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All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Credible Criticality Safety Margin in the 30B Package with LEU+ UF 6 and Hypothetical Water Ingress

The commercial nuclear industry is pursuing advancements in fuel and reactor design that increase the uranium enrichment above 5 wt. % 235 U. These advancements will necessitate the ability to transport bulk quantities of UF 6 at increased enrichments. Currently, the 30B cylinder is the primary container used by the industry for UF 6 storage and transportation and has a long history of successful shipments. This container can support up to 2,277 kg of UF 6 at a maximum enrichment of 5 wt. % 235 U. Previous evaluations have assessed the potential impact of criticality safety for 30B transport at higher enrichments but assumed moderator intrusion would not require evaluation. Although current regulations allow for the exception of moderator intrusion for UF 6 packages through the design and quality control of the package content, this exception is limited to enrichments up to 5 wt. % 235 U. Thus, an investigation of moderator intrusion into a 30B cylinder should be performed. Moderator intrusion into a 30B cylinder is a unique condition for criticality safety evaluation in transportation because of the violent chemical reactions that occur between UF 6 and H 2 O. The resulting intrusion is strongly dependent on the breach size, breach location, breach interface solid/ullage of the UF 6 content, the UF 6 distribution (which is temperature dependent), and temperature/pressure conditions which are dynamic in accident conditions. Additionally, the complexity of the HF-UO 2 F 2 -H 2 O interface that occurs during the event can influence the potential solubility of uranium in the system, as well as influence the amount of UF 6 reaction with H 2 O. With the operating experience from Orano Federal Services LLC, the UF 6 chemical expertise from Oak Ridge National Laboratory (ORNL), and the criticality safety expertise from ORNL, this paper evaluates the neutronic conditions (i.e., k eff ) that apply the understood chemistry and experimental conditions that occur during moderator intrusion of a breached 30B cylinder under postulated accidents. This report examines the historical evaluations of UF 6 transport and expands these evaluations for the enrichments expected for nuclear industry advancement. These simulations primarily feature a homogeneous mixture of UF 6 and H 2 O as an infinite media system and as a sphere with water reflection given an impurity limit of 0.5 wt. % UF 6 . This report demonstrates that this H/U limit is valid up to 8 wt. % enrichment for both H 2 O and HF as the moderating mixture. The water-reflected homogeneous mixed spheres evaluated demonstrate the amount of safety margin applied by restricting the 30B cylinder impurity limit to 0.5 wt. %. Additionally, this report evaluates moderator ingress scenarios of a 30B cylinder. The 30B cylinder simulations vary the cylinder orientation, the mass of UF 6 in the system, the mass of H 2 O in the system, and how much H 2 O has reacted with UF 6 . The moderator ingress of a 30B cylinder was evaluated for the water-reflected homogeneous mixed spheres to demonstrate the amount of safety margin applied by restricting the 30B cylinder impurity limit to 0.5 wt. %. These simulations are standard practice and are independent of the UF 6 -H 2 O reaction. This work also explored more complex simulations that layer the H 2 O over the UF 6 , which incorporates the amount of reacted UF 6 as a separate layer and considers solubility limits of UO 2 F 2 in H 2 O as it is produced. This approach is intended to simulate the postulated event of a large hairline crack occurring on a submerged cylinder. Finally, this work considers the potential of H 2 O mixing into the UF 6 solid heterogeneously using a sponge-like model. The water ingress into the UF 6 is treated as random size spheres, and the reaction products form into a layer over the spheres.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Findings on subtask 3.3 – applicability of automated brine chemistry determinations for treatment and recovery processes through facility automation/modularization: engineering design study

