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At least 973 records · Page 54

TRUST-EABM Contact Thermal Conductance (CTC) Report

(U) Single Feature Testbeds to Reduce Uncertainty in Simulations and Tests [3] provided an overview for the need of experiments, with accompanying models and simulations, specifically designed to reduce uncertainties and build confidence in complex testing and analysis applications. The Contact Thermal Conductance (CTC) testbed is a joint effort between W-13 (formerly E-13) and MST-8. The objective of this study was to design a testbed, with accompanying finite element models, to quantify, reduce, and propagate measurement uncertainties in contact thermal conductance measurements between two mating components in WR-like thermal environments. The knowledge gained through this simplified experiment would educate more complex assessments and interaction conditions with WR-like materials and geometries.

42 ENGINEERING↗

Out-of-Pile Furnace Tests on Fast Reactor Metallic Fuels Conducted at the AGHCF

An extensive out-of-pile furnace test program was conducted at Argonne’s Alpha-Gamma Hot Cell Facility (AGHCF) from 1987-1994 to evaluate the fuel/clad compatibility and performance of fast reactor metallic fuels. This test program included over 150 tests on irradiated fuels conducted in two furnace apparatuses. The available records of these tests have been preserved with the support of the Advanced Reactor Technology program and organized in the OPTD (Out-of-Pile Transient Database). This report provides at-a-glance summary information for each of the out-of-pile furnace tests, including information about the tested fuel samples, test conditions, purpose of the tests, and key results. It is intended for open and unlimited distribution to allow all interested persons to view key information about the out-of-pile tests.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Multifunctional Li-ion Conducting Interfacial Materials for Lithium Metal Batteries”

The overall approach will focus on the development and optimization of synthesis methods and precursors for multifunctional Li-ion conducting interfacial materials, protective layer composition, and protective layer fabrication methods. This will be accompanied by property measurement and characterization (conductivity, mechanical properties, etc.) for the protective layer on Li metal, along with cell testing.

25 ENERGY STORAGE↗

Innovative Proton Conductive Membranes Based on Two-Dimensional Materials

The team of Oak Ridge National Laboratory, New Mexico State University, and General Graphene Corporation staff will develop and commercialize paradigm-shifting low-cost, high-performing, proton-conductive membranes made from abundant and durable 2D materials. Proposed membranes are expected to be an order of magnitude better in performance and cost compared with the current state-of-the-art formulation, Nafion, and thus are expected to eliminate huge roadblocks in proliferation of fuel cells and flow batteries. The major goal for this work is to develop a fundamentally new learning curve for novel proton exchange membranes needed for various applications. The new technology will overcome the shortcomings of the current state-of-the-art membranes that are based upon Nafion polymer by offering higher proton conductivities, the ability to operate at much lower external humidity levels and higher temperatures (>120°C), and negligible fuel and oxidant crossover through the membrane.

36 MATERIALS SCIENCE↗

Silver Nanowire-Indium Zinc Oxide Composite Flexible Transparent Conducting Electrodes Made by Spin- coating and Photonic Curing

Realizing high-throughput, low-cost perovskite solar cell (PSC) manufacturing is highly sought-after in photovoltaic (PV) research in recent years. To fully achieve roll-to-roll (R2R) manufacturing of PSCs, it is important to consider the flexible transparent electrode (TE). PET/ITO is a commonly used substrate for making flexible PSCs. When optimizing transparent conducting materials, there is a tradeoff between sheet resistance (Rsh) and optical transparency. Because commercial PET/ITO substrates are made with slow (~1 m/min) vacuum deposition processes, they tend to be expensive. Therefore, it would be advantageous to develop a high-throughput, R2R compatible, solution-deposition approach for fabricating the TE on PET substrates. While various solution-deposition processes, such as blade coating or slot-die coating, can achieve the desired web speed of > 10 m/min, there is still a need to improve the post-deposition annealing step. One promising post-deposition processing technique is intense-pulsed-light processing, also known as photonic curing. Photonic curing delivers short (0.01 – 100 ms) pulses of broadband (200 – 1500 nm) light from a xenon flash lamp to the samples. Any materials in the sample stack that absorb light will convert the impinging light pulse into heat within the sample, which drives changes in the sample (calcination, phase change, crystallization, etc.). Photonic curing has three main advantages over thermal annealing: 1. Faster processing speed (milliseconds or seconds). 2. Compatibility with plastic substrates. 3. Smaller physical footprint and less wasted energy. Since the light pulses are on for a short time, the intensity can be high while the total energy delivered to the sample is low, minimizing damages to the plastic substrates. In this work, a hybrid TE material is fabricated on PET substrates using photonic curing. The hybrid TE material contains a layer of silver nanowires (AgNWs) and a layer of metal-oxide (InOx, ITO, IZO, etc.). The AgNWs increase the light absorbed by the film during the photonic curing process, which leads to higher processing temperatures, possibly improving the conversion of the metal-oxide layer. The AgNWs also enhance the electrical conductivity of the final TE layer after photonic curing. A AgNW and metal-oxide bilayer is formed by spin coating each solution onto the PET substrate sequentially followed by a single photonic curing process. We use average optical transmittance (Tavg) from 400 to 700 nm and average Rsh to evaluate the TE performance. The following photonic curing parameters are varied to optimize Tavg (maximize) and Rsh (minimize): Pulse voltage, pulse envelope, number of micro-pulses, duty cycle, number of pulses, and pulse repetition rate. Preliminarily, we also observe a significant impact on the TE properties by the volume of AgNW deposited during the spin coating deposition step. Using dispense volumes of 80 µL and 20 µL, we achieve samples with Tavg = 73%, Rsh = 19 Ω/sq, and roughness = 9 nm, and Tavg = 83%, Rsh = 58 Ω/sq, and roughness = 5.6 nm, respectively, after photonic curing.

