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At least 991 records · Page 55

An Integrated Multiscale Experimental-Numerical Analysis on Reconsolidation of Salt-Clay Mixture for Disposal of Heat-Generating Waste (Final NEUP Technical Report)

The overall purpose of this research is to improve understanding of THMC coupling effect on the reconsolidation of granular (or crushed) salt-clay mixture used for seal systems of shafts and drifts in salt repositories. This proposed work is partially motivated by the recent work on the Waste Isolation Pilot Plant (WIPP) that shows the promising sealing capability of clay-salt mixture compared to crushed salt. In particular, primary emphasis is to develop a fully integrated multiscale experiment-numerical study to determine and explain what leads to the superior sealing ability of the clay-salt mixture. These research activities are designed to seek further understanding of (1) why clay additives may enhance the fluid trapping and (2) whether this flow barrier effect may prevail under different combinations of temperature, confining pressure, deviatoric stress and other foreseeable environmental factors. If successful, this enhanced flow trapping ability of the seal provides significant improvement to the seal and repository performance and therefore make the repository safer in the long-term. The experiment component includes microstructural investigation and macroscopic tests on a reconsolidated salt-clay mixture. In the microstructural study, the goal is to (1) characterize microscopic distributions of distinct phases (e.g., clay, salt crystal boundaries, trapped brine, and pore) to examine the connectivity of the pore network inside the salt-clay mixture with different amounts of clay additive and moisture content and (2) analyze multiscale imaging data to reconstruct the polycrystalline microstructures for numerical simulations. Meanwhile, macroscopic tests are performed to analyze how clay alters the failure/creep mechanisms in the salt-clay mixture. Microscopic and macroscopic experimental observations will both be used to calibrate and validate a multiscale model that explicitly simulates the capillary and multiphase flow in the connected pores and the deformation due to the presence of intra-crystalline brine at the pore scale via a new polyhedral discrete element–lattice Boltzmann method (DEM-LBM) coupling model. The pore-scale simulations are homogenized via an upscaling procedure that converts pore-scale information (e.g. force exerted on grain boundary, sliding, pressure-solution) to continuum measures (e.g. Cauchy stress, Darcy’s flow) at each integration point in the macroscopic multiphase TMHC model. This multiscale scheme will allow coupling be- tween high-fidelity simulations of brine-salt-clay interaction and the macroscopic TMHC model. The multiscale model helps the understanding of how the trapped brine inclusion affects the pressure-solution mechanism with the presence of clay and moisture. This work brings new insight into the sealing capacity of salt-clay mixture under elevated temperature over a long period of time - a key to evaluating the potential of salt-clay mixture usage for salt repositories.

42 ENGINEERING↗

Threading–Unthreading Transition of Linear-Ring Polymer Blends in Extensional Flow

Adding small amounts of ring polymers to a matrix of their linear counterparts is known to increase the zero-shear-rate viscosity because of linear-ring threading. Uniaxial extensional rheology measurements show that, unlike its pure linear and ring constituents, the blend exhibits an overshoot in the stress growth coefficient. By combining these measurements with ex-situ small-angle neutron scattering and nonequilibrium molecular dynamics simulations, this overshoot is shown here to be driven by a transient threading–unthreading transition of rings embedded within the linear entanglement network. Prior to unthreading, embedded rings deform affinely with the linear entanglement network and produce a measurably stronger elongation of the linear chains in the blend compared to the pure linear melt. Thus, rings uniquely alter the mechanisms of transient elongation in linear polymers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The cerebrospinal fluid proteome in HIV infection: change associated with disease severity.

