. In this work, metabolite analyses using high-performance liquid chromatography (HPLC) coupled with either optical or mass spectrometric detection were applied to characterize metabolite production and flux in E. coli S30 lysates. Specifically, this report describes the preparation of samples from CFME lysates for HPLC analyses using refractive index detection (RID) to quantify the generation of central metabolic intermediates and by-products in the conversion of low-cost substrates (i.e., glucose) to various high-value products. The analysis of metabolite conversion in CFME reactions fed with 13 C-labeled glucose through reversed-phase liquid chromatography coupled to tandem mass spectrometry (MS/MS), a powerful tool for characterizing specific metabolite yields and lysate metabolic flux from starting materials, is also presented. Altogether, applying these analytical methods to CFME lysate metabolism enables the advancement of these systems as alternative platforms for executing faster or novel metabolic engineering tasks.

59 BASIC BIOLOGICAL SCIENCES↗

ON THE NONTHERMAL κ-DISTRIBUTED ELECTRONS IN PLANETARY NEBULAE AND H ii REGIONS: THE κ INDEX AND ITS CORRELATIONS WITH OTHER NEBULAR PROPERTIES

Recently, a suspicion arose that the free electrons in planetary nebulae (PNs) and H ii regions might have nonthermal energy distributions. In this scenario, a κ index is introduced to characterize the electron energy distributions, with smaller κ values indicating larger deviations from Maxwell–Boltzmann distributions. Assuming that this is the case, we determine the κ values for a sample of PNs and H ii regions by comparing the intensities of [O iii] collisionally excited lines and the hydrogen Balmer jump. We find the average κ indices of PNs and H ii regions to be 27 and 32, respectively. Correlations between the resultant κ values and various physical properties of the nebulae are examined to explore the potential origin of nonthermal electrons in photoionized gaseous nebulae. However, no positive result is obtained. Thus, the current analysis does not lend support to the idea that κ-distributed electrons are present in PNs and H ii regions.

79 ASTRONOMY AND ASTROPHYSICS↗

STELLAR ATMOSPHERES, ATMOSPHERIC EXTENSION, AND FUNDAMENTAL PARAMETERS: WEIGHING STARS USING THE STELLAR MASS INDEX

One of the great challenges of understanding stars is measuring their masses. The best methods for measuring stellar masses include binary interaction, asteroseismology, and stellar evolution models, but these methods are not ideal for red giant and supergiant stars. In this work, we propose a novel method for inferring stellar masses of evolved red giant and supergiant stars using interferometric and spectrophotometric observations combined with spherical model stellar atmospheres to measure what we call the stellar mass index, defined as the ratio between the stellar radius and mass. The method is based on the correlation between different measurements of angular diameter, used as a proxy for atmospheric extension, and fundamental stellar parameters. For a given star, spectrophotometry measures the Rosseland angular diameter while interferometric observations generally probe a larger limb-darkened angular diameter. The ratio of these two angular diameters is proportional to the relative extension of the stellar atmosphere, which is strongly correlated to the star’s effective temperature, radius, and mass. We show that these correlations are strong and can lead to precise measurements of stellar masses.

79 ASTRONOMY AND ASTROPHYSICS↗

RELATIONSHIP BETWEEN DISTRIBUTION OF MAGNETIC DECAY INDEX AND FILAMENT ERUPTIONS

The decay index n of a horizontal magnetic field is considered to be an important parameter in judging the stability of a flux rope. However, the spatial distribution of this parameter has not been extensively explored so far. In this paper, we present a delineative study of the three-dimensional maps of n for two eruptive events, in which filaments underwent asymmetrical eruptions. The corresponding n -distributions are both found to show that the filaments tend to erupt at abnormal regions (dubbed ABN regions) of n . These ABN regions appear to be divided into two subregions, with larger and smaller n . Moreover, an analysis of the magnetic topological configuration of the ABN regions has been also performed. The results indicate that these ABN regions are associated with a kind of special quasi-separatrix layer across which the connectivity of magnetic field is discontinuous. The presented observations and analyses strongly suggest that the torus instability in ABN regions may play a crucial role for the triggering of an asymmetrical eruption. Additionally, our investigation can provide a way of forecasting how a filament might erupt, and predicting the location for an asymmetrically eruptive filament to be split through analyzing the spatial structure of n .

