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At least 973 records · Page 54

Additives Lower Pickup Of Moisture By Polyimides

Series of new polyimide-processing additives decrease free volume and pickup of moisture in new 422 copolyimide. Physical properties of several copolyimides synthesized from linear BDSDA/ODA/MPD homopolymers investigated previously, by positron-annihilation spectroscopy, with results indicating copolyimides have unique transition molecular structure characterized by higher electron densities and stronger bonds. Transition structure permits both physical and chemical entry of water molecules into it.

St. Clair, Terry L.↗

Monitoring seasonal variations of soil moisture and vegetation cover using satellite microwave radiometry

The NIMBUS-7 scanning multichannel microwave radiometer measured brightness temperatures at 5 frequencies (6.6, 10.7, 18, 21, 37 GHz), all dual-polarized with a 50 deg incidence angle over Africa since 1978. A 3 yr data set is being processed (1983 to 1985), and a theoretical model was developed, allowing investigation of the microwave emissivity of land features in the frequency range 6.6 to 37 GHz and of the extent to which vegetation and roughness can be determined in order to improve the soil moisture estimation.

Kerr, Y. H.↗

Moisture interaction and stability of ZOT (Zinc Orthotitanate) thermal control spacecraft coating

Two of the many performance requirements of the zinc orthotitanate (ZOT) ceramic thermal control paint covering parts of the Jupiter-bound Galileo spacecraft are that it be sufficiently electrically conductive so as to prevent electrostatic discharge (ESD) damage to onboard electronics and that it adhere to and protect the substrate from corrosion in terrestrial environments. The bulk electrical resistivity of ZOT on an aluminum substrate was measured over the ranges 22 C to 90 C and 0 percent RH to 100 percent RH, and also in soft (10 (minus 2) Torr) and hard (10 (minus 7) Torr) vacuums. No significant temperature dependence was evident, but measured resistivity values ranged over 9 orders of magnitude: 10 to the 5th power ohm-cm at 100 percent RH greater than 10 to the 12th power ohm-cm in a hard vacuum. The latter value violates the ESD criterion for a typical 0.019 cm thick coating. The corrosion study involved exposing typical ZOT substrate combinations to two moisture environments - 30 C/85 percent RH and 85 C/85 percent RH - for 2000 hours, during which time the samples were periodically removed for front-to-back electrical resistance and scratch/peel test measurements. It was determined that the ZOT/Al and ZOT/Mg systems are stable (no ZOT delamination), although some corrosion (oxide formation) and resistivity increases observed among the ZOT/Mg samples warrant that exposure of some parts to humid environments be minimized.

Mon, Gordon R.↗

Concept for Geostationary Experimental Temperature and Moisture Sounder (GETMS)

The concept of the Geostationary Experimental Temperature and Moisture Sounder (GETMS) is described, with special attention given to the system constraints and its performance characteristics. The GETMS concept supports operation in a high-resolution 'nominal experimental mode' that could achieve spectral resolution of the order 0.2/cm in the 4.2-micron region with signal/noise sufficient to achieve temperature profile retrievals with vertical resolution of the order 1 to 2 km and accuracy to 1 K or less. The concept includes a cryogenic module to provide cryogenic cooling of the focal plane. The GETMS functional diagram and diagrams of the GETMS spectrometer and of the cryogenics module are included.

Kumer, J. B.↗

Observation of atmospheric fronts using Raman lidar moisture measurements

This paper presents the results of a field program using a ground-based Raman lidar system to observe changes in moisture profiles as a cold and a warm front passed over the NASA/Goddard Space Flight Center in Greenbelt, Maryland. The lidar operating only during darkness is capable of providing continuous high vertical resolution profiles of water vapor mixing ratio and aerosol scattering ratio from near the surface to about 7 km altitude. The lidar data acquired on three consecutive nights from shortly after sunset to shortly before sunrise, along with upper air data from specially launched rawinsondes, have provided a unique visualization of the detailed structure of the two fronts.

Melfi, S. H.↗

Global distribution of moisture, evaporation-precipitation, and diabatic heating rates

Global archives were established for ECMWF 12-hour, multilevel analysis beginning 1 January 1985; day and night IR temperatures, and solar incoming and solar absorbed. Routines were written to access these data conveniently from NASA/MSFC MASSTOR facility for diagnostic analysis. Calculations of diabatic heating rates were performed from the ECMWF data using 4-day intervals. Calculations of precipitable water (W) from 1 May 1985 were carried out using the ECMWF data. Because a major operational change on 1 May 1985 had a significant impact on the moisture field, values prior to that date are incompatible with subsequent analyses.