Central nervous system (CNS) infection is a constant feature of systemic HIV infection with a clinical spectrum that ranges from chronic asymptomatic infection to severe cognitive and motor dysfunction. Analysis of cerebrospinal fluid (CSF) has played an important part in defining the character of this evolving infection and response to treatment. To further characterize CNS HIV infection and its effects, we applied advanced high-throughput proteomic methods to CSF to identify novel proteins and their changes with disease progression and treatment. After establishing an accurate mass and time (AMT) tag database containing 23,141 AMT tags for CSF peptides, we analyzed 91 CSF samples by LC-MS from 12 HIV-uninfected and 14 HIV-infected subjects studied in the context of initiation of antiretroviral and correlated abundances of identified proteins (a) within and between subjects, (b) with all other proteins across the entire sample set, and (c) with 'external' CSF biomarkers of infection (HIV RNA), immune activation (neopterin) and neural injury (neurofilament light chain protein, NFL). We identified a mean of 2,333 +/- 328 (SD) peptides covering 307 +/-16 proteins in the 91 CSF sample set. Protein abundances differed both between and within subjects sampled at different time points and readily separated those with and without HIV infection. Proteins also showed inter-correlations across the sample set that were associated with biologically relevant dynamic processes. One-hundred and fifty proteins showed correlations with the external biomarkers. For example, using a threshold of cross correlation coefficient (Pearson's) {le}0.3 and {ge}0.3 for potentially meaningful relationships, a total of 99 proteins correlated with CSF neopterin (43 negative and 56 positive correlations) and related principally to neuronal plasticity and survival and to innate immunity. Pathway analysis defined several networks connecting the identified proteins, including one with amyloid precursor protein as a central node. Advanced CSF proteomic analysis enabled the identification of an array of novel protein changes across the spectrum of CNS HIV infection and disease. This initial analysis clearly demonstrated the value of contemporary state-of-the-art proteomic CSF analysis as a discovery tool in HIV infection with likely similar application to other neurological inflammatory and degenerative diseases.

59 BASIC BIOLOGICAL SCIENCES↗

Long-Period, Long-Duration Seismic Events and Their Probable Role in Reservoir Stimulation and Stage Productivity

Hydraulic fracturing is a well-established technique to extract gas or liquid hydrocarbons from low-permeability formations like shale and tight gas reservoirs. Diffusion of hydrofracturing fluid outward from the stimulated fractures into the target formation produces slip across preexisting fractures and other discontinuities in the rock. Microseismic events recorded by downhole seismic monitoring arrays are a manifestation of associated deformation. Recent investigations suggest that the total cumulative seismic moment of microearthquakes during hydraulic fracturing is only a small portion of the total seismic energy release expected for the fluid volume injected into the formation. These observations suggest that other sources of energy release (such as inelastic deformation), contemporaneous with microseismicity, should be considered as relevant to the hydraulic fracturing process. Recent observations on long period, long duration (LPLD) seismic events suggest that slow slip emission along weaknesses that are misaligned with respect to the present-day stress field are likely an important mechanism of deformation and should be better understood and quantified in reservoir stimulations. In Morgantown, West Virginia, we carried out seismic monitoring of hydraulic fracturing activity using an array of five broadband, three-component surface seismometers. Using this network, we identified 89 high-amplitude, impulsive events and 436 long period, long duration (LPLD) events, with highly emergent waveform characteristics. In these interpreted LPLD events, we observed a significant concentration of energy in the 0.8-3 Hz frequency range. During hydraulic fracturing, LPLD events were found to occur most frequently when the pumping pressure and rate were at or near maximum values. As the main purpose of hydraulic fracturing is to stimulate oil and gas production from the less permeable reservoir, we compared the relative production contribution per stage to the frequency of occurrence of suspected LPLD events. We found positive correlation between the frequency of LPLD events and stage-by-stage gas production, highlighting the potential contribution of slow deformation processes and its effectiveness in the reservoir stimulation.

