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NASA NTRS1986

Chemical Bonding Technology: Direct Investigation of Interfacial Bonds

This is the third Flat-Plate Solar Array (FSA) Project document reporting on chemical bonding technology for terrestrial photovoltaic (PV) modules. The impetus for this work originated in the late 1970s when PV modules employing silicone encapsulation materials were undergoing delamination during outdoor exposure. At that time, manufacturers were not employing adhesion promoters and, hence, module interfaces in common with the silicone materials were only in physical contact and therefore easily prone to separation if, for example, water were to penetrate to the interfaces. Delamination with silicone materials virtually vanished when adhesion promoters, recommended by silicone manufacturers, were used. The activities related to the direct investigation of chemically bonded interfaces are described.

Koenig, J. L.↗

NASA NTRS1986

The measurement of aircraft performance and stability and control after flight through natural icing conditions

The effects of airframe icing on the performance and stability and control of a twin-engine commuter-class aircraft were measured by the NASA Lewis Research Center. This work consisted of clear air tests with artificial ice shapes attached to the horizontal tail, and natural icing flight tests in measured icing clouds. The clear air tests employed static longitudinal flight test methods to determine degradation in stability margins for four simulated ice shapes. The natural icing flight tests employed a data acquisition system, which was provided under contract to NASA by Kohlman Systems Research Incorporated. This system used a performance modeling method and modified maximum likelihood estimation (MMLE) technique to determine aircraft performance degradation and stability and control. Flight test results with artificial ice shapes showed that longitudinal, stick-fixed, static margins are reduced on the order of 5 percent with flaps up. Natural icing tests with the KSR system corroborated these results and showed degradation in the elevator control derivatives on the order of 8 to 16 percent depending on wing flap configuration. Performance analyses showed the individual contributions of major airframe components to the overall degration in lift and drag.

Ranaudo, R. J.↗

NASA NTRS1986

Evolution of thiol protective systems in prokaryotes

Biological thiols are essential elements in most aspects of cell function but undergo rapid oxidation to disulfides in the presence of oxygen. The evolution of systems to protect against such oxygen toxicity was essential to the emergence of aerobic life. The protection system used by eukaryotes is based upon glutathione (GSH) and GSH-dependent enzymes but many bacteria lack GSH and apparently use other mechanisms. The objective of this research is to elaborate the thiol protective mechanisms employed by prokaryotes of widely divergent evolutionary origin and to understand why GSH became the central thiol employed in essentially all higher organisms. Thiol-selective fluorescent labeling and HPLC analysis has been used to determine key monothiol components.

Fahey, R. C.↗

NASA NTRS1986

Cosmic dust collection with a sub-satellite tethered to a space station

The number concentration and density of 1 micron and submicron sized grains in interplanetary space, as well as their relation to the larger zodical dust particles, and the importance of the Beta meteoroid phenomenon are currently being questioned. The best approach to collecting large numbers of intact micron and submicron sized cosmic dust particles in real time while avoiding terrestrial and man made contamination would be to employ a tethered subsatellite from a space station down into the Earth's atmosphere. Such a subsatellite tied to the space shuttle by a 100 km long tether is being developed. It is also possible that a permanent space station would allow the use of a tether even longer that 100 km. It should be noted that the same tethered collectors could also be employed to study the composition and flux of man made Earth orbiting debris in any direction within 100 km or so of the space station.

Corso, G. J.↗

NASA NTRS1985

Photovoltaics module interface: General purpose primers

The interfacial chemistry established between ethylene vinyl acetate (EVA) and the aluminized back surface of commercial solar cells was observed experimentally. The technique employed is called Fourier Transform Infrared (FTIR) spectroscopy, with the infrared signal being reflected back from the aluminum surface through the EVA film. Reflection infrared (IR) spectra are given and attention is drawn to the specific IR peak at 1080/cm which forms on hydrolytic aging of the EVA/aluminum system. With this fundamental finding, and the workable experimental techniques, candidate silane coupling agents are employed at the interface, and their effects on eliminating or slowing hydrolytic aging of the EVA/aluminum interface are monitored.

