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At least 991 records · Page 55

Ionospheric ion composition from satellite measurements made during 1970-1980 - Altitude profiles

Ion-mass spectrometers were carried by a number of satellites in the 1970s. The ion-composition measurements from two of these missions, the Orbiting Geophysical Observatory-6 and the Atmosphere Explorer-C, are collected into an ion composition data base to evaluate several widely used empirical and theoretical models for the species H(+), He(+), N(+), O(+), NO(+), N2(+), and O2(+). The data base covers all latitudes and local times, and the altitude range from 150 km to 1200 km, but here altitude plots are presented of the ion densities at noon and at dip latitudes of 20-40 deg N. The satellite data are compared with an early ion-density profile, with the Koehnlein and IRI-90 empirical models, and with the Utah State University theoretical ionosphere model. These comparisons serve to verify some aspects of the models, but they also reveal some outstanding differences. The solar activity dependence of H(+), He(+), N(+), and O(+) is demonstrated, although this has not been possible for the molecular ions because low altitude measurements have not been made near solar maximum.

Hoegy, W. R.↗

A study of pressure-based methodology for resonant flows in non-linear combustion instabilities

This paper presents a systematic assessment of a large variety of spatial and temporal differencing schemes on nonstaggered grids by the pressure-based methods for the problems of fast transient flows. The observation from the present study is that for steady state flow problems, pressure-based methods can be very competitive with the density-based methods. For transient flow problems, pressure-based methods utilizing the same differencing scheme are less accurate, even though the wave speeds are correctly predicted.

Yang, H. Q.↗

Hubble Space Telescope Faint Object Spectrograph and ground-based observations of the broad absorption line quasar 0226-1024

Faint Object Spectrograph data from the Hubble Space Telescope of the broad absorption line quasar 0226-1024 have revealed the presence of 8-10 absorbing ions between 680 and 1000 A (restframe): C III, N III, N IV, O III, O IV, O VI, S V, S VI, possibly Ne VIII, and possibly O V* arising from a metastable excited state. We also present ground-based optical observations of the broad line troughs for the following ions: H I, C IV, N V, Si IV, and possibly Fe III, S IV, P V, and C III* (also arising from a metastable excited state). The results of this fit are used to estimate the absorbing ionic column densities. There is evidence that the broad absorption line clouds are optically thick and either do not completely cover the continuum source or narrow unresolved lines are present.

Korista, Kirk T.↗

Experimental verification of a progressive damage model for composite laminates based on continuum damage mechanics

Progressive failure is a crucial concern when using laminated composites in structural design. Therefore the ability to model damage and predict the life of laminated composites is vital. The purpose of this research was to experimentally verify the application of the continuum damage model, a progressive failure theory utilizing continuum damage mechanics, to a toughened material system. Damage due to tension-tension fatigue was documented for the IM7/5260 composite laminates. Crack density and delamination surface area were used to calculate matrix cracking and delamination internal state variables, respectively, to predict stiffness loss. A damage dependent finite element code qualitatively predicted trends in transverse matrix cracking, axial splits and local stress-strain distributions for notched quasi-isotropic laminates. The predictions were similar to the experimental data and it was concluded that the continuum damage model provided a good prediction of stiffness loss while qualitatively predicting damage growth in notched laminates.

Coats, Timothy William↗

An approximate Kalman filter for ocean data assimilation: An example with an idealized Gulf Stream model

A practical method of data assimilation for use with large, nonlinear, ocean general circulation models is explored. A Kalman filter based on approximation of the state error covariance matrix is presented, employing a reduction of the effective model dimension, the error's asymptotic steady state limit, and a time-invariant linearization of the dynamic model for the error integration. The approximations lead to dramatic computational savings in applying estimation theory to large complex systems. We examine the utility of the approximate filter in assimilating different measurement types using a twin experiment of an idealized Gulf Stream. A nonlinear primitive equation model of an unstable east-west jet is studied with a state dimension exceeding 170,000 elements. Assimilation of various pseudomeasurements are examined, including velocity, density, and volume transport at localized arrays and realistic distributions of satellite altimetry and acoustic tomography observations. Results are compared in terms of their effects on the accuracies of the estimation. The approximate filter is shown to outperform an empirical nudging scheme used in a previous study. The examples demonstrate that useful approximate estimation errors can be computed in a practical manner for general circulation models.

