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At least 973 records · Page 54

Tunable Electronic Energy Level Alignment and Exciton Diversity in Organic–Inorganic van der Waals Heterostructures

van der Waals stacking of two-dimensional (2D) materials offers a powerful platform for engineering material interfaces with tailored electronic and optical properties. While most van der Waals multilayers have featured inorganic monolayers, incorporating molecular monolayers introduces additional degrees of tunability and functionality. Here, in this study, we investigate hybrid bilayers composed of atomically thin perylene-based molecular crystals interfaced with monolayer transition metal dichalcogenides (TMDs), specifically MoS 2 and WS 2 . Using the ab initio many-body perturbation theory within the GW approximation and the Bethe-Salpeter equation approach, we predict emergent properties beyond those of the isolated constituent systems. Notably, we find substantial renormalization of monolayer molecular crystal band gap due to TMD-induced polarization. Furthermore, by varying the TMD monolayer, we demonstrate tuning of the energy level alignment of the bilayer and subsequent control over a diversity of lowest-energy excitons, which include strongly bound hybrid excitons and long-lived charge-transfer excitons. These findings establish organic-inorganic van der Waals heterostructures as a promising class of materials for tunable optoelectronic devices and quantum excitonic phenomena, expanding the design space for low-dimensional systems.

GW-BSE calculations↗

A long path-length optical property measurement device for highly transparent detector media

Measurements of the optical properties of highly transparent liquids are necessary for large-scale detectors that seek to detect optical signatures in kiloton-scale or larger volumes. Detailed understanding of the attenuation and scattering properties of fill media is critical to the ability to accurately simulate detector performance, and yet is often unavailable until in-situ measurements can be performed. Moreover, in-situ measurements may rely on effective attenuation lengths or other approximations to characterize performance, rather than absolute measurements of attenuation and scattering. To better understand the optical properties of potential fill media and purification schemes, a system has been developed which provides simultaneous attenuation and differential scattering cross-section measurements for highly transparent liquids. This horizontal, adjustable path-length “long-arm” system provides excellent isolation from the atmosphere, a high degree of vibration insensitivity, and a simple and reliable method of calibration. Further, scattering measurements can be carried out simultaneously at ports along the beamline equipped with optics allowing the selection of scatter angle and polarization. This enables both reliable quantitative scatter measurements and phase-function separation. This system has been extensively tested using deionized (DI) water as a benchmark, and has demonstrated repeatable measurements of attenuation lengths exceeding 100 m and scattering lengths approaching 1 km.

47 OTHER INSTRUMENTATION↗

Radio and optical observations of the jets from L1555 IRS 5

New high-sensitivity radio continuum and optical observations of jets associated with the recently formed star IRS 5 are presented. The observations suggest that IRS 5 is the source of a collimated high-velocity outflow of partially ionized gas that produces the observed bipolar molecular outflow in L1551. The emission from the jets can be traced for over 10 arcsec from IRS 5; the jets are aligned with the axis of the molecular bipolar outflow observed by Snell, Loren, and Plambeck (1981). The integrated radio spectrum of the jets is flat, indicating emission by an optically thin plasma. The total mass of ionized gas is estimated to be 0.4-8 x 10 to the -6th solar mass. The absence of optical emission from the northeast jet is best explained by the presence of a dense disk of gas that lies perpendicular to the outflow axis which obscures the northeast jet and may also be responsible for collimating the outflow into two initially opposed jets.

Snell, R. L.↗

Fabrication techniques for very fast diffractive lenses

Aspheric lenses with arbitrary phase functions can be fabricated on thin light weight substrates via the binary optics fabrication technique. However, it is difficult and costly to fabricate a fast lens (f/number less than 1) for use as the shorter wavelengths. The pitch of the masks and the alignment accuracy must be very fine. For a large lens, the space-bandwidth product of the element can also become impractically large. In this paper, two alternate approaches for the fabrication of fast aspheric diffractive lenses are described. The first approach fabricates the diffractive lens interferometrically, utilizing a spherical wavefront to provide the optical power of the lens and a computer generated hologram to create the aspheric components. The second approach fabricates the aspheric diffractive lens in the form if a higher order kinoform which trades groove profile fidelity for coarser feature size. The design and implementation issues for these two fabrication techniques are discussed.

