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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Friction and wear of plasma-sprayed coatings containing cobalt alloys from 25 deg to 650 deg in air

Four different compositions of self-lubricating, plasma-sprayed, composite coatings with calcium fluoride dispersed throughout cobalt alloy-silver matrices were evaluated on a friction and wear apparatus. In addition, coatings of the cobalt alloys alone and one coating with a nickel alloy-silver matrix were evaluated for comparison. The wear specimens consisted of two, diametrically opposed, flat rub shoes sliding on the coated, cylindrical surface of a rotating disk. Two of the cobalt composite coatings gave a friction coefficient of about 0.25 and low wear at room temperature, 400 and 650 C. Wear rates were lower than those of the cobalt alloys alone or the nickel alloy composite coating. However, oxidation limited the maximum useful temperature of the cobalt composite coating to about 650 C compared to about 900 C for the nickel composite coating.

Sliney, H. E.↗
NASA NTRS1980

Catalyst surfaces for the chromous/chromic redox couple

An electricity producing cell of the reduction-oxidation (REDOX) type is described. The cell is divided into two compartments by a membrane, each compartment containing a solid inert electrode. A ferrous/ferric couple in a chloride solution serves as a cathode fluid which is circulated through one of the compartments to produce a positive electric potential disposed therein. A chromic/chromous couple in a chloride solution serves as an anode fluid which is circulated through the second compartment to produce a negative potential on an electrode disposed therein. The electrode is an electrically conductive, inert material plated with copper, silver or gold. A thin layer of lead plates onto the copper, silver or gold layer when the cell is being charged, the lead ions being available from lead chloride which was added to the anode fluid. If the REDOX cell is then discharged, the current flows between the electrodes causing the lead to deplate from the negative electrode and the metal coating on the electrode will act as a catalyst to cause increased current density.

Giner, J. D.↗
NASA NTRS1980

ESA battery development

The improvement of nickel cadmium batteries and the development of a silver hydrogen cell for spacecraft power systems are discussed. The design of nickel cadmium batteries is examined with a particular emphasis on weight reduction concepts. Results from performance tests on silver hydrogen cells are given and comparisons are made with current nickel cadmium cells.

Young, H. J.↗
NASA NTRS1980

Friction and wear of plasma-sprayed coatings containing cobalt alloys from 25 deg to 650 deg in air

Four different compositions of self-lubricating, plasma-sprayed, composite coatings with calcium fluoride dispersed throughout cobalt alloy-silver matrices were evaluated on a friction and wear apparatus. In addition, coatings of the cobalt alloys alone and of one coating with a nickel alloy-silver matrix were evaluated for comparison. The wear specimens consisted of two, diametrically opposed, flat rub shoes sliding on the coated, cylindrical surface of a rotating disk. Two of the cobalt composite coatings gave a friction coefficient of about 0.25 and low wear at room temperature, 400 and 650 C. Wear rates were lower than those of the cobalt alloys alone or the nickel alloy composite coating. However, oxidation limited the maximum useful temperature of the cobalt composite coating to about 650 C compared to about 900 C for the nickel composite coating.

Sliney, H. E.↗
NASA NTRS1979

Evaluation program for secondary spacecraft cells: Cycle life test

The service life and storage stability for several storage batteries were determined. The batteries included silver-zinc batteries, nickel-cadmium batteries, and silver-cadmium batteries. The cell performance characteristics and limitations are to be used by spacecraft power systems planners and designers. A statistical analysis of the life cycle prediction and cause of failure versus test conditions is presented.

Harkness, J. D.↗
NASA NTRS1980

Study of thermal control systems for orbiting power systems. Materials experiment carrier thermal control system study

Four possible arrangements of the materials experiment carrier (MEC) and power system (PS) thermal control loops were defined which would provide one kW of heat rejection for each kW of power to the MEC payload. These arrangements were compared to the baseline reference concept which provides only 16 kW heat rejection to show the cost of obtaining symmetry in terms of dollars, weight, complexity, growth potential, ease of integration, technology and total launch weight. The results of these comparisons was that the concept which splits the PS thermal control loop into two systems, one to reject PS waste heat and one payload waste heat, appeared favorable. The fluid selection study resulted in recommendation of FC72 as the MEC heat transport fluid based on the thermal and physical characteristics. The coatings reviewed indicated anodized and alodine treated aluminum surfaces or silver teflon are the best choices for the MEC vehicle where durability is an important factor. For high temperature radiators silver teflon or zinc orthotitanate are recommended choices.

