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At least 973 records · Page 54

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DOE OSTI2020

Long-term hybrid stabilization of the carrier-envelope phase

Controlling the carrier envelope phase (CEP) in mode-locked lasers over practically long timescales is crucial for real-world applications in ultrafast optics and precision metrology. We present a hybrid solution that combines a feed-forward technique to stabilize the phase offset in fast timescales and a feedback technique that addresses slowly varying sources of interference and locking bandwidth limitations associated with gain media with long upper-state lifetimes. We experimentally realize the hybrid stabilization system in an Er:Yb:glass mode-locked laser and demonstrate 75 hours of stabilization with integrated phase noise of 14 mrad (1 Hz to 3 MHz), corresponding to around 11 as of carrier to envelope jitter. Additionally, we examine the impact of environmental factors, such as humidity and pressure, on the long-term stability and performance of the system.

47 OTHER INSTRUMENTATION↗

DOE OSTI2019

Integrable nonlinear evolution of the qubit

Highlights: •We study the nonlinear generalization of the von Neumann equation. •We discuss the nonlinear von Neumann equation for the qubit states. •We analyze solutions to the Riccati system corresponding to evolution of a qubit. -- Abstract: The nonlinear generalization of the von Neumann equation is studied. The global version of this equation preserves convexity of the space of states. The particular case of the evolution of pure states refers to the nonlinear Schrödinger equation discovered by Gisin. The concrete realization of the nonlinear von Neumann equation is investigated in detail for the density matrix representing the qubit states. Such equation reduces to the integrable classical Riccati system of nonlinear ordinary differential equations. An interesting property of the nonlinear dynamics described by this system is the global asymptotical stability of stationary solutions related to evolution from mixed states to pure states.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2026

Evaluating Np(v) disproportionation: effect of Np concentration

The role of Np(V) concentration as a potential chemical driver of Np(V) disproportionation was investigated by probing Np redox chemistry in two different acid media using visible-near-infrared absorbance spectroscopy. In situ spectroscopy of chemically and electrochemically manipulated Np oxidation states at molar concentrations of Np underscores the difficulty in stabilizing pure Np(V), even in dilute acid. A Np(VI) component coexisting with the majority Np(V) component was observed in both HNO 3 and HCl. Electrochemical tuning and subsequent spectroscopic analysis of the Np(VI/V) ratio revealed neptunyl self-complexation as a key mechanism occurring in both acid media. Chemical reduction of the Np(VI) component and stabilization of a minor Np(IV) component in HNO 3 were observed; however, spectral data indicated that these two oxidation states were not observed to coexist, and pure Np(V) was stabilized only briefly. These findings demonstrate that high Np concentrations significantly affect the redox chemistry of Np in acidic solutions. Finally, the occurrence of Np(V) disproportionation could not be definitely determined by spectral data, but other mechanisms such as self-complexation and radiolysis, which potentially compete with disproportionation, must be considered.

Gilson, Sara E. [Oak Ridge National Laboratory (OR↗

DOE OSTI2022

Hydrogen bonds enhanced composite polymer electrolyte for high-voltage cathode of solid-state lithium battery

Polymer electrolyte is one of the important components for developing advanced solid-state lithium batteries (SSLBs). However, the narrow electrochemical stability window restricts the practical application with high-voltage cathodes. In this study, a series of composite solid electrolytes (CSEs), possessing both wide electrochemical stability window (up to 5.0 V vs. Li + /Li) and high ionic conductivity (over 1.35×10 -3 S/cm at 25 °C), were reported by integrating SiO 2 nanoparticles into poly(vinyl ethylene carbonate) polymer electrolyte. The enhanced anti-oxidation performances are mainly caused and confirmed by the local intermolecular interactions of hydrogen bonds in CSE. Based on this CSE, the SSLBs with LiCoO 2 cathode present good cycle stability at high voltage, and the capacity retention with 4.5 V cut-off voltage is about 94% after 200 cycles. This work not only proves the importance of intermolecular interactions in CSE, but also provides an effective method for achieving high-energy SSLBs with enhanced interface compatibility between polymer electrolyte and highvoltage cathodes