Christy, John R.↗

Tropical Pacific moisture variability

Research objectives are to: (1) describe the synoptic scale variability of moisture over the tropical Pacific Ocean; (2) describe the systems leading to this variability; and (3) develop and implement satellite analysis procedures to facilitate (1) and (2) over the data sparse Pacific.

Mcguirk, James P.↗

An investigation of satellite sounding products for the remote sensing of the surface energy balance and soil moisture

Improved techniques for the remote sensing of the land surface energy balance (SEB) and soil moisture would greatly improve prediction of climate and weather as well as be of benefit to agriculture, hydrology and many associated fields. Most of the satellite remote sensing methods which were researched to date rely upon satellite-measured infrared surface temperatures or their time changes as a remote sensing signal. Optimistically, only four or five levels of information (wet to dry) in surface heating/evaporation are discernable by surface temperature methods and a good understanding of atmospheric conditions is necessary to bring them to this accuracy level. Skin temperature methods were researched as well as begun work on several new methods for the remote sensing of the SEB, some elements of which are applicable to current and retrospective data sources and some which will rely on instrumentation from the Earth Observing System (EOS) program in the 1990s.

Diak, George R.↗

Clouds, precipitation, and the global heat and moisture budgets during SOP-1, FGGE

Two sets of precipitation estimates are derived using the budget method equations: one is based on the apparent heat source or Q1-budget technique, the other is based on the apparent moisture sink or Q2-budget technique. Both techniques and application results are presented for the period of January 10 to February 13, 1979 which was part of SOP-1, FGGE. Maps of time-averaged outgoing longwave radiation (OLR) are shown for two periods running from January 10 to January 24, 1979 and from January 26 to February 7, 1979. The present study of estimating precipitation was initiated because of agreement between OLR and circulation patterns, and the noted regional differences and similarities in deep convections between these two periods.

Pedigo, Catherine B.↗

Tropical precipitation rates during SOP-1, FGGE, estimated from heat and moisture budgets

Using the NASA Goddard Laboratory analyses collected during the first FGGE Special Observing Period, global estimates of precipitation rates were derived for the domain between 30-deg N to 30-deg S, and the results were compared to OLR patterns and to each other to evaluate their consistency and reliability. Regional averages are presented to examine the variability of rainfall rates among selected regions of the Southern Hemisphere tropics. Finally, precipitable water was computed and compared to results derived from SMMR estimates and to the precipitation patterns. Results show that the heat and moisture budget estimates of precipitation compare favorably. Vertical profiles reveal that maximum convective heating occurs in the middle troposphere. The profile of the South Pacific convergence zone region compares best with profiles obtained over the western North Pacific.

Pedigo, Catherine B.↗

Boundary-layer heat and moisture budgets from FIFE

Aircraft stacks were flown upwind and downwind of the First International Satellite Land Surface Climatology Project Field Experiment site in Kansas to measure the heat and moisture budgets of the boundary layer under fairly clear skies for four daytime periods. The terms in the conservation equation are evaluated. The vertical flux divergence and advection do not account for the difference between surface and low-level aircraft flux estimates. Budget estimates of the surface fluxes using the aircraft data agree well with surface flux measurements, but extrapolation of the aircraft fluxes gives surface fluxes that are too low.

Desjardins, R. L.↗

Remote measurement of soil moisture over vegetation using infrared temperature measurements

Better methods for remote sensing of surface evapotranspiration, soil moisture, and fractional vegetation cover were developed. The objectives were to: (1) further develop a model of water movement through the soil/plant/atmosphere system; (2) use this model, in conjunction with measurements of infrared surface temperature and vegetation fraction; (3) determine the magnitude of radiometric temperature response to water stress in vegetation; (4) show at what point one can detect that sensitivity to water stress; and (5) determine the practical limits of the methods. A hydrological model that can be used to calculate soil water content versus depth given conventional meteorological records and observations of vegetation cover was developed. An outline of the results of these initiatives is presented.

