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At least 991 records · Page 55
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Surface reaction and pore diffusion in flow-tube reactors

The interaction of gas diffusion with surface reaction in porous solids is discussed and applied specifically to heterogeneous rate measurements in flow-tube reactors. External diffusion to the outer surface of a reactive solid, internal diffusion within the pores, surface reaction, and laminar flow are considered. A procedure is developed to correct observed surface rate constants for the interaction of these processes. Measured surface areas and bulk densities are used to construct a semiempirical model for porous diffusion in vapor-formed HNO3-H2O ices which are used to simulate polar stratospheric cloud surfaces. The model is tested experimentally by varying the thickness of these ices from about 15 to 120 microns. The results are consistent with the model predictions and show that the HNO3-H2O ices used are highly porous, and the internal surface must be considered in calculating kinetic parameters from observed loss rates. The best fit of the data yields a tortuosity factor of 3.3 +/-1.1 for the ice substrates.

Keyser, Leon F.↗
NASA NTRS1992

Accurate far-infrared rotational frequencies of carbon monoxide

This study presents high-resolution measurements of the pure rotational absorption spectrum of CO in its ground state for the range J arcsec - 5-37. A least-squares fit to this data set, augmented by previous microwave measurements of the J arcsec = 0-4 rotational transitions in the literature, determined accurate values for the molecular constants. A table of calculated CO rotational frequencies is provided for the range J arcsec = 0-45.

Varberg, Thomas D.↗
NASA NTRS1992

Statistics of cosmological gamma-ray bursts

A phenomenological model of gamma-ray burst spectra is used to calculate the statistics of gamma-ray bursts originating at cosmological distances. A model of bursters with no source evolution in a q sub 0 = 1/2 Friedmann cosmology is in accord with recent observations of the differential V/Vmax distribution. The data are best fit with an average peak-burst luminosity of (4 +/- 2) x 10 exp 51 ergs/s and a present-day source emissivity of 940 +/- 440 bursts/(10 exp 10 yr) cu Mpc. A spectral test of the cosmological hypothesis is proposed.

Dermer, Charles D.↗
NASA NTRS1991

Vertical column abundances and seasonal cycle of acetylene, C2H2, above the Jungfraujoch station, derived from IR solar observations

Results derived from a spectroscopic analysis of the nu5 band R19 transition of C2H2 observed in solar spectra recorded at the Jungfraujoch station, Switzerland, between June 1986 and April 1991 are reported. A least-squares sine fit to the data reveals a seasonal variability with an amplitude of about +/-40 percent of the mean; the maximum occurs during mid-winter and the minimum in summer. In general, the observed seasonal observations are comparable with those derived from airborne in-situ measurements and those reported from ground-based stations.

Zander, R.↗
NASA NTRS1992

The Galileo and Pioneer Venus ultraviolet spectrometer experiments - Solar Lyman-alpha latitude variation at solar maximum from interplanetary Lyman-alpha observations

Solar Ly-alpha latitude variation at solar maximum is examined on the basis of interplanetary Ly-alpha observations made during the Galileo and Pioneer Venus UV spectrometer experiments. A comparison is made of the latitude variation of the interplanetary (IP) Ly-alpha signal in 1986 at solar minimum from Pioneer Venus and in 1990 at solar maximum from Galileo. The Galileo EUV spectrometer shows that a large enhancement of the IP Ly-alpha emission occurred over the intervening four years near the solar equator. An IP Ly-alpha model is developed which considers the latitude variation of the solar Ly-alpha flux. The model fit to the data shows a 25-percent decrease of the full disk solar Ly-alpha flux from solar equator to solar pole in 1990. A detailed study of the Galileo IP Ly-alpha observations on day-of-year 190, 193, 197, and 200 in 1990 reveals that large variations occur in response to the 27-d solar variation. Analysis of these data shows that a maximum variation of 20 percent can be expected in the IP Ly-alpha upwind intensity over this 27-d period.