79 ASTRONOMY AND ASTROPHYSICS↗

Estimation of mass of compact object in H 1743-322 from 2010 and 2011 outbursts using TCAF solution and spectral index–QPO frequency correlation

The well-known black hole candidate (BHC) H 1743-322 exhibited temporal and spectral variabilities during several outbursts. The variation of the accretion rates and flow geometry that change on a daily basis during each of the outbursts can be very well understood using the recent implementation of the two-component advective flow solution of the viscous transonic flow equations as an additive table model in XSPEC. This has dramatically improved our understanding of accretion flow dynamics. Most interestingly, the solution allows us to treat the mass of the BHC as a free parameter and its mass could be estimated from spectral fits. In this paper, we fitted the data of two successive outbursts of H 1743-322 in 2010 and 2011 and studied the evolution of accretion flow parameters, such as two-component (Keplerian and sub-Keplerian) accretion rates, shock location (i.e., size of the Compton cloud), etc. We assume that the model normalization remains the same across the states in both these outbursts. We used this to estimate the mass of the black hole and found that it comes out in the range of 9.25--12.86 M{sub ⊙}. For the sake of comparison, we also estimated mass using the Photon index versus Quasi Periodic Oscillation frequency correlation method, which turns out to be 11.65±0.67 M{sub ⊙} using GRO J1655-40 as a reference source. Combining these two estimates, the most probable mass of the compact object becomes 11.21{sub −1.96}{sup +1.65} M{sub ⊙}.

79 ASTRONOMY AND ASTROPHYSICS↗

Particle Matter Index and Fuel Wall-wetting Relations on Stochastic Pre-ignition

This works explores the effect of the particle matter index (PMI) and aromatic content on fuel wall impingement and associated stochastic pre-ignition (SPI) propensity. Statically significant measurements of SPI rates are directly coupled with laser induced florescence (LIF) measurements of fuel dilution from spray-linear impingement. Literature suggests that PMI is could be correlated with the number of SPI events, but the root cause(s) of PMI and SPI are directly causational or are a predicator of SPI. Three fuels have been used in this study with 3 different PMI and two different aromatic contents. These fuels are direct injected at two different injection timings, an earlier injection timing which targets the piston crown, 310°CA bTDC, and a later injection timing that the linear, 220°CA bTDC start of injection timings (SOI) respectively. The earlier 310 SOI injection increases soot, whereas the later 220°CD SOI targets the linear and increases wall-wetting. The findings of this work highlight that the SPI activity has a weak correlation with the soot promoted by the combustion process and increased PMI. However, SPI activity shows a strong dependency with high levels of oil dilution and aromatic content, suggesting that PMI might be an indicator of fuel chemistry conducive to SPI and the soot form increased PMI fuels is not a strong source of SPI relative to fuel wall wetting.

42 ENGINEERING↗

Projections of leaf area index in earth system models

The area of leaves in the plant canopy, measured as leaf area index (LAI), modulates key land–atmosphere interactions, including the exchange of energy, moisture, carbon dioxide (CO 2 ), and other trace gases and aerosols, and is therefore an essential variable in predicting terrestrial carbon, water, and energy fluxes. Here our goal is to characterize the LAI projections from the latest generation of earth system models (ESMs) for the Representative Concentration Pathway (RCP) 8.5 and RCP4.5 scenarios. On average, the models project increases in LAI in both RCP8.5 and RCP4.5 over most of the globe, but also show decreases in some parts of the tropics. Because of projected increases in variability, there are also more frequent periods of low LAI across broad regions of the tropics. Projections of LAI changes varied greatly among models: some models project very modest changes, while others project large changes, usually increases. Modeled LAI typically increases with modeled warming in the high latitudes, but often decreases with increasing local warming in the tropics. The models with the most skill in simulating current LAI in the tropics relative to satellite observations tend to project smaller increases in LAI in the tropics in the future compared to the average of all the models. Using LAI projections to identify regions that may be vulnerable to climate change presents a slightly different picture than using precipitation projections, suggesting LAI may be an additional useful tool for understanding climate change impacts. Going forward, users of LAI projections from the CMIP5 ESMs evaluated here should be aware that model outputs do not exhibit clear-cut relationships to vegetation carbon and precipitation. Lastly, our findings underscore the need for more attention to LAI projections, in terms of understanding the drivers of projected changes and improvements to model skill.

54 ENVIRONMENTAL SCIENCES↗

WIND Toolkit Power Data Site Index

This spreadsheet contains per-site metadata for the WIND Toolkit sites and serves as an index for the raw data hosted on Globus connect (nrel#globus:/globusro/met_data). Aside from the metadata, per site average power and capacity factor are given. This data was prepared by 3TIER under contract by NREL and is public domain. Authoritative documentation on the creation of the underlying dataset is at: Final Report on the Creation of the Wind Integration National Dataset (WIND) Toolkit and API: http://www.nrel.gov/docs/fy16osti/66189.pdf

17 WIND ENERGY↗