Boerio, J.↗

NASA NTRS1985

Continuous inline blending of antimisting kerosene

A continuous inline blender was developed to blend polymer slurries with a stream of jet A fuel. The viscosity of the slurries ranged widely. The key element of the blender was a static mixer placed immediately downstream of the slurry injection point. A positive displacement gear pump for jet A was employed, and a progressive cavity rotary screw pump was used for slurry pumping. Turbine flow meters were employed for jet A metering while the slurry flow rate was calibrated against the pressure drop in the injection tube. While using one of the FM-9 variant slurries, a provision was made for a time delay between the addition of slurry and the addition of amine sequentially into the jet A stream.

Parikh, P.↗

NASA NTRS1986

Theoretical dissociation energies for ionic molecules

Ab initio calculations at the self-consistent-field and singles plus doubles configuration-interaction level are used to determine accurate spectroscopic parameters for most of the alkali and alkaline-earth fluorides, chlorides, oxides, sulfides, hydroxides, and isocyanides. Numerical Hartree-Fock (NHF) calculations are performed on selected systems to ensure that the extended Slater basis sets employed for the diatomic systems are near the Hartree-Fock limit. Extended Gaussian basis sets of at least triple-zeta plus double polarization equality are employed for the triatomic system. With this model, correlation effects are relatively small, but invariably increase the theoretical dissociation energies. The importance of correlating the electrons on both the anion and the metal is discussed. The theoretical dissociation energies are critically compared with the literature to rule out disparate experimental values. Theoretical (sup 2)Pi - (sup 2)Sigma (sup +) energy separations are presented for the alkali oxides and sulfides.

Langhoff, S. R.↗

NASA NTRS1985

Applications of spherical shells

A new technique of producing hollow spheres of many materials at a very rapid rate, at very low cost, and with high reproducibility of shell diameter and wall thickness has been developed. Shells formed of metal or of other solid materials are expected to find numerous technical and industrial applications. For example, metal shells might be used as inertial confinement fusion targets, or as the principal constituents in lightweight structural materials for NASA Space Stations or DOD large antennas and mirrors, or be employed as containers for phase-change heat-storage media, or serve as containers for hazardous materials, or be employed as catalytic surface agents.

Wang, T. G.↗

NASA NTRS1985

Finite-amplitude steady waves in plane viscous shear flows

Computations of two-dimensional solutions of the Navier-Stokes equations are carried out for finite-amplitude waves on steady unidirectional flow. Several cases are considered. The numerical method employs pseudospectral techniques in the streamwise direction and finite differences on a stretched grid in the transverse direction, with matching to asymptotic solutions when unbounded. Earlier results for Poiseuille flow in a channel are re-obtained, except that attention is drawn to the dependence of the minimum Reynolds number on the physical constraint of constant flux or constant pressure gradient. Attempts to calculate waves in Couette flow by continuation in the velocity of a channel wall fail. The asymptotic suction boundary layer is shown to possess finite-amplitude waves at Reynolds numbers orders of magnitude less than the critical Reynolds number for linear instability. Waves in the Blasius boundary layer and unsteady Rayleigh profile are calculated by employing the artifice of adding a body force to cancel the spatial or temporal growth. The results are verified by comparison with perturbation analysis in the vicinity of the linear-instability critical Reynolds numbers.

Milinazzo, F. A.↗

NASA NTRS1984

MLA instruments and SWIR focal-plane technology

It is pointed out that next-generation sensors for earth observation will utilize Multispectral Linear Array (MLA) technology wherein linear detector arrays will scan the earth in pushbroom fashion. MLA instruments will permit a dramatic increase in detector dwell time, which can be utilized to improve spatial, spectral, and radiometric resolution. In connection with the considered applications for MLA sensors, the employed detector arrays should cover the visible, near-infrared, and shortwave infrared (SWIR) spectral bands. The present paper is mainly concerned with the development of mercury-cadmium-telluride focal-plane arrays for the SWIR spectral regime (1-2.5 microns). Attention is given to the requirements, design details regarding the detector array, the employed multiplexer technique, the hybrid concept, packaging, and the program status.

