Development of an oxidation resistant carbon- carbon system for space shuttle components
Lightweight oxidation resistant carbon-carbon composites for space shuttle leading edge components thermal protection
Forcht, B. A.↗
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Flight-service evaluation of composite structural components
A review of programs aimed at flight-service evaluation of composite materials in various applications is presented. These flight-service programs are expected to continue for up to 5 years and include selective reinforcement of an airplane center wing box a helicopter tail cone, and composite replacements for commercial aircraft spoilers and fairings. These longtime flight-service programs will help provide the necessary information required by commercial airlines to commit advanced composites to aircraft structures with confidence. Results of these programs will provide information concerning the stability of composite materials when subjected to various flight environments.
Dexter, H. B.↗
Structure of lunar glasses by Raman and soft X-ray spectroscopy.
X-ray spectra and Raman spectra have been measured from individual particles of lunar glasses. Each particle was analyzed separately by electron microprobe. Silicon emission shifts vary between parent rock types and can be interpreted as a range of Si-O distances from 1.612 to 1.637 A. Aluminum emission shifts relate to the amount of 4- and 6-coordinated Al in the glass. Raman spectra show broadened bands. Certain bands recur in many specimens and relate to the main normative minerals for the glass bulk composition, olivine, pyroxene, and anorthite.
Fabel, G. W.↗
Age-color relationships in the lunar highlands
The depth of the absorption feature near 1 micron in the reflectance spectra of immature lunar soils is determined primarily by the amount of pyroxene present in the soil. As a soil matures, the agglutinitic glass content increases and the Fe(2+) glass band dominates the absorption feature. An empirical relationship between the 1 micron band depth and the percentage of magnetic agglutinates, and hence maturity, is demonstrated for mature highland soils of a given composition. A similar variation of 1 micron band depth is observed in the telescopic spectra of lunar highland craters and is positively correlated with the surface maturity as determined by the small-impact erosion model of Soderblom (1970). Knowledge of both maturity and the 1 micron band depth of a lunar surface feature allows compositional information to be derived.
Charette, M. P.↗
Satellite spectrophotometry and surface compositions
A summary of available spectrophotometric data for planetary satellites is presented. Most data given is for the 0.3 to about 3 micron spectral region. The spectrophotometric results are compared with spectral reflectivity curves of cosmologically abundant substances to provide information on the possible composition of surfaces of planetary satellites, excluding earth's moon. Water ice and other frosts appear to be common in the outer solar system; however, most surface compositions cannot be unambiguously defined.
Johnson, T. V.↗
Development of a realistic stress analysis for fatigue analysis of notched composite laminates
A finite element stress analysis which consists of a membrane and interlaminar shear spring analysis was developed. This approach was utilized in order to model physically realistic failure mechanisms while maintaining a high degree of computational economy. The accuracy of the stress analysis predictions is verified through comparisons with other solutions to the composite laminate edge effect problem. The stress analysis model was incorporated into an existing fatigue analysis methodology and the entire procedure computerized. A fatigue analysis is performed upon a square laminated composite plate with a circular central hole. A complete description and users guide for the computer code FLAC (Fatigue of Laminated Composites) is included as an appendix.
Humphreys, E. A.↗
Spectroscopic determination of the in-situ composition of epoxy matrices in glass fiber reinforced composites
Computerized infrared analysis is applied to the characterization of a glass-reinforced crosslinked polyester. The method of factor analysis determines the number of independent components which constitute the polymeric matrix. Subsequently, the spectra of those components are fitted by a least-squares criterion to spectra of the multicomponent matrix, or, if the glass spectrum is included as an additional component, to the spectra of composites. The least-squares coefficients yield the matrix composition in terms of the initial reactant composition and the extent of crosslinking.
Antoon, M. K.↗
Spectroscopic determination of the in-situ composition of epoxy matrices in glass-fiber-reinforced composites
Computerized infrared analysis is applied to the characterization of a glass-reinforced crosslinked polyester. The method of factor analysis determines the number of independent components which constitute the polymeric matrix. Subsequently, the spectra of those components are fitted by a least-squares criterion to spectra of the multicomponent matrix, or, if the glass spectrum is included as an additional component, to the spectra of composites. The least-squares coefficients yield the matrix composition in terms of the initial reactant composition and the extent of crosslinking.