25 ENERGY STORAGE↗

NASA NTRS2012

Validation of the Radiometric Stability of the Atmospheric Infrared Sounder

It has been widely accepted that an infrared sounder in low polar orbit is capable of producing climate quality data, if the spectral brightness temperatures have instrumental trends of less than 10 mK/yr. Achieving measurement stability at this level is not only very demanding of the design of the instrument, it is also pushes the state of art of measuring on orbit what stability is actually achieved. We discuss this using Atmospheric Infrared Sounder (AIRS) L1B data collected between 2002 and 2011. We compare the L1B brightness temperature observed in cloud filtered night tropical ocean spectra (obs) to the brightness temperature calculated based on the known surface emissivity, temperature and water vapor profiles from the ECMWF ReAnalysis (ERA) and the growth rates of CO2, N2O and Ozone. The trend in (obs-calc) is a powerful tool for the evaluation of the stability of the 2378 AIRS channels. We divided the channels into seven classes: All channels which sound in the stratosphere (at pressure levels below 150 hPa), 14 micron CO2 sounding, 4 micron CO2 P-branch sounding, 4 micron CO2 R-branch sounding, water vapor sounding, shortwave surface sounding and longwave surface sounding. The peak in the weighting function at 1050 hPa separates sounding and surface channels. The boundary between shortwave and longwave is 5 microns. Except for the stratosphere sounding channels, the remaining six groups have (obs-calc) trends of less than 20 mK/yr. The longwave surface channels have trends of 2 mK/yr, significantly less than the 8 mK/yr trend seem in the shortwave window channels. Based on the design of the instrument, trends within a group of channels should be the same. While the longwave and shortwave trends are less than the canonical 10 mK/yr, the larger trend in the shortwave channels could be an artifact of using the pre-launch determined calibration coefficients. This is currently under evaluation. The trend in (obs-calc) for the non-surface sounding channels, in particular for stratosphere sounding and upper tropospheric water channels, is dominated by artifacts created in calc, most likely due to changes in the ERA Ozone and water vapor. Based on this argument the best estimate of the trend for the channels within a channel group is given by the surface sensitive channels within the group. Based on this consideration we estimated the trend of all AIRS longwave channels as 2 mK/yr, while the shortwave channels have a trend of 8 mK/yr.

CO2↗

DOE OSTI2020

Progress in extending high poloidal beta scenarios on DIII-D towards a steady-state fusion reactor and impact of energetic particles

To prepare for steady-state operation of future fusion reactors (e.g. the International Thermonuclear Experimental Reactor and China Fusion Engineering Test Reactor (CFETR)), experiments on DIII-D have extended the high poloidal beta ( β P ) scenario to reactor-relevant edge safety factor q 95 ~ 6.0, while maintaining a large-radius internal transport barrier (ITB) using negative magnetic shear. Excellent energy confinement quality ( H 98y2 > 1.5) is sustained at high normalized beta ( β N ~ 3.5). This high-performance ITB state with Greenwald density fraction near 100% and q min ≥ 3 is achieved with toroidal plasma rotation V tor ~ 0 at ρ ≥ 0.6. This is a key result for reactors expected to have low V tor . At high β P (≥1.9), large Shafranov shift can stabilize turbulence leading to a high confinement state with a low pedestal and an ITB. At lower β P (<1.9), negative magnetic shear in the plasma core contributes to turbulence suppression and can compensate for reduced Shafranov shift to continue to access a large-radius ITB and excellent confinement with low V tor , consistent with the results of gyrofluid transport simulations. These high- β P cases are characterized by weak/no Alfvén eigenmodes (a.e.) and classical fast-ion transport. At high density, the fast-ion deceleration time decreases and Δ β fast is lower; these reduce a.e. drive. The reverse-shear Alfvén eigenmodes are weaker or stable because the negative magnetic shear region is located at higher radius, away from the peaked fast-ion profile. Resistive wall modes can be a limitation at simultaneous high β N , low internal inductance, and low rotation. Analysis suggests that additional off-axis external current drive could provide a more stable path at reduced q 95 . Based on a DIII-D high- β P plasma with large-radius ITB, two scenarios are proposed for CFETR Q = 5 steady-state operation with ~1 GW fusion power: a lower-$l_i$($l_i$ ~ 0.66) and a higher-$l_i$($l_i$ ~ 0.75) case. Using a Landau closure model, multiple energetic particle (EP) effects on the a.e. stability are analyzed modifying the growth rate of the a.e.s triggered by the neutral-beam-injection EPs and alpha particles, although the stabilizing/destabilizing effect is weak for the cases analyzed. The stabilizing effects of the combined EP species β , energy, and density profile in CFETR need further investigation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