Brown, F. G.↗

NASA NTRS1986

An economical semi-analytical orbit theory for micro-computer applications

An economical algorithm is presented for predicting the position of a satellite perturbed by drag and zonal harmonics J2 through J4. Simplicity being of the essence, drag is modeled as a secular decay rate in the semimajor axis (retarded motion) with the zonal perturbations modeled from a modified version of Brouwers formulas. The algorithm is developed as an alternative on-board orbit predictor; a back up propagator requiring low energy consumption; or a ground based propagator for microcomputer applications (e.g., at the foot of an antenna). An O(J2) secular retarded state partial matrix (matrizant) is also given to employ with state estimation. The theory has been implemented in BASIC on an inexpensive microcomputer, the program occupying under 8K bytes of memory. Simulated trajectory data and real tracking data are employed to illustrate the theory's ability to accurately accommodate oblateness and drag effects.

Gordon, R. A.↗

NASA NTRS1986

The flowfield structure of the 3-D shock wave - Boundary layer interaction generated by a 20 deg sharp fin at Mach 3

The three-dimensional oblique shock wave-turbulent boundary layer interaction generated by a sharp fin attached to a flat plate is investigated experimentally and theoretically for Mach 3 and Reynolds number 9 x 10 to the 5th using two different models. Both models employ the three-dimensional compressible Navier-Stokes equations in mass-averaged variables; one model utilizes the algebraic turbulent eddy viscosity model of Baldwin and Lomax (1978), while the other model employs the two-equation turbulence model of Jones and Launder (1972) coupled with the wall function model of Viegas and Rubesin (1985). The computed surface pressure, surface streamlines, pitot pressure, and yaw angle profiles are found to be in good agreement with experimental data. The three-dimensional velocity fields computed by both models are in close agreement, although the eddy viscosity profiles differ significantly within the three-dimensional interaction. This result indicates that the overall structure of this three-dimensional sharp fin interaction is insensitive to the turbulence model.

Knight, D. D.↗

NASA NTRS1985

Accelerated solution of the steady Euler equations

The present paper is concerned with two methods for the accelerated solution of the steady Euler equations. One method makes use of a second-order embedding to facilitate the derivation of the relaxation solution of the steady equations of motion, while the other method employs a multile-gridding concept to accelerate the convergence of a simple, explicit, time-marching scheme applied to the unsteady equations. It is pointed out that the surrogate equation technique provides a means for formulating problems involving the full steady Euler equations in such a way as to allow the use of relaxation solution procedures. It is, therefore, possible to solve either irrotational or rotational flow problems spanning the entire spectrum of subsonic, transonic, and supersonic conditions. The solutions can be obtained without an employement of either derived dependent variables, semidirect methods, or an unsteady formulation.

Johnson, G. M.↗

NASA NTRS1986

Theory of idealized two-dimensional ballute in Newtonian hypersonic flow

A differential equation governing the geometry of a two-dimensional ballute in hypersonic flow and its constraining boundary conditions are derived under idealized assumptions. By solving these equations, the shape of the ballute is determined over a range of conditions. Lift, drag, pitching moment, and the allowed limit of center-of-gravity location for stability (meta-center) are then calculated using Newtonian hypersonic approximation. It is shown that the meta-center occurs near the forward end because of compliance of the ballute membrane to the shock layer pressures, especially at low free-stream densities. In order for the vehicle employing the ballute to be stable at all densities, the center of gravity must be within approximately the forward 20 percent of overall length of the vehicle. However, typical flight trajectories of an aeroassisted orbital transfer vehicle employing the ballute for aerobraking show that the vehicle may be able to complete its atmospheric flight without tumbling provided that the center of gravity is located within the forward 43 percent of the vehicle length because of the relatively short duration of flight through the destabilizing low-density regime.