14 SOLAR ENERGY↗

Effect of Lateral Conduction in a Rectangular Fuel Plate and Optimum Stripe Widths for the OPAL Reactor

The impetus for this work is the Proliferation Resistance Optimization (PRO-X) program, which was created by the National Nuclear Security Administration (NNSA) of the US Department of Energy (DOE) to provide a framework for developing reactor designs that minimize the production of special nuclear materials while maximizing performance for peaceful uses. The Argentine company INVAP and Argonne National Laboratory collaborated to share knowledge and expertise regarding the thermal analysis of research reactors. Working together, they designed a series of test problems based on the Open Pool Australian Light Water (OPAL) reactor, whose fuel is in the form of flat plates cooled by water flowing through narrow rectangular channels. ANL used their PLTEMP/ANL code. INVAP used their TERMIC code (and its new multi-plate version, TERMIC-MP). Then, INVAP and ANL compared the two sets of results. 1-D models were used during the collaboration since for research reactor analysis, largely 1-D thermal-hydraulics models are commonly used because they are simple to apply and technically defendable. The collaboration between the two organizations aims for improvements in thermal-hydraulic models. Improvements to methods and models can reduce modeling uncertainties and excessive conservatism, allowing greater reactor performance without reducing predicted safety margins. Therefore, these improvements potentially expand the design space, making additional designs feasible, which, in turn, may achieve better fuel utilization and proliferation resistance in the designs. This report provides justification for the lateral node size (stripe width) chosen for the 1-D computer models during the collaboration. The lateral heat conduction in OPAL fuel plates is evaluated using the two-dimensional conduction capability of PLTEMP/ANL to determine a representative hot-stripe width that can be conservatively used for one-dimensional steady-state thermal-hydraulic analysis. Basically, a representative hot-stripe width needs to be selected so that the actual heat flux averaged over this stripe width is greater than or equal to the maximum heat flux obtained by the two-dimensional analysis. Detailed results in this report show that a hot-stripe width of 8.125 mm can be conservatively used for the one-dimensional thermal-hydraulics analysis of all plates. Therefore, eight equal stripes (8.125 mm each) are recommended to be modeled in the MCNP and PLTEMP/ANL full core models of the OPAL reactor.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Community Planning for Solar: Conducting a Solar Resource and Infrastructure Assessment

This guide describes how to conduct a Solar Resource and Infrastructure Assessment. The guide is designed to assist community officials, volunteers, and regional planning agency staff in conducting a preliminary assessment for a municipality, community, or other jurisdiction, based primarily on a desktop analysis of existing documents and data. The guide provides a process that can be used to inventory and describe existing infrastructure, community needs, and resources from the perspective of solar development planning.

