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At least 973 records · Page 54
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NASA NTRS1990

Analysis of pressure-broadened ozone spectra in the 3 micron region

The Molecular Spectroscopy Lab at NASA-Langley has been involved in a long term effort to carefully characterize the infrared spectra of small molecules of atmospheric interest, including methane, water vapor, ozone, and their isotopic counterparts. High resolution gas phase infrared spectra are obtained using both a tunable diode laser system, and the McMath Fourier transform spectrometer at the Kitt Peak Solar Observatory. Spectra are obtained at various pressures and temperatures for pure gas samples, and for samples containing mixtures of the species of interest in nitrogen, oxygen, or air. From these spectra, using a nonlinear least squares fitting technique, spectral parameters of position, intensity, and half-width were determined for varying laboratory conditions that approximate atmospheric conditions experienced in remote sensing situations. These parameters are of interest in theoretical studies of these species, as well as in allowing more accurate interpretation of remote sensing data. The current work involves the analysis of a series of McMath FTIR spectra of ozone broadened by mixing with air, nitrogen, or oxygen. Each spectrum covers the region from 2396 to 4057/cm. Each vibrational band is analyzed by first diving its region into small intervals containing a few well isolated absorption lines of reasonable intensity. Each of these small intervals is fit by multiple iterations of the nonlinear least square program until residuals are minimized to a reasonable value which corresponds to the noise level of the measured spectrum. Intervals for the 3 nu(sub 3) ozone band in the region from 3000 to 3060 wavenumbers are being examined.

Prochaska, Eleanor S.↗
NASA NTRS1990

NGC 1058: Gas motions in an extended, quiescent spiral disk

Researchers investigate in detail the motion of gas in the galaxy NGC 1058 using the very large array (VLA) to map the emission in the 21-cm line. This galaxy is so nearly face-on that the contribution to the line width due to the variation of the rotational velocity across the D-array beam is small compared with the random z-motion of the gas. Researchers confirm results of earlier studies (Lewis 1987, A. and A. Suppl., 63, 515; van der Kruit and Shostak 1984, A. and A., 134, 258) of the galaxy's total neutral hydrogen (HI) and kinematics, including the fact that the rotation curve drops faster than Keplerian at the outer edge of the disk, which is interpreted as a fortuitous twist of the plane of rotation in the outer disk. However, their very high velocity resolution (2.58 km s(exp -1) after Hanning smoothing) coupled with good spatial resolution, allows researchers to measure more accurately the line width, and even to some extent its shape, throughout the disk. One of the most interesting results of this study is the remarkable constancy of the line width in the outer disk. From radius 90 to 210 seconds the Gaussian velocity dispersion (sigma sub nu) of the 21-cm line has a mean value of 5.7 km s(exp -1) (after correcting for the spectral resolution) with a dispersion of less than 0.9 km s(exp -1) (after correcting for the spectral resolution) with a dispersion of less than 0.9 km s(exp -1). Translating this directly into a kinetic temperature (Doppler temperature): T sub Dopp equals 121K (sigma sub mu exp 2/(km s(exp -1) (exp 2) gives 4000 K, with a dispersion of less than 1500 K over the outer disk. This constancy is observed even when comparing the spiral arms versus inter-arm regions, which in the radius range from 100 to 150 seconds the surface density modulates (defined as the ratio N sub peak -N sub trough/N sub peak + N sub trough) from 0.5 to 0.25 in the range 150 to 200 seconds.

