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At least 991 records · Page 55

Thermomechanical characterization of Hastelloy-X under uniaxial cyclic loading

In most high-temperature engineering applications, components are subjected to complex combinations of thermal and mechanical loading during service. A number of viscoplastic constitutive models were proposed which potentially can provide mathematical descriptions of material response under such conditions. Implementation of these models into large finite element codes such as MARC has already resulted in much improved inelastic analysis capability for hot-section aircraft engine components. However, a number of questions remain regarding the validity of methods adopted in characterizing these constitutive models for particular high-temperature materials. One area of concern is that the majority of experimental data available for this purpose are determined under isothermal conditions. This is in contrast to service conditions which, as noted above, almost always involve some form of thermal cycling. The obvious question arises as to whether a constitutive model characterized using an isothermal data base can adequately predict material response under thermomechanical conditions. An experimental program was initiated within the HOST program to address this particular concern. The results of the most recent isothermal and thermomechanical experiments are described.

Ellis, J. R.↗

Automated Performance Characterization of DSN System Frequency Stability Using Spacecraft Tracking Data

This software provides an automated capability to measure and qualify the frequency stability performance of the Deep Space Network (DSN) ground system, using daily spacecraft tracking data. The results help to verify if the DSN performance is meeting its specification, therefore ensuring commitments to flight missions; in particular, the radio science investigations. The rich set of data also helps the DSN Operations and Maintenance team to identify the trends and patterns, allowing them to identify the antennas of lower performance and implement corrective action in a timely manner. Unlike the traditional approach where the performance can only be obtained from special calibration sessions that are both time-consuming and require manual setup, the new method taps into the daily spacecraft tracking data. This new approach significantly increases the amount of data available for analysis, roughly by two orders of magnitude, making it possible to conduct trend analysis with good confidence. The software is built with automation in mind for end-to-end processing. From the inputs gathering to computation analysis and later data visualization of the results, all steps are done automatically, making the data production at near zero cost. This allows the limited engineering resource to focus on high-level assessment and to follow up with the exceptions/deviations. To make it possible to process the continual stream of daily incoming data without much effort, and to understand the results quickly, the processing needs to be automated and the data summarized at a high level. Special attention needs to be given to data gathering, input validation, handling anomalous conditions, computation, and presenting the results in a visual form that makes it easy to spot items of exception/ deviation so that further analysis can be directed and corrective actions followed.

Pham, Timothy T.↗

Automated Performance Characterization of DSN System Frequency Stability Using Spacecraft Tracking Data

This software provides an automated capability to measure and qualify the frequency stability performance of the Deep Space Network (DSN) ground system, using daily spacecraft tracking data. The results help to verify if the DSN performance is meeting its specification, therefore ensuring commitments to flight missions; in particular, the radio science investigations. The rich set of data also helps the DSN Operations and Maintenance team to identify the trends and patterns, allowing them to identify the antennas of lower performance and implement corrective action in a timely manner. Unlike the traditional approach where the performance can only be obtained from special calibration sessions that are both time-consuming and require manual setup, the new method taps into the daily spacecraft tracking data. This new approach significantly increases the amount of data available for analysis, roughly by two orders of magnitude, making it possible to conduct trend analysis with good confidence. The software is built with automation in mind for end-to-end processing. From the inputs gathering to computation analysis and later data visualization of the results, all steps are done automatically, making the data production at near zero cost. This allows the limited engineering resource to focus on high-level assessment and to follow up with the exceptions/deviations. To make it possible to process the continual stream of daily incoming data without much effort, and to understand the results quickly, the processing needs to be automated and the data summarized at a high level. Special attention needs to be given to data gathering, input validation, handling anomalous conditions, computation, and presenting the results in a visual form that makes it easy to spot items of exception/deviation so that further analysis can be directed and corrective actions followed.