Fukumori, Ichiro↗

Experimental Verification of a Progressive Damage Model for IM7/5260 Laminates Subjected to Tension-Tension Fatigue

The durability and damage tolerance of laminated composites are critical design considerations for airframe composite structures. Therefore, the ability to model damage initiation and growth and predict the life of laminated composites is necessary to achieve structurally efficient and economical designs. The purpose of this research is to experimentally verify the application of a continuum damage model to predict progressive damage development in a toughened material system. Damage due to monotonic and tension-tension fatigue was documented for IM7/5260 graphite/bismaleimide laminates. Crack density and delamination surface area were used to calculate matrix cracking and delamination internal state variables to predict stiffness loss in unnotched laminates. A damage dependent finite element code predicted the stiffness loss for notched laminates with good agreement to experimental data. It was concluded that the continuum damage model can adequately predict matrix damage progression in notched and unnotched laminates as a function of loading history and laminate stacking sequence.

Coats, Timothy W.↗

Charge and Spin Dynamics of the Hubbard Chains

We calculate the local correlation functions of charge and spin for the one-chain and two-chain Hubbard model using density matrix renormalization group method and the recursion technique. Keeping only finite number of states we get good accuracy for the low energy excitations. We study the charge and spin gaps, bandwidths and weights of the spectra for various values of the on-site Coulomb interaction U and the electron filling. In the low energy part, the local correlation functions are different for the charge and spin. The bandwidths are proportional to t for the charge and J for the spin respectively.

Park, Youngho↗

Solid-State Power Generating Microdevices for Distributed Space System Architectures

Deep space missions have a strong need for compact, high power density, reliable and long life electrical power generation and storage under extreme temperature conditions. Conventional power generating devices become inefficient at very low temperatures (temperatures lower than 200 K encountered during Mars missions for example) and rechargeable energy storage devices cannot be operated thereby limiting mission duration. At elevated temperatures (for example for planned solar probe or Venus lander missions), thin film interdiffusion destroys electronic devices used for generating and storing power. Solar power generation strongly depends upon the light intensity, which falls rapidly in deep interplanetary missions (beyond 5 AU), and in planetary missions in the sun shadow or in dusty environments (Mars, for example). Radioisotope thermoelectric generators (RTGs) have been successfully used for a number of deep space missions RTGs. However, their energy conversion efficiency and specific power characteristics are quite low, and this technology has been limited to relatively large systems (more than 100 W). The National Aeronautics and Space Administration (NASA) and the Jet Propulsion Laboratory (JPL) have been planning the use of much smaller spacecrafts that will incorporate a variety of microdevices and miniature vehicles such as microdetectors, microsensors, and microrovers. Except for electrochemical batteries and solar cells, there are currently no available miniaturized power sources. Novel technologies that will function reliably over a long duration mission (ten years and over), in harsh environments (temperature, pressure, and atmosphere) must be developed to enable the success of future space missions. It is also expected that such micropower sources could have a wide range of terrestrial applications, in particular when the limited lifetime and environmental limitations of batteries are key factors. Additional information is contained in the original extended abstract.

Fleurial, J.-P.↗

Quantum Chemical Evaluation of the Astrochemical Significance of Reactions between S Atom and Acetylene or Ethylene

Addition-elimination reactions of S atom in its P-3 ground state with acetylene (C2H2) and ethylene (C2H4) were characterized with both molecular orbital and density functional theory calculations employing correlation consistent basis sets in order to assess the likelihood either reaction might play a general role in astrochemistry or a specific role in the formation of S2 (X (sup 3 SIGMA (sub g) (sup -)) via a mechanism proposed by Saxena and Misra (Mon. Not. R. Astron. Soc. 1995, 272, 89). The acetylene and ethylene reactions proceed through C2H2S ((sup 3)A")) and C2H4S ((sup 3)A")) intermediates, respectively, to yield HCCS ((sup 2)II)) and C2H3S ((sup 2)A')). Substantial barriers were found in the exit channels for every combination of method and basis set considered in this work, which effectively precludes hydrogen elimination pathways for both S + C2H2 and S + C2H4 in the ultracold interstellar medium where only very modest barriers can be surmounted and processes without barriers tend to predominate. However, if one or both intermediates is formed and stabilized efficiently under cometary or dense interstellar cloud conditions, they could serve as temporary reservoirs for S atom and participate in reactions such as S + C2H2S (right arrow) S2 = C2H2 or S + C2H4S (right arrow) S2 + C2H4. For formation and stabilization to be efficient, the reaction must possess a barrier height small enough to be surmountable at low temperatures yet large enough to prevent redissociation to reactants. Barrier heights computed with B3LYP and large basis sets are very low, but more rigorous QCISD(T) and RCCSD(T) results indicate that the barrier heights are closer to 3-4 kcal/mol. The calculations therefore indicate that S + C2H2 or S + C2H4 could contribute to the formation of S2 in comets and may serve as a means to gauge coma temperature. The energetics of the ethylene reaction are more favorable.

