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At least 991 records · Page 55
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NASA NTRS1987

Optical observations related to the molecular chemistry in diffuse interstellar clouds

Observations, which have been published since 1979, of molecular species in diffuse clouds are discussed. Particular attention is given to the ultraviolet measurements of CO with the Copernicus and IUE satellites and to ground-based optical measurements of CH, CH(+), CN, and 02. These data encompass large enough samples to test the chemical schemes expected to occur in diffuse clouds. Upper limits for other species (e.g., H2O, H2O(+), and C3) place restrictions on the pathways for molecular production. Moreover, analysis of the rotational distribution of the C2 molecule results in the determination of the physical conditions of the cloud. These parameters, including density, temperature, and the intensity of the radiation field, are necessary for modeling the chemistry.

Federman, S. R.↗
NASA NTRS1987

The relationship between low activity comets and more active comets

Low activity comets were observed to see if they are normal, or if they show intrinsic differences. The comets were selected because they have no C2 or C3 emissions and sometimes no emissions were detected at all. It is shown that the low activity comets are intrinsically different from normal comets in that they are depleted in C2 and C3 relative to the observed CN, or that they are without any emissions at small heliocentric distances. Possible causes for the differences between the two groups of comets are suggested. Observational effects are discounted, since the same observational set-up and reduction procedure was used in all cases. Discrepancies may be due to differences at the time of formation, or during evolution, or a combination of both.

Cochran, A. L.↗
NASA NTRS1987

Evidence for first polymer in Comet Halley: Polyoxymethylene

The RPA2-Positive Ion Cluster Composition Analyzer (PICCA) on the Giotto spacecraft detected 5 mass peaks with regular spacing of 15 amu up to approximately 120 amu. Starting at 45 amu, the peaks decrease in intensity with increasing mass. Within their half-width they are in good agreement with dissociation products of formaldehyde polymer (POM). A production sequence in which cosmic radiation formed POM from water and carbon monoxide on grains that were aggregated into cometesimals is suggested. Other polymers, possibly containing CN, may also exist. Observations suggest that at least some of the H-, C-, and O-containing dust particles detected by the Particle Impact Analyzer (PIA) on board the Giotto spacecraft and its equivalent on the VEGA-1 and -2 spacecraft contain POM. The properties of POM are consistent with many of the unexpected observations in the coma.

Huebner, W. F.↗
NASA NTRS1987

Comet Sugano-Saigusa-Fujikawa (1983V) - A small, puzzling comet

Spectroscopic and infrared observations of Comet Sugano-Saigusa-Fujikawa (1983V) were obtained during its close approach to the earth on June 11-14, 1983. The forbidden O I production rates of 1.8 + or - 0.9 x 10 to the 26th atoms/s observed on June 12.3 and 7 + or - 3.5 x 10 to the 26th atoms/s on June 13.4 lead to derived water-production rates of 3 x 10 to the 27th mol/s on June 12 and 1.1 x 10 to the 28th mol/s on June 13. The abundances of the minor species NH2, CN, C2, and C3 are unusually low relative to forbidden O I. The upper limit to the average nuclear radius from infrared and visual photometry on June 12-13 (assuming that the entire signal came from the nucleus) is about 370 m. The dust/gas mass ratio was less than 0.01 on June 12 and less than 0.005 on June 13.

Hanner, M. S.↗
NASA NTRS1987

Near-nucleus optical observations of P/Halley

The Near-Nucleus Studies Net of the International Halley Watch has obtained an extensive series of high resolution optical images of P/Halley during its most active phases in 1985-86 which may be useful in interpreting radio observations of Comet Halley. They often show coma structure resulting from anisotropic emission of dust and gas from the inhomogeneous nucleus. Images were obtained in broadband spectral regions to study dust coma morphology, and in medium to narrow spectral bands to isolate the principal emissions of CN, C3, C2, CO+ and H2O+. The goals and methods of near-nucleus studies are discussed and recent studies of 1910 images are briefly reviewed. The role of dust jets and cometary activity in P/Halley is discussed and several examples of anisotropic emission of dust during the current apparition are shown.