Pryor, W. R.↗
NASA NTRS1992

Postglacial rebound with a non-Newtonian upper mantle and a Newtonian lower mantle rheology

A composite rheology is employed consisting of both linear and nonlinear creep mechanisms which are connected by a 'transition' stress. Background stress due to geodynamical processes is included. For models with a non-Newtonian upper-mantle overlying a Newtonian lower-mantle, the temporal responses of the displacements can reproduce those of Newtonian models. The average effective viscosity profile under the ice-load at the end of deglaciation turns out to be the crucial factor governing mantle relaxation. This can explain why simple Newtonian rheology has been successful in fitting the uplift data over formerly glaciated regions.

Gasperini, Paolo↗
NASA NTRS1992

A model for the global variation in oceanic depth and heat flow with lithospheric age

Variations in sea-floor depth and heat flow with age provide the main constraints on the thermal structure and evolution of the oceanic lithosphere. Joint fitting of heat flow and bathymetry yields a model with a hotter, thinner lithosphere than in previous models. The new model provides a significantly better fit to the data, including those from older lithosphere previously treated as anomalous. This will facilitate the analysis of lithospheric processes, including the effects of mid-plate volcanism and swells, regional subsidence, and hydrothermal circulation near spreading centers.

Stein, Carol A.↗
NASA NTRS1987

Observation of gamma ray low state of Cygnus X-1

Cygnus X-1 was observed on 25 Sep. 1980 with a high-resolution cooled germanium spectrometer in the Low Energy Gamma-Ray Spectrometer (LEGS) balloon-borne experiment. The source was in a very low gamma-ray state: the differential flux at 45 keV was 1.3 x 10 exp -3 ph/sq cm sec keV. The results of a power low fit to our data are compared with three other observations of a similar state. All of these spectra represent significantly lower gamma-ray fluxes than normally observed in the x-ray low or high state. Only HEAO-3 has simultaneous x-ray data and, for that case, Cygnus X-1 was in the x-ray low state which normally corresponds to the highest gamma-ray emission. The similarity of the gamma-ray spectra suggest that all these measurements may correspond to the unusual state observed by HEAO-3.

Tueller, T.↗
NASA NTRS1992

An evaluation of corrosion protection by two epoxy primers on 2219-T87 and 7075-T73 aluminum

A comparison of the corrosion protection provided by two amine epoxy primers was made using salt fog, alternate immersion, and total immersion as exposure media. The study is the result of a request to use an unqualified low volatile organic carbon (VOC) primer (AKZO 463-6-78) in place of the current primer (AKZO 463-6-3) because environmental regulations have eliminated use of the current primer in many states. Primed, scribed samples of 2219-T87 and 7075-T73 aluminum were exposed to 5-percent NaCl salt fog and 3.5-percent NaCl alternate immersion for a period of 90 days. In addition, electrode samples immersed in 3.5-percent NaCl were tested using electrochemical impedance spectroscopy (EIS). The EG&G model 368 ac impedance measurement system was used to monitor changing properties of AKZO 463-6-78 and AKZO 463-6-3 primed 2219-T87 aluminum for a period of 30 days. The response of the corroding system of a frequency scan can be modeled in terms of an equivalent circuit consisting of resistors and capacitors in a specific arrangement. Each resistor/capacitor combination represents physical processes taking place within the electrolyte, at the electrolyte/primer surface, within the coating, and at the coating/substrate surface. Values for the resistors and capacitors are assigned following a nonlinear least squares fit of the data to the equivalent circuit. Changes in the values of equivalent circuit parameters during the 30-day exposure allow assessment of the time to and mechanism of coating breakdown.

