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At least 991 records · Page 55

DIBS independent of accretion in T Tauri stars

The examination of high resolution spectra (5200 - 7000 Angstroms) of 36 T Tauri stars ranging in accretion rates was performed. Only the lambda lambda 5780, 5797, and 6613 bands were found detectable to within an equivalent width of 10 micro Angstroms. They are strongest in DG Tau, DR Tau, Dl Tau, and AS 353A. DR Tau was monitored over the course of four years; during this time, the accretion rate varied by a factor of five, but the equivalent widths of the DIB's (Diffuse Interstellar Bands) remained constant. The lack of correlation of the strength of the bands with the accretion rates implies that the bands are not directly produced by UV radiation from the accretion process. The bands have line strengths and ratios characteristic of the diffuse interstellar medium, from which we conclude that the diffuse interstellar bands seen in the spectra of T Tauri stars do not originate in the stars' immediate environment. Instead, they are part of a foreground extinction, probably due to the parent molecular cloud.

Ghandour, Louma↗

Heat Transfer to a Thin Solid Combustible in Flame Spreading at Microgravity

The heat transfer rate to a thin solid combustible from an attached diffusion flame, spreading across the surface of the combustible in a quiescent, microgravity environment, was determined from measurements made in the drop tower facility at NASA-Lewis Research Center. With first-order Arrhenius pyrolysis kinetics, the solid-phase mass and energy equations along with the measured spread rate and surface temperature profiles were used to calculate the net heat flux to the surface. Results of the measurements are compared to the numerical solution of the complete set of coupled differential equations that describes the temperature, species, and velocity fields in the gas and solid phases. The theory and experiment agree on the major qualitative features of the heat transfer. Some fundamental differences are attributed to the neglect of radiation in the theoretical model.

Bhattacharjee, S.↗

Cooling rates of chondrules: A new approach

Mineralogy and texture of chondrules have been reproduced experimentally and it was demonstrated that the abundance of heterogeneous nuclei is an important factor controlling chondrule textures. Cooling rates of chondrules were estimated from the zoning patterns of olivine. Low cooling rates (less than 100 C/h) yielded chemically homogeneous olivine crystals, whereas higher cooling rates, between 100 and 2000 C/h, produced olivine compositions similar to those observed in natural chondrules. We present a new approach to determining cooling rates of chondrules based on the microstructure of chondrule clinopyroxene and plagioclase. All observations were made on Allende chondrules. Two independent processes (Ca and Mg diffusion in pyroxene and Al/Si ordering in plagioclase) yield similar cooling rates on the order of 10-1 C/h for granular olivine pyroxene (GOP) chondrules in Allende. Our cooling rates are at least one order of magnitude lower than those derived from dynamic crystallization experiments.

Weinbruch, S.↗

Atmospheric corrosion model and monitor for low cost solar arrays

An atmospheric corrosion model and corrosion monitoring system has been developed for low cost solar arrays (LSA). The corrosion model predicts that corrosion rate is the product of the surface condensation probability of water vapor and the diffusion controlled corrosion current. This corrosion model is verified by simultaneous monitoring of weather conditions and corrosion rates at the solar array test site at Mead, Nebraska.

Kaelble, D. H.↗

A mechanistic study of mesoporous TiO 2 nanoparticle negative electrode materials with varying crystallinity for lithium ion batteries