Pham, Timothy T.↗

The Radio Fundamental Catalogue. I. Astrometry

We present the all-sky catalogue of absolute positions and estimates of correlated flux density of 21,942 compact radio sources determined from processing interferometric visibility data of virtually all VLBI observing sessions at 2 to 23~GHz from 72 programs suitable for absolute astrometry collected for 30 years. We used a novel technique of generation of a dataset of fused observables that allowed us to incorporate all available data in our analysis. The catalogue is the most complete and most precise to date. It forms the foundation and reference for positional astronomy, space geodesy, space navigation, population analysis of active galactic nuclei (AGNs), and provides calibrators for phase-referencing for differential astrometry and VLBI astrophysical observations. Its accuracy was evaluated through a detailed accounting systematic errors, rigorous decimation tests, comparison of different datasets, and comparison with other catalogues. The catalogue samples preferentially the AGNs with a strong contemporary parsec-scale synchrotron emission. Its milliarcsecond level positional accuracy allows association of these AGNs with detections in a wide range of the electromagnetic spectrum from low-frequency radio to gamma-rays and high energy neutrinos. We describe the innovative data processing and calibration technique in full detail, report the in depth analysis of random and systematic positional errors, and provide the list of associations with large surveys at different wavelengths.

Astronomy↗

Fossil fuel CO 2 emissions over metropolitan areas from space: A multi-model analysis of OCO-2 data over Lahore, Pakistan

Urban areas, where gathering more than 55% of the global population, alone contributed to more than 70% of anthropogenic fossil fuel carbon dioxide (CO 2ff ) emissions. Accurate quantification of CO 2ff emissions from urban areas is of great importance to the formulation of global warming mitigation policies to achieve carbon neutrality by 2050. Satellite-based inversion techniques are unique among “top-down” approaches, potentially allowing us to track CO 2ff emission changes over cities globally. However, its accuracy is still limited by incomplete background information, cloud blockages, aerosol contaminations, and uncertainties in models and emission inventories used as prior. To evaluate the current potential of space-based quantification techniques, we present the first attempt to monitor long-term changes in CO 2ff emissions based on the OCO-2 satellite measurements of column-averaged dry-air mole fractions of CO 2 (X CO2 ) over a fast-growing Asian metropolitan area: Lahore, Pakistan. We first examined the OCO-2 data availability at global scale. About 17% of OCO-2 soundings are marked as high-quality soundings by quality flags over the global 70 most populated cities over the period 2014-2019. Cloud blockage and aerosol contamination are the two main causes of data loss. As an attempt to recover additional soundings, we evaluated the effectiveness of OCO-2 quality flags at the city level by comparing three flux quantification methods (WRF-Chem, X-STILT, and flux cross-sectional integration method), all based on the Open-Data Inventory for Anthropogenic Carbon dioxide (ODIAC) product. The satellite/bottom-up emissions (OCO-2/ODIAC) ratios of the high-quality tracks better converged across the three methods compared to the all-data tracks with reduced uncertainties in emissions. Thus, OCO-2 quality flags are useful filters of low-quality OCO-2 retrievals at local scales, although originally designed for global-scale studies. All three methods consistently suggested that the ratio medians are greater than 1, which implies that the ODIAC slightly underestimated the CO2ff emissions over Lahore. Additionally, our estimation of the a posteriori CO2ff emission trend was about 734 kt C/year (i.e., an annual 6.7% increase). 10,000 Monte Carlo simulations of the Mann-Kendall upward trend test showed that less than 10% prior uncertainty for 8 tracks (or less than 20% prior uncertainty for 25 tracks) is required to achieve a greater-than-50% trend significant possibility at a 95% confidence level. It implies that the trend is driven by the prior and not due to the assimilation of OCO-2 retrievals. The key to improving the role of satellite data in CO 2 emission trend detection lies in collecting more frequent high-quality tracks near metropolitan areas to achieve significant constraints from X CO2 retrievals.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

α-cluster structure of 18 Ne

In this work, we investigate α-clustering in 18 Ne and compare it with what is known about clustering in the mirror nucleus 18 O. The excitation function for resonant elastic scattering of 14 O + α was measured in inverse kinematics using the TexAT active-target detector system, covering excitation energies from 8 to 17 MeV. The data were analyzed using a multi-channel R-matrix approach. Detailed spectroscopic information—including excitation energies, spin and parity assignments, and partial α and total widths—was extracted from the R-matrix analysis and compared with theoretical models and previously available data. Correspondence between levels in 18 O and 18 Ne is established. An extensive shell-model analysis of the 18 O– 18 Ne mirror pair shows very good agreement between theory and experiment, especially in the distribution of clustering strength. The comparison reveals that certain states, particularly at higher excitation energies, exhibit significantly stronger α-cluster character than predicted. This suggests that these states have a collective structure aligned with the corresponding α-reaction channel.