Tai, Anthony M.↗

Morphology Control of Self-Assembled Three-Phase Au-BaTiO 3 –ZnO Hybrid Metamaterial for Tunable Optical Properties

Microstructural control in metal-dielectric hybrid metamaterials presents enormous opportunities in tailoring the physical properties including the magnetic and optical properties. In this paper, we demonstrate a strong tunability achieved in the microstructure of self-assembled ordered three-phase Au-BaTiO 3 –ZnO hybrid metamaterial along with its optical properties, grown by a pulsed laser deposition method. Varying the growth temperature, deposition frequency, and template thickness evolves the microstructure by tuning the Au and ZnO pillar geometry as well as the shape and size of the Au nanoparticles capping the ZnO nanowires. The three-phase hybrid metamaterials exhibit unique optical properties, including enhanced nonlinear optical properties, hyperbolic dispersion in the visible and near-infrared wavelength region, and tuned epsilon-near-zero (ENZ) wavelength upon varying the deposition parameters. This study suggests that the three-phase hybrid metamaterials present great potential in the microstructure and optical property tuning that can also be applied to other two-phase and three-phase nanocomposite systems.

36 MATERIALS SCIENCE↗

Fast wave interferometer for ion density measurement on DIII-D

=A fast wave interferometer (FWI), which can measure ion mass density, has been developed on DIII-D for its use on future fusion reactors, as well as for the study of ion behavior in current plasma devices. The frequency of the fast waves used for the FWI is around 60 MHz, and require antennas and coaxial cables or waveguides, which, unlike traditional mirror-based optical interferometers, are less susceptible to neutron/gamma-ray radiation and are relatively immune to impurity deposition and erosion as well as alignment issues. The bulk ion density evaluated using FWI show good agreement with that derived from CO 2 interferometry within about 15%. When the ion mass density measurement by FWI is combined with an electron density measurement from CO 2 interferometry, Z eff measurements are also enabled and are in agreement with those from visible Bremsstrahlung measurements. Additionally, large-bandwidth FWI measurements clearly resolve 10–100 kHz coherent modes and demonstrate its potential as a core fluctuation diagnostic, sensitive to both magnetic and ion density perturbations.

Instruments & Instrumentation↗

Large space telescope, phase A. Volume 3: Optical telescope assembly

The development and characteristics of the optical telescope assembly for the Large Space Telescope are discussed. The systems considerations are based on mission-related parameters and optical equipment requirements. Information is included on: (1) structural design and analysis, (2) thermal design, (3) stabilization and control, (4) alignment, focus, and figure control, (5) electronic subsystem, and (6) scientific instrument design.

Source record↗

Angular device for optical filters

Device provides a means for precise angular adjustment of optical filters in Raman calibration detector units. Device prevents stray light from entering system and has the capability of repeated alignments to predetermined angles.

Overbay, L. W.↗

Optical-noise supression unit: A concept

Device is used with coherent optical-processing spatial-filtering computer. It is isexpensive to manufacture and is made from readily available standard components. Its alignment is not critical.

Horner, J. L.↗

Optomechanical design considerations in the development of the DDLT laser diode collimator

A laser diode collimator objective was developed in support of the Direct Detection Transceiver program. Close attention to optomechanical design issues including athermalization, alignment, selection of materials, mounting of elements, and hermetic sealing of the assembly was necessary to insure that the desired optical performance was maintained in space deployment.

Kampe, Thomas U.↗

Thermal compensating mount

The main objective is to provide a device for maintaining the alignment integrity of an alignment sensitive component over a wide range of temperatures. A thermal compensating mount is presented. A cylindrical extension is integrally formed to the alignment sensitive component. Both the extension and component share the same coefficient of thermal expansion. The cylindrical extension is placed into a mounting structure which has a diameter greater than that of the extension. An adhesive secures the cylindrical extension to the mount. The difference between the diameters of the cylindrical extension and the cylindrical receptacle is such that the differential thermal expansion across the extension and the receptacle edges is exactly compensated for by the thermal compensation of the adhesive between them. Accordingly, the alignment sensitive component does not change position when subjected to temperature variations. One application of this invention is laser optical-path folding prisms, which are fixed to the mounting surface by a small amount of epoxy adhesive.