Mendrek, M. J.↗
NASA NTRS1992

Quasar x-ray spectra revisited

A sample of 45 quasars observed by the Imaging Proportional Counter (IPC) on the Einstein satellite is used to re-examine the relationship between the soft (0.2-3.5 keV) X-ray energy index and radio-loudness. We found the following: (1) the tendency for radio-loud quasars to have systematically flatter X-ray slopes than radio-quiet quasars (RQQ's) is confirmed with the soft X-ray excess having negligible effect; (2) there is a tendency for the flatness of the X-ray slope to correlate with radio core-dominance for radio-loud quasars, suggesting that a component of the X-ray emission is relativistically beamed; (3) for the RQQ's the soft X-ray slopes, with a mean of approximately 1.0, are consistent with the slopes found at higher energies (2-10 keV) although steeper than those observed for Seyfert 1 galaxies (also 2-10 keV) where the reflection model gives a good fit to the data; (4) the correlation of FeII emission line strength with X-ray energy index is confirmed for radio-quiet quasars using a subset of 18 quasars. The radio-loud quasars show no evidence for a correlation. This relation suggests a connection between the ionizing continuum and the line emission from the broad emission line region (BELR) of radio-quiet quasars, but in the opposite sense to that predicted by current photoionization models; and (5) the correlations of X-ray slope with radio core dominance and FeII equivalent width within the radio-loud and radio-quiet sub-classes respectively imply that the observed wide range of X-ray spectral slopes is real rather than due to the large measuring uncertainties for individual objects.

Shastri, P.↗
NASA NTRS1992

Closed form expressions for crack mouth displacements and stress intensity factors for chevron notched short bar and short rod specimens based on experimental compliance measurements

A set of equations are presented describing certain fracture mechanics parameters for chevron notch bar and rod specimens. They are developed by fitting compliance calibration data reported earlier. The equations present the various parameters in their most useful forms. The data encompass the entire range of the specimen geometries most commonly used. Their use will facilitate the testing and analysis of brittle metals, ceramics, and glasses.

Bubsey, R. T.↗
NASA NTRS1992

A method for modeling discontinuities in a microwave coaxial transmission line

A method for modeling discontinuities in a coaxial transmission line is presented. The methodology involves the use of a nonlinear least-squares fit program to optimize the fit between theoretical data (from the model) and experimental data. When this method was applied to modeling discontinuities in a slightly damaged Galileo spacecraft S-band (2.295-GHz) antenna cable, excellent agreement between theory and experiment was obtained over a frequency range of 1.70-2.85 GHz. The same technique can be applied for diagnostics and locating unknown discontinuities in other types of microwave transmission lines, such as rectangular, circular, and beam waveguides.

Otoshi, T. Y.↗
NASA NTRS1993

Some effects of dust on photometry of high-z galaxies: Confounding the effects of evolution

Photometric observations of very distant galaxies--e.g., color vs. z or magnitude vs. z, have been used over the past decade or so in investigations into the evolution of the stellar component. Numerous studies have predicted significant color variations as a result of evolution, in addition to the shifting of different rest wavelengths into the band of observation. Although there is significant scatter, the data can be fit with relatively straightforward, plausible models for galaxian evolution. In very few cases are the effects of dust extinction included in the models. This is due in a large part to the uncertainty about the distribution and optical properties of the grains, and even whether or not they are present in significant numbers in some types of galaxies such as ellipticals. It is likely that the effects of dust on broadband observations are the greatest uncertainty in studies of very distant galaxies. We use a detailed Monte Carlo radiative transfer model within a spherical geometry for different star/dust distributions to examine the effects of dust on the broadband colors of galaxies as a function of redshift. The model fully accounts for absorption and angular redistribution in scattering. In this summary, we consider only the effects on color vs. redshift for three simple geometries each with the same total dust optical depth. Elsewhere at this conference, Capuano, Thronson, & Witt consider other effects of altering the relative dust/star distribution.