Under the Energy & Environmental Research Center’s (EERC’s) ~$\$$22 million Phase II Brine Extraction and Storage Test (BEST) Program, a multimillion-dollar brine treatment technology test bed facility was established in western North Dakota to provide a platform for evaluating developing technologies and approaches for brine treatment and volume reduction. The initial facility, and associated research effort, was funded by the U.S. Department of Energy (DOE), with in-kind contributions provided by several industry participants and the state of North Dakota. Since its opening, the Brine Technology Test Facility (BTTF) has supported performance evaluations of desalination technologies capable of treating high-salinity produced water (PW) and enabled data collection for multiple approaches of PW management and critical material recovery. As part of the decommissioning process for the original project, facility ownership and liability were transferred to Select Water, which is providing the EERC with a continuing site access option for state or federal research and/or commercial technology development. This report documents the findings from a design study conducted by the EERC and the engineering firm that was originally contracted to design and construct the facility (Advanced Engineering and Environmental Services, LLC [AE2S]) that evaluated the current status of BTTF and its systems and developed a retrofit design to increase the facility’s capabilities through automation and modularization of its PW treatment infrastructure. The proposed retrofit will provide DOE and industry with an expanded range of conditioned PW that can be produced at the facility for evaluating fit-for-purpose water treatment technologies, online instrumentation for brine chemistry determination, and systems that recover critical materials like lithium and magnesium. The current facility consists of an 9600-square-foot facility that includes a 40-foot by 65-foot Class 1, Division 2-rated demonstration area and associated control rooms and lab-ready space capable of sourcing oil and gas PW and wastewater from industrial sources or tailoring brine compositions up to 300,000 mg/L total dissolved solids (TDS) and supplying them at rates up to 25 gpm for extended-duration technology demonstrations. The colocation of the facility with Select Water’s water management facilities allows for access and unloading of more than 10,000 bbl/day of trucked water delivered to site and associated access to on-site Class I and Class II brine disposal wells and nearby hazardous waste landfills operated and/or contracted by Select Water to dispose of concentrate and/or effluents associated with the testing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Phenomenon Identification and Ranking Table Development for Future Application Figure-of-Merit Studies on Thermal Energy Storage Integrations with Light Water Reactors

There are no standard prioritization criteria for evaluating thermal energy storage (TES) options for use in integrated energy systems. A framework for proposing, analyzing, and presenting energy storage integration with power producers and users is presented along with a specific figure-of-merit (FOM) study based in this framework. This basis for evaluating storage technologies can provide a structure for the energy industry to analyze and prioritize energy storage in different applications and environments. The phenomena identification and ranking table (PIRT) presents a series of design questions specific to energy storage applications. The FOM study, built in this PIRT framework based on a nuclear-renewable hybrid energy system using TES to produce power and provide process energy for a secondary user, successfully identified specific technologies to use based on the project requirements. Expanding the library of projects using this framework will expand the deployable options for energy storage and increase its potential for energy security.

25 ENERGY STORAGE↗
NASA NTRS1979

Application of LANDSAT digital data for monitoring drought

A technique utilizing transformed LANDSAT digital data for detection of agricultural vegetative water stress was developed during the 1976 South Dakota drought, and expanded to the U.S. Great Plains the following year to evaluate its effectiveness in detecting and monitoring vegetative stress water stress over large areas. This technique, the green index number (GIN), indicated when the vegetation within a segment was undergoing stress. Segments were classified as either moisture-stressed or normal using remote sensing techniques combined with a knowledge of crop condition. The remote sensing-based information was compared to a weekly ground-based index (the crop moisture index) provided by the U.S. Dept. of Commerce. The approaches used and the results from the GIN monitoring program are presented.

Thompson, D. R.↗
DOE OSTI2026

Lignin Extraction and Condensation as a Function of Temperature, Residence Time, and Solvent System in Flow-through Reactors

Solvolytic extraction of lignin from biomass is a critical step in lignin-first biorefining, including the reductive catalytic fractionation (RCF) process. Key to optimal RCF processing is the ability to rapidly extract lignin from biomass at high delignification extents and transfer the lignin molecules to a catalyst surface in a time frame that minimizes lignin condensation reactions. Here, we use a flow-through reactor to study the effects of temperature (175–250 °C), residence time (9 to 36 min), and solvent composition (methanol and methanol–water) on lignin extraction and condensation. We evaluated three metrics at each condition: total delignification, delignification rate, and extent of condensation, the latter measured by a decrease in monomer yield for batch hydrogenolysis reactions of solvolysis liquor compared to batch RCF reactions. We observe that delignification is predominantly determined by temperature, while residence time dictates the lignin condensation extent. Moreover, the extent of both extraction and condensation increased in the methanol–water solvent system compared to that in the methanol system. Lignin extracted in methanol is stable up to 18-min residence times at or below 225 °C, while a majority of the lignin extracted in methanol–water is condensed with a 9-min residence time at 200 °C. These results can inform reactor designs and solvent selection for lignin-first biorefining processes that aim to physically separate the biomass and catalyst.