Larson, Stephen M.↗
NASA NTRS1988

The small molecular cloud toward HD 169454

Optical absorption line observations of the B1 supergiant HD 169454 reveal the presence of an intervening translucent interstellar cloud. Millimeter wavelength observations of CO emission show that the absorption lines can be attributed to a well-defined cloud approximately 18 by 22 min in extent at the same radial velocity as the C2 and CN absorption lines. The map of the CO emission shows three large condensations and evidence of unresolved structure on smaller scales. Various procedures for determining the cloud mass are compared. The estimated mass is 7-14 M solar masses if the cloud lies at the distance (D about 125 pc) of an extended atomic cloud at the same radial velocity, and is 250-500 M solar masses if the kinematic distance (D about 750 pc) is adopted. The dynamical state of the cloud is examined. The composition and structure of the cloud are discussed with reference to detailed theoretical models and the properties of other interstellar clouds.

Jannuzi, Buell T.↗
NASA NTRS1988

Observations of comets and asteroids

All available ground-based observational techniques are used to study the chemical and physical properties of the small bodies of the solar system, primarily comets and secondarily asteroids. The ultimate goal is to use these bodies to understand the formation and evolution of the solar system. The analysis of charge coupled device (CCD) images of comet P/Halley continued. This included a mojor revision of a paper on the periodicities of CN jets in Halley showing that their periodicity is 7.3 days, not 2.2 days. It also included an analysis of the continuum images which showed that the dust in jets is much redder than in the ambient coma. Calculations with Mie theory suggest that the particles that show the strongest effects of radiation pressure. Much effort was expended devising methods to estimate the level of sky background of the many images in which comet extends to the edge of the chip. Examined images of comet Wilson were taken over many months in 1987. Wilson, a dynamically new comet, shows none of the short-term variability or jet structure (either dusty jets or jets of radicals seen in Halley. This is presumably due to the lack of a mantle or the nucleus. Median-imaging of sky was as a technique for removing residual flat-fielding errors in CCD images. A Monte Carlo model and a convolution model were developed for studying temporal variability of gaseous daughter products.

Ahearn, Michael F.↗
NASA NTRS1988

Imaging and spectroscopy of Comet P/Halley

The goals of this investigation are the analysis of a large set of high-resolution echelle/reticon spectra, and the reduction and analysis of a set of narrow-band-filtered charge coupled device (CCD) images of Comet Halley taken during the preperihelion period at Oak Ridge Observatory by Dr. R. E. McCrosky. The scientific objectives associated with these goals are the determination of the spatial distributions of several important radicals, atoms and ions in the coma. These include C2, CN, C3, H2O(+) and CO(+) from the image data. The analysis of the neutral species distribution with Monte Carlo models will aid in the understanding of their production and decay mechanisms as well as serve as an important indicator of the physical conditions in the inner coma. The spatial distributions of the ions will serve as a guide to constrain the complex model necessary for understanding the interaction of the solar wind and the cometary ions. Work during this past year has been devoted largely to the reduction of the standard star photometry for the CCD image data set, as well as the re-flat-fielding of a number of the comet images. We are pleased to report that despite a number of setbacks and the small effort devoted to this work (2 1/2 months for the PI and a generous share of completely unsupported time by Dr. McCrosky) that this portion of the work has been successfully completed. The goals for the upcoming final year of this project (under a new project number) are to complete the calibration of the CCD image data for inclusion in the IHW archive, to analyze a select portion of the neutral radical images with our Monte Carlo models, and to present the results of the 6300/region spectra as a guide to low-resolution spectral observers in order to yield the unambiguous separation of the contributions of cometary O(1D), airglow O(1D), and the numerous NH2 lines in that region of the spectrum.