Jalink, Antony, Jr.↗

Wavefront Sensing for WFIRST with a Linear Optical Model

In this paper we develop methods to use a linear optical model to capture the field dependence of wavefront aberrations in a nonlinear optimization-based phase retrieval algorithm for image-based wavefront sensing. The linear optical model is generated from a ray trace model of the system and allows the system state to be described in terms of mechanical alignment parameters rather than wavefront coefficients. This approach allows joint optimization over images taken at different field points and does not require separate convergence of phase retrieval at individual field points. Because the algorithm exploits field diversity, multiple defocused images per field point are not required for robustness. Furthermore, because it is possible to simultaneously fit images of many stars over the field, it is not necessary to use a fixed defocus to achieve adequate signal-to-noise ratio despite having images with high dynamic range. This allows high performance wavefront sensing using in-focus science data. We applied this technique in a simulation model based on the Wide Field Infrared Survey Telescope (WFIRST) Intermediate Design Reference Mission (IDRM) imager using a linear optical model with 25 field points. We demonstrate sub-thousandth-wave wavefront sensing accuracy in the presence of noise and moderate undersampling for both monochromatic and polychromatic images using 25 high-SNR target stars. Using these high-quality wavefront sensing results, we are able to generate upsampled point-spread functions (PSFs) and use them to determine PSF ellipticity to high accuracy in order to reduce the systematic impact of aberrations on the accuracy of galactic ellipticity determination for weak-lensing science.

Jurling, Alden S.↗

Performance of the Primary Mirror Center-of-curvature Optical Metrology System During Cryogenic Testing of the JWST Pathfinder Telescope

The James Webb Space Telescope (JWST) primary mirror (PM) is 6.6 m in diameter and consists of 18 hexagonal segments, each 1.5 m point-to-point. Each segment has a six degree-of-freedom hexapod actuation system and a radius-of-curvature (RoC) actuation system. The full telescope will be tested at its cryogenic operating temperature at Johnson Space Center. This testing will include center-of-curvature measurements of the PM, using the Center-of-Curvature Optical Assembly (COCOA) and the Absolute Distance Meter Assembly (ADMA). The COCOA includes an interferometer, a reflective null, an interferometer-null calibration system, coarse & fine alignment systems, and two displacement measuring interferometer systems. A multiple-wavelength interferometer (MWIF) is used for alignment & phasing of the PM segments. The ADMA is used to measure, and set, the spacing between the PM and the focus of the COCOA null (i.e. the PM center-of-curvature) for determination of the ROC. The performance of these metrology systems was assessed during two cryogenic tests at JSC. This testing was performed using the JWST Pathfinder telescope, consisting mostly of engineering development & spare hardware. The Pathfinder PM consists of two spare segments. These tests provided the opportunity to assess how well the center-of-curvature optical metrology hardware, along with the software & procedures, performed using real JWST telescope hardware. This paper will describe the test setup, the testing performed, and the resulting metrology system performance. The knowledge gained and the lessons learned during this testing will be of great benefit to the accurate & efficient cryogenic testing of the JWST flight telescope.