biorefining↗
DOE OSTI2025

Lignin Extraction and Condensation as a Function of Temperature, Residence Time, and Solvent System in Flow-through Reactors

Solvolytic extraction of lignin from biomass is a critical step in lignin-first biorefining, including the reductive catalytic fractionation (RCF) process. Key to optimal RCF processing is the ability to rapidly extract lignin from biomass at high delignification extents and transfer the lignin molecules to a catalyst surface in a time frame that minimizes lignin condensation reactions. Here, we use a flow-through reactor to study the effects of temperature (175-250 °C), residence time (9 to 36 min), and solvent composition (methanol and methanol-water) on lignin extraction and condensation. We evaluated three metrics at each condition: total delignification, delignification rate, and extent of condensation, the latter measured by a decrease in monomer yield for batch hydrogenolysis reactions of solvolysis liquor compared to batch RCF reactions. We observe that delignification is predominantly determined by temperature, while residence time dictates the lignin condensation extent. Moreover, the extent of both extraction and condensation increased in the methanol-water solvent system compared to that in the methanol system. Lignin extracted in methanol is stable up to 18-min residence times at or below 225 °C, while a majority of the lignin extracted in methanol-water is condensed with a 9-min residence time at 200 °C. These results can inform reactor designs and solvent selection for lignin-first biorefining processes that aim to physically separate the biomass and catalyst.

09 BIOMASS FUELS↗
NASA NTRS1984

A First Evaluation of LANDSAT TM Data to Monitor Suspended Sediments in Lakes

A comparison was made between ground data collected from Lake Chicot, Arkansas, and Thematic Mapper (TM) data collected on September 23, 1982. A preliminary analysis of limited data indicate tht Thematic Mapper data may be useful in monitoring suspended sediment and chlorophyll in a lake with high suspended sediment loads. Total suspended loads ranged from 168 to 508 mg/l. TM Band 3 appears to be most useful with Bands 1, 2 and 4 also containing useful information relative to suspended sediments. Considering water data only, Bands 1, 2 and 3 appear to provide similar information. Bands 3 and 4 are also significantly related. Bands 5 and 7 appear to have independent information content relative to the presence or absence of water. Insufficient range of water temperature ground truth data made an evaluation of TM Band 6 difficult.

Schiebe, F. R.↗
NASA NTRS1973

Vacuum distillation/vapor filtration water recovery, phases 1 and 2

The research is reported on the development of an evaporator for vacuum distillation/vapor filtration VD/VF water reclamation system for use on manned space flights. The design, fabrication, and tests of a six-man evaporator are described. It is concluded that: (1) A condenser with an internal rotating impeller and coolant surfaces directly opposite the condensing surfaces is an effective condenser. (2) The VD/VF evaporator, catalyst unit and condenser function satisfactorily based on thermal, mechanical and recovery performance during a 145-hour evaluation test. (3) The quality of recovered water, as measured by analyses for total organic carbon, pH, conductivity, turbidity, and viable bacteria density was within established limits for potability.