Fleming, M. L.↗
NASA NTRS1981

Catalyst surfaces for the chromous/chromic redox couple

An electricity producing cell of the reduction-oxidation (REDOX) type divided into two compartments by a membrane is disclosed. A ferrous/ferric couple in a chloride solution serves as a cathode fluid to produce a positive electric potential. A chromic/chromous couple in a chloride solution serves as an anode fluid to produce a negative potential. The electrode is an electrically conductive, inert material plated with copper, silver or gold. A thin layer of lead plates onto the copper, silver or gold layer when the cell is being charged, the lead ions being available from lead chloride which has been added to the anode fluid. If the REDOX cell is then discharged, the lead deplates from the negative electrode and the metal coating on the electrode acts as a catalyst to increase current density.

Giner, J. D.↗
NASA NTRS1982

Bridging Gaps Between Refractory Tiles

Excessively large gaps between tiles on Space Shuttle eliminated without time-consuming and costly procedure of removing and replacing tiles. Ceramic tile silver is bonded in gap. Bonded silver prevents airframe under gap from getting too hot during reentry and presents aerodynamically smooth exterior surface.

Haney, J. W. J.↗
NASA NTRS1981

Evaluation program for secondary spacecraft cells: Seventeenth annual report of cycle life test

Acceptance tests were conducted on nickel cadmium, silver cadmium, and silver zinc cells to insure that all cells put into the life cycle program meet the specifications outlined in the respective purchase contracts. Statistical information is presented on cell performance characteristics and limitations. Weaknesses discovered in cell design are reported and aid in research and development efforts toward improving the reliability of space batteries. Battery weaknesses encountered in satellite programs such as IMP, NIMBUS, OGO, OAO, SAS, and TETR were studied and remedied through special tests.

Harkness, J. D.↗
NASA NTRS1981

Development of CdO-graphite-Ag coatings for gas bearings to 427 C

Graphite is one of the most commonly known lubricants. Its effectiveness in a range between room temperature (RT) and 540 C is reportedly improved by adding cadmium oxide. CdO-graphite powder in a gas carrier has been used in numerous applications that rely on dry lubrication. A coating of this composition was developed and successfully tested in foil air bearings for long periods up to a temperature of 427 C and at a normal contacting load (during starting and stopping) of 14 kPa based on bearing projected area. The addition of ultra-fine silver to the CdO-graphite has improved the coating endurance. At 427 C, the CdO-graphite-Ag coating performed better than CdO-graphite without silver, both for extended periods at 14 kPa loading and for limited periods at 35 kPa. At 288 C, the coating was tested for an extended period up to 28 kPa and has also successfully completed high-speed shock tests to an acceleration level of 100g.

Bhushan, B.↗
NASA NTRS1983

Reducing the Resistance of Conductive-Adhesive Bonds

Current pulses lower resistance of silver-filled epoxies. Capacitive discharge reduces interfacial resistance between aluminum surfaces joined with silver-filled epoxy. Technique offers noninvasive solution to problem of attaching grounding brackets to aluminum honeycomb structures.

Guertin, L. J.↗
NASA NTRS1982

Terrestrial growth of lead-tin-telluride by techniques related to low G growth

A modified Bridgman-Stockbarger furnace was constructed for a study of the solidification of silver, germanium and lead-tin-telluride. The melt-solid interface position with respect to the furnace and its temperature profile was determined by measuring the discontinuity in the slope of temperature as a function of position in the melt and in the solid. The results show that the interface position of the semiconductors germanium and lead-tin-telluride was essentially constant with respect to the furnace and hence the growth rate was constant and equal to the sample translation rate of 0.046 cm/min and 0.178 cm/min in each case. The metal, silver, on the other hand showed a continuous interface migration toward the hot zone of the furnace and always exhibited a growth rate which was higher than the ampoule translation rate. The K sub L/K sub S ratio of lead-tin-telluride was determined to be 2.33 + or - 0.06 where K sub L,S denotes the thermal conductivity of the liquid, solid respectively. The value of K sub L was calculated to be about 0.054 Watt 0.1 cm 0.1 K. The diffusion boundary layer thickness was calculated for lead-tin-telluride to be about 0.05 cm using a liquid diffusivity of .00007 sq cm/sec.