Hanson, Margaret Murray↗
NASA NTRS1990

Reactivity of pi-complexes of Ti, V, and Nb towards dithioacetic acid: Synthesis and structure of novel metal sulfur-containing complexes

In order to use sulfur-containing resources economically and with minimal environmental damage, it is important to understand the desulfurization processes. Hydrodesulfurization, for example, is carried out on the surface of a heterogeneous metal sulfide catalyst. Studies of simple, soluble inorganic systems provide information regarding the structure and reactivity of sulfur-containing compounds with metal complexes. Further, consistent with recent trends in materials chemistry, many model compounds warrant further study as catalyst precursors. The reactivity of low-valent organometallic sandwich pi-complexes toward dithiocarboxylic acids is described. For example, treatment of bisbenzene vanadium with CH3CSSH affords a divanadium tetrakis(dithioacetate) complex. The crystallographically determined V-V bond distance, 2.800(2), is nearly the same as the V-V bond distance in a V(mu-nu squared-S2)2V' unit in the mineral patonite (VS4)n. The stability of the V2S4 core in the dimer is demonstrated by evidence of V2S4(+) in the mass spectrum (70 eV, solid probe) of the vanadium dimer. Several other systems relevant to HDS catalysis are also discussed.

Duraj, Stan A.↗
NASA NTRS1990

Comet Brorsen-Metcalf in the 3.5 micron region

Comet Brorsen-Metcalf was observed on UT 21 to 24 Aug. 1989 using the CRSP spectrometer and the 1.3 meter telescope at Kitt Peak National Observatory. The cometary continuum was detected on all nights. The data are very noisy, due to the short observation window and the untried nature of the instrument. Low resolution (0.0227 micron) spectra show the 3.4 micron C-H stretch feature having a contrast of at most a factor of two to the neighboring continuum. High resolution (0.0031 micron) spectra between 3.4 and 3.6 microns show 1 sigma features that might be attributed to the nu 5 band of formaldehyde (H2CO). Similar spectra of the region between 3.2 and 3.4 microns show one 3 sigma line at 3.34 microns, which is as yet unidentified. Although the cometary spectra were more spatially extended than the spectra of standard stars, no extension of the line emission beyond the continuum was observed.

Storrs, A. D.↗
NASA NTRS1991

The contribution of methanol to the 3.4 micron feature in comets

With the advent of improved detectors and improved moderate resolution spectrometers several interesting features have been seen in the infrared spectra of comets. In particular, an emission excess at 3.52 microns was observed in several comets, and has recently been tentatively assigned to the nu 3 band of methanol (CH3OH). Using a developed model it is possible to calculate the relative strengths of the CH3OH features. The 3.52 microns emission strengths were used in a number of comets to retrieve methanol amounts, and the model was used to predict the fraction of the 3.4 micron flux which is contributed by the species. Implications for cometary formation are discussed.

Reuter, Dennis C.↗
NASA NTRS1990

The effects of vacuum polarization on thermonuclear reaction rates

Added to the pure Coulomb potential, the contribution from vacuum polarization increases the barrier, reducing the wave function (u) for reacting nuclei within the range of nuclear forces. The cross section and reaction rate are then reduced accordingly by a factor proportional to u squared. The effect is treated by evaluating the vacuum polarization potential as a small correction to the Coulomb term, then computing u in a WKB formulation. The calculation is done analytically employing the small r power-series expansion for the Uehling potential to express the final result in terms of convenient parameters. At a temperature of 1.4 x 10 to the 7th K the (negative) correction is 1.3 percent for the fundamental fusion process p + p yields d + e(+) + nu.

Gould, Robert J.↗
NASA NTRS1991

Photoabsorption and photoionization cross sections of NH3, PH3, H2S, C2H2, and C2H4 in the VUV region

Using synchrotron radiation as a continuum light source, the photoabsorption and photoionization cross sections of NH3, PH3, H2S, C2H2, and C2H4 have been measured from their respective ionization thresholds to 1060 A. The vibrational constants associated with the nu(2) totally symmetric, out-of-plane bending vibration of the ground electronic state of PH3(+) have been obtained. The cross sections and quantum yields for producing neutral products through photoexcitation of these molecules in the given spectral regions have also been determined. In the present work, autoionization processes were found to be less important than dissociation and predissociation processes in NH3, PH3, and C2H4. Several experimental techniques have been employed in order to examine the various possible systematic errors critically.

