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At least 973 records · Page 54

Clementine High Resolution Camera Mosaicking Project: CL 6020; 80 deg N to 90 deg N Latitude, South Periapsis - Volume 20

This compact disk (CD) is part of the Clementine I high resolution (HiRes) camera lunar image mosaics developed by Malin Space Science Systems (MSSS). These mosaics were developed through calibration and semi-automated registration against the recently released geometrically and photometrically controlled Ultraviolet/Visible (UV/Vis) Basemap Mosaic, which is available through the PDS, as CD-ROM volumes CL_3001-3015. The HiRes mosaics are compiled from non-uniformity corrected, 750 nanometer ("D") filter high resolution observations from the HiRes imaging system onboard the Clementine Spacecraft. The geometric control is provided by the U.S. Geological Survey (USGS) Clementine Basemap Mosaic compiled from the 750 nm Ultraviolet/Visible Clementine imaging system. Calibration was achieved by removing the image nonuniformity largely caused by the HiRes system's light intensifier. Also provided are offset and scale factors, achieved by a fit of the HiRes data to the corresponding photometrically calibrated UV/Vis basemap that approximately transform the 8-bit HiRes data to photometric units. The mosaics on this CD are compiled from polar data (latitudes greater than 80 degrees), and are presented in the stereographic projection at a scale of 30 m/pixel at the pole, a resolution 5 times greater than that (150 m/pixel) of the corresponding UV/Vis polar basemap. This 5:1 scale ratio is in keeping with the sub-polar mosaic, in which the HiRes and UV/Vis mosaics had scales of 20 m/pixel and 100 m/pixel, respectively. The equal-area property of the stereographic projection made this preferable for the HiRes polar mosaic rather than the basemap's orthographic projection. Thus, a necessary first step in constructing the mosaic was the reprojection of the UV/Vis basemap to the stereographic projection. The HiRes polar data can be naturally grouped according to the orbital periapsis, which was in the south during the first half of the mapping mission and in the north during the second half. Images in each group have generally uniform intrinsic resolution, illumination, exposure and gain. Rather than mingle data from the two periapsis epochs, separate mosaics are provided for each, a total of 4 polar mosaics. The mosaics are divided into 100 square tiles of 2250 pixels (approximately 2.2 deg near the pole) on a side. Not all squares of this grid contain HiRes mosaic data, some inevitably since a square is not a perfect representation of a (latitude) circle, others due to the lack of HiRes data. This CD also contains ancillary data files that support the HiRes mosaic. These files include browse images with UV/Vis context stored in a Joint Photographic Experts Group (JPEG) format, index files ('imgindx.tab' and 'srcindx.tab') that tabulate the contents of the CD, and documentation files. For more information on the contents and organization of the CD volume set refer to the "FILES, DIRECTORIES AND DISK CONTENTS" section of this document. The image files are organized according to NASA's Planetary Data System (PDS) standards. An image file (tile) is organized as a PDS labeled file containing an "image object".

Malin, Michael↗

Clementine High Resolution Camera Mosaicking Project: CL 6021; 80 deg S to 90 deg S Latitude, North Periapsis - Volume 21

This compact disk (CD) is part of the Clementine I high resolution (HiRes) camera lunar image mosaics developed by Malin Space Science Systems (MSSS). These mosaics were developed through calibration and semi-automated registration against the recently released geometrically and photometrically controlled Ultraviolet/Visible (UV/Vis) Basemap Mosaic, which is available through the PDS, as CD-ROM volumes CL_3001-3015. The HiRes mosaics are compiled from non-uniformity corrected, 750 nanometer ("D") filter high resolution observations from the HiRes imaging system onboard the Clementine Spacecraft. The geometric control is provided by the U. S. Geological Survey (USGS) Clementine Basemap Mosaic compiled from the 750 nm Ultraviolet/Visible Clementine imaging system. Calibration was achieved by removing the image nonuniformity largely caused by the HiRes system's light intensifier. Also provided are offset and scale factors, achieved by a fit of the HiRes data to the corresponding photometrically calibrated UV/Vis basemap that approximately transform the 8-bit HiRes data to photometric units. The mosaics on this CD are compiled from polar data (latitudes greater than 80 degrees), and are presented in the stereographic projection at a scale of 30 m/pixel at the pole, a resolution 5 times greater than that (150 m/pixel) of the corresponding UV/Vis polar basemap. This 5:1 scale ratio is in keeping with the sub-polar mosaic, in which the HiRes and UV/Vis mosaics had scales of 20 m/pixel and 100 m/pixel, respectively. The equal-area property of the stereographic projection made this preferable for the HiRes polar mosaic rather than the basemap's orthographic projection. Thus, a necessary first step in constructing the mosaic was the reprojection of the UV/Vis basemap to the stereographic projection. The HiRes polar data can be naturally grouped according to the orbital periapsis, which was in the south during the first half of the mapping mission and in the north during the second half. Images in each group have generally uniform intrinsic resolution, illumination, exposure and gain. Rather than mingle data from the two periapsis epochs, separate mosaics are provided for each, a total of 4 polar mosaics. The mosaics are divided into 100 square tiles of 2250 pixels (approximately 2.2 deg near the pole) on a side. Not all squares of this grid contain HiRes mosaic data, some inevitably since a square is not a perfect representation of a (latitude) circle, others due to the lack of HiRes data. This CD also contains ancillary data files that support the HiRes mosaic. These files include browse images with UV/Vis context stored in a Joint Photographic Experts Group (JPEG) format, index files ('imgindx.tab' and 'srcindx.tab') that tabulate the contents of the CD, and documentation files. For more information on the contents and organization of the CD volume set refer to the "FILES, DIRECTORIES AND DISK CONTENTS" section of this document. The image files are organized according to NASA's Planetary Data System (PDS) standards. An image file (tile) is organized as a PDS labeled file containing an "image object".