Combi, Michael R.↗
NASA NTRS1988

Asteroid and comet surfaces

Photometric and spectrophotometric studies of asteroids and comets are in progress to address questions about the mineralogical relationship between asteroids near the 3:1 Kirkwood gap and ordinary chondrite meteorites and between cometary nuclei and the surface of asteroids. Progress was made on a method to convert the measured excess UV flux in the spectrum of 2201 Oljato to column abundance of OH and CN. Spectral reflectance measurements of large asteroids near the 3:1 Kirkwood gap, which is expected to be the source of ordinary chondrite meteorites, were briefly examined and show no spectral signatures that are characteristic of ordinary chondrite meteorite powders measured in the lab.

Mcfadden, Lucy-Ann↗
NASA NTRS1989

Middle atmosphere electrical energy coupling

The middle atmosphere (MA) has long been known as an absorber of radio waves, and as a region of nonlinear interactions among waves. The region of highest transverse conductivity near the top of the MA provides a common return for global thunderstorm, auroral Birkeland, and ionospheric dynamo currents, with possibilities for coupling among them. Their associated fields and other transverse fields map to lower altitudes depending on scale size. Evidence now exists for motion-driven aerosol generators, and for charge trapped at the base of magnetic field lines, both capable of producing large MA electric fields. Ionospheric Maxwell currents (curl H) parallel to the magnetic field appear to map to lower altitudes, with rapidly time-varying components appearing as displacement currents in the stratosphere. Lightning couples a (primarily ELF and ULF) current transient to the ionosphere and magnetosphere whose wave shape is largely dependent on the MA conductivity profile. Electrical energy is of direct significance mainly in the upper MA, but electrodynamic transport of minor constituents such as smoke particles or CN may be important at other altitudes.

Hale, L. C.↗
NASA NTRS1988

The hydrogen shell game - Pulsational instabilities in hydrogen shell-burning planetary nebula nuclei

Fully nonadiabatic g-mode pulsation calculations have been obtained for evolutionary models of planetary nebula nuclei (PNN) with active hydrogen-burning shells. Expressions have been developed for the phase delays which can develop between the temperature variations and the abundance variations of agents in the CN cycle. G-mode instabilities are noted that are driven by the epsilon mechanism at the position of the nuclear burning shells in standard PNN models. The results indicate that the central stars do not retain sufficient hydrogen to support nuclear burning following ejection of the planetary nebula.

Kawaler, Steven D.↗
NASA NTRS1988

Electron attachment lineshapes, cross sections and rate constants at ultra-low energies in several halomethyl and haloethyl molecules

Electron attachment lineshapes, cross sections and rate constants are reported for the molecules CH2Br2, CF2Br2, CF3Br, CBrCl3, BrCN, C2H2Br4, CH3l, C2H5l and 1,1,1,-C2Cl3F3. Use is made of the krypton photoionization method. In addition, the signal intercomparison technique is used to obtain individual channel cross sections and rate constants for Br(-) and CN(-) formation from BrCN, and for Br(-) and Br2(-) formation from CF2Br2. Present results in 1,1,1,-C2Cl3F3 using a new ion extraction grid geometry are compared with earlier results, and differences discussed in terms of the electric field equipotentials of two extraction systems used in the present work. Approximate potential energy curves for BrCN are presented, and the temperature dependence of the Br(-) channel cross section discussed.

Alajajian, S. H.↗
NASA NTRS1989

Fast molecular shocks. I - Reformation of molecules behind a dissociative shock

The physical and chemical processes that operate in the cooling gas behind a fast, dissociative, single-fluid shock propagating in a dense interstellar cloud are discussed. The treatment extends previous theoretical work on fast molecular shocks by including the effects of the conversion of Ly-alpha photons into radiation of the two-photon continuum and into H2 Lyman band emission lines, the effects of CO photodissociation following line absorption, and the formation and destruction of molecules containing the elements nitrogen, silicon, and sulphur, and of the complex hydrocarbons. Abundance profiles for the molecular species of interest are presented. After molecular hydrogen begins to reform, by means of gas phase and grain surface processes, the neutral species OH, H2O, O2, CO, CN, HCN, N2, NO, SO, and SiO reach substantial abundances. The molecular ions HeH(+), OH(+), SO(+), CH(+), H2(+), and H3(+), are produced while the gas is still hot and partially ionized. Emissions from them provide a possible diagnostic probe of fast molecular shocks.