Xia, T. J.↗
NASA NTRS1991

Infrared laser absorption spectroscopy of the nu4 (sigma u) fundamental and associated nu11(pi u) hot band of C7 - Evidence for alternating rigidity in linear carbon clusters

The first characterization of the bending potential of the C7 cluster is reported via the observation of the v = 1(1) and v = 2 deg levels of the nu11 (pi u) bend as hot bands associated with the nu4 (sigma u) antisymmetric stretch fundamental. The lower state hot band rotational constants are measured to be 1004.4(1.3) and 1123.6(9.0) MHz, constituting a 9.3 and 22 percent increase over the ground state rotational constant, 918.89 (41) MHz. These large increases are strong quartic and sextic centrifugal distortion constants determined for the ground and nu 4 = 1 states are found to be anomalously large and negative, evidencing strong perturbations between stretching and bending modes.

Heath, J. R.↗
NASA NTRS1991

Laboratory studies of the newly discovered infrared band at 4705.2/cm (2.1253 microns) in the spectrum of Io - The tentative identification of CO2

The present evaluation of results from over 120 laboratory experiments relevant to the Trafton et al. (1991) discovery of a 2.1253-micron line in the spectrum of Io demonstrates that this band is produced by neither overtones nor combinations of the fundamental bands of molecules already noted on Io. Since the band's frequency is close to the first overtone of the nu(3) asymmetric stretching mode of CO2, attention is given this molecule's behavior under Io conditions. While pure solid CO2, and CO2 intimately mixed in a matrix of solid SO2 and H2S, generate bands of similar widths, these fall at frequencies lower than the Io band. Attention is given to the possible identification of the Io band with CO2 multimers of 'clusters' on Io.

Sandford, Scott A.↗
NASA NTRS1991

On the embedding-dimension analysis of AE and AL time series

Several authors have employed the embedding-dimension method to analyze time series of geomagnetic indices, with differing results for the value of the correlation dimension nu. It is argued that these differences may arise from corresponding differences in the length and construction of the various data sets used. Practical application of the method to sets of discretized data requires use of a delay time scale set by the autocorrelation time of the data set. It is found that a particular data set containing 35 days of AE exhibits an autocorrelation time tau(c) longer by an order of magnitude than that of a short-duration (less than 5 days) set, raising the possibility that extant analyses of long-duration sets may have employed delay times shorter than tau(c). In addition, the power spectrum of AE reveals modulation at a period of 24 hr. A numerical experiment on the logistic map shows that such modulation introduces an extra degree of freedom in the data, resulting in an augmented correlation dimension.

Shan, Lin-Hua↗
NASA NTRS1991

Analysis of pressure-broadened ozone spectra in the 3 micron region

This work involves the analysis of a series of McMath Fourier Transform Infrared (FTIR) spectra of ozone broadened by mixing with air (four different pressures), nitrogen (three pressures), or oxygen (three pressures). Each spectrum covers the region from 2396 to 4057 cm(-1). This study focused on the 3 sub nu sub 3 band in t 3000 to 3060 cm(-1). The band is analyzed by first dividing its region into small intervals containing a few well isolated absorption lines of reasonable intensity. Each of these small intervals is fit by multiple iterations of the nonlinear least squares program until residuals (the difference between calculated and observed spectrum, as a percent of the strongest intensity in the interval) are minimized to a reasonable value which corresponds to the noise level of the measured spectrum. Position, intensity, and half-width are recorded for later analysis. From the measured half-widths, a pressure broadening coefficient was determined for each absorption line. Pressure shifts were determined by comparing observed line positions in the spectra of the diluted ozone samples to tabulated line positions determined from spectra of pure gas samples. Comparisons to other work on ozone indicate that the broadening and shift coefficients determined in this study are consistent with those determined in other spectral regions.