Nanoscale oxide-based negative electrodes are of great interest for lithium ion batteries due to their high energy density, power density and enhanced safety. In this work, we conducted a case study on mesoporous TiO 2 nanoparticle negative electrodes with uniform size and varying crystallinity in order to investigate the trend in the electrochemical properties of oxide-based nanoscale negative electrodes with varying crystallinity. Furthermore, mesoporous solid spherical TiO 2 nanoparticles with a uniform particle size and varying crystallinity, i.e. , amorphous TiO 2 (A-TiO 2 ), partially crystalline TiO 2 (PC-TiO 2 ) and fully crystalline TiO 2 (FC-TiO 2 ) nanoparticles were studied. At low current rate (quasi steady-state), the specific capacity of the samples drops with the decrease of crystallinity. Ex situ synchrotron pair distribution function analysis reveals that the 1D zigzag Li ion diffusion pathway becomes expanded with the increase of crystallinity, which promotes ion mobility and charge storage. At high current rates (away from equilibrium states), however, the A-TiO 2 sample demonstrates slightly larger capacity than the FC-TiO 2 sample, both of which show larger capacities than that of the PC-TiO 2 sample. Both A-TiO 2 and FC-TiO 2 samples exhibit higher capacitive contribution to the charge storage and larger Li + diffusivity than those of the PC-TiO 2 sample, which explains their better rate capability. Moreover, the larger Li + diffusivity of the A-TiO 2 sample leads to the slightly larger specific capacity than the FC-TiO 2 sample at the highest current rate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effects of C/O Ratio and Temperature on Sooting Limits of Spherical Diffusion Flames

Limiting conditions for soot particle inception in spherical diffusion flames were investigated numerically. The flames were modeled using a one-dimensional, time accurate diffusion flame code with detailed chemistry and transport and an optically thick radiation model. Seventeen normal and inverse flames were considered, covering a wide range of stoichiometric mixture fraction, adiabatic flame temperature, residence time and scalar dissipation rate. These flames were previously observed to reach their sooting limits after 2 s of microgravity. Sooting-limit diffusion flames with scalar dissipation rate lower than 2/s were found to have temperatures near 1400 K where C/O = 0.51, whereas flames with greater scalar dissipation rate required increased temperatures. This finding was valid across a broad range of fuel and oxidizer compositions and convection directions.

Lecoustre, V. R.↗

Stochastic self-tuning hybrid algorithm for reaction-diffusion systems

Many biochemical phenomena involve reactants with vastly different concentrations, some of which are amenable to continuum-level descriptions, while the others are not. We present a hybrid self-tuning algorithm to model such systems. The method combines microscopic (Brownian) dynamics for diffusion with mesoscopic (Gillespie-type) methods for reactions and remains efficient in a wide range of regimes and scenarios with large variations of concentrations. Furthermore, its accuracy, robustness, and versatility are balanced by redefining propensities and optimizing the mesh size and time step. We use a bimolecular reaction to demonstrate the potential of our method in a broad spectrum of scenarios: from almost completely reaction-dominated systems to cases where reactions rarely occur or take place very slowly. The simulation results show that the number of particles present in the system does not degrade the performance of our method. This makes it an accurate and computationally efficient tool to model complex multireaction systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydrogen adsorption and diffusion, and subcritical-crack growth in high strength steels and nickel base alloys

Embrittlement, or the enhancement of crack growth by gaseous hydrogen in high strength alloys, is of primary interest in selecting alloys for various components in the space shuttle. Embrittlement is known to occur at hydrogen gas pressures ranging from fractions to several hundred atmospheres, and is most severe in the case of martensitic high strength steels. Kinetic information on subcritical crack growth in gaseous hydrogen is sparse at this time. Corroborative information on hydrogen adsorption and diffusion is inadequate to permit a clear determination of the rate controlling process and possible mechanism in hydrogen enhanced crack growth, and for estimating behavior over a range of temperatures and pressures. Therefore, coordinated studies of the kinetics of crack growth, and adsorption and diffusion of hydrogen, using identical materials, have been initiated. Comparable conditions of temperature and pressure will be used in the chemical and mechanical experiments. Inconel 718 alloy and 18Ni(200) maraging steel have been selected for these studies. Results from these studies are expected to provide not only a better understanding of the gaseous hydrogen embrittlement phenomenon itself, but also fundamental information on hydrogen adsorption and diffusion, and crack growth information that can be used directly for design.