Park, C.↗

NASA NTRS1986

Raman Doppler velocimetry - A unified approach for measuring molecular flow velocity, temperature, and pressure

Molecular flow velocity (one component), translational temperature, and static pressure of N2 are measured in a supersonic wind tunnel using inverse Raman spectroscopy. For velocity, the technique employs the large Doppler shift exhibited by the molecules when the pump and probe laser beams are counterpropagating (backward scattering). A retrometer system is employed to yield an optical configuration insensitive to mechanical vibration, which has the additional advantage of simultaneously obtaining both the forward and backward scattered spectra. The forward and backward line breadths and their relative Doppler shift can be used to determine the static pressure, translational temperature, and molecular flow velocity. A demonstration of the technique was performed in a continuous airflow supersonic wind tunnel in which data were obtained under the following conditions: (1) free-stream operation at five set Mach number levels over the 2.50-4.63 range; (2) free-stream operation over a range of Reynolds number (at a fixed Mach number) to vary systematically the static pressure; and (3) operation in the flow field of a simple aerodynamic model to assess beam steering effects in traversing the attached shock layer.

Exton, R. J.↗

NASA NTRS1986

Comparison of Euler and full potential marching techniques for flows over complex configurations

Two recently developed aerodynamic prediction techniques based on the steady full potential equation and the unsteady Euler equations have been applied to a variety of three-dimensional supersonic flow problems exhibiting embedded subsonic regions. Both techniques utilize planar Gauss-Seidel relaxation in the marching direction and approximate factorization in the cross-flow plane. A conservative switching scheme and flux bias technique are employed in the full potential method to transition from the supersonic marching procedure to a subsonic relaxation algorithm and vice versa. A new unified approach with finite volume, high accuracy (up to third order) Total Variation Diminishing formulation (based on Roe's scheme) is used in the Euler solver. In the supersonic regions of the flow an 'infinitely large' time step is employed, and a finite time step is applied in the subsonic regions of the flow to reach the steady-state as a time-asymptote. Numerical solutions are obtained for a number of complex configurations, including: (1) an elliptic waverider, (2) a realistic fighter configuration, (3) the Space Shuttle, and (4) a Shuttle-like configuration. Both the Full Potential and Euler numerical results are in good agreement with available experimental data.

Szema, K. Y.↗

NASA NTRS1985

Application of the finite element method in the calculation of transmission loss of flat and curved panels

This investigation represents an extension of a study of Roussos (1985) who considered the noise transmission loss of a rectangular plate in an infinite baffle. Roussos, who employed an analytical formulation, considered an unstiffened plate. While it is difficult to consider stiffeners by means of analytical methods, the difficulties can be avoided by employing a finite element procedure. For this reason, the present study is concerned with the implementation of a finite element method. The representation of the panel transmission loss is discussed, and the determination of the panel motion by means of the finite element technique is described, taking into account an isotropic flat panel, the exciting force, an eigenvalue problem, the radiation pressure, a plate element, and a cylindrical shell element. Numerical results are considered for a flat panel, a curved panel, and a stiffened flat panel.

Koval, L. R.↗

NASA NTRS1985

To speak or not to speak - A multiple resource perspective

The desirability of employing speech response in a dynamic dual task situation was discussed from a multiple resource perspective. A secondary task technique was employed to examine the time-sharing performance of five dual tasks with various degrees of resource overlap according to the structure-specific resource model of Wickens (1980). The primary task was a visual/manual tracking task which required spatial processing. The secondary task was either another tracking task or a spatial transformation task with one of four input (visual or auditory) and output (manual or speech) configurations. The results show that the dual task performance was best when the primary tracking task was paired with the visual/speech transformation task. This finding was explained by an interaction of the stimulus-central processing-response compatibility of the transformation task and the degree of resource competition between the time-shared tasks. Implications on the utility of speech response were discussed.

Tsang, P. S.↗