6 ≤ A ≤ 19↗

Understanding and modeling current and future coastal wetland methane dynamics (Final Report)

The coastal terrestrial-aquatic interface (TAI) is a highly dynamic component of the Earth system that plays a critical role in biogeochemical cycling. Due to its dynamic nature, the processes that regulate decomposition and methane (CH 4 ) emissions are of greater significance at the TAI than in upland systems. Despite this, we have limited mechanistic understanding of how climate stressors interact to regulate the electron acceptors and donors that determine decomposition pathways within TAIs, including the generation of hot spots and hot moments. Accurately modeling these processes is critical for incorporating the coastal TAI into Earth systems models, such as DOE’s E3SM. With previous DOE support, we adapted an aerobic terrestrial representation of decomposition using PFLOTRAN, a reactive flow and transport model, and added anerobic decomposition pathways, salinity, and oxygen (O 2 ) that fluctuates independently of water table level. However, because this model (PFLOTRAN TAI ) is based on decomposition rates and organic matter carbon to nitrogen ratios from terrestrial systems, its performance in TAI systems is currently limited by the lack of empirical data to properly parameterize variables. In addition, while PFLOTRAN TAI can simulate movement of O 2 into sediments, it is not currently capable of tracking the movement of CH 4 gas through plant tissues due to both current model structure and lack of available data. Our overall objective of the project was the increase our mechanistic understanding of CH 4 dynamics in response to environmental change, such that we can improve the representation of these dynamics in PFLOTRAN. We installed automated flux chambers in a new field-scale active soil warming experiment and set up marsh organs (mesocosms) to test effects of warming, flooding, and salinity. This resulted in a new dataset consisting of chamber-level CH 4 flux measurements across multiple sites, ecological conditions, and timeframes, as well as corresponding measurements on porewater chemistry, soil carbon quality, plant biomass, and redox reaction rates. Using these data, we improved PFLOTRAN TAI to more accurately model CH 4 dynamics and successfully tested our hypotheses. This grant contributed to the professional development of 3 postdocs, 4 undergraduate interns, 4 teacher interns, 17 technicians, and 15 participatory scientists. The automated chamber technology designed for this grant has also been shared with multiple new projects.

54 ENVIRONMENTAL SCIENCES↗

Optical fiber spectroscopy: A study of the luminescent properties of the europium ion for thermal sensors

Recently, there has been interest in developing a distributed temperature sensor integrated into an optical fiber. Such a system would allow embedding of the optical fiber within or on a structural material to provide for continuous monitoring of the material's temperature. Work has already begun on the development of a temperature sensor using the temperature dependent emission spectra from the lanthanide rare earths doped into crystalline hosts. The lifetime, the linewidth and the integrated intensity of this emission are each sensitive to changes in the temperature and can provide a basis for thermometry. One concept for incorporating this phenomena into an optical fiber based sensor involves bonding the optically active material to the cladding of an optical fiber and allowing the luminescent light to couple into the the fiber by the evanescent wave. Experimental work developing this concept has already been reported. Measurements of the linewidth of Eu3+:Y2O3, diffused into a fiber, made by Albin clearly show a strong and regular dependence on temperature over the range of 300 to 1000 K. We report here on a study of the temperature dependence of the lineshape of the emission at 611 nm using the data in references. We focus attention on understanding the general behavior of the Eu3+:Y2O3 system. Building upon understanding of this system we will be able to establish the physical criterial for a good optical fiber based temperature sensor and then to examine available data on other lanthanide rare earths and transition metal ions to determine the best luminescent system for temperature sensing in an optical fiber.