Neufeld, David A.↗
NASA NTRS1989

Are low-activity comets intrinsically different from more active comets?

A group of comets defined as 'normal' by Cochran (1987) is compared with comets from which no C2 or C3 emissions have been detected and exhibit anomalously low activity. It is established that the low-activity comets are C2- and C3-depleted relative to CN, and that this depletion is not due to these comets' being low producers of all types of gases. A study of all the orbital parameters of the group of comets is conducted, but no parameter is found able to account for the observed difference between normal and low-activity types. Several alternative scenarios for the differences in question are proposed and discussed.

Cochran, Anita L.↗
NASA NTRS1989

Shock chemistry in the molecular clouds associated with SNR IC 443

Observations of several interstellar molecules toward the highly perturbed B and G clouds associated with SNR IC 443 are reported. The results suggest that hot and dense material is present in the SNR, and that shocks are present in both regions. The HCO(+) abundance is shown to be a few times greater that found in cold quiescent gas, in contradiction with previous results. The SO, CS, CN, and NH3 abundances are similar to those found in cold dark clouds.

Ziurys, L. M.↗
NASA NTRS1989

Halley's polymeric organic molecules

The detection of polymeric organic compounds in the mass spectrum of Comet Halley obtained with the Positive Ion Cluster Composition analyzer on Giotto are examined. It is found that, in addition to polyoxymethylene, other polymers and complex molecules may exist in the comet. It is suggested that polymerized hydrogen cyanide may be a source for the observed CN and NH2 jets.

Huebner, W. F.↗
NASA NTRS1989

Fast molecular shocks. II - Emission from fast dissociative shocks

The line radiations emitted in the cooling gas behind a fast dissociative shock are studied. The intensities emitted in high rotational transitions of the neutral molecules CO, SiO, HCN, CN, NO, and SO are estimated, as well as in rovibrational transitions of the molecular ions HeH(+) and OH(+) in radio recombination lines of atomic hydrogen and in fine-structure transitions of C, C(+), O, and Si(+). The predictions are compared with the observed intensities of line emission from the Orion-KL region. For Orion-KL the observations do not exclude, but probably do not require, the presence of a fast dissociative shock. Emission from SiO in high-J rotational states and from vibrationally excited OH(+), HeH(+), HeH(+), and SO(+) may be detectable from dissociative shocks under suitable conditions of preshock density and shock velocity; such emission may prove to be a useful diagnostic probe of fast shock activity.

Neufeld, David A.↗
NASA NTRS1990

Carbon-rich particles in Comet Halley

The majority of particles detected in the coma of Comet Halley contain carbon atoms; many of these grains appear to consist preponderately or only of light elements. These light-element particles may be composed of organic compounds. Of the possible combinations of the elements hydrogen, carbon, nitrogen, and oxygen, numerous examples are found of particles containing the combinations (H,C,O,N), (H,C,N), (H,C,O), and (H,C). These results may bear on the recent detection of polyoxymethylene fragments, the observation of cyanojets (CN patterns consistent with release from solid particles), the possible presence of cyanopolyacetylenes or HCN polymer and the make-up of the CHON particles. If cometary matter could reach the surface of the earth without complete disruption, these diverse organic and mixed particles could create unique microenvironments, possibly with significant or even pivotal prebiotic chemical activity. Here a speculative insight into possible relationships between carbon in comets and carbon in life is given, as well as a brief overview of on-going analysis of data from the highly successful Particle Impact Analyzer (PIA) experiment flown on the Giotto spacecraft for the flyby of Comet Halley (development and implementation of PIA was under the direction of J. Kissel of the Max Planck Institute for Kernphysik, Heidelberg). PIA is a time-of-flight analyzer which obtains mass spectra of ions from individual particles impacting on a Pt-Ag foil target within the instrument.

Clark, Benton C.↗