optical testing↗

Phase-Shifting Liquid Crystal Point-Diffraction Interferometry

Microgravity fluid physics experiments frequently measure concentration and temperature. Interferometers such as the Twyman Green illustrated have performed full-field measurement of these quantities. As with most such devices, this interferometer uses a reference path that is not common with the path through the test section. Recombination of the test and reference wavefronts produces interference fringes. Unfortunately, in order to obtain stable fringes, the alignment of both the test and reference paths must be maintained to within a fraction of the wavelength of the light being used for the measurement. Otherwise, the fringes will shift and may disappear. Because these interferometers are extremely sensitive to bumping, jarring and transmitted vibration, they are typically mounted on optical isolation tables. Schlieren deflectometers or the more recent Shack-Hartmann wavefront sensors also measure concentration and temperature in laboratory fluid flows. Ray optics describe the operation of both devices. In a schlieren system, an expanded, collimated beam passes through a test section where refractive index gradients deflect rays. A lens focuses the beam to a filter placed in the rear focal plane of the decollimating lens. In a quantitative color schlieren system, gradients in the index of refraction appear as colors in the field of view due to the action of the color filter. Since sensitivity is a function of the focal length of the decollimating lens, these systems are rather long and filter fabrication and calibration is rather difficult. A Shack-Hartmann wavefront sensor is an array of small lenslets. Typical diameters are on the order of a few hundred microns. Since these lenslets divide the test section into resolution elements, the spatial resolution can be no smaller than an individual lenslet. Such a device was recently used to perform high-speed tomography of heated air exiting a 1.27 cm diameter nozzle. While these wavefront sensors are very compact, the limited spatial resolution and the methods required for data reduction suggest that a more useful instrument needs to be developed. The category of interferometers known as common path interferometers can eliminate much of the vibration sensitivity associated with traditional interferometry as described above. In these devices, division of the amplitude of the wavefront following the test section produces the reference beam. Examples of these instruments include shearing and point diffraction interferometers. In the latter case, shown schematically, a lens focuses light passing through the test section onto a small diffracting object. Such objects are typically either a circle of material on a high quality glass plate or a small sphere in a glass cell. The size of the focused spot is several times larger than the object so that the light not intercepted by the diffracting object forms the test beam while the diffracted light generates a spherical reference beam. While this configuration is mechanically stable, phase shifting one beam with respect to the other is difficult due to the common path. Phase shifting enables extremely accurate measurements of the phase of the interferogram using only gray scale intensity measurements and is the de facto standard of industry. Mercer and Creath 2 demonstrated phase shifting in a point diffraction interferometer using a spherical spacer in a liquid crystal cell as the diffracting object. By changing the voltage across the cell, they were able to shift the phase of the undiffracted beam relative to the reference beam generated by diffraction from the sphere. While they applied this technology to fluid measurements, the device shifted phase so slowly that it was not useful for studying transient phenomena. We have identified several technical problems that precluded operation of the device at video frame rates and intend to solve them to produce a phase-shifting liquid crystal point-diffraction interferometer operating at video frame rates. The first task is to produce high contrast fringes. Since the diffracted beam is much weaker than the transmitted beam, interferograms have poor contrast unless a dye is added to the liquid crystal to reduce the intensity of the undiffracted light. Dyes previously used were not rigorously characterized and suffered from hysteresis in both the initial alignment state of the device and the electro-optic switching characteristics. Hence, our initial effort will identify and characterize dyes that do not suffer from these difficulties and are readily soluble in the liquid crystal host. Since the ultimate goal of this research is to produce interferometers capable of phase shifting at video frame rates, we will quantify the difference in switching times between ferroelectric and nematic liquid crystals. While we have more experience with nematic crystals, they typically switch more slowly than ferroelectric cells. As part of that effort, we will investigate the difference in the modulation of the interferograms as a function of the type of liquid crystal in the cell. Because the temporal switching response of a liquid crystal cell is directly related its thickness, we intend to explore techniques required to produce cells that are as thin as possible. However, the cells must still produce a total phase shift of two pi radians.

Griffin, DeVon W.↗

Concerning the Development of the Wide-Field Optics for WFXT Including Methods of Optimizing X-Ray Optical Prescriptions for Wide-Field Applications

We present a progress report on the various endeavors we are undertaking at MSFC in support of the Wide Field X-Ray Telescope development. In particular we discuss assembly and alignment techniques, in-situ polishing corrections, and the results of our efforts to optimize mirror prescriptions including polynomial coefficients, relative shell displacements, detector placements and tilts. This optimization does not require a blind search through the multi-dimensional parameter space. Under the assumption that the parameters are small enough so that second order expansions are valid, we show that the performance at the detector can be expressed as a quadratic function with numerical coefficients derived from a ray trace through the underlying Wolter I optic. The optimal values for the parameters are found by solving the linear system of equations creating by setting derivatives of this function with respect to each parameter to zero.

Weisskopf, M. C.↗

The Micro-Arcsecond Metrology Testbed

The Micro-Arcsecond Metrology (MAM) testbed is a ground-based system of optical and electronic equipment for testing components, systems, and engineering concepts for the Space Interferometer Mission (SIM) and similar future missions, in which optical interferometers will be operated in outer space. In addition, the MAM testbed is of interest in its own right as a highly precise metrological system. The designs of the SIM interferometer and the MAM testbed reflect a requirement to measure both the position of the starlight central fringe and the change in the internal optical path of the interferometer with sufficient spatial resolution to generate astrometric data with angular resolution at the microarcsecond level. The internal path is to be measured by use of a small metrological laser beam of 1,319-nm wavelength, whereas the position of the starlight fringe is to be estimated by use of a charge-coupled-device (CCD) image detector sampling a large concentric annular beam. For the SIM to succeed, the optical path length determined from the interferometer fringes must be tracked by the metrological subsystem to within tens of picometers, through all operational motions of an interferometer delay line and siderostats. The purpose of the experiments performed on the MAM testbed is to demonstrate this agreement in a large-scale simulation that includes a substantial portion of the system in the planned configuration for operation in outer space. A major challenge in this endeavor is to align the metrological beam with the starlight beam in order to maintain consistency between the metrological and starlight subsystems at the system level. The MAM testbed includes an optical interferometer with a white light source, all major optical components of a stellar interferometer, and heterodyne metrological sensors. The aforementioned subsystems are installed in a large vacuum chamber in order to suppress atmospheric and thermal disturbances. The MAM is divided into two distinct subsystems: the test article (TA), which is the interferometer proper, and the inverse interferometer pseudo-star (IIPS), which synthesizes the light coming from a distant target star by providing spatially coherent wavefronts out of two mirrors, separated by the MAM baseline, that feed directly into two siderostats that are parts of the TA. The two feed mirrors of the IIPS are articulated (in translation and tilt) in order to simulate stars located at different orientations in space, while still illuminating the TA siderostats. The spectrum of the simulated starlight of the IIPS corresponds to that of a blackbody at a temperature of about 3,100 K.