58 GEOSCIENCES↗

Calcium silicate ceramic scaffolds toughened with hydroxyapatite whiskers for bone tissue engineering

Calcium silicate possessed excellent biocompatibility, bioactivity and degradability, while the high brittleness limited its application in load-bearing sites. Hydroxyapatite whiskers ranging from 0 to 30 wt.% were incorporated into the calcium silicate matrix to improve the strength and fracture resistance. Porous scaffolds were fabricated by selective laser sintering. The effects of hydroxyapatite whiskers on the mechanical properties and toughening mechanisms were investigated. The results showed that the scaffolds had a uniform and continuous inner network with the pore size ranging between 0.5 mm and 0.8 mm. The mechanical properties were enhanced with increasing hydroxyapatite whiskers, reached a maximum at 20 wt.% (compressive strength: 27.28 MPa, compressive Young's modulus: 156.2 MPa, flexural strength: 15.64 MPa and fracture toughness: 1.43 MPa·m{sup 1/2}) and then decreased by addition of more hydroxyapatite whiskers. The improvement of mechanical properties was due to whisker pull-out, crack deflection and crack bridging. Moreover, the degradation rate decreased with the increase of hydroxyapatite whisker content. A layer of bone-like apatite was formed on the scaffold surfaces after being soaked in simulated body fluid. Human osteoblast-like MG-63 cells spread well on the scaffolds and proliferated with increasing culture time. These findings suggested that the calcium silicate scaffolds reinforced with hydroxyapatite whiskers showed great potential for bone regeneration and tissue engineering applications. - Highlights: • HA whiskers were incorporated into CS to improve the properties. • The scaffolds were successfully fabricated by SLS. • Toughening mechanisms was whisker pull-out, crack deflection and bridging. • The scaffolds showed excellent apatite forming ability.

36 MATERIALS SCIENCE↗

Effects of hydration on fractures and shale permeability under different confining pressures: An experimental study

Water-rich fracturing fluids are injected into gas shale formations to promote the effective development of gas. However, the relationship between gas production decreases and the variability flow-back fluid behavior (rate and amount) remains a significant challenge to the industry. This study focused on the effects of water hydration on the rock fracture properties of a major gas shale formation in China. Shale from hydration experiments was characterized for a number of key parameters including length, volume, width, surface area, thickness and fracture frequency. X-ray computed tomography (CT) scanning was conducted on shale reservoir samples exposed to water at zero overburden stress and under three different confining pressures (725 psi, 2175 psi, and 2900 psi). CT scanning images were obtained to evaluate fracture evolutions during hydration for both the connected and unconnected fracture networks. In addition, permeabilities before and after hydration were also quantified. Results from the ambient condition experiment revealed the propagation of fractures, the formation of new fractures, and the formation of better connectivity caused by a more complicated fracture network. However, the fracture evolution of the other three samples under confining pressures are markedly different, including: more unconnected fracture networks, less fracture volume, and a poorer connectivity of fractures.

bio-inspired, mechanical behavior, carbon sequestr↗

Programming the Navier-Stokes computer: An abstract machine model and a visual editor

The Navier-Stokes computer is a parallel computer designed to solve Computational Fluid Dynamics problems. Each processor contains several floating point units which can be configured under program control to implement a vector pipeline with several inputs and outputs. Since the development of an effective compiler for this computer appears to be very difficult, machine level programming seems necessary and support tools for this process have been studied. These support tools are organized into a graphical program editor. A programming process is described by which appropriate computations may be efficiently implemented on the Navier-Stokes computer. The graphical editor would support this programming process, verifying various programmer choices for correctness and deducing values such as pipeline delays and network configurations. Step by step details are provided and demonstrated with two example programs.

Middleton, David↗

Visualization of unsteady computational fluid dynamics

The current computing environment that most researchers are using for the calculation of 3D unsteady Computational Fluid Dynamic (CFD) results is a super-computer class machine. The Massively Parallel Processors (MPP's) such as the 160 node IBM SP2 at NAS and clusters of workstations acting as a single MPP (like NAS's SGI Power-Challenge array) provide the required computation bandwidth for CFD calculations of transient problems. Work is in progress on a set of software tools designed specifically to address visualizing 3D unsteady CFD results in these super-computer-like environments. The visualization is concurrently executed with the CFD solver. The parallel version of Visual3, pV3 required splitting up the unsteady visualization task to allow execution across a network of workstation(s) and compute servers. In this computing model, the network is almost always the bottleneck so much of the effort involved techniques to reduce the size of the data transferred between machines.