Honegger, R. J.↗
DOE OSTI2025

Hybridization capture sequencing for Vibrio spp. and associated virulence factors

ABSTRACT Proliferation ofVibriospp. in aquatic ecosystems is associated with climate change and, concomitantly, increased incidence of vibriosis. They are autochthonous to aquatic environments globally, but traditional metagenomic methods for detecting and typing pathogenicVibriospp. are challenged by their presence in relatively low abundance and ability to persist in a viable but nonculturable state. In the study reported here, hybridization capture sequencing (HCS) was employed to profile low-abundanceVibriospp. in environmental samples. The HCS panel targeted a family of molecular chaperones (CPN60) specific to 69Vibriospp. and 162Vibrio-specific virulence factors. This approach was evaluated in parallel with traditional whole-community shotgun sequencing in a metagenomic analysis of water and oyster samples collected from the Chesapeake Bay. In addition,Vibrio parahaemolyticusandVibrio vulnificusstrains isolated from the samples were subjected to whole-genome sequencing to determine the genetic characteristics of pathogenicVibriospp. circulating in an aquatic environment. HCS, employed to determine the incidence and characterization of specificVibriospp., yielded significantly greater metagenomic insight, notably a variety of otherVibriospp., including detection ofVibrio cholerae,Vibrio fluvialis, andVibrio aestuarianus, in addition toVibrio parahaemolyticusandVibrio vulnificus, and also important virulence factors not detectable using traditional molecular methods. Thus, pathogenicVibriospp. in aquatic ecosystems may be far more common than currently understood. It is concluded that environmental surveillance should include HCS, a valuable tool for the detection and characterization of pathogenic agents in aquatic ecosystems, notably vibrios. IMPORTANCE The increasing prevalence of pathogenicVibriospp. in aquatic ecosystems, driven by climate change, is closely linked to a rise in cholera and vibriosis cases, emphasizing the need for improved environmental surveillance. Vibrios are naturally occurring in aquatic environments globally, but traditional metagenomic methods for detecting and typing pathogenicVibriospp. are challenged by their presence in relatively low abundance and ability to persist in a viable but nonculturable state. In the study reported here, hybridization capture sequencing was employed to profile low-abundanceVibriospp. in metagenomic samples, namely water and oysters collected from the Chesapeake Bay. This approach was evaluated in parallel with traditional whole-community shotgun sequencing and whole-genome sequencing ofVibrio parahaemolyticusandVibrio vulnificusstrains isolated from the samples. Results suggest pathogenicVibriospp. in aquatic ecosystems may be far more common than currently understood, when multiple methods are considered for environmental surveillance.

Microbiology↗
NASA NTRS1981

The functional status of the human vestibular analysor following 56 days in an aqueous immersion medium

Two male volunteers were kept hypokinetic in the immersion and physiological parameters were evaluated following the experiment. Prophylactic measures (g-forces, physical exercises, and supplementary salt and water) were applied daily. Caloric and equilibrium tests were utilized to evaluate the physiological responses. The functional changes observed after the 56 day immersion were found to be of a moderate type which normalized quite quickly.

Matsnev, E. I.↗
NASA NTRS2021

Evaluation of High Mountain Asia-Land Data Assimilation System (Version 1) from 2003 to 2016, Part I: A Hyper-Resolution Terrestrial Modeling System

This first paper of the two-part series focuses on demonstrating the accuracy of a hyper-resolution, offline terrestrial modeling system used for the High Mountain Asia (HMA) region. To this end, this study systematically evaluates four sets of model simulations at point scale, basin scale, and domain scale obtained from different spatial resolutions including 0.01° (∼1-km) and 0.25° (∼25-km). The assessment is conducted via comparisons against ground-based observations and satellite-derived reference products. The key variables of interest include surface net shortwave radiation, surface net longwave radiation, skin temperature, near-surface soil temperature, snow depth, snow water equivalent, and total runoff. In the evaluation against ground-based measurements, the superiority of the 0.01° estimates are mostly demonstrated across relatively complex terrain. Specifically, hyper-resolution modeling improves the skill in meteorological forcing estimates (except precipitation) by 9% relative to coarse-resolution estimates. The model forced by downscaled forcings in its entirety yields the highest skill in model output states as well as precipitation, which improves the skill obtained by coarse-resolution estimates by 7%. These findings, on one hand, corroborate the importance of employing the hyper-resolution versus coarse-resolution modeling in areas characterized by complex terrain. On the other hand, by evaluating four sets of model simulations forced with different precipitation products, this study emphasizes the importance of accurate hyper-resolution precipitation products to drive model simulations.