Wei, R. P.↗

Atmospheric studies related to aerospace activities and remote sensing technology

Parallel investigations were conducted relating to: the sensitivity of 1-D photochemical model simulated column ozone perturbations due to a projected fleet of 1000 aircraft cruising 7 hours per day at altitudes of 15-16 and 18-19 km to uncertainties in kinetic rate constant data determining modeled OH concentrations and eddy diffusivity profile parameterization and a comparison of the inherent strengths and weaknesses of Eulerian and Langrangian averaging processes in the development of multidimensional models and investigation of approaches to applying the Generalized Lagrangian Mean (GLM) formalism to zonal-mean models. The role of multiple scattering and Earth curvature in the evaluation of diurnally dependent photodissociation rates and trace species variations was examined.

Sze, N. D.↗

Centrifugal Compressor Surge Margin Improved With Diffuser Hub Surface Air Injection

Aerodynamic stability is an important parameter in the design of compressors for aircraft gas turbine engines. Compression system instabilities can cause compressor surge, which may lead to the loss of an aircraft. As a result, engine designers include a margin of safety between the operating line of the engine and the stability limit line of the compressor. The margin of safety is typically referred to as "surge margin." Achieving the highest possible level of surge margin while meeting design point performance objectives is the goal of the compressor designer. However, performance goals often must be compromised in order to achieve adequate levels of surge margin. Techniques to improve surge margin will permit more aggressive compressor designs. Centrifugal compressor surge margin improvement was demonstrated at the NASA Glenn Research Center by injecting air into the vaned diffuser of a 4:1-pressure-ratio centrifugal compressor. Tests were performed using injector nozzles located on the diffuser hub surface of a vane-island diffuser in the vaneless region between the impeller trailing edge and the diffuser-vane leading edge. The nozzle flow path and discharge shape were designed to produce an air stream that remained tangent to the hub surface as it traveled into the diffuser passage. Injector nozzles were located near the leading edge of 23 of the 24 diffuser vanes. One passage did not contain an injector so that instrumentation located in that passage would be preserved. Several orientations of the injected stream relative to the diffuser vane leading edge were tested over a range of injected flow rates. Only steady flow (nonpulsed) air injection was tested. At 100 percent of the design speed, a 15-percent improvement in the baseline surge margin was achieved with a nozzle orientation that produced a jet that was bisected by the diffuser vane leading edge. Other orientations also improved the baseline surge margin. Tests were conducted at speeds below the design speed, and similar results were obtained. In most cases, the greatest improvement in surge margin occurred at fairly low levels of injected flow rate. Externally supplied injection air was used in these experiments. However, the injected flow rates that provided the greatest benefit could be produced using injection air that is recirculating between the diffuser discharge and nozzles located in the diffuser vaneless region. Future experiments will evaluate the effectiveness of recirculating air injection.

Skoch, Gary J.↗

Transport phenomena in the crystallization of lysozyme by osmotic dewatering and liquid-liquid diffusion in low gravity

Two methods of protein crystallization, osmotic dewatering and liquid-liquid diffusion, like the vapor diffusion (hanging-drop and sessile-drop) methods allow a gradual approach to supersaturation conditions. The crystallization of hen egg-white lysozyme, an extensively characterized protein crystal, in the presence of sodium chloride was used as an experimental model with which to compare these two methods in low gravity and in the laboratory. Comparisons of crystal growth rates by the two methods under the two conditions have, to date, indicated that the rate of crystal growth by osmotic dewatering is nearly the same in low gravity and on the ground, while much faster crystal growth rates can be achieved by the liquid-liquid diffusion method in low gravity.

Todd, Paul↗

Separation of dilute plutonium(IV) from nitric acid solutions via Reillex HPQ anion exchange resin

Anion exchange is a common method for the separation of plutonium (Pu) in aqueous systems, providing high recovery and decontamination from impurities. Reillex HPQ anion exchange resin has been used around the Department of Energy complex in this application for decades but has typically been used for Pu feed concentrations greater than 1 g/L. It is desirable to recover Pu at more dilute concentrations from a dissolved used fuel or target element, for example. In this work, the performance of Reillex HPQ anion exchange resin was characterized with feed solutions of ca. 0.24 g/L Pu. A significant reduction in the performance of the resin was realized with this dilute concentration relative to a feed solution of 2.35 g/L Pu with similar feed flow rates and the same resin column, likely due to the increased driving force for mass transfer with a higher feed concentration. The maximum capacity of Reillex HPQ resin for Pu can be improved by reducing the flow rate and increasing the feed Pu concentration. Furthermore, the breakthrough point of Pu can be improved in the same manner and by increasing the resin bed height. Diffusion of Pu into the resin was illustrated to be the rate limiting step.