Prochaska, Eleanor S.↗
NASA NTRS1992

Low Reynolds number multiple-time-scale turbulence model and calculations of steady and pulsating shear layers

A low Reynolds number multiple-time-scale turbulence model (LMS) and its application to fully developed turbulent channel flows and pulsating pipe flows are presented. The LMS can describe the inequilibrium turbulence phenomena down to the viscous sublayer. The calculated fluid flow and turbulence fields for the channel flows are in better agreement with the direct numerical simulation (DNS) results than those obtained using a Reynolds stress turbulence model, and the calculated near-wall dissipation rates are in qualitatively correct agreement with the DNS results. The LMS also successfully predicts the rapidly varying phase-lead of the wall shearing stress that occurs in a narrow range of the dimensionless frequency omega (+) = (omega x nu)/(upsilon x tau(exp2)) for the pulsating pipe flows while various other turbulence models fail to predict this phenomenon, and the LMS yields significantly improved numerical results for a wide range of the dimensionless frequency compared with those obtained using a rapid distortion theory (RDT).

Kim, Sang-Wook↗
NASA NTRS1990

Direct numerical simulations of stably-stratified sheared turbulence: Implications for oceanic mixing

Direct numerical simulations of the time evolution of homogeneous stably stratified turbulent shear flows have been performed for several Richardson numbers Ri and Reynolds numbers R(sub lambda) in earlier works. The results show excellent agreement with length scale models developed from laboratory experiments to characterize oceanic turbulence. When the Richardson number Ri is less than the stationary value Ri(sub s), the turbulence intensity grows at all scales, and the growth rate appears to be a function of Ri. The size of the vertical density inversions also increases. On the other hand, when Ri is greater than or equal to Ri(sub s) the largest turbulent eddies become vertically constrained by buoyancy when the Ellison (turbulence) scale L(sub E) and the Ozmidov (buoyancy) scale L(sub O) are equal. At this point, the mixing efficiency is maximal and corresponds to a flux Richardson number R(sub f) = 0.20. The vertical mass flux becomes counter-gradient when epsilon = 19(nu)N(exp 2) and vertical density overturns are suppressed in less than half a Brunt-Vaisala period. The results of the simulations were also recast in terms of the Hydrodynamic Phase Diagram introduced in fossil turbulence models. The so-called point of fossilization occurs when epsilon = 4DCN(exp 2); Gibson proposed 13DCN(exp 2). This value is in agreement with indirect laboratory observations and field observations. Finally, the validity of the steady-state models to estimate vertical eddy diffusivities in the oceanic thermocline is discussed.

Itsweire, E. C.↗
NASA NTRS1992

The first identification of a mainbelt asteroid source for a meteorite Class E-type Apollo asteroid (3103) 1982BB: A link between the Hungaria asteroid zone and the Aubrite meteorites

One of the major goals of asteroid investigators has been to determine the source bodies of the meteorites, and, thus, to provide the needed spatial context. However, despite careful investigation of many of these asteroids, no specific mainbelt asteroidal parent bodies for particular meteorites have yet been identified. Results are reported that represent the first direct link of a set of meteorites (the aubrites or enstatite achondrites) back to a particular source region in the asteroid belt (the Hungaria zone of the innermost belt located at a heliocentric distance of about 1.9 AU (1.9 times the Earth's distance from the Sun)). Since most asteroids in the belt are still located near their original heliocentric formation distances, this link allows the composition and temperature of the solar nebula to be determined at a specific distance from the Sun during the time of planetesimal formation. Orbital considerations suggest that 3103 could be derived from the Hungaria zone. However, the spectral gype of 3103 makes such a source probable. The Hungaria zone is the only region of the asteroid belt where E-type asteroids are common. E-type objects constitute about 55 percent of the classified Hungaria population. Although a more detailed investigation of the dynamical evolution of this object is needed, it appears highly probable that 3103 1982BB was derived from the Hungaria region of the innermost asteroid belt, that it is a fragment of the collisional breakup of an E-object near 1.9 AU, and escaped the mainbelt via the nu sup 16 resonance.