DOE OSTI2023

Grid-forming Control of Single- and Two-Stage Solar PV Systems with Mode Transition

Legacy power systems once dominated by con-ventional synchronous machines are transitioning into systems driven by fast-acting power-electronic converters that integrate renewable resources. The majority of integrated renewables such as PV and wind bring down system inertia and can cause stability issues due to their volatile nature. The state-of-the-art grid-forming (GFM) control is proven to enhance system inertia and stability in low-inertia systems. However, most of the existing GFM inverters are applied for battery systems, which are much more expensive than PV. Motivated by this, in this paper we propose a holistic grid-forming (GFM) control strategy for PV systems without the need of energy storage. The proposed strategy is developed on the secondary level of the grid-forming control that enables the PV inverter to operate smoothly among islanded, synchronization, GFM, and limited grid-forming (LGF) modes. The practical criteria for determining the operation modes are established and implemented based on the grid operation scenarios. Here, the proposed design is successfully validated by case studies with a laboratory prototype using Siemens Software Defined Inverters.

24 POWER TRANSMISSION AND DISTRIBUTION↗

NASA NTRS1994

CO2-Doped Diamond: A Potential Solid-State CO2 Laser Material?

This paper describes a novel concept for a solid-state CO subscript 2 laser medium which, by eschewing the gas-phase approach, may offer prospects for a compact, robust 9 - 11 (micro)m coherent source, coupled with the potentially superior frequency stability characteristics afforded by monolithic solid-state construction.

solid-phase CO2↗

DOE OSTI2024

Iron( IV ) alkyl complexes: electronic structure contributions to Fe–C bond homolysis and migration reactions that form N–C bonds from N 2

High-valent iron alkyl complexes are rare, as they are prone to Fe–C bond homolysis. Here, we describe an unusual way to access formally iron(IV) alkyl complexes through double silylation of iron(I) alkyl dinitrogen complexes to form an NNSi 2 group. Spectroscopically validated computations show that the disilylehydrazido(2−) ligand stabilizes the formal iron(IV) oxidation state through a strongly covalent Fe–N π-interaction, in which one π-bond fits an “inverted field” description. This means that the two bonding electrons are localized more on the metal than the ligand, and thus an iron(II) resonance structure is a significant contributor, similar to the previously-reported phenyl analogue. However, in contrast to the phenyl complex which has an S = 1 ground state, the ground state of the alkyl complex is S = 2, which places one electron in the π* orbital, leading to longer and weaker Fe–N bonds. The reactivity of these hydrazido(2−) complexes is dependent on the steric and electronic properties of the specific alkyl group. When the alkyl group is the bulky trimethylsilylmethyl, the formally iron(IV) species is stable at room temperature and no migration of the alkyl ligand is observed. However, the analogous complex with the smaller methyl ligand does indeed undergo migration of the carbon-based ligand to the NNSi 2 group to form a new N–C bond. This migration is followed by isomerization of the hydrazido ligand, and the product exists as two isomers that have distinct η 1 and η 2 binding of the hydrazido group. Lastly, when the alkyl group is benzyl, the Fe–C bond homolyzes to give a three-coordinate hydrazido(2−) complex which is likely due to the greater stability of a benzyl radical compared to that for methyl or trimethylsilylmethyl. These studies demonstrate the availability of a hydrocarbyl migration pathway at formally iron(IV) centers to form new N–C bonds directly to N 2 , though product selectivity is highly dependent on the identity of the migrating group.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Extensive hydrogen incorporation is not necessary for superconductivity in topotactically reduced nickelates

Abstract A key open question in the study of layered superconducting nickelate films is the role that hydrogen incorporation into the lattice plays in the appearance of the superconducting state. Due to the challenges of stabilizing highly crystalline square planar nickelate films, films are prepared by the deposition of a more stable parent compound which is then transformed into the target phaseviaa topotactic reaction with a strongly reducing agent such as CaH 2 . Recent studies, both experimental and theoretical, have introduced the possibility that the incorporation of hydrogen from the reducing agent into the nickelate lattice may be critical for the superconductivity. In this work, we use secondary ion mass spectrometry to examine superconducting La 1−x X x NiO 2 / SrTiO 3 (X= Ca and Sr) and Nd 6 Ni 5 O 12 / NdGaO 3 films, along with non-superconducting NdNiO 2 / SrTiO 3 and (Nd,Sr)NiO 2 / SrTiO 3 . We find no evidence for extensive hydrogen incorporation across a broad range of samples, including both superconducting and non-superconducting films. Theoretical calculations indicate that hydrogen incorporation is broadly energetically unfavorable in these systems, supporting our conclusion that extensive hydrogen incorporation is not generally required to achieve a superconducting state in layered square-planar nickelates.