Goullioud, Renaud↗

Direct Characterization of Type-I Band Alignment in 2D Ruddlesden–Popper Perovskites

2D Ruddlesden–Popper halide perovskites have attracted considerable attention due to their desirable optoelectronic properties, high chemical and structural tunability, and improved environmental stability. However, the understanding of their structure–properties relationships is still limited. In particular, the energy level positions and band alignments at interfaces involving these materials, which are important features to control in the context of any applications, are still under debate. Here, the electronic structure of high-purity films of BA 2 MA n-1 Pb n I 3n+1 for n = 1–5 (where BA stands for butylammonium and MA for methylammonium) is investigated, using optical absorption, ultraviolet, and inverse photoemission spectroscopies, and density functional theory calculations. Further, this study determines the ionization energy and electron affinity of each compound and demonstrates a type-I band alignment for the BA 2 MA n-1 Pb n I 3n+1 series. This study further describes the evolution of the exciton binding energy as a function of the thickness of the inorganic layers.

2D Ruddlesden–Popper perovskites↗

Optical Performance Modeling of FUSE Telescope Mirror

We describe the Metrology Data Processor (METDAT), the Optical Surface Analysis Code (OSAC), and their application to the image evaluation of the Far Ultraviolet Spectroscopic Explorer (FUSE) mirrors. The FUSE instrument - designed and developed by the Johns Hopkins University and launched in June 1999 is an astrophysics satellite which provides high resolution spectra (lambda/Delta(lambda) = 20,000 - 25,000) in the wavelength region from 90.5 to 118.7 nm The FUSE instrument is comprised of four co-aligned, normal incidence, off-axis parabolic mirrors, four Rowland circle spectrograph channels with holographic gratings, and delay line microchannel plate detectors. The OSAC code provides a comprehensive analysis of optical system performance, including the effects of optical surface misalignments, low spatial frequency deformations described by discrete polynomial terms, mid- and high-spatial frequency deformations (surface roughness), and diffraction due to the finite size of the aperture. Both normal incidence (traditionally infrared, visible, and near ultraviolet mirror systems) and grazing incidence (x-ray mirror systems) systems can be analyzed. The code also properly accounts for reflectance losses on the mirror surfaces. Low frequency surface errors are described in OSAC by using Zernike polynomials for normal incidence mirrors and Legendre-Fourier polynomials for grazing incidence mirrors. The scatter analysis of the mirror is based on scalar scatter theory. The program accepts simple autocovariance (ACV) function models or power spectral density (PSD) models derived from mirror surface metrology data as input to the scatter calculation. The end product of the program is a user-defined pixel array containing the system Point Spread Function (PSF). The METDAT routine is used in conjunction with the OSAC program. This code reads in laboratory metrology data in a normalized format. The code then fits the data using Zernike polynomials for normal incidence systems or Legendre-Fourier polynomials for grazing incidence systems. It removes low order terms from the metrology data, calculates statistical ACV or PSD functions, and fits these data to OSAC models for the scatter analysis. In this paper we briefly describe the laboratory image testing of FUSE spare mirror performed in the near and vacuum ultraviolet at John Hopkins University and OSAC modeling of the test setup performed at NASA/GSFC. The test setup is a double-pass configuration consisting of a Hg discharge source, the FUSE off-axis parabolic mirror under test, an autocollimating flat mirror, and a tomographic imaging detector. Two additional, small fold flats are used in the optical train to accommodate the light source and the detector. The modeling is based on Zernike fitting and PSD analysis of surface metrology data measured by both the mirror vendor (Tinsley) and JHU. The results of our models agree well with the laboratory imaging data, thus validating our theoretical model. Finally, we predict the imaging performance of FUSE mirrors in their flight configuration at far-ultraviolet wavelengths.

Saha, Timo T.↗