Antoon, M. K.↗
On the original igneous source of Martian fines
The composition of the silicate portion of Martian regolith fines indicates derivation of the fines from mafic to ultramafic rocks, probably rich in pyroxene. Rock types similar in chemical and mineralogical composition include terrestrial Archean basalts and certain achondrite meteorites. If these igneous rocks weathered nearly isochemically, the nontronitic clays proposed earlier as an analog to Martian fines could be formed. Flood basalts of pyroxenitic lavas may be widespread and characteristic of early volcanism on Mars, analogous to maria flood basalts on the moon and early Precambrian basaltic komatiites on earth. Compositional differences between lunar, terrestrial, and Martian flood basalts may be related to differences in planetary sizes and mantle compositions of the respective planetary objects.
Baird, A. K.↗
Absorption of visible radiation in atmosphere containing mixtures of absorbing and nonabsorbing particles
The presence of a strongly absorbing material, tentatively identified as graphitic carbon, or 'soot', is indicated by measurements of single-scattering albedo of tropospheric aerosols. Although theoretical calculations based on models of the ways in which soot may mix with other aerosol materials yield the single-scattering albedo values of 0.6, accounted for by a minimum 20% soot by volume, in urban regions and 0.8, yielded by 1-5% soot by volume, in rural settings, it is found that these same values can be produced by similar amounts of the iron oxide magnetite. Magnetite is shown to be indistinguishable from soot by optical measurements performed on bulk samples, and calculation of various mixtures of soot indicate the difficulty of determining aerosol composition by optical scattering techniques.
Ackerman, T. P.↗
Advanced powder metallurgy aluminum alloys and composites
The differences between powder and ingot metallurgy processing of aluminum alloys are outlined. The potential payoff in the use of advanced powder metallurgy (PM) aluminum alloys in future transport aircraft is indicated. The national program to bring this technology to commercial fruition and the NASA Langley Research Center role in this program are briefly outlined. Some initial results of research in 2000-series PM alloys and composites that highlight the property improvements possible are given.
W. B. Lisagor↗
Tough poly(arylene ether) thermoplastics as modifiers for bismaleimides
Several aspects of research on thermoplastics as toughness modifiers are discussed, including the contribution of the backbone chemistry and the concentration of the poly(arylene ether) thermoplastic to fracture toughness, influence of the molecular weight of the poly(arylene ether) thermoplastic on neat resin fracture toughness, and the morphology of the thermoplastic modified networks. The results show that fracture toughness of brittle bismaleimide resins can be improved significantly with poly(arylene ether) thermoplastic levels of 20 percent by weight, and that high molecular weight poly(arylene ether) based on bisphenol A provides the highest degree of toughening. Preliminary composite evaluation shows that improvements in neat resin toughness translate into carbon fabric composite.
Stenzenberger, H. D.↗
Parental magmas of Mare Fecunditatis - Evidence from pristine glasses
Results are presented on the petrography and electron microprobe analyses of 14 discrete glass beads from the Luna 16 core sample (21036,15) from Mare Fecunditatis regolith, that were previously characterized as representing pristine glasses. Compared to Apollo pristine glasses analyzed by Delano (1986), the Luna 16 pristine glasses have higher CaO and Al2O3 contents but lower MgO and Ni. On the basis of their contents of MgO, FeO, Al2O3, and CaO, these pristine glasses could be divided into two groups, A and B. It is suggested that at least two parental magmas are needed to explain the chemical variations among these glasses. The Group B glasses appear to represent primitive parental magma that evolved by olivine fractionation to the compositions of the Luna 16 aluminous mare basalts, whereas the Group A volcanic glasses may represent an unusual new basalt magma type that contains a high plagioclase component.
Jin, Y.↗
The Alphonsus region - A geologic and remote-sensing perspective
A number of interesting questions exist concerning the composition and origin of a number of geologic units in the west-central highlands crater Alphonsus. This paper utilizes a variety of newly obtained remote sensing data to address these questions and improve the current understanding of the geologic history of the Alphonsus region. Near-infrared and UV/VIS reflectance spectra were obtained and analyzed for many of the geologic features, the results of which are presented here. Spectra collected for pyroclastic debris associated with three endogenic dark halo crater complexes on the floor of Alphonsus indicate a basaltic assemblage rich in olivine. These pyroclastic deposits exhibit generally low returns on the depolarized 3.8 cm radar image. An exogenic dark halo crater was identified on the interior of Alphonsus and appears to be composed of a mixture of pyroclastic debris and highlands material. The light plains deposits and other highland units in the Alphonsus region generally exhibit a noritic compostion. However, the Alphonsus central peak is composed of pure anorthosite. This composition is unique within the region.