Buoncristiani, A. Martin↗

The Role of Phytoplankton Dynamics in the Seasonal and Interannual Variability of Carbon in the Subpolar North Atlantic - a Modeling Study

We developed an ecosystem/biogeochemical model system, which includes multiple phytoplankton functional groups and carbon cycle dynamics, and applied it to investigate physical-biological interactions in Icelandic waters. Satellite and in situ data were used to evaluate the model. Surface seasonal cycle amplitudes and biases of key parameters (DIC, TA, pCO2, air-sea CO2 flux, and nutrients) are significantly improved when compared to surface observations by prescribing deep water values and trends, based on available data. The seasonality of the coccolithophore and "other phytoplankton" (diatoms and dinoflagellates) blooms is in general agreement with satellite ocean color products. Nutrient supply, biomass and calcite concentrations are modulated by light and mixed layer depth seasonal cycles. Diatoms are the most abundant phytoplankton, with a large bloom in early spring and a secondary bloom in fall. The diatom bloom is followed by blooms of dinoflagellates and coccolithophores. The effect of biological changes on the seasonal variability of the surface ocean pCO2 is nearly twice the temperature effect, in agreement with previous studies. The inclusion of multiple phytoplankton functional groups in the model played a major role in the accurate representation of CO2 uptake by biology. For instance, at the peak of the bloom, the exclusion of coccolithophores causes an increase in alkalinity of up to 4 μmol kg(sup −1) with a corresponding increase in DIC of up to 16 μmol kg(sup −1). During the peak of the bloom in summer, the net effect of the absence of the coccolithophores bloom is an increase in pCO2 of more than 20 μatm and a reduction of atmospheric CO2 uptake of more than 6 mmolm(sup −2) d(sup −1). On average, the impact of coccolithophores is an increase of air-sea CO2 flux of about 27 %. Considering the areal extent of the bloom from satellite images within the Irminger and Icelandic Basins, this reduction translates into an annual mean of nearly 1500 tonnes C yr(sup −1).

Earth Resources↗

Improving Spacecraft Data Visualization Using Splunk

EPOXI, like all spacecraft missions, receives large volumes of telemetry data from its spacecraft, DIF. It is extremely important for this data to be updated quickly and presented in a readable manner so that the flight team can monitor the status of the spacecraft. Existing DMD pages for monitoring spacecraft telemetry, while functional, are limited and do not take advantage of modern search technology. For instance, they only display current data points from instruments on the spacecraft and have limited graphing capabilities, making it difficult to see historical data. The DMD pages have fixed refresh rates so the team must often wait several minutes to see the most recent data, even after it is received on the ground. The pages are also rigid and require an investment of time and money to update. To more easily organize and visualize spacecraft telemetry, the EPOXI team has begun experimenting with Splunk, a commercially-available data mining system. Splunk can take data received from the spacecraft's different data channels, often in different formats, and index all the data into a common format. Splunk allows flight team members to search through the different data formats from a single interface and to filter results by time range and data field to make finding specific spacecraft events quick and easy. Furthermore, Splunk provides functions to create custom interfaces which help team members visualize the data in charts and graphs to show how the health of the spacecraft has changed over time.One of the goals of my internship with my mentor, Victor Hwang, was to develop new Splunk interfaces to replace the DMD pages and give the spacecraft team access to historical data and visualizations that were previously unavailable. The specific requirements of these pages are discussed in the next section.

spacecraft missions↗

Assessment and Improvement of RANS-based Transition Models based on Experimental Data of the Common Research Model with Natural Laminar Flow

Transition models based on auxiliary transport equations augmenting the Reynolds-averaged Navier-Stokes (RANS) framework often rely upon the correlations that were derived from a limited number of low-speed experiments and do not account for all of the transition mechanisms and/or their variation with the significant flow parameters. Available data from a recent experiment in the National Transonic Facility at the NASA Langley Research Center are used to assess the current transition modeling capability in NASA's OVERFLOW 2.2o code for a swept wing configuration at transonic cruise conditions. Specifically, the OVERFLOW solutions are used together with detailed stability analysis of the boundary layer flow over the new Common Research Model with Natural Laminar Flow (CRM-NLF) to evaluate the accuracy and the robustness of the transport-equation-based transition models, with the goal of proposing improvements that would help to strengthen the physical basis of these models for the important class of flows involving the combined effects of crossflow and flow compressibility. Results highlight the significant underprediction of the laminar flow extent within the inboard region of the wing, wherein the onset of transition may be attributed to a gradual amplification of Tollmien-Schlichting instabilities.