14 SOLAR ENERGY↗

Community Planning for Solar: Conducting a Community Solar Survey

This guide is designed to assist community officials, volunteers, and regional planning agency staff in conducting a survey of residents to learn about attitudes and development preferences towards solar energy within the community. The guide will provide the key steps, timelines, distribution options, ethics, and considerations that should be made in developing a survey distribution strategy. The guide also contains an overview of various question types and response categories, with considerations for the type of data that are needed for the study. The guide concludes with recommendations for managing data and databases, data visualization, and reporting results. The appendix includes samples of materials used in a solar energy survey, from invitation letters to the survey. This document is intended to provide a practical guide for implementing a survey in communities that are proactively planning for solar development. The guide offers a practical “how-to” plan for conducting a survey. It may be advantageous to consult with an expert in survey development who will be familiar with any methods and techniques described in this guide, but this is not necessary. This guide offers basic considerations and examples of questions and analyses to help a community understand preferences of the community.

14 SOLAR ENERGY↗

Thermal Conductivity of AM Fabricated Stainless Steel 316L Part

Thermal properties are an integral part of many diverse engineering applications, and additive manufacturing (AM), particularly laser powder bed fusion (LPBF) is shown to affect thermal properties due to the laser processing parameters. For 316L stainless steel, there is little prior research to determine the effects of the process on thermal properties. In this work, the temperature gradient is shown to create uniform, chess board-like distributions of grains in the build direction. These zones create dislocations which were visualized with EBSD techniques. Processing parameters cause hierarchal grain size distribution, with localized concentrations of small grains and large grains. Thermomechanical stresses in the rapid solidification increases dislocation density during grain formation. Previous research shows a higher density of dislocations decreases local thermal conductivity. Local and bulk thermal conductivity are shown in this work to have statistically lowered values to an average of 10-12 W/m-K compared to 14 W/m-K for conventional 316L.

36 MATERIALS SCIENCE↗

Beam Optics Design of A Prototype 20 kW Conduction-Cooled SRF Accelerator for Medical Sterilization

Superconducting technology has significantly advanced the capabilities of particle accelerators, facilitating higher beam-power operations for fundamental research at a comparatively lower cost. However, the conventional implementation of superconducting technology introduces complexities in the form of cryogenic plants, cryogenic distribution systems and substantial construction and operational cost. In response to these challenges, recent research efforts at Fermilab have been dedicated to the development of a cryogen-free, conduction-cooled Nb3Sn-based superconducting technology. This paper outlines the beam optics design of a 20-kW conduction-cooled compact superconducting accelerator for medical sterilization. The paper reviews both the physics and practical constraints associated with high beam-power operation within the context of industrial applications. The focus is on providing insights into the potential of this innovative technology to overcome existing challenges and pave the way for more accessible and efficient industrial particle accelerators.

43 PARTICLE ACCELERATORS↗

Intermediate Temperature Proton‐Conducting Solid Oxide Electrolysis Cells with Improved Performance and Durability

Technical understanding: A high-performance and stable intermediate temperature proton-conducting solid oxide electrolysis cell (PCEC) will add significantly to the hydrogen roadmap of EERE. However, the low electrocatalytic activity of the air electrode and the instability of the electrolyte are technical barriers. In this research, we utilized computational fluid dynamic modeling and materials/microstructure engineering to investigate the complex reaction chain and to improve the performance and reliability of the protonic ceramic electrochemical cells. An active and stable Pr 1.8 Ba 0.2 NiO 4+δ -BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3-δ (BZCYYb) scaffold conformal coating electrode was rationally designed where the robust Pr 1.8 Ba 0.2 NiO 4+δ functions both as a catalytic active and a protective layer. The PCECs with porosity-optimized scaffold conformal coating electrodes demonstrate 1.46 Acm -2 under 1.3 V at 600°C, which is among the highest in recent years. The final optimization by computational fluid dynamic modeling and conformal coating technique was applied to evolve the PCEC air electrode from Pr 2 NiO 4+δ to Pr 1.8 Ba 0.2 NiO 4+δ -BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3-δ scaffold conformal coating. The electrolysis current was boosted from 0.445A/cm 2 to 1.46A/cm 2 at 600°C and 1.3V. A superior low degradation rate of 1mV/kh was achieved in a 5000-hour of operation. Technical effectiveness and economic feasibility: The effectiveness of this TCO conformal coating on electrolyte backbone as air electrode has been proven by long-term demonstration. Based on the highly conductive BZCYYb electrolyte and the TCO steam electrode PNO, this project rationally took advantage of the existent materials to structure a PCEC device with high TRL and low risk. The solution infiltration method used to structure the conformal coating is a standard method used by the solid oxide cell community. Very minimal adoption is needed in the current SOC fabrication process. It is a cost-effective, scalable method for manufacturing, and brings up remarkable impact on the current technical status of PCEC. Benefit to the public: The findings in the research showed the industry that the severe challenge in PCEC can be overcome in a practical way. A various energy-hydrogen ecosystem is not beyond reach. The success of this technology provides sustainable and affordable H 2 to society. It will stimulate investment from the governmental and private sectors in response to the device manufacture and deployment, and the related infrastructure construction. It will generate high-pay domestic jobs and environmental benefits to the general public in the United States.