Plutonium separations↗

Our Sun IV: The Standard Model and Helioseismology: Consequences of Uncertainties in Input Physics and in Observed Solar Parameters

Helioseismic frequency observations provide an extremely accurate window into the solar interior; frequencies from the Michaelson Doppler Imager (MDI) on the Solar and Heliospheric Observatory (SOHO) spacecraft, enable the adiabatic sound speed and adiabatic index to be inferred with an accuracy of a few parts in 10(exp 4) and the density with an accuracy of a few parts in 10(exp 3). This has become a Serious challenge to theoretical models of the Sun. Therefore, we have undertaken a self-consistent, systematic study of the sources of uncertainties in the standard solar models. We found that the largest effect on the interior structure arises from the observational uncertainties in the photospheric abundances of the elements, which affect the sound speed profile at the level of 3 parts in 10(exp 3). The estimated 4% uncertainty in the OPAL opacities could lead to effects of 1 part in 10(exp 3); the approximately 5%, uncertainty in the basic pp nuclear reaction rate would have a similar effect, as would uncertainties of approximately 15% in the diffusion constants for the gravitational settling of helium. The approximately 50% uncertainties in diffusion constants for the heavier elements would have nearly as large an effect. Different observational methods for determining the solar radius yield results differing by as much as 7 parts in 10(exp 4); we found that this leads to uncertainties of a few parts in 10(exp 3) in the sound speed int the solar convective envelope, but has negligible effect on the interior. Our reference standard solar model yielded a convective envelope position of 0.7135 solar radius, in excellent agreement with the observed value of 0.713 +/- 0.001 solar radius and was significantly affected only by Z/X, the pp rate, and the uncertainties in helium diffusion constants. Our reference model also yielded envelope helium abundance of 0.2424, in good agreement with the approximate range of 0.24 to 0.25 inferred from helioseismic observations; only extreme Z/X values yielded envelope helium abundance outside this range. We found that other current uncertainties, namely, in the solar age and luminosity, in nuclear rates other than the pp reaction, in the low-temperature molecular opacities, and in the low-density equation of state, have no significant effect on the quantities that can be inferred from helioseismic observations. The predicted pre-main-sequence lithium depletion is uncertain by a factor of 2. The predicted neutrino capture rate is uncertain by approximately 30% for the Cl-27 experiment and by approximately 3% for Ga-71 experiments, while the B-8 neutrino flux is uncertain by approximately 30%.

Boothroyd, Arnold I.↗

Applying and validating the RANS-3D flow-solver for evaluating a subsonic serpentine diffuser geometry

Subsonic inlet ducts for advanced, high-performance aircraft are evolving towards complex three-dimensional shapes for reasons of overall integration and weight. These factors lead to diffuser geometries that may sacrifice inlet performance, unless careful attention to design details and boundary layer management techniques are employed. The ability of viscous computational fluid dynamic (CFD) analysis of such geometries to aid the aircraft configurator in this complex design problem is herein examined. The RANS-3D Reynolds-Averaged Navier-Stokes solver is applied to model the complex flowfield occurring in a representative diffuser geometry and the solutions are compared to experimental results from a static test of the inlet duct. The computational results are shown to compare very favorably with experimental results over a range of mass flow rates, including those involving large amounts of separation in the diffuser. In addition, a novel grid topology is presented, and two turbulence models are evaluated in this study as part of the RANS-3D code.