Haimes, Robert↗

Learning nonlinear level sets for dimensionality reduction in function approximation

We developed a Nonlinear Level-set Learning (NLL) method for dimensionality reduction in high-dimensional function approximation with small data. This work is motivated by a variety of design tasks in real-world engineering applications, where practitioners would replace their computationally intensive physical models (e.g., high-resolution fluid simulators) with fast-to-evaluate predictive machine learning models, so as to accelerate the engineering design processes. There are two major challenges in constructing such predictive models: (a) high-dimensional inputs (e.g., many independent design parameters) and (b) small training data, generated by running extremely time-consuming simulations. Thus, reducing the input dimension is critical to alleviate the over-fitting issue caused by data insufficiency. Existing methods, including sliced inverse regression and active subspace approaches, reduce the input dimension by learning a linear coordinate transformation; our main contribution is to extend the transformation approach to a nonlinear regime. Specifically, we exploit reversible networks (RevNets) to learn nonlinear level sets of a high-dimensional function and parameterize its level sets in low-dimensional spaces. A new loss function was designed to utilize samples of the target functions' gradient to encourage the transformed function to be sensitive to only a few transformed coordinates. The NLL approach is demonstrated by applying it to three 2D functions and two 20D functions for showing the improved approximation accuracy with the use of nonlinear transformation, as well as to an 8D composite material design problem for optimizing the buckling-resistance performance of composite shells of rocket inter-stages.

Zhang, Guannan↗

Core Angular Momentum and the IERS Sub-Centers Activity for Monitoring Global Geophysical Fluids: Core Angular Momentum and Earth Rotation - Part 1

The part of the grant was to use recordings of seismic waves travelling through the earth's core (PKP waves) to study the inner core rotation and constraints on possible density anomalies in the fluid core. The shapes and relative arrival times of such waves associated with a common source were used to reduce the uncertainties in source location and excitation and the effect of unknown mantle structure. The major effort of the project is to assemble historical seismograms with long observing base lines. We have found original paper records of SSI earthquakes at COL between 1951 and 1966 in a warehouse of the U.S. Geological Survey office in Golden, Colorado, extending the previous measurements at COL by Song and Richards [1996] further back 15 years. Also in Alaska, the University of Alaska, Fairbanks Geophysical Institute (UAFGI) has been operating the Alaskan Seismic Network with over 100 stations since the late 1960s. Virtually complete archives of seismograms are still available at UAFGI. Unfortunately, most of the archives are in microchip form (develocorders), for which the use of waveforms is impossible. Paper seismograms (helicorders) are available for a limited number of stations, and digital recordings of analog signals started around 1989. Of the paper records obtained, stations at Gilmore Dome (GLM, very close to COL), Yukon (FYU), McKinley (MCK), and Sheep Creek Mountain (SCM) have the most complete continuous recordings.

Song, Xia-Dong↗

Multi-resolution partial differential equations preserved learning framework for spatiotemporal dynamics

Traditional data-driven deep learning models often struggle with high training costs, error accumulation, and poor generalizability in complex physical processes. Physics-informed deep learning (PiDL) addresses these challenges by incorporating physical principles into the model. Most PiDL approaches regularize training by embedding governing equations into the loss function, yet this depends heavily on extensive hyperparameter tuning to weigh each loss term. To this end, we propose to leverage physics prior knowledge by “baking” the discretized governing equations into the neural network architecture via the connection between the partial differential equations (PDE) operators and network structures, resulting in a PDE-preserved neural network (PPNN). This method, embedding discretized PDEs through convolutional residual networks in a multi-resolution setting, largely improves the generalizability and long-term prediction accuracy, outperforming conventional black-box models. The effectiveness and merit of the proposed methods have been demonstrated across various spatiotemporal dynamical systems governed by spatiotemporal PDEs, including reaction-diffusion, Burgers’, and Navier-Stokes equations.