Gaffey, M. J.↗
NASA NTRS1991

Non-LTE models of Titan's upper atmosphere

Models for the thermal structure of Titan's upper atmosphere, between 0.1 mbar and 0.01 nbar are presented. The calculations include non-LTE heating/cooling in the rotation-vibration bands of CH4, C2H2, and C2H6, absorption of solar IR radiation in the near-IR bands of CH4 and subsequent cascading to the nu-4 band of CH4, absorption of solar EUV and UV radiation, thermal conduction and cooling by HCN rotational lines. Unlike earlier models, the calculated exospheric temperature agrees well with observations, because of the importance of HCN cooling. The calculations predict a well-developed mesopause with a temperature of 135-140 K at an altitude of approximately 600 km and pressure of about 0.1 microbar. The mesopause is at a higher pressure than predicted by earlier calculations because non-LTE radiative transfer in the rotation-vibration bands of CH4, C2H2, and C2H6 is treated in an accurate manner. The accuracy of the LTE approximation for source functions and heating rates is discussed.

Yelle, Roger V.↗
NASA NTRS1992

Mt. Pinatubo SO2 column measurements from Mauna Loa

Absorption features of the nu sub 1 band of SO2 are identified in high-resolution IR solar-absorption spectra recorded from Mauna Loa, Hawaii, on July 9 and 12, 1991, shortly after the arrival of the first eruption plume from the Mt. Pinatubo volcano. A total SO2 vertical column amount of (5.1 +/- 0.5) x 10 exp 16 molecules/sq cm on July 9 is retrieved based on nonlinear least-squares spectral fittings of 9 selected SO2 absorption features with an updated set of SO2 spectral parameters. A SO2 total-column upper limit of 0.9 x 10 exp 16 molecules/sq cm deduced from measurements on September 20-24, 1991, is consistent with the dispersion of the SO2 cloud and the rapid conversion of the SO2 vapor into volcanic aerosol particles.

Goldman, A.↗
NASA NTRS1992

Stratospheric HNO3 measurements from 0.002/cm resolution solar occultation spectra and improved spectroscopic line parameters in the 5.8-micron region

Very-high-resolution FWHM solar-occultation spectra are investigated with a balloon-borne interferometer using revised spectroscopic line parameters for HNO3, O3, and H2O. The O3 and H2O data are evaluated to determine their capacity for interference in the HNO3 line which is studied in the nu sub 2 band at 5.8 microns. The line parameters developed with the stratospheric data are compared to data based on a HITRAN compilation as well as laboratory spectra with a 0.002/cm resolution. The line list is calculated and shown to include J and Ka transitions which improve the line parameters for HNO3 by accounting for the weaker absorption features in the stratospheric spectra. The stratospheric HNO3 profile developed analytically is compared to those based on reported measurements, and the one developed with the stratospheric solar spectra is found to be consistent with the measurements and confirm inherent measurement biases.

Goldman, A.↗
NASA NTRS1992

Dynamics of the young LMC cluster NGC 1866

The 1.0-m telescope at Las Campanas was used to obtain V-band CCD images of the young LMC cluster NGC 1866 out to a projected radius of 100 pc. Radial velocities with a mean precision of 1.0 km/s were measured for 69 member supergiants using the echelle spectrograph on the 2.5-m telescope. The total cluster luminosity is 6.5 +/-0.3 x 10 exp 5 solar luminosities. A star-subtracted, median-filtered U frame was employed to determine photometric shape parameters. The stellar radial velocities indicate that NGC 1866 has a systemic velocity of 301.2 +/-1.0 km/s. A comparison of the derived values for NGC 1866 and the theoretical nu-0/sigma-0 - epsilon relationship indicates that the observed flattening is consistent with rotation. The quality of the fits for models with rotation is clearly superior to those without, and isotropic orbits agree best with the data in both cases.

Fischer, Philippe↗