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At least 973 records · Page 54

Codisposal Waste Package Loading Options for DOE SNF and HLW

The U.S. Department of Energy (DOE) is responsible for managing spent nuclear fuel (SNF) that is currently in, or will in the future come into, its possession. DOE must continue to safely store that SNF, transport it to an interim storage site or a repository, and dispose of it. These fuels come from a wide range of reactor types, such as light- and heavy-water-moderated reactors, graphite-moderated reactors, and breeder reactors, with various cladding materials and enrichments. Many of these reactors, now decommissioned, had unique design features, such as core configuration, fuel element and assembly geometry, moderator and coolant materials, operational characteristics, and neutron spatial and spectral properties resulting in a large diversity of reactor and fuel designs. Because of the wide variety and condition of SNF, a robust canister termed the DOE Standardized SNF Canister was proposed that would confine radionuclides and preclude moderator. The DOE Standard SNF Canister had four variations consisting of a 10- or 15-foot length and an 18- or 24-inch diameter. For ultimate disposal in the Yucca Mountain Repository these canisters were to be grouped with 24-inch diameter HLW canisters in a codisposal waste package. The 18-inch DOE Standardized SNF Canister could be placed in the middle of five HLW canisters. The 24-inch DOE Standardized SNF Canister would take the place of one the five HLW canister on the outer ring in the codisposal waste package. No DOE Standardized SNF Canisters have been loaded, and many fuel types can be loaded in multiple canisters. Depending on the selected diameter of the DOE Standardized SNF Canister for a particular fuel, the number of potential codisposal waste packages could vary. In addition, different types of DOE SNF may be able to be combined in a single canister. This could significantly change the number of DOE SNF canisters that are loaded and result in a decrease of the number of total potential codisposal waste packages. Ultimately, if too many HLW canisters need disposition, then a reduction in the number of DOE Standardized SNF Canisters will change the final total of codisposal waste packages very little. Likewise, if the ratio of DOE Standardized SNF Canisters to HLW canister produced is too high, then DOE Standardized SNF Canisters will not have enough HLW canisters to surround them in the codisposal waste package. This paper examines the results of differing loading strategies for a few DOE SNFs. It also compares the ranges of DOE Standardized SNF Canisters that may be produced to the ranges of HLW canisters that may be produced in order to determine potential scenarios.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Non-perturbative renormalization scheme for the C P -odd three-gluon operator

We define a regularization-independent momentum-subtraction scheme for the C P -odd three-gluon operator at dimension six. This operator appears in effective field theories for heavy physics beyond the Standard Model, describing the indirect effect of new sources of C P -violation at low energies. In a hadronic context, it induces permanent electric dipole moments. The hadronic matrix elements of the three-gluon operator are non-perturbative objects that should ideally be evaluated with lattice QCD. We define a non-perturbative renormalization scheme that can be implemented on the lattice and we compute the scheme transformation to \( \overline{\mathrm{MS}} \) at one loop. Our calculation can be used as an interface to future lattice-QCD calculations of the matrix elements of the three-gluon operator, in order to obtain theoretically robust constraints on physics beyond the Standard Model from measurements of the neutron electric dipole moment.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Nitrate Controls on the Extent and Type of Metal Retention in Fine-Grained Sediments of a Simulated Aquifer

Aquifer groundwater quality is largely controlled by sediment composition and physical heterogeneity, which commonly sustain a unique redox gradient pattern. Attenuation of heavy metals within these heterogeneous aquifers is reliant on multiple factors, including redox conditions, and redox-active species that can further influence biogeochemical cycling. Here, we simulated an alluvial aquifer system using columns filled with natural coarse-grained sediments and two domains of fine-grained sediment lenses. Our goal was to examine heavy metal (Ni and Zn) attenuation within a complex aquifer network and further explore nitrate-rich groundwater conditions. The fine-grained sediment lenses sustained reducing conditions and served as a sink for Ni sequestration – in the form of Ni-silicates, Ni-organic matter, and a dominant Ni-sulfide phase. Further, the silicate clay and sulfide pools were also important retention mechanisms for Zn; however, Ni was associated more extensively with organic matter compared to Zn that formed layered double hydroxides. Nitrate-rich conditions promoted denitrification within the lenses that was coupled to the oxidation of Fe(II) and the concomitant precipitation of an Fe(III) phase with higher structural distortion. A decreased metal sulfide pool also resulted, where nitrate-rich conditions generated in an average 20% decrease in solid phase Ni, Zn, and Fe. Ultimately, nitrate plays a significant role in the aquifer’s biogeochemical cycling and capacity to retain heavy metals.