97 MATHEMATICS AND COMPUTING↗

Characterization of Acoustic Emissions From Analogue Rocks Using Sparse Regression‐DMDc

Abstract Moisture loss in rock is known to generate acoustic emissions (AE). Phenomena that result in AE during drying are related to the movement of fluids through the pores and induced‐cracks that arise from differential mineral shrinkage, especially in clay‐bearing rock. AE from the movement of fluids occurs from the reconfiguration of fluid interfaces during drying, while AE from mineral shrinkage involves the debonding within or between minerals. Here, analogue rock samples were used to examine the differences in the AE signatures when one or both AE source‐types are present. An unsupervised sparse regression model, Dynamic Mode Decomposition with control, that extends Dynamic Mode Decomposition is used to characterize the AE signals recorded during the drying of porous analogue rock samples fabricated with ordinary Portland cement, with and without clay. This method can effectively and accurately reconstruct acoustic signals emitted from samples that only experience moisture loss without cracking. However, the method struggles to reconstruct signals from samples with intricate crack networks that formed during drying because AE generating mechanisms can emit contemporaneously, and the resulting waves propagate through drying‐induced cracks that can lead to multiple internal reflections. Thus, the differential reconstruction accuracy of time series generated by different underlying physical processes provides a robust filter for reducing large data catalogs. In general, both dynamics and sparse initiating events are learned directly from data and this method exposes a data hierarchy based on the complexity of the intrinsic dynamics.

58 GEOSCIENCES↗

Monitoring Fracture Hydromechanical Evolution in the Lab and Field Using Unsupervised Metric Learning

Fractures evolve in time through thermal‐hydraulic‐mechanical‐chemical (THMC) processes that alter their long‐range hydraulic transport properties and modify subsurface behavior and activities. The location of subsurface fractures makes it necessary to use remote sensing techniques such as passive or active seismic monitoring for fracture characterization. In this paper, we develop a machine learning approach to monitor the evolution of fracture properties using passive seismic sources in a laboratory setting and using active seismic monitoring from the Sanford Underground Research Facility in Lead, South Dakota, at a depth of 1.25 km in amphibolite rock during stimulation of natural fractures as well as during induced fracturing. The unsupervised metric learning technique applies tandem neural networks (twin (Siamese) or triplet) with contrastive loss and adaptive margins to track slowly varying systems for which class or similarity labels are not available. The approach adopts locality‐sensitive hashing to divide time‐ordered contiguous data into an arbitrary number of pseudo‐classes. Contrastive‐loss training with many hash bins generates an evolving latent‐space trajectory. This approach enables unsupervised metric learning for seismic data stacks under the condition of contiguous state sampling and slowly varying fracture properties. The displacement discontinuity theory provides a mechanistic foundation for the fracture‐dependent trajectories that are related to relaxation of fractures with time‐dependent specific stiffness responding to changes in stress or fluid saturation.