Carlson, Toby N.↗

Diamondlike carbon as a moisture barrier and antireflecting coating on optical materials

Diamondlike carbon (DLC) is amorphous, hard, semitransparent, and is under consideration for use as a coating material for infrared optics. DLC is also designated as a-C:H to indicate its amorphous nature as well as to indicate the presence of large (20 to 55 percent) amounts of hydrogen in the film. Two important questions arise with respect to use of DLC in infrared optics. Will the lack of grain boundaries help to keep moisture from penetrating the film. Secondly, application as an antireflection coating places restrictions on the allowed values of the index of refraction of the film relative to the particular substrate material being used. Will DLC have the correct index range. These two questions are addressed in this paper.

Woollam, John A.↗

Tropical Pacific moisture variability

The research objectives were to describe synoptic scale variability of moisture over the tropical Pacific Ocean and the systems leading to this variability, to implement satellite analysis procedures to accomplish that objective, to incorporate additional satellite information into operational analysis/forecast systems at the National Meteorological Center (NMC), and to synthesize knowledge gained from satellite observations through diagnosis and numerical models. In the past year, three significant satellite data analysis tasks were accomplished: comparisons for upwelling radiance fields for 1983 and 1984 were completed for the purpose of testing the sensitivity of water vapor/greenhouse feedback to local sea surface temperature variations; the interaction between tropical plumes, wave features over Central America, traveling waves in the upper tropospheric tropics, and the tropical interseasonal oscillation was examined; and planning and early efforts on the construction of a model and the infrared based climatology of daily precipitable water was completed. Research on tropical plume mechanisms included is briefly discussed.

Mcguirk, James P.↗

Effects of vegetation on soil moisture distribution and flux with implications for the global hydrologic cycle

Recent climate modeling experiments have identified the critical need for a better understanding of land surface - atmosphere interactions. An important issue in global climate modeling is to be able to relate land surface and atmospheric processes. In the past this link has been inadequately represented due to the lack of understanding of the interaction between the processes and also due to the large spatial variability of the hydrological and soil properties. A project was initiated at the Marshall Space Flight Center (MSFC) in FY-90 under the Center's Directorate Discretionary Fund (CDDF) to study small-scale effects of vegetation on the distribution and fluxes of soil moisture. Installation of a large array of instruments was accomplished during that first year (FY-90). During this second year of the project, the instrumentation and data collection systems were improved and data has begun to be taken. Preliminary analysis of the data show that the equipment has been functioning properly. Some of the preliminary results that have recently been analyzed are given.

Macari, Emir Jose↗

An airborne study of boundary layer heat and moisture fluxes for project FIFE

A summary of work accomplished during the first International Satellite Cloud Climatology Project (ISLSCP) Field Experiment is presented. The Wyoming King Air participated in Intensive Field Campaigns (IFCs) 3 and 4 in 1987, which were committed to a combination of airborne sensible and latent heat flux measurements and soil moisture mappings, with the University of Kansas' X-band side-looking airborne radar (SLAR). A total of 9 flux missions were flown in 1987 using several different flight designs. A critical decision in the first round of aircraft flux analyses, agreed to by all the flux aircraft investigators, was to pass the aircraft data through a high-pass filter prior to the eddy-correlation flux calculations. Several conclusions were drawn from this study: (1) boundary layer (BL) profiles of heat fluxes were usually linear; (2) high-pass filtering applied to the aircraft data did not add to the disagreement between the profile; (3) undersampling at high frequencies could have accounted for as much as a 15 percent underestimate of surface fluxes; (4) disagreement between the aircraft and surface latent heat fluxes changed signs between summer and fall; (5) magnitude and sign of disagreement between aircraft and surface heat fluxes varied systematically with BL depth or height of aircraft profile; and (6) Bowen ratios from both detrended and filtered aircraft data agreed with surface values better for moist, summer cases than for dry cases.

Kelly, Robert D.↗

Heat and moisture flux modeling of the FIFE grassland canopy aided by satellite derived canopy variables

Satellite data corresponding to radiance variables are used to derive three canopy properties which describe slowly modulating boundary conditions of the interface between the biosphere and the atmosphere. The canopy properties are key factors in the regulation of heat and moisture transfer and are found to be radiance patterns within a homogeneous ecosystem. The physical modeling technique is enhanced by the satellite data, and the surface fluxes are represented more accurately in the resulting biosphere-interface model.

Smith, Eric A.↗