Woon, David E.↗

Electron Stark Broadening Database for Atomic N, O, and C Lines

A database for efficiently computing the electron Stark broadening line widths for atomic N, O, and C lines is constructed. The line width is expressed in terms of the electron number density and electronatom scattering cross sections based on the Baranger impact theory. The state-to-state cross sections are computed using the semiclassical approximation, in which the atom is treated quantum mechanically whereas the motion of the free electron follows a classical trajectory. These state-to-state cross sections are calculated based on newly compiled line lists. Each atomic line list consists of a careful merger of NIST, Vanderbilt, and TOPbase line datasets from wavelength 50 nm to 50 micrometers covering the VUV to IR spectral regions. There are over 10,000 lines in each atomic line list. The widths for each line are computed at 13 electron temperatures between 1,000 K 50,000 K. A linear least squares method using a four-term fractional power series is then employed to obtain an analytical fit for each line-width variation as a function of the electron temperature. The maximum L2 error of the analytic fits for all lines in our line lists is about 5%.

Liu, Yen↗

High Modulus and High T(sub g) Thermally Stable Polymers from p-Ethynyl-Terminated Rigid-Rod Monomers

Novel p-ethynyl-substituted rigid rod monomers were studied by pressure Differential Scanning Calorimetry (DSC), ThermoGravimetric Analysis (TGA), IsothermoGravimetric Analysis (IGA), and TGA-IR. These monomers, 4,4'-bis(((4-ethynylphenyl)carbonyl)oxy)biphenyl, designated 1, 1,5-bis-(((4-ethynylphenyl)carbonyl)oxy)naphthalene, designated 2, and bis(4-ethynylphenyl)pyromellitimide, designated 3, were polymerized in the solid state. Thermal polymerization in N2 or air produced highly cross-linked resins with polymerization exotherms centered between 212 and 276 C. The (delta)H's of polymerization of these resins in air were found to be double those in N2. When monomers 1 and 2 were heated in air from 23 to 750 C at 10 C/min, the main decomposition product was carbon dioxide, evolving at a maximum rate between 500 and 600 C; water was also detected as a decomposition product. Void-free neat resin moldings, designated lp to 3p, were made by compression molding the monomers and then heating them. The resulting polymers were highly cross-linked, and their glass transition temperatures (T(sub g)) were much higher than their polymerization temperatures. Using ThermoMechanical Analysis (TMA), we found that polymers lp to 3p had T(sub g)'s of 422, 329, and 380 C, respectively. The thermal and thermooxidative stabilities improved when lp to 3p were postcured in N2 (the postcured polymers were designated 1pp to 3pp). The Linear Thermal Expansions (LTE) for lp and 3p were 1% between 23 and 420 C. Using rheological analysis, we could not clearly detect the T(sub g)'s of lp to 3p because their moduli dropped only slightly between 23 and 490 C and the changes in tan beta were very low. Because of high cross-link density, their moduli changed little as the resins went from a glassy to a rubbery state. Their shear storage moduli in air ranged from 0.82 (3p, 3pp) to 1.6 GPa (lpp) at 23 C, from 0.16 (2p) to 0.7GPa(lpp) at 380 C, and from 0.18(lpp)to 0.6GPa(2p) at 490 C. Finally, these novel-p-ethynyl polymers exhibited an excellent combination of high T(sub g), low LTE, and high thermooxidative stability. Most notably, 3pp lost only 3% of its initial weight when it was aged for 500 h at 288 C in air.

Melissaris, Anastasios P.↗

Airborne Laser Altimetry Mapping of the Greenland Ice Sheet: Application to Mass Balance Assessment

In 1998 and '99, the Arctic Ice Mapping (AIM) program completed resurveys of lines occupied 5 years earlier revealing elevation changes of the Greenland ice sheet and identifying areas of significant thinning, thickening and balance. In planning these surveys, consideration had to be given to the spatial constraints associated with aircraft operation, the spatial nature of ice sheet behavior, and limited resources, as well as temporal issues, such as seasonal and interannual variability in the context of measurement accuracy. This paper examines the extent to which the sampling and survey strategy is valid for drawing conclusions on the current state of balance of the Greenland ice sheet. The surveys covered the entire ice sheet with an average distance of 21.4 km between each location on the ice sheet and the nearest flight line. For most of the ice sheet, the elevation changes show relatively little spatial variability, and their magnitudes are significantly smaller than the observed elevation change signal. As a result, we conclude that the density of the sampling and the accuracy of the measurements are sufficient to draw meaningful conclusions on the state of balance of the entire ice sheet over the five-year survey period. Outlet glaciers, however, show far more spatial and temporal variability, and each of the major ones is likely to require individual surveys in order to determine its balance.