Boundary layer transition↗

Optical vibrational spectra and proposed crystal structure of ε-UO 3

ε-UO 3 is an exotic polymorph in the uranium trioxide system with an undetermined crystal structure and limited optical vibrational spectroscopic data. To improve understanding of this compound, we synthesize and investigate the crystal structure and optical vibrational spectra of ε-UO 3 . Infrared spectra collected for ε-UO 3 are in good agreement with previously published results, and our studies extend the available data into the low-energy (600–100 cm –1 ) regime. For the first time, Raman spectra are presented for ε-UO 3 using both 785 and 532 nm excitation wavelengths. Previous reports suggest an impurity phase may be present in ε-UO 3 produced by calcination of U 3 O 8 ; however, spectral center-of-mass calculations, principal component analyses, and Raman spectroscopic mapping employed to investigate this possibility indicate that the product of U 3 O 8 calcined in O 3 (g) in this work is likely phase-pure. A possible novel structure solution for ε-UO 3 is determined via Rietveld refinement of powder X-ray diffraction data and is triclinic, P-1, with a = 4.01 Å, b = 3.85 Å, c = 4.18 Å, and α = 98.26°, β = 90.41°, γ = 120.46° (R wp = 8.30%). The asymmetric unit of ε-UO 3 consists of U(VI) in hexagonal bipyramidal coordination with displaced equatorial oxygen. Further analysis reveals that the structure of ε-UO3 is best described by a 2 × 1 × 2 supercell structure in P-1 with a = 8.03 Å, b = 3.86 Å, c = 8.37 Å with α = 98.26°, β = 90.41°, and γ = 120.46°, although a higher-symmetry structure is possible. Optical vibrational spectroscopic and structural measurements of ε-UO 3 presented here furthers our understanding of this complex uranium oxide and clarifies the origin of reported structural similarity to U 3 O 8 .

-UO3↗

Nuclear Data Sheets for A=214

Here, experimental nuclear structure and decay data are evaluated for all of 12 known nuclides of mass 214 (Hg, Tl, Pb, Bi, Po, At, Rn, Fr, Ra, Ac, Th, Pa). For each nuclide, detailed evaluated spectroscopic information is presented in each reaction and decay, and the best values combining all available data are recommended for level properties, γ and β radiations, and other spectroscopic properties in the Adopted Levels and Gammas. The present evaluation supersedes the earlier one on A=214 by S.-C. Wu (2009Wu02), published in Nuclear Data Sheets 110, 681 (2009).

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Precision measurements on oxygen formation in stellar helium burning with gamma-ray beams and a Time Projection Chamber

The carbon/oxygen (C/O) ratio at the end of stellar helium burning is the single most important nuclear input to stellar evolution theory. However, it is not known with sufficient accuracy, due to large uncertainties in the cross-section for the fusion of helium with 12 C to form 16 O, denoted as 12 C( α , γ ) 16 O. Here we present results based on a method that is significantly different from the experimental efforts of the past four decades. With data measured inside one detector and with vanishingly small background, angular distributions of the 12 C( α , γ ) 16 O reaction were obtained by measuring the inverse 16 O( γ , α ) 12 C reaction with gamma-beams and a Time Projection Chamber (TPC) detector. We agree with current world data for the total reaction cross-section and further evidence the strength of our method with accurate angular distributions measured over the 1 - resonance at E cm ~2.4 MeV. Our technique promises to yield results that will surpass the quality of the currently available data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Implementing an electronic sideband offset lock for isotope shift spectroscopy in radium