02 PETROLEUM↗

SECARB Geochemical Data

Hydrotest, gas composition, injection fluid, mass spectrometer, and U-tube gas sample analysis data gathered during SECARB project at Cranfield oil site in Mississippi. Geochemical data collected as part of geologic characterization phase of SECARB. Associated Publications: Lu, J., Cook, P. J., Hosseini, S. A., Yang, C., Romanak, K. D., Zhang, T., Freifeld, B. M., Smyth, R. C., Zeng, H., and Hovorka, S. D., 2012, Complex fluid flow revealed by monitoring CO 2 injection in a fluvial formation: Journal of Geophysical Research, v. 117, B03208, doi:10.1029/2011JB008939. Lu, J., Kharaka, Y. K., Thordsen, J. J., Horita, J., Karamalidis, A., Griffith, C., Hakala, J. A., Ambats, G., Cole, D. R., Phelps, T. J., Manning, M. A., Cook, P. J., and Hovorka, S. D., 2012, CO 2 -rock-brine interactions in Lower Tuscaloosa Formation at Cranfield CO2 sequestration site, Mississippi, U.S.A.: Chemical Geology, v. 291, p. 269-277. Yang, C., Hovorka, S. D., Treviño, R. H., and Delgado-Alonso, J., 2015, Integrated framework for assessing impacts of CO 2 leakage on groundwater quality and monitoring-network efficiency: case study at a CO 2 enhanced oil recovery site: Environmental Science &Technology, v. 49, p. 8887–8898, doi:10.1021/acs.est.5b01574.

carbon capture and storage↗

Convection zone origins of solar atmospheric heating

Spicules are examined as a means for supplying the corona with mass, energy, and magnetic field. It is suggested that spicules form from the supersonic upward expansion of material on nearly evacuated network flux tubes embedded within the sun's convection zone. This allows supersonic but subescape velocities to be attained by the material as it flows outward through the photosphere. Although supersonic, the kinetic energy (subescape) of the spicule material, as observed, is insufficient for coronal heating. It is suggested that, through buoyancy changes on evacuated flux tubes, the magnetic field first 'wicks' material flow into the solar atmosphere. Subsequently, the magnetic field energizes the gaseous material to form the conventional hot, dynamically expanding, solar corona. This occurs through momentum and energy transport by Alfven waves and associated Maxwell stresses concurrently flowing upward on these 'geysers' (spicules). The vertical momentum equation governing fluid flow is examined, and a particular equipartition solution is presented for the flow velocity along a simple field geometry.

Schatten, Kenneth H.↗

Thermal and Fluid Modeling of the CRYogenic Orbital TEstbed (CRYOTE) Ground Test Article (GTA)

The purpose of this study was to anchor thermal and fluid system models to data acquired from a ground test article (GTA) for the CRYogenic Orbital TEstbed - CRYOTE. To accomplish this analysis, it was broken into four primary tasks. These included model development, pre-test predictions, testing support at Marshall Space Flight Center (MSFC} and post-test correlations. Information from MSFC facilitated the task of refining and correlating the initial models. The primary goal of the modeling/testing/correlating efforts was to characterize heat loads throughout the ground test article. Significant factors impacting the heat loads included radiative environments, multi-layer insulation (MLI) performance, tank fill levels, tank pressures, and even contact conductance coefficients. This paper demonstrates how analytical thermal/fluid networks were established, and it includes supporting rationale for specific thermal responses seen during testing.

Piryk, David↗

Examining Two-Phase Flow with Optical Sensors

In lieu of the events that occurred at Fukushima in 2011, passive safety shutdowns for nuclear reactors has become a focus area for recent research. At Argonne National Laboratory this research has been simulated using air as a means of cooling down a experimental reactor core. This operates on the principals of natural convection and can be further studied in the report devised by Lisowski et al. in 2014. The air reactor cavity cooling system (RCCS) at Argonne National Laboratory is currently being transitioned into a water cooled system for passive safety reactor shutdown systems. In this system eight water pipes (1.5'' schedule 160 stainless steel) will transfer heat by means of natural convection. However, the primary network pipe will be 4 inch schedule 40 stainless steel pipe. The adiabatic chimney portion of this piping segment will be under analysis for void fraction. Based on the internal temperature of the water pipes, the characteristic regimes of two-phase flow that could exist inside of the pipe are an area of interest for experimental analysis. Determining which phase the water exists is instrumental to understanding the state of the processes inside of the water cooling pipe. Knowledge of these states allows for analysis of the efficiency of the RCCS as it shuts down. The state of two-phase flow can be measured by the analysis of the fluids void fraction.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