Yuan Xue↗
NASA NTRS1983

Investigation of indigenous water, salt and soil for solar ponds

The existence of salt-gradient solar ponds in nature is a strong indication that the successful exploitation of this phenomenon must account adequately for the influences of the local setting. Sun, weather and other general factors are treated elsewhere. This paper deals with water, salt, and soil. A general methodology for evaluating and, where feasible, adjusting the effects of these elements is under development. Eight essential solar pond characteristics have been identified, along with a variety of their dependencies upon properties of water, salt and soil. The comprehensive methodology, when fully developed, will include laboratory investigation in such diverse areas as brine physical chemistry, light transmission, water treatment, brine-soil interactions, sealants, and others. With the Salton Sea solar pond investigation as an example, some methods under development will be described.

Marsh, H. E.↗
NASA NTRS2015

Process Development for Removal of Siloxanes from ISS Atmosphere

Dimethylsilanediol (DMSD) has been identified as a problematic organic contaminant aboard the ISS. This contaminant was initially identified in humidity condensate and in the Water Processor Assembly (WPA) product water in 2010 when routine water quality monitoring an increasing total organic carbon (TOC) trend in the WPA product water. Although DMSD is not a crew health hazard at the levels observed in the product water, it can degrade the WPA catalytic reactor's effectiveness and cause early replacement of Multifiltration Beds. DMSD may also degrade the performance of the Oxygen Generation System (OGS) which uses the WPA product water for electrolysis. An investigation into the source of DMSD has determined that polydimethylsiloxane (PDMS) compounds are likely hydrolyzing in the Condensing Heat Exchangers (CHX) to form DMSD. PDMS compounds are prevalent aboard ISS from a variety of sources, including crew hygiene products, adhesives, caulks, lubricants, and various nonmetallic materials. PDMS compounds are also known to contribute to CHX hydrophilic coating degradation by rendering it hydrophobic and therefore adversely affecting its ability to effectively transmit water to the condensate bus. Eventually this loss in performance results in water droplets in the air flow exiting the CHX, which may lead to microbial growth in the air ducts and may impact the performance of downstream systems. Several options have been evaluated to address these concerns. Modifications to the Water Processor Multifiltration Beds and Catalytic Reactor for removal of DMSD were not considered viable, and did not address the issue with PDMS compound degradation of the CHX coating. Design concepts are now in development for removing PDMS compounds from the air stream before they can reach the CHX coating, thus preventing coating degradation and hydrolysis of the PDMS compounds to DMSD. This paper summarizes the current status of the effort to treat these contaminants on ISS.

Carter, Layne↗
NASA NTRS2012

Heat Rejection from a Variable Conductance Heat Pipe Radiator Panel

A titanium-water heat pipe radiator having an innovative proprietary evaporator configuration was evaluated in a large vacuum chamber equipped with liquid nitrogen cooled cold walls. The radiator was manufactured by Advanced Cooling Technologies, Inc. (ACT), Lancaster, PA, and delivered as part of a Small Business Innovative Research effort. The radiator panel consisted of five titanium-water heat pipes operating as thermosyphons, sandwiched between two polymer matrix composite face sheets. The five variable conductance heat pipes were purposely charged with a small amount of non-condensable gas to control heat flow through the condenser. Heat rejection was evaluated over a wide range of inlet water temperature and flow conditions, and heat rejection was calculated in real-time utilizing a data acquisition system programmed with the Stefan-Boltzmann equation. Thermography through an infra-red transparent window identified heat flow across the panel. Under nominal operation, a maximum heat rejection value of over 2200 Watts was identified. The thermal vacuum evaluation of heat rejection provided critical information on understanding the radiator s performance, and in steady state and transient scenarios provided useful information for validating current thermal models in support of the Fission Power Systems Project.