08 HYDROGEN↗

CABLE Stage 3 – Ultra‐High Strength/Highly Conductive Al Alloys

This work is to be conducted in support of the CABLE Conductor Manufacturing Prize Program awarded by NREL. The intent is to connect competitor teams with national laboratories that can help accelerate the development of innovative solutions and products. Teams who receive CABLE Prize awards are eligible to utilize vouchers at national laboratories to advance their ideas. NanoAL LLC has been awarded a voucher to utilize at Ames National Laboratory. Ames National Laboratory will perform a scale‐up trial of Nano 6000‐T9 to evaluate and optimize the heat treatment and other processing variables to validate the lab‐scale work done at NanoAL. The final processing schedule will be used to fabricate the submission samples for the Stage 3 contest. All work will be supported by mechanical and electrical conductivity testing be performed by Ames.

36 MATERIALS SCIENCE↗

Financial Analysis of the High Flow Experiment conducted at the Glen Canyon Dam during Water Year 2023

The Glen Canyon Dam (GCD) is a Colorado River Storage Project (CRSP) power resource that is a component of the Salt Lake City Area Integrated Projects (SLCA/IP). The 2016 record of decision (ROD) for the GCD long-term experimental and management plan (LTEMP) final Environmental Impact Statement (EIS) specified criteria for GCD monthly water releases, daily and hourly operating limits, and experimental releases. This report examines the financial implications of the high flow experiment (HFE) conducted at GCD during the spring of Water Year (WY) 2023 as required by the LTEMP HFE Protocol. This report is part of a series of reports that describe the financial costs of LTEMP experimental releases since the 2016 ROD was adopted in January 2017. Previous reports analyzed the impact of several past HFEs and Bug Flow Experiments. This report focuses on the HFE conducted in April 2023. For this experimental release, financial costs of approximately $1.33 million were incurred because the HFE required sustained water releases exceeding the power plant’s maximum turbine flow rate. In addition, during the experiment, operators were not allowed to shape GCD power production, either to follow Firm Electric Service (FES) customer day-ahead energy deliveries or to respond to market prices. This study identifies the main factors contributing to the HFE costs and examines the interdependencies among these factors. It applies an integrated set of tools to estimate Western Area Power Administration (WAPA) financial impacts by simulating GCD under two types of cases; namely, (1) a “With Experiment” case that mimics the operations that actually occurred and (2) a “Without Experiment” case that simulates operations under the assumption that the HFE did not occur. The “With Experiment” case mimics operations during the HFE and the entire month the HFE occurred. It complies with LTEMP hourly and daily operating criteria. The “Without Experiment” case assumes that the HFE did not occur. The monthly water release volume is assumed to be identical under both cases. The Colorado River Storage Project Python-based model (CRiSPPy) model was the main modeling tool used to simulate the dispatch of the GCD hydropower plant and associated water releases from Lake Powell. In the modeling process, the research team used extensive data sets and historical information on SLCA/IP power plant characteristics, hydrologic conditions, and WAPA’s power purchases and sales prices. In addition to estimating the financial impact of the HFE, the team used the CRiSPPy model to gain insights into the interplay among ROD operating criteria, exceptions made to criteria to accommodate the HFE, and WAPA operating practices.

13 HYDRO ENERGY↗

Advancing Conduction-Cooled 650 MHZ SRF Technology for Industrial Accelerators at Fermilab S IARC

The National Nuclear Security Administration (NNSA) funds the Illinois Accelerator Research Center (IARC) at Fermilab in developing a high-power, conduction-cooled Superconducting Radio Frequency (SRF) accelerator tailored for industrial applications requiring robust and efficient operation. A 650 MHz, 1.6 MeV, 20 kW SRF accelerator is currently under development, employing a conduction cooling approach to simplify cryogenic requirements and enhance accessibility for industrial use. The accelerator's control system is implemented on the Blinky Lite platform, selected for its open-source architecture, secure remote access capabilities, and operational flexibility attributes advantageous for industrial deployment and sustained operation. A dedicated beamline is designed to measure essential beam parameters and test the integrated performance of the accelerator and control systems, thereby validating their operational readiness for intended applications.