54 ENVIRONMENTAL SCIENCES↗

Advanced Composite Pistons

New concept involving improved configuration of reinforcing fibers and improved fabrication process proposed to improve thermal and mechanical properties of composite piston structures. Reduces amount of labor necessary to manufacture piston structures, with attendant reductions in costs. Single knitted-carbon-fiber sock used to form external surfaces of piston. Advantages include elimination of heavy dependence on inherently weak interlaminar properties of carbon-carbon; ease of automation to reduce fabrication costs; readily modifiable architecture to vary mechanical properties to desired values; and reduction in number of elements required to fabricate pistons. Advantage of piston structures lies in applications where light weight and high specific performance primary considerations.

Taylor, Allan H.↗

Cosmic ray composition investigations using ICE/ISEE-3

The analysis of data from the high energy cosmic experiment on ISEE-3 and associated modeling and interpretation activities are discussed. The ISEE-3 payload included two instruments capable of measuring the composition of heavy cosmic rays. The designs of these two instruments incorporated innovations which made it possible, for the first time, to measure isotopic as well as the chemical composition for a wide range of elements. As the result of the demonstrations by these two instruments of the capability to resolve individual cosmic ray isotopes, a new generation of detectors was developed using very similar designs, but having improved reliability and increased sensitive area. The composition measurements which were obtained from the ISEE-3 experiment are summarized.

Wiedenbeck, Mark E.↗

Risk Analysis of On-Orbit Spacecraft Refueling Concepts

On-orbit refueling of spacecraft has been proposed as an alternative to the exclusive use of Heavy-lift Launch Vehicles to enable human exploration beyond Low Earth Orbit (LEO). In these scenarios, beyond LEO spacecraft are launched dry (without propellant) or partially dry into orbit, using smaller or fewer element launch vehicles. Propellant is then launched into LEO on separate launch vehicles and transferred to the spacecraft. Refueling concepts are potentially attractive because they reduce the maximum individual payload that must be placed in Earth orbit. However, these types of approaches add significant complexity to mission operations and introduce more uncertainty and opportunities for failure to the mission. In order to evaluate these complex scenarios, the authors developed a Monte Carlo based discrete-event model that simulates the operational risks involved with such strategies, including launch processing delays, transportation system failures, and onorbit element lifetimes. This paper describes the methodology used to simulate the mission risks for refueling concepts, the strategies that were evaluated, and the results of the investigation. The results of the investigation show that scenarios that employ refueling concepts will likely have to include long launch and assembly timelines, as well as the use of spare tanker launch vehicles, in order to achieve high levels of mission success through Trans Lunar Injection.

Cirillo, William M.↗

High operating temperature heat transfer fluids for solar thermal power generation. Final report

This is the final technical report for the DOE MURI project on developing high-operating temperature heat transfer fluids for solar thermal power generation. This project aimed to evaluate liquid metals as a heat-transport fluid and potential energy storage medium for concentrated solar powered (CSP) systems. The project consisted of five phases, starting with fluid selection and screen and ending with potential CSP integration. The initial fluid selection arrived at heavy liquid metals as candidate fluids such as lead bismuth eutectic (LBE) as the prime liquid-alloy candidate to be studied, given the conditions above. Fifty-seven liquid compositions were initially identified with liquidus temperatures lower than 200°C, composed of elements that provide no driving force to the reduction of Cr 2 O 3 or Al 2 O 3 passivation layers in pipe material which is required for corrosion prevention. LBE was identified as the primary candidate fluid after these compositions were compared against computational thermodynamic modeling to screen all of the selected systems that would be compatible with our design objectives. Twenty-eight of these compositions were also investigated with the rapid characterization methods; the accuracies of the liquidus temperature and the specific heats predicted by the computations were better than 3 percent and 9 percent, respectively. We conducted numerus corrosion tests of various Fe-Cr-Al based steels in LBE and its variants at temperate as high as 800°C. It was found that minor additions to the liquid did not provide sufficient corrosion protection to warrant their use in real applications. Furthermore, we investigated the detailed mechanism of corrosion between heavy liquid metal and the pipe material at these very high temperatures. A liquid metal loop was constructed to operate at these high temperatures. The loop construction and operation lead to valuable lessons learned that will be needed for industrial scale loops. Furthermore, we learned that electromagnetic pumps at these extreme temperatures will have to be reengineered and redesigned to be used for CSP applications.