Thronson, H. A., Jr.↗
NASA NTRS1992

Soil surface CO2 fluxes and the carbon budget of a grassland

Measurements of soil surface CO2 fluxes are reported for three sites within the First International Satellite Land Surface Climatology Project (ISLSCP) Field Experiment (FIFE) area, and simple empirical equations are fit to the data to provide predictions of soil fluxes from environmental observations. A prototype soil chamber, used to make the flux measurements, is described and tested by comparing CO2 flux measurements to a 40-L chamber, a 1-m/cu chamber, and eddy correlation. Results suggest that flux measurements with the prototype chamber are consistent with measurements by other methods to within about 20 percent. A simple empirical equation based on 10-cm soil temperature, 0- to 10-cm soil volumetric water content, and leaf area index predicts the soil surface CO2 flux with a rms error of 1.2 micro-mol sq m/s for all three sites. Further evidence supports using this equation to evaluate soil surface CO2 during the 1987 FIFE experiment. The soil surface CO2 fluxes when averaged over 24 hours are comparable to daily gross canopy photosynthetic rates. For 6 days of data the net daily accumulation of carbon is about 0.6 g CO2 sq m/d; this is only a few percent of the daily gross accumulation of carbon by photosynthesis. As the soil became drier in 1989, the net accumulation of carbon by the prairie increased, suggesting that the soil flux is more sensitive to temperature and drought than the photosynthetic fluxes.

Norman, J. M.↗
NASA NTRS1993

The millimeter-wave spectrum of the MgH and MgD radicals

The pure rotational spectrum of MgH radical (X 2 Sigma (+)) in its ground state v = 0 and v = 1 vibrational modes has been observed in the laboratory using millimeter/submillimeter direct absorption spectroscopy. The rotational spectra of two isotopically substituted species, MgD and (Mg-26)H, have been detected as well. All six hyperfine components of the N = 0 -1 transition of MgH in its v = 0 and v = 1 states have been directly measured to an accuracy of +/-50 kHz, and the five components have been observed for (Mg-26)H. The N = 0 +/-1 and N = 1 -2 transitions of MgD have also been detected. Rotational, fine structure, and hyperfine constants were determined for all species from a nonlinear least-squared fit to the data using a 2 Sigma Hamiltonian.

Ziurys, L. M.↗
NASA NTRS1993

The X-ray spectral variability of the BL Lacertae type object PKS 2155-304

We present a detailed study of the hard X-ray properties of the BL Lacertae object PKS 2155-304 based on measurements made in 1988 and 1989 with the Large Area Counter (LAC) on board the Ginga satellite. The source exhibited a high degree of variability with a dynamic range of a factor 7 in the 2-6 keV band. The fastest amplitude variation was a factor 2 decline in the intensity in this band within 4 hours. The spectrum is characterized by a break which occurs at about 4 keV. Spectral fits to the data integrated in 6400 s time bins reveal that, in common with previous observations of BL Lacertae objects, the spectral slope is generally anticorrelated with intensity in the sense that the spectrum hardens as the intensity increases. However, the tracks of sequential points in the index-intensity plane are occasionally seen to differ during the rise and decay stages of individual flares. Furthermore, during one, or possibly two, flaring episodes the spectral index is observed to correlate with intensity variations.

Sembay, S.↗
NASA NTRS1992

Coded aperture devices for viewing extended objects from space

Coded aperture sensors for photons or energetic neutral atoms (ENAs), which incorporate FOV limiters and subdivide the object field into a number of elements which is smaller than the number of detector pixels, are described. A least squares fit to the data is made in reconstructing the object field. To evaluate the optics and reconstruction algorithms, two 'breadboard' sensors have been constructed, one based on a film camera and the other upon a UV-light sensitive microchannel plate detector system. Results obtained thus far show that the concept is viable, and no special difficulties should be encountered in adapting the detector geometries to neutral particle imaging systems. Charged particle deflection plates could be incorporated into the region between the FOV limiter and the aperture, or installed ahead of the limiter.

Curtis, C. C.↗
NASA NTRS1992

Aperture codes for sensors viewing extended objects from space

The paper describes aperture codes viewing extended objects form space which find application in imaging an extended object which may have relatively low contrast, and whose lateral limits extend beyond the FOV of the sensor. Those elements of an extended object lying near the FOV limits are only partially coded, i.e., flux from those elements cannot cast a shadow of the entire aperture code onto the detector, as can elements near the center of the FOV. This has consequences for the algorithms used to reconstruct the image. The object field is divided into a number of elements which is smaller than the number of detector pixels, and a least squares fit to the data is performed. The methods used for choosing the matrices representing the aperture codes are discussed, and computer simulations of the effects of noise are described.

Curtis, C. C.↗