Science & Technology - Other Topics↗

DOE OSTI2026

Persistence of collectivity in the low-lying states of 30,31 Na inside the 𝑁 = 20 island of inversion

Near the 𝛽-stability line, nuclei with magic numbers are expected to exhibit spherical ground states. However, mass measurements of neutron-rich nuclei near the 𝑁 = 20 island of inversion have indicated an excess in the binding energies. These results, together with subsequent spectroscopic studies and theoretical works, point to the structural evolution from normal configurations to intruder-deformed configurations characterized by particle-hole excitations across the shell gap. Despite evidence of intruder-dominant ground states for the 30,31 Na isotopes in the vicinity of 𝑁 = 20, a question remains as to whether the deformation persists into the ground-state bands beyond the first excited states. Here, in this work, we report on a heavy-ion inelastic scattering measurement performed with GRETINA, the TRIPLEX device, and the S800 spectrograph to study the low-lying excitations in neutron-rich 30,31 Na . The observed gamma rays for the (4 + ) → (3 + ), (3 + ) → 2$^+_{g.s.}$, and (4 + ) → 2$^+_{g.s.}$ decays in 30 Na and for the (7/2 + ) → (5/2 + ) and (5/2 + )→3/2$^+_{g.s.}$ decays in 31 Na were used to extract the reduced transition probabilities 𝐵⁡(𝐸⁢2↑). We report the first measurement of the 𝐵⁡(𝐸⁢2↑) between the 3/2$^+_{g.s.}$ and the (7/2 + ) states in 31 Na . The results from this study are compared to shell-model calculations, confirming the persistence of large collectivity in the low-lying excited states consistent with the formation of the well-deformed ground-state bands in 30,31 Na .

collective models↗

DOE OSTI2024

High voltage aqueous electrolyte system for lithium metal or graphite anode

The present invention is directed to aqueous solid state electrolytes that comprise a fluoride additive to stabilize the interface between the anode and aqueous electrolyte. The present invention is also directed to methods of making the solid state electrolyte materials and methods of using the solid state electrolyte materials in batteries and other electrochemical technologies.

Xu, Kang↗

DOE OSTI2025

Integrated modeling of advanced tokamaks for tearing mode avoidance on DIII-D

Understanding the physics of the onset and evolution of tearing modes (TMs) in tokamak plasmas is crucial for high-performance steady-state operations. The onset condition of (m,n) = (2,1) tearing stability, $Δ′$ > $Δ_c^′$> 0, has been studied in DIII-D steady-state hybrid discharges with accurate equilibrium reconstruction and well-measured plasma profiles. Here, m is the poloidal mode number and n is the toroidal mode number. The onset of n = 1 TMs is carefully identified using the Mirnov array to determine in-phase signals for the onset time and using electron cyclotron emission measurements to trace back from the saturated island width in the experiments for both initial island width and its growth rate. The tearing stability index $Δ′$ at TM onset is calculated in multiple ways, using the modified Rutherford equation and using the PEST-III or resistive DCON magnetohydrodynamic codes, and the results are in reasonable agreement with each other. The calculated $Δ′$ is compared with an analytical formula of the tearing stability threshold $Δ_c^′$ to determine the condition for the mode onset, $Δ′$ > $Δ_c^′$. Finally, the local gradient effect of the plasma current and the pressure profiles on the tearing stability is investigated in terms of the difference between $Δ′$ and $Δ_c^′$ through a series of modeled equilibria with the parametric variations. A database of experimental mode instability onsets is compatible with the simulated regions of instability obtained from the parametric variations.