14 SOLAR ENERGY↗

Y(III) Sorption at the Orthoclase (001) Surface Measured by X-ray Reflectivity

Interactions of heavy metals with charged mineral surfaces control their mobility in the environment. Here, we investigate the adsorption of Y(III) onto the orthoclase (001) basal plane, the former as a representative of rare earth elements and an analogue of trivalent actinides and the latter as a representative of naturally abundant K-feldspar minerals. In this study, we apply in situ high-resolution X-ray reflectivity to determine the sorption capacity and molecular distribution of adsorbed Y species as a function of the Y 3+ concentration, [Y 3+ ], at pH 7 and 5. With [Y 3+ ] ≥ 1 mM at pH 7, we observe an inner-sphere (IS) sorption complex at a distance of ~1.5 Å from the surface and an outer-sphere (OS) complex at 3–4 Å. Based on the adsorption height of the IS complex, a bidentate, binuclear binding mode, in which Y 3+ binds to two terminal oxygens, is proposed. In contrast, mostly OS sorption is observed at pH 5. The observed maximum Y coverage is ~1.3 Y 3+ /A UC (A UC : area of the unit cell = 111.4 Å 2 ) for all the investigated pH values and Y concentrations, which is in the expected range based on the estimated surface charge of orthoclase (001).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ceramic valve development for heavy-duty low heat rejection diesel engines

Monolithic ceramic valves can be successfully operated in a heavy-duty diesel engine, even under extreme low heat rejection operating conditions. This paper describes the development of a silicon nitride valve from the initial design stage to actual engine testing. Supplier involvement, finite element analysis, and preliminary proof of concept demonstration testing played a significant role in this project's success.

Weber, K. E.↗

Multiple Reservoirs of Volatiles in the Moon Revealed by the Isotopic Composition of Chlorine in Lunar Basalts

The isotopes of chlorine (37Cl and 35Cl) are highly fractionated in lunar samples compared to most other Solar System materials. Recently, the chlorine isotope signatures of lunar rocks have been attributed to large-scale degassing processes that occurred during the existence of a magma ocean. In this study we investigated how well a suite of lunar basalts, most of which have not previously been analyzed, conform to previous models. The Cl isotope compositions (δ37Cl (‰) = [(37Cl/35Clsample/37Cl/35ClSMOC) − 1] × 1000, where SMOC refers to standard mean ocean chloride) recorded range from ∼+7 to +14‰ (Apollo 15), +10 to +19‰ (Apollo 12), +9 to +15‰ (70017), +4 to +8‰ (MIL 05035), and +15 to +22‰ (Kalahari 009). The Cl isotopic data from the present study support the mixing trends previously reported by Boyce et al. (2015) and Barnes et al. (2016), as the Cl isotopic composition of apatites are positively correlated with bulk-rock incompatible trace element abundances in the low-Ti basalts, inclusive of low-Ti and KREEP basalts. This trend has been interpreted as evidence that incompatible trace elements, including Cl, were concentrated in the urKREEP residual liquid of the lunar magma ocean, rather than the mantle cumulates, and that urKREEP Cl had a highly fractionated isotopic composition. The source regions for the basalts were thus created by variable mixing between the mantle (Cl-poor and relatively unfractionated) and urKREEP. The high-Ti basalts show much more variability in measured Cl isotope ratios and scatter around the trend formed by the low-Ti basalts. Most of the data for lunar meteorites also fits the mixing of volatiles in their sources, but Kalahari 009, which is highly depleted in incompatible trace elements, contains apatites with heavily fractionated Cl isotopic compositions. Given that Kalahari 009 is one of the oldest lunar basalts and ought to have been derived from very early-formed mantle cumulates, a heavy Cl isotopic signature is likely not related to its mantle source, but more likely to magmatic or secondary alteration processes, perhaps via impact-driven vapor metasomatism of the lunar crust.

Mccubbin, Francis M.↗

Testing of a Composite Conical-Cylindrical Shell

Launch-vehicle shell structures, which can be comprised of both cylindrical and conical sections, are known to be susceptible to buckling due to their large radius-to-thickness ratios. The advancements in composite manufacturing and numerical methods have enabled designers to consider more nontraditional shapes, such as connecting the conical and cylindrical sections with a toroidal transition to create a single-piece conical-cylindrical shell. This single-piece construction eliminates the need for a heavy interface ring between sections and has the potential to save mass. To better understand the buckling behavior, a composite conical-cylindrical shell was designed, fabricated, and tested. Prior to test, a finite element model that included thickness variations and radial imperfections was created. The test article buckled elastically at 251.8 kN, approximately 8.8% higher than the predicted buckling load of 231.4 kN Continued research in conical-cylindrical structures has the potential to expand the design space for launch-vehicle structures and lead to improved designs and reduced weight.