Ji, Yichen [Fermilab]↗

Enhancements Of Interior Flux In Magnetic Bodies & Exterior Surface Fields On Conducting Objects Of Various Shapes

The magnetic flux induced in magnetic bodies of several shapes are examined. In addition the surface magnetic field intensity on the exterior surface of conducting objects is estimated since it is the driver for narrow slot aperture inductive ports of entry. In this report lower frequencies are the focus, but we also include the magnetic field intensity of a conducting cylinder near the first resonance and a reference to the high frequency limit.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Probing Surface Hydration and Isotope Exchange Kinetics in Proton-Conducting Ceramics Using DRIFTS and EIS

This internship project investigates how water vapor partial pressure (pH2O) affects surface hydration and H/D isotope-exchange kinetics in BaZr0.4Ce0.4Y0.1Yb0.1O3?d (4411) proton-conducting ceramic electrolytes. Diffuse reflectance infrared Fourier-transform spectroscopy (DRIFTS) is used to monitor surface hydroxyl and deuteroxyl species under controlled humidified atmospheres during gas-switching experiments. These surface kinetic trends are to be correlated with bulk, grain-boundary, and total electrolyte resistance measured by electrochemical impedance spectroscopy (EIS) under matching conditions. The future goals of this study are to clarify the relationship between surface hydration dynamics and proton conduction behavior, improving interpretation of EIS data and guiding the optimization of ceramic electrolytes for energy applications.

08 - HYDROGEN↗

Cycling of block copolymer composites with lithium-conducting ceramic nanoparticles

Solid polymer and perovskite-type ceramic electrolytes have both shown promise in advancing solid-state lithium metal batteries. Despite their favorable interfacial stability against lithium metal, polymer electrolytes face issues due to their low ionic conductivity and poor mechanical strength. Highly conductive and mechanically robust ceramics, on the other hand, cannot physically remain in contact with redox-active particles that expand and contract during charge-discharge cycles unless excessive pressures are used. To overcome the disadvantages of each material, polymer-ceramic composites can be formed; however, depletion interactions will always lead to aggregation of the ceramic particles if a homopolymer above its melting temperature is used. In this study, we incorporate Li 0.33 La 0.56 TiO 3 (LLTO) nanoparticles into a block copolymer, polystyrene- b -poly (ethylene oxide) (SEO), to develop a polymer-composite electrolyte (SEO-LLTO). TEMs of the same nanoparticles in polyethylene oxide (PEO) show highly aggregated particles whereas a significant fraction of the nanoparticles are dispersed within the PEO-rich lamellae of the SEO-LLTO electrolyte. We use synchrotron hard x-ray microtomography to study the cell failure and interfacial stability of SEO-LLTO in cycled lithium-lithium symmetric cells. Three-dimensional tomograms reveal the formation of large globular lithium structures in the vicinity of the LLTO aggregates. Encasing the SEO-LLTO between layers of SEO to form a “sandwich” electrolyte, we prevent direct contact of LLTO with lithium metal, which allows for the passage of seven-fold higher current densities without signatures of lithium deposition around LLTO. We posit that eliminating particle clustering and direct contact of LLTO and lithium metal through dry processing techniques is crucial to enabling composite electrolytes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Structural, Thermal, and Mechanical Characterization of a Thermally Conductive Polymer Composite for Heat Exchanger Applications

Polymer composites are being considered for numerous thermal applications because of their inherent benefits, such as light weight, corrosion resistance, and reduced cost. In this work, the microstructural, thermal, and mechanical properties of a 3D printed polymer composite with high thermal conductivity are examined using multiple characterization techniques. Infrared spectroscopy and X-ray diffraction reveal that the composite contains a polyphenylene sulfide matrix with graphitic fillers, which is responsible for the high thermal conductivity. Furthermore, differential scanning calorimetry determines that the glass transition and melting point of the composite are 87.6 °C and 285.6 °C, respectively. Thermogravimetric analysis reveals that the composite is thermally stable up to ~400 °C. Creep tests are performed at different isotherms to evaluate the long-term performance of the composite. The creep result indicates that the composite can maintain mechanical integrity when used below its glass transition temperature. Nanoindentation tests reveal that modulus and hardness of the composite is not significantly influenced by heating or creep conditions. These findings indicate that the composite is potentially suitable for heat exchanger applications.

36 MATERIALS SCIENCE↗