Fletcher, Michael J.↗

Performance of a short annular dump diffuser using suction-stabilized vortices at inlet Mach numbers to 0.41

A short, annular dump diffuser was designed to use suction to establish stabilized vortices on both walls for improved flow expansion in the region of an abrupt area change. The diffuser was tested at near ambient inlet pressure and temperature. The overall diffuser area ratio was 4.0. The inlet height was 2.54 cm and the exit pitot-static rakes were located at a distance from the vortex fence equal to two or six times the inlet height. Performance data were taken at near ambient temperature and pressure for nominal inlet Mach numbers of 0.18 to 0.41 with suction rates of 0 to 18 percent of the total inlet airflow. The exit velocity profile could be shifted toward either wall by adjusting the inner- or outer-wall suction rate. Symmetrical exit velocity profiles were unstable, with a tendency to shift back to hub- or tip-weighted profile. Diffuser effectiveness was increased from about 47 percent without suction to over 85 percent at a total suction rate of about 14 percent. The diffuser total pressure losses at inlet Mach numbers of 0.18 and 0.41 decreased from 1.1 and 5.6 percent without suction to 0.48 and 5.2 percent at total suction rates of 14.4 and 5.6 percent, respectively.

Smith, J. M.↗

Efficient estimation of diffusion during dendritic solidification

A very efficient finite difference method has been developed to estimate the solute redistribution during solidification with diffusion in the solid. This method is validated by comparing the computed results with the results of an analytical solution derived by Kobayashi (1988) for the assumptions of a constant diffusion coefficient, a constant equilibrium partition ratio, and a parabolic rate of the advancement of the solid/liquid interface. The flexibility of the method is demonstrated by applying it to the dendritic solidification of a Pb-15 wt pct Sn alloy, for which the equilibrium partition ratio and diffusion coefficient vary substantially during solidification. The fraction eutectic at the end of solidification is also obtained by estimating the fraction solid, in greater resolution, where the concentration of solute in the interdendritic liquid reaches the eutectic composition of the alloy.

Yeum, K. S.↗

Isothermal and Cyclic Oxidation of Haynes 282 Processed by Electron Beam Melting (EBM) and Laser Powder Bed Fusion (LPBF) in Dry Air at 800 and 950°C

Here, the isothermal and cyclic oxidation behavior of Haynes 282 (H282) processed by laser powder bed fusion and electron beam melting was compared to its cast counterpart during exposures in air at 800 and 950°C. The specific microstructure of the AM alloys compared to coarse-grain cast 282 resulted in differences in oxidation rates, internal oxidation and spallation behavior. At 800°C, faster Ti diffusion to the surface due to the smaller grain size of the AM alloys led to Ti doping of the Cr 2 O 3 scale and faster oxidation rates. The higher density of grain boundaries also resulted in more pronounced internal oxidation. At 950°C, a duplex Cr 2 O 3 scale was observed with a dense inner layer and porous cracked outer layer with embedded TiO 2 particles. The impact of the external and internal oxide compositions and oxidation-induced elemental depletions on the oxidation lifetime, creep properties and spallation behavior is discussed.

36 MATERIALS SCIENCE↗

A phase-field model for void and gas bubble superlattice formation in irradiated solids

A phase-field model to simulate the formation of both void and gas bubble superlattices is derived from a grand potential functional, assuming 1D diffusion of self-interstitial atoms. The model is capable of accounting for superlattice formation by either a nucleation and growth or spinodal decomposition mechanism; in this work, we focus on the nucleation and growth mechanism, using a discrete nucleation approach in the phase-field model. In simulations of void formation, short aligned rows of voids were initially formed, followed by growth in the size of the aligned rows, and finally leading to superlattice formation, consistent with experimental observations. Void superlattice spacing as a function of model parameters was quantified. Increased nucleation rates led to smaller superlattice spacing, while increased vacancy diffusivity led to larger superlattice spacing. In simulations of gas bubble superlattice formation, superlattice spacing decreased with increasing gas atom flux, consistent with experimental observations. Here, simulations with increasing ratio of gas atom flux to vacancy-interstitial pair production led to increased superlattice spacing, which is inconsistent with experimental observations at high gas atom flux rates; this discrepancy is attributed to the fact that the model does not account for bound gas atom-vacancy pairs that may dominate at high gas flux rates.

36 MATERIALS SCIENCE↗