Jaworske, D. A.↗
NASA NTRSDate not supplied

Mars Entry, Descent, Landing, and Ascent Systems Sensitivities to Landing Site and Atmospheric Dust

Plans for human missions to Mars continue to go through several architectural changes, dating all the way back to the 1950s [1]. The continuous study, reformulation, and refinement of Mars architectures and system concepts is necessary in order to incorporate evolving mission objectives, technology advancements, and growth in the body of knowledge regarding human factors and the various environments of human space travel. This evolution has continued into the 21st century, with architectures concepts such as NASA’s Design Reference Architecture 5.0 in 2009 [2], The Evolvable Mars Campaign in 2016 [3], and as recently as 2020, an architecture focused on a crewed mission as early as the 2030s that aims to minimizing crewed duration and infrastructure investment for the first mission [4]. Within these architectures, numerous studies around the current concept designs for Mars entry, descent, landing, and ascent (EDLA) systems have been performed over the last half a decade [[5], [6], [7], [8], [9], [10]]. Despite the breadth and depth of these studies, landing site, a key design parameter relevant to the design of EDLA systems, has remained nebulous over the years, largely due to the ever evolving mission objectives and architecture concept over the decades. However, the specific landing site has direct impact on the altitude and atmospheric conditions, which subsequently impact the design of EDLA systems. To accommodate the lack of a specific landing site, a baseline reference altitude of 0 km relative to the Mars Orbiter Laser Altimeter (MOLA), which is similar to an Earth sea level reference, has typically been selected and fixed for these past studies. Similarly, a baseline reference atmosphere has typically been utilized in these studies, either the Mars Global Reference Atmospheric Model [11], or a general 1982 standard warm, high pressure atmosphere model derived from Viking lander data [12]. Fig. 1 shows the range of elevations across the surface of Mars. Current architectures are focused on latitudes greater than 30 degrees north in an effort to ensure access to frozen water ice. From the figure, it is quickly evident that elevations over the range of longitudes at or above this latitude are significantly varied between roughly -4 to +4 km MOLA. Based on these observations, initial qualitative assessments of the impacts of landing site elevation on EDLA systems were performed. Fig. 2 depicts the expected trends in EDLA system mass for variations in both land site latitude and elevation. The background coloring is a qualitative evaluation of the current knowledge on ice water availability at the latitudes. Further modeling and simulation was performed to obtain numerical predictions of sensitivities to these parameters. Results indicate up to +2% to -4% mass variation from the current baseline Mars Ascent Vehicle concept, with the potential for greater than 6% mass variation at latitudes greater than 70 degrees north. However, variations in the descent system due to landing site were much more significant with mass variations in the range of -15% to +30% around the current baseline Mars Descent System concept. Additionally, Fig. 3 provides a depiction of potential Mars atmospheric density variations with both dust and Martian season. Though the Martian atmosphere is relatively thin compared to Earth’s atmosphere, it still poses significant impact on the design of EDLA systems. Variations in atmospheric density indicated by this slice of data would have significant impact on the design of EDLA systems. However, due to the highly complex nature of atmospheric flight, a qualitative assessment could not be performed. Rather, sensitivity results relied on modeling and simulation to provide numerical results for sensitivities on the current EDLA design concepts under consideration. Understanding these sensitivities is vital to the overall systems design of a Mars architecture. The resulting mass impacts on EDLA systems, driven by landing site elevation and dust level variations, has rippling impacts throughout the architecture that, ultimately, impact the viability of the architecture. Results showed fairly minor mass impacts to the current Mars Ascent Vehicle baseline configuration, roughly -0.6% to + 0.4% mass variations, while the Mars Descent System say greater variations due to dust, roughly -4% to +6% around the baseline concept.

EDLA↗
DOE OSTI2023

Degradation of Poly- and Perfluoroalkyl Substances (PFASs) in Water via High Power, Energy-Efficient Electron Beam Accelerator

The goal of this study was to evaluate the overall effectiveness of e-beam treatment in the degradation of PFASs in water treatment. This included validation of the expected process flows and required electron beam doses, with the first year dedicated to experimentally assessing the optimal electron beam treatment parameters required to decompose the contaminants of concern. In the second year, FNAL’s technical efforts focused on evaluating three different accelerator technologies that could be implemented in the treatment process of PFASs.

43 PARTICLE ACCELERATORS↗