Buckling↗

Test and Analysis of a Composite Conical-Cylindrical Shell

Launch-vehicle shell structures, which can be comprised of both cylindrical and conical sections, are known to be susceptible to buckling due to their large radius-to-thickness ratios. The advancements in composite manufacturing and numerical methods have enabled designers to consider more nontraditional shapes, such as connecting the conical and cylindrical sections with a toroidal transition to create a single-piece conical-cylindrical shell. This single-piece construction eliminates the need for a heavy interface ring between sections and has the potential to save mass. To better understand the buckling behavior, a composite conical-cylindrical shell was designed, fabricated, and tested. Prior to test, a finite element model that included thickness variations and radial imperfections was created. The test article buckled elastically at 251.8 kN, approximately 8.8% higher than the predicted buckling load of 231.4 kN Continued research in conical-cylindrical structures has the potential to expand the design space for launch-vehicle structures and lead to improved designs and reduced weight.

Buckling↗

Equations of Motion for the Vertical Rigid-Body Rotor: Linear and Nonlinear Cases

Centuries ago, the prolific mathematician Leonhard Euler (1707–1783) wrote down the equations of motion (EOM) for the heavy symmetrical top with one point fixed. The resulting set of equations turned out to be nonlinear and had a limited number of closed-form solutions.Today, tools such as transfer matrix and finite elements enable the calculation of the rotordynamic properties for rotor-bearing systems. Some of these tools rely on the “linearized” version of the EOM to calculate the eigenvalues, unbalance response, or transients in these systems.In fact, industry standards mandate that rotors be precisely balanced to have safe operational characteristics. However, in some cases, the nonlinear aspect of the EOM should be considered.The purpose of this chapter is to show examples of how the linear vs. nonlinear formulations differ. This chapter also shows how excessive unbalance is capable of dramatically altering the behavior of the system and can produce chaotic motions associated with the “jump” phenomenon.

Laos, Hector↗

Mars Sample Return Using Commercial Capabilities: Mission Architecture Overview

Mars Sample Return (MSR) is the highest priority science mission for the next decade as recommended by the recent Decadal Survey of Planetary Science. This paper presents an overview of a feasibility study for an MSR mission. The objective of the study was to determine whether emerging commercial capabilities can be used to reduce the number of mission systems and launches required to return the samples, with the goal of reducing mission cost. We report the feasibility of a complete and closed MSR mission design using the following scenario that covers three synodic launch opportunities, beginning with the 2022 opportunity: A Falcon Heavy injects a SpaceX Red Dragon capsule and trunk onto a Trans Mars Injection (TMI) trajectory. The capsule is modified to carry all the hardware needed to return samples collected on Mars including a Mars Ascent Vehicle (MAV), an Earth Return Vehicle (ERV), and hardware to transfer a sample collected in a previously landed rover mission to the ERV. The Red Dragon descends to land on the surface of Mars using Super Sonic Retro Propulsion (SSRP). After previously collected samples are transferred to the ERV, the single-stage MAV launches the ERV from the surface of Mars. The MAV uses a storable liquid bi-propellant propulsion system to deliver the ERV to a Mars phasing orbit. After a brief phasing period, the ERV, which also uses a storable bi-propellant system, performs a Trans Earth Injection (TEI) burn. Upon arrival at Earth, the ERV performs Earth and lunar swing-bys and is placed into a lunar trailing circular orbit - an Earth orbit, at lunar distance. A later mission, using Dragon and launched by a Falcon Heavy, performs a rendezvous with the ERV in the lunar trailing orbit, retrieves the sample container and breaks the chain of contact with Mars by transferring the sample into a sterile and secure container. With the sample contained, the retrieving spacecraft makes a controlled Earth re-entry preventing any unintended release of pristine martian materials into the Earth's biosphere. The analysis methods employed standard and specialized aerospace engineering tools. Mission system elements were analyzed with either direct techniques or by using parametric mass estimating relationships (MERs). The architecture was iterated until overall mission convergence was achieved on at least one path. Subsystems analyzed in this study include support structures, power system, nose fairing, thermal insulation, actuation devices, MAV exhaust venting, and GN&C. Best practice application of loads, mass growth contingencies, and resource margins were used. For Falcon Heavy capabilities and Dragon subsystems we utilized publically available data from SpaceX, published analyses from other sources, as well as our own engineering and aerodynamic estimates. Earth Launch mass is under 11 mt, which is within the estimated capability of a Falcon Heavy, with margin. Total entry masses between 7 and 10 mt were considered with closure occurring between 9 and 10 mt. Propellant mass fractions for each major phase of the EDL - Entry, Terminal Descent, and Hazard Avoidance - have been derived. An assessment of the effect of the entry conditions on the thermal protection system (TPS), currently in use for Dragon missions, shows no significant stressors. A useful payload mass of 2.0 mt is provided and includes mass growth allowances for the MAV, the ERV, and mission unique equipment. We also report options for the MAV and ERV, including propulsion systems, crewed versus robotic retrieval mission, as well as direct Earth entry. International planetary protection policies as well as verifiable means of compliance will have a large impact on any MSR mission design. We identify areas within our architecture where such impacts occur. We also describe preliminary compliance measures that will be the subject of future work. This work shows that emerging commercial capabilities as well as new methodologies can be used to efficiently support an important planetary science objective. The work also has applications for human exploration missions that use propulsive EDL techniques