Abdalati, W.↗

Microcraters on Apollo 15 and 16 rocks

Microcrater frequency distributions, determined for 11 Apollo 16 rocks and three Apollo 15 rocks, fall into four categories. Category 1 rocks (68415, 68416, 62235) are angular, cratered on one side only, and have moderate crater densities. Category 2 rocks (60016, 66075, 61175) are subrounded, cratered on all sides, and have distributions suggestive of the steady state. Category 3 rocks (61015, 62295) are subangular and cratered on only one side, but the crater frequency distributions have some of the characteristics of category 2 rocks. Category 4 rocks (15015, 15017, 15076, 60335) are angular, cratered on only one side, and have moderated to very low crater densities. The crater frequency distributions of categories 1 and 4 have properties indicating the possibility of estimating the time they were exposed to micrometeor bombardment. Category 1 rocks appear to have been exposed for 2 to 3 m.y. These rocks, particularly 68415, 68416, and 69935, may be ejecta from South Ray Crater, indicating an age of 2 to 3 m.y. for South Ray Crater. Category 4 rocks have been exposed for much shorter periods.

Morrison, D. A.↗

GaAs-oxide interface states - Gigantic photoionization via Auger-like process

Spectral and transient responses of photostimulated current in MOS structures were employed for the study of GaAs-anodic oxide interface states. Discrete deep traps at 0.7 and 0.85 eV below the conduction band were found with concentrations of 5 x 10 to the 12th/sq cm and 7 x 10 to the 11th/sq cm, respectively. These traps coincide with interface states induced on clean GaAs surfaces by oxygen and/or metal adatoms (submonolayer coverage). In contrast to surfaces with low oxygen coverage, the GaAs-thick oxide interfaces exhibited a high density (about 10 to the 14th/sq cm) of shallow donors and acceptors. Photoexcitation of these donor-acceptor pairs led to a gigantic photoionization of deep interface states with rates 1000 times greater than direct transitions into the conduction band. The gigantic photoionization is explained on the basis of energy transfer from excited donor-acceptor pairs to deep states.

Lagowski, J.↗

Saturn Satellite Densities and the C/O Chemistry of the Solar Nebula

The composition of material condensed in the outer solar system is very dependent on the state of carbon and oxygen in the solar or circumplanetary nebula, since oxygen is the dominant solid-forming element in a solar composition gas (in the form of silicates and water ice), and carbon is about half as abundant. Past discussions of solid material formed in these regions have focused on differences expected between material formed near giant planets where carbon is generally expected to be in the reduced, CH4, form and material formed in the outer protoplanetary solar nebula where CO is believed to be the dominant form [1]. The composition and expected density of these materials are quite sensitive to the C and O solar abundances in all these models. We discuss here the effects of recently suggested modifications to solar abundances on the interpretation of the mean densities for satellites in the Saturn system.

Johnson, T. V.↗

Instabilities caused by oscillating accelerations normal to a viscous fluid-fluid interface

The case of two incompressible viscous fluids (with different densities) which meet at a planar interface and are subject to an externally imposed oscillating acceleration directed normal to the interface is studied. The linear evolution of perturbations to the basic-state flow is investigated. It is found that the critical Stokes-Reynolds number and the most unstable perturbation wavelengths are insensitive to the degree of density and viscosity differences between the two fluids.

Jacqmin, David↗

On the dust jet model of SS 433

The dust jet model for production of narrow gamma-ray lines from SS 433 is examined and shown to be implausible. Sputtering rates at disk temperatures are high, and self-absorption rates in the disk and jet are important; both imply that dust particles would easily be destroyed. The energy deposited in the dust jet particles by collisions with the ambient protons should be radiated in the optical and infrared in amounts greatly exceeding that observed. The dust momentum pumps ambient gas out of the beam at rates which imply that for the steady state, the ambient gas has to have an initial temperature exceeding one million K. The ambient medium is also required to have densities exceeding those postulated for the H-alpha-emitting gas jet, and the interaction within the gas jet material would result in appreciable broadening of the H-alpha emission lines. At present, there is no viable model for the steady state production of the gamma-ray line radiation.

Helfer, H. L.↗

Balloon borne in-situ detection of OH in the stratosphere from 37 to 23 km

The OH number density in the stratosphere has been measured over the altitude interval of 37 to 23 km at midday via a balloon-borne gondola launched from Palestine, Texas on July 6, 1988. OH radicals are detected with a laser-induced fluorescence instrument employing a 17-kHz-repetition-rate copper vapor laser-pumped dye laser optically coupled to an enclosed flow, in-situ sampling chamber. OH abundances ranged from 88 + or - 3l pptv in the 36 to 35 km interval to 0.9 + or - 0.8 pptv in the 24 to 23 km interval. The stated uncertainty includes that from both measurement precision and accuracy. Simultaneous detection of ozone and water vapor densities was carried out with separate on-board instruments.

Stimpfle, R. M.↗