Linear stability analysis↗

DOE OSTI2022

Angular-momentum Transport in Proto-neutron Stars and the Fate of Neutron Star Merger Remnants

Both the core collapse of rotating massive stars, and the coalescence of neutron star (NS) binaries result in the formation of a hot, differentially rotating NS remnant. The timescales over which differential rotation is removed by internal angular-momentum transport processes (viscosity) have key implications for the remnant’s long-term stability and the NS equation of state (EOS). Guided by a nonrotating model of a cooling proto-NS, we estimate the dominant sources of viscosity using an externally imposed angular-velocity profile Ω(r). Although the magneto-rotational instability provides the dominant source of effective viscosity at large radii, convection and/or the Tayler–Spruit dynamo dominate in the core of merger remnants where dΩ/dr ≥ 0. Furthermore, the viscous timescale in the remnant core is sufficiently short that solid-body rotation will be enforced faster than matter is accreted from rotationally supported outer layers. Guided by these results, we develop a toy model for how the merger remnant core grows in mass and angular momentum due to accretion. We find that merger remnants with sufficiently massive and slowly rotating initial cores may collapse to black holes via envelope accretion, even when the total remnant mass is less than the usually considered threshold ≈1.2 M TOV for forming a stable solid-body rotating NS remnant (where M TOV is the maximum nonrotating NS mass supported by the EOS). This qualitatively new picture of the post-merger remnant evolution and stability criterion has important implications for the expected electromagnetic counterparts from binary NS mergers and for multimessenger constraints on the NS EOS

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2022

Carbazole-Based Hole Transport Polymer for Methylammonium-Free Tin-Lead Perovskite Solar Cells with Enhanced Efficiency and Stability

As the most commonly used hole transport material (HTM) in tin-lead (Sn-Pb) perovskite solar cells (PSCs), poly(3,4-ethylenedioxythiophene) polystyrenesulfonate (PEDOT:PSS) limits the power conversion efficiency (PCE) and stability of the PSCs due to its acidic characteristics. Herein, an easily synthesized polymer HTM poly[(phenyl)imino[9-(2-ethylhexyl)carbazole]-2,7-diyl] (CzAn) with a shallow highest occupied molecular orbital (HOMO) level of -4.95 eV is used in a p-i-n structure, methylammonium-free, Sn-Pb PSC to replace PEDOT:PSS. Upon optimization using doping and surface engineering, high quality Sn-Pb PSCs could be successfully fabricated, boosting the PCE to 22.6% (stabilized PCE of 21.3%) compared with 21.2% for PEDOT:PSS. The perovskite films prepared on the modified CzAn HTM possess improved crystallinity, reduced trap-state density, and larger carrier mobility resulting in PSCs with greatly improved stability.

carrier mobility↗

DOE OSTI2024

Structure, bonding and electronic characteristics of amorphous Se

Ovonic threshold switching (OTS) selector can effectively improve the storage density and suppress the leakage current of advanced phase-change memory. As a prototypical OTS material, amorphous GeSe is widely investigated. But the attentions paid to amorphous Se (i.e., the functional constituent in amorphous GeSe) is very limited up to now. Here, in this work, we have explored the structure, bonding and electronic characteristics of amorphous Se using ab initio molecular dynamics simulations. The results reveal that the Se atoms in amorphous Se tend to form the 2-coordinated configurations, and they connect with each other to form the long chains. The fraction of vibrational density of state located in high frequency range is relatively large, and the formation energy of Se-Se bond is as large as 4.44 eV, hinting that the Se-Se bonds in chains possess a high stability. In addition, the mid-gap state related to the OTS behavior is also found in the amorphous Se despite of the small proportion. Our findings enrich the knowledge of the amorphous Se, which contributes to the applications of Se-based OTS selectors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2020

Observation of spontaneous ferromagnetism in a two-dimensional electron system

Significance Ground states of low-disorder, interacting, dilute electron systems are of fundamental interest in understanding electron–electron interaction phenomena. Our experimental data on a clean two-dimensional electron system reveal a sequence of transitions as the density is lowered. Starting from high densities, we observe a transition from a metallic state to an exotic insulating phase that is stabilized by disorder and interaction. As we further lower the density, we observe signs of a spontaneous transition to a ferromagnetic ground state and then to a strongly insulating state whose characteristics suggest that it is a pinned solid phase, possibly a (ferromagnetic) Wigner solid. We also find that the onset of ferromagnetism can be controlled by tuning the electrons’ valley degree of freedom.

2D electron system↗

NASA NTRS1991

New bounds on parameter uncertainties for robust stability

The problem of robust stability in linear systems with parametric uncertainties is considered. A method is developed to determine bounds on uncertain parameters in the state-space model of the system, so that stability is preserved. Both continuous- and discrete-time systems are considered. Unlike previous results, the stability bounds are derived in terms of actual parameters instead of their absolute values, and consequently the stable region in the parameter space is not necessarily symmetric with respect to the origin. Furthermore, the uncertain parameters do not have to be linearly independent to each other.

Gao, Zhiqiang↗