Inverse Design of Solid-State Materials via a Continuous Representation
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An Electron-Ion Collider (EIC) has been proposed to further explore the strong force and QCD, focusing on the structure and the interaction of gluon-dominated matter. A generic detector R& D program (EIC PID consortium) for the particle identification in EIC experiments was formed to explore technologically advanced solutions in this scope. In this context two Ring Imaging Cherenkov (RICH) counters have been proposed: a modular RICH detector which consists of an aerogel radiator, a Fresnel lens, a mirrored box, and pixelated photon sensor; a dual-radiator RICH, consisting of an aerogel radiator and C 2 F 6 gas in a mirror-focused configuration. We present the simulations of the two detectors and their estimated performance.
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A proof of concept study for a new type of carbon capture system is considered for post-combustion CO2 capture based on porous hollow fiber sorbents with ionic liquids sorbed in the cell walls of the fiber. This study proves that delicate morphological features in the open-celled porous wall can be maintained during the infusion process. Mixtures of task specific ionic liquid (i.e. [BMIM][Tf2N]) and superbase (i.e. DBU) were loaded into polyamide-imide (PAI) fibers by a so-called two-step non-solvent infusion protocol. In the protocol, methanol carries ionic liquids into the pore cell walls of hollow fibers and then hexane carries superbase to create an efficient CO2 sorbent. Our ionic liquid/superbase impregnation technique overcomes a serious increase in mass transfer resistance upon reaction with CO2, thereby allowing its large scale utilization for post-combustion CO2 capture. The investigation on the effect of different pore former additives (different molecular weights of polyvinylpyrrolidone, lithium nitrate, and their mixtures) suggested that a large molecular weight of PVP (M-w; 1300k) including dope composition produces highly interconnected open cell pore structures of PAI hollow fibers. Lastly, a lumen side barrier layer was successfully formed on the bore side of neat PAI fibers by using a mixture of Neoprene (R) with crosslinking agents (TSR-633) via a post-treatment process. The lumen layer will enable heat removal from the fiber sorbents during their application in rapid thermal swing cycling processes. (C) 2012 Elsevier Ltd. All rights reserved.
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