Jesser, W. A.↗
NASA NTRS1982

Development of an all-metal thick film cost effective metallization system for solar cells

Electrodes made with pastes produced under the previous contract were analyzed and compared with raw materials. A needle-like structure observed on the electroded solar cell was identified as eutectic copper-silicon, a phase considered to benefit the electrical and metallurgical properties of the contact. Electrodes made from copper fluorocarbon and copper silver fluoride also contained this phase but had poor adhesion. A liquid medium, intended to provide transport during carbon fluoride decomposition was incorporated into the paste resulting in better adhesion. The product survived preliminary environmental tests. A 2 cm by 2 cm solar cell made with fluorocarbon activated copper electrodes and gave 7% AMI efficiency (without AR coating). Both silver fluoride and fluorocarbon screened paste electrodes can be produced for approximately $0.04 per watt.

Ross, B.↗
NASA NTRS1982

Development of technologies for welding interconnects to fifty-micron thick silicon solar cells

A program was conducted to develop technologies for welding interconnects to 50 microns thick, 2 by 2 cm solar cells. The cells were characterized with respect to electrical performance, cell thickness, silver contact thickness, contact waviness, bowing, and fracture strength. Weld schedules were independently developed for each of the three cell types and were coincidentally identical. Thermal shock tests (100 cycles from 100 C to -180 C) were performed on 16 cell coupons for each cell type without any weld joint failures or electrical degradation. Three 48 cell modules (one for each cell type) were assembled with 50 microns thick cells, frosted fused silica covers, silver clad Invar interconnectors, and Kapton substrates.

Patterson, R. E.↗
NASA NTRS1983

Standard free energy of formation of iron iodide

An experiment is reported where silver iodide is used to determine the standard free energy of formation of iron iodide. By using silver iodide as a solid electrolyte, a galvanic cell, Ag/AgI/Fe-FeI2, is formulated. The standard free energy of formation of AgI is known, and hence it is possible to estimate the standard free energy of formation of FeI2 by measuring the open-circuit emf of the above cell as a function of temperature. The free standard energy of formation of FeI2 determined by this method is -38784 + 24.165T cal/mol. It is estimated that the maximum error associated with this method is plus or minus 2500 cal/mol.

Khandkar, A.↗
NASA NTRS1983

Results of apparent atomic oxygen reactions on Ag, C, and Os exposed during the Shuttle STS-4 orbits

Films selected for anticipated reaction with atomic oxygen, namely carbon, silver, and osmium, were exposed during the Shuttle STS-4 mission. A silver film within 5 nm of 225 nm thick was converted to a transparent blue-green interference film within 5 nm of 355 nm thick. Both carbon and osmium films 10-30 nm thick apparently formed volatile oxides and disappeared, except where well shielded. A calculated total of approximately 7 x 10 to the 19th oxygen atoms per sq cm struck the surfaces, which could have removed on the order of 3 microns of material if only 10 percent reacted. The absence of apparent effects on adjacent thin and thick gold films is offered as evidence that sputtering is not responsible.

Peters, P. N.↗
NASA NTRS1984

The friction behavior of semiconductors Si and GaAs in contact with pure metals

The friction behavior of the semiconductors silicon and gallium arsenide in contact with pure metals was studied. Five transition and two nontransition metals, titanium, tantalum, nickel, palladium, platinum, copper, and silver, slid on a single crystal silicon (111) surface. Four metals, indium, nickel, copper and silver, slid on a single crystal gallium arsenide (100) surface. Experiments were conducted in room air and in a vacuum of 10 to the minus 7th power N/sq cm (10 to the minus 9th power torr). The results indicate that the sliding of silicon on the transition metals exhibits relatively higher friction than for the nontransition metals in contact with silicon. There is a clear correlation between friction and Schottky barrier height formed at the metal silicon interface for the transition metals. Transition metals with a higher barrier height on silicon had a lower friction. The same effect of barrier height was found for the friction of gallium arsenide in contact with metals.

Mishina, H.↗
NASA NTRS1983

Welding interconnects to 50-micron silicon solar cells

A program was conducted to develop technologies for welding interconnects to 50-micron thick, 2 by 2 cm solar cells obtained from three suppliers. The cells were characterized with respect to electrical performance, cell thickness, silver contact thickness, contact waviness, bowing, and fracture strength. Weld schedules were independently developed for each of the three cell types and were coincidentally identical. Thermal shock tests (100 cycles from 100 deg to -180 deg C) were performed on 16-cell coupons for each cell type without any weld joint failures or electrical degradation. Three 48-cell modules (one for each cell type) were assembled with 50-micron thick cells, frosted fused silica covers, silver clad Invar interconnectors, and Kapton substrates.

Patterson, R. E.↗