Coombs, C. R.↗
Remote compositional mapping of lunar titanium and surface maturity
Lunar ilmenite (FeTiO3) is a potential resource capable of providing oxygen for life support and spacecraft propellant for future lunar bases. Estimates of TiO2 content in mature mare soils can be made using an empirical relation between the 400/500 nm reflectance ratio and TiO2 wt percent. A TiO2 abundance map was constructed for the entire near-side lunar maria accurate to + or - 2 wt percent TiO2 using CCD images obtained at the Tumamoc Hill 0.5 m telescope in Tucson, employing bandpass filters centered at 400 and 560 nm. Highest TiO2 regions in the maria are located in western Mare Tranquillitatis. Greater contrast differences between regions on the lunar surface can be obtained using 400/730 nm ratio images. The relation might well be refined to accommodate this possibly more sensitive indicator of TiO2 content. Another potential lunar resource is solar wind-implanted He-3 which may be used as a fuel for fusion reactors. Relative soil maturity, as determined by agglutinate content, can be estimated from 950/560 nm ration images. Immature soils appear darker in this ratio since such soils contain abundant pyroxene grains which cause strong absorption centered near 950 nm due Fe(2+) crystal field transitions. A positive correlation exists between the amount of He-3 and TiO2 content in lunar soils, suggesting that regions high in TiO2 should also be high in He-3. Reflectance spectrophotometry in the region 320 to 870 nm was also obtained for several regions. Below about 340 nm, these spectra show variations in relative reflectance that are caused by as yet unassigned near-UV absorptions due to compositional differences.
Johnson, J. R.↗
Certification of damage tolerant composite structure
A reliability based certification testing methodology for impact damage tolerant composite structure was developed. Cocured, adhesively bonded, and impact damaged composite static strength and fatigue life data were statistically analyzed to determine the influence of test parameters on the data scatter. The impact damage resistance and damage tolerance of various structural configurations were characterized through the analysis of an industry wide database of impact test results. Realistic impact damage certification requirements were proposed based on actual fleet aircraft data. The capabilities of available impact damage analysis methods were determined through correlation with experimental data. Probabilistic methods were developed to estimate the reliability of impact damaged composite structures.
Rapoff, Andrew J.↗
Infrared reflectance spectra (4-12 microns) of typical lunar samples
A laboratory study of the mid-infrared spectral reflectance properties of typical Apollo lunar rock and soil samples was conducted using a modern interferometric spectrometer. The results show that characteristic spectral features exist in the 4-12 micrometer range that are diagnostic of rock composition and mineralogy, especially for the plagioclase-rich rocks and soils. This is the first phase of a comprehensive infrared reflectance study under way to better understand the use of infrared emission spectroscopy for mapping the surface composition of the moon and other silicate bodies.
Nash, Douglas B.↗
Near infrared reflectance spectra: Applications to problems in asteroid-meteorite relationships
An observing program designed to search for evidence of ordinary chondrite parent bodies near the 3:1 Kirkwood Gap was carried out in 1985 and 1986. Studies by Wisdom (1985), Wetherill (1985), and subsequent work by Milani et al. (1989) indicate that the 3:1 Kirkwood gap is the most probable source region for the majority of ordinary chondrite meteorites. The diversity of the reflectance spectra among this small data set is surprising. Early work by Gaffey and McCord (1978) showed that the inner region of the main asteroid belt is dominated by high albedo objects with mafic silicate surfaces. One would expect to see mostly spectra with 1- and 2-micron absorption bands based on this earlier work. Only 5 (of 12) spectra have these expected features. The distribution of taxonomic types presented by Gradie and Tedesco (1982) is in most cases a useful simplification of the compositional structure of the asteroid belt. The range of spectral characteristics seen with higher resolution in the near-IR has not been previously reported and is not represented in the standard asteroid taxonomy. Near-IR spectra contain valuable mineralogical information which enhances knowledge of the composition and structure of asteroids.
Mcfadden, Lucy A.↗