Red Dragon↗

Climatic controls on soil and saprock nitrogen distribution and persistence in the Sierra Nevada

Nitrogen (N) is an essential nutrient in soil that regulates plant growth, terrestrial sequestration of atmospheric carbon dioxide, and persistence of organic compounds. However, major knowledge gaps remain about how climate change may impact N accumulation and persistence, especially in deep soil and saprock (friable weakly weathered bedrock). Our objective was to understand how climate impacts the accumulation of N in soil and saprock and how climate impacts soil N distribution, persistence, and mechanisms of N persistence. We investigated N concentration in bulk soil and density fractions. We estimated N persistence along a bio-climatic sequence—sites range from a low-elevation oak savannah, mid-elevation pine-oak/mixed-conifer forest, to a high-elevation subalpine forest—in the southern Sierra Nevada in California. A combination of radiocarbon and elemental composition measurements along with a first-order kinetic model was used. The N concentration in the bulk soil and density fractions declined with depth, and there was a relatively greater mineral-associated heavy fraction (HF) N in deeper samples. The cooler/wetter mixed conifer site held 37% of profile N in saprock, which was greater than that of the entire soil profile at the drier/hotter oak savannah. The majority of N in soil, which was in the HF, was not influenced by climate proxies tested. However, both unprotected and occluded fractions of N were strongly influenced by climate. Soil N mean residence time (MRT) showed that drier/hotter climates have a shorter MRT, compared to mid-elevation sites with cooler/wetter climates. The effect of climate on deep saprock N storage might be indirect, primarily through climatic influence on the thickness of saprock. Overall, our findings suggest the mineral-associated HF N pool will not be vulnerable to changes in climate and will continue to contribute to the persistent soil N pool. The amount of topsoil and subsoil unprotected and occluded N can be explained by gross primary productivity and mean annual precipitation indicating that changes in climate can influence N partitioning. N stored in deep soil and saprock may be less vulnerable to climate than N stored in drier/hotter climates with less deeply stored N. It is critical to dig deeper to understand terrestrial ecosystems’ response to climate.

58 GEOSCIENCES↗

Equations of Motion for the Vertical Rigid-Body Rotor: Linear and Nonlinear Cases

Centuries ago, the prolific mathematician Leonhard Euler (1707–1783) wrote down the equations of motion (EOM) for the heavy symmetrical top with one point fixed. The resulting set of equations turned out to be nonlinear and had a limited number of closed-form solutions. Today, tools such as transfer matrix and finite elements enable the calculation of the rotor dynamic properties for rotor-bearing systems. Some of these tools rely on the “linearized” version of the EOM to calculate the eigenvalues, unbalance response, or transients in these systems. In fact, industry standards mandate that rotors be precisely balanced to have safe operational characteristics. However, in some cases, the nonlinear aspect of the EOM should be considered. The purpose of this paper is to show examples of how the linear vs. nonlinear formulations differ. This paper will also show how excessive unbalance is capable of dramatically altering the behavior of the system and can produce chaotic motions associated with the “jump” phenomenon.

42 ENGINEERING↗