We demonstrate laser frequency stabilization with at least 6 GHz of offset tunability using an in-phase/quadrature (IQ) modulator to generate electronic sidebands (ESB) on a titanium sapphire laser at 714 nm and we apply this technique to perform isotope shift spectroscopy of 226 Ra and 225 Ra. By locking the laser to a single resonance of a high finesse optical cavity and adjusting the lock offset, we determine the frequency difference between the magneto-optical trap (MOT) transitions in the two isotopes to be 2630.0 ± 0.3 MHz, a factor of 29 more precise than the previously available data. Using the known value of the hyperfine splitting of the 3 P 1 level, we calculate the isotope shift for the 1 S 0 to 3 P 1 transition to be 2267.0 ± 2.2 MHz, a factor of 8 more precise than the best available value. Our technique could be applied to countless other atomic systems to provide unprecedented precision in isotope shift spectroscopy and other relative frequency comparisons.

47 OTHER INSTRUMENTATION↗

Building ControlScore: General Service Administration Office Building Deployment

Improvements to building control systems can lead to energy savings and increased occupant comfort. In an optimized system, process variables such as air temperature will closely follow their desired setpoints and avoid excess energy use. Typically, experts must manually inspect individual control loops to identify poor performance and opportunities for improvement. However, this approach is difficult in modern buildings that have a prohibitively large number of controllers. To address this issue, Pacific Northwest National Laboratory (PNNL) created the ControlScore concept, which takes operating data from the many controllers within a building and generates standardized scores for each loop on a scale of 0 to 10 (a score of 0 indicates poor control, a score of 10 indicates good control). PNNL applied the Building ControlScore application to all available data from a General Services Administration office building within the period of January 1, 2023, to March 9, 2023. The building scored a 4.7 overall, with all 74 of the building’s loops fitting a roughly normal distribution centered around 5. These results indicate that the analyzed systems have below-average performance with room for improvement, especially in the poorly scored systems. Airflow loops tended to have much lower scores than zone temperature loops. The lowest and highest performing systems in the building section were identified, as were all loops with a score less than 1. While the ControlScore identifies loops and systems that aren’t meeting their designated setpoints, it does not indicate the cause of those issues. For example, consider a supply air terminal unit’s airflow loop that received a low score due to it delivering less air than specified by the setpoint. The lower-than-desired airflow could be due to equipment limitations (e.g., the terminal unit or duct serving is too small to accommodate that airflow), malfunctioning equipment (e.g., a stuck damper or bad sensor), or something else entirely. The ControlScore does not diagnose problems it simply identifies the symptoms that can be explored and addressed by building operators.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Neutrally stable atmospheric flow over a two-dimensional rectangular block

The phenomena of atmospheric flow over a two dimensional surface obstruction such as a building modeled as a rectangular block are analyzed by an approach using the Navier-Stokes equations with a two equation model of turbulence. The partial differential equations for the vorticity, stream function, turbulence kinetic energy, and turbulence length scale are solved by a finite difference technique. The predicted results are in agreement with the limited experimental data available. Current computed results show that the separation bubble originates from the upper front corner of the block and extends approximately 11.5 block heights behind the block. The decay of the mean velocity along the wake center line coincides almost perfectly with the experimental data. The vertical profiles of the mean velocity defect are also in reasonable agreement with wind tunnel results. Velocity profiles in the mixing region are shown to agree with the error function profile typically found in the shear layer. Details of the behavior of the turbulence kinetic energy and the turbulence length scale are also discussed.

Shieh, C. F.↗

Constraints on rift thermal processes from heat flow and uplift

The implications of heat flow data available from five major Cenozoic continental rift systems for the processes of continental rifting are discussed, and simple thermal models of lithospheric thinning which predict uplift are used to further constrain the thermal processes in the lithosphere during rifting. Compilations of the heat flow data are summarized and the salient results of these compilations are briefly discussed. The uplift predictions of the slow and rapid thinning models, in which thinning is assumed to occur at a respectively slower and faster rate than heat can be conducted into the lithosphere, are presented. Comparison of uplift rates with model results indicates that the lithosphere is in a state between the two models. While uplift is predicted to continue after thinning has ceased due to thermal relaxation of the lithosphere, the rapid thinning model is always predicted to apply to surface heat flow, and an anomaly in this flow is not predicted to develop until after thinning has stopped.

Morgan, P.↗