Malin, Michael↗

Clementine High Resolution Camera Mosaicking Project: CL 6019; 80 deg N to 90 deg N Latitude, North Periapsis - Volume 19

This compact disk (CD) is part of the Clementine I high resolution (HiRes) camera lunar image mosaics developed by Malin Space Science Systems (MSSS). These mosaics were developed through calibration and semi-automated registration against the recently released geometrically and photometrically controlled Ultraviolet/Visible (UV/Vis) Basemap Mosaic, which is available through the PDS, as CD-ROM volumes CL_3001-3015. The HiRes mosaics are compiled from non-uniformity corrected, 750 nanometer ("D") filter high resolution observations from the HiRes imaging system onboard the Clementine Spacecraft. The geometric control is provided by the U. S. Geological Survey (USGS) Clementine Basemap Mosaic compiled from the 750 nm Ultraviolet/Visible Clementine imaging system. Calibration was achieved by removing the image nonuniformity largely caused by the HiRes system's light intensifier. Also provided are offset and scale factors, achieved by a fit of the HiRes data to the corresponding photometrically calibrated UV/Vis basemap that approximately transform the 8-bit HiRes data to photometric units. The mosaics on this CD are compiled from polar data (latitudes greater than 80 degrees), and are presented in the stereographic projection at a scale of 30 m/pixel at the pole, a resolution 5 times greater than that (150 m/pixel) of the corresponding UV/Vis polar basemap. This 5:1 scale ratio is in keeping with the sub-polar mosaic, in which the HiRes and UV/Vis mosaics had scales of 20 m/pixel and 100 m/pixel, respectively. The equal-area property of the stereographic projection made this preferable for the HiRes polar mosaic rather than the basemap's orthographic projection. Thus, a necessary first step in constructing the mosaic was the reprojection of the UV/Vis basemap to the stereographic projection. The HiRes polar data can be naturally grouped according to the orbital periapsis, which was in the south during the first half of the mapping mission and in the north during the second half. Images in each group have generally uniform intrinsic resolution, illumination, exposure and gain. Rather than mingle data from the two periapsis epochs, separate mosaics are provided for each, a total of 4 polar mosaics. The mosaics are divided into 100 square tiles of 2250 pixels (approximately 2.2 deg near the pole) on a side. Not all squares of this grid contain HiRes mosaic data, some inevitably since a square is not a perfect representation of a (latitude) circle, others due to the lack of HiRes data. This CD also contains ancillary data files that support the HiRes mosaic. These files include browse images with UV/Vis context stored in a Joint Photographic Experts Group (JPEG) format, index files ('imgindx.tab' and 'srcindx.tab') that tabulate the contents of the CD, and documentation files. For more information on the contents and organization of the CD volume set refer to the "FILES, DIRECTORIES AND DISK CONTENTS" section of this document. The image files are organized according to NASA's Planetary Data System (PDS) standards. An image file (tile) is organized as a PDS labeled file containing an "image object".

Malin, Michael↗

Clementine High Resolution Camera Mosaicking Project: CL 6018; 80 deg N to 80 deg S Latitude, 330 deg E to 360 deg E Longitude - Volume 18

This compact disk (CD) is part of the Malin Space Science Systems (MSSS) effort to mosaic Clementine I high resolution (HiRes) camera lunar images. These mosaics were developed through calibration and semi-automated registration against the recently released geometrically and photometrically controlled Ultraviolet/Visible (UV/Vis) Basemap Mosaic, which is available through the PDS, as CD-ROM volumes CL_3001-3015. The HiRes mosaics are compiled from non-uniformity corrected, 750 nanometer ("D") filter high resolution observations from the HiRes imaging system onboard the Clementine Spacecraft. These mosaics are spatially warped using the sinusoidal equal-area projection at a scale of 20 m/pixel. The geometric control is provided by the 100 m/pixel U. S. Geological Survey (USGS) Clementine Basemap Mosaic compiled from the 750 nm Ultraviolet/Visible Clementine imaging system. Calibration was achieved by removing the image nonuniformity largely caused by the HiRes system's light intensifier. Also provided are offset and scale factors, achieved by a fit of the HiRes data to the corresponding photometrically calibrated UV/Vis basemap that approximately transform the 8-bit HiRes data to photometric units. The mosaics on this CD were compiled from sub-polar data (latitudes 80 degrees South to 80 degrees North; -80 to +80) within the longitude range 0-30 deg E. The mosaics are divided into tiles that cover approximately 1.75 degrees of latitude and span the longitude range of the mosaicked frames. Images from a given orbit are map projected using the orbit's nominal central latitude. This CD contains ancillary data files that support the HiRes mosaic. These files include browse images with UV/Vis context stored in a Joint Photographic Experts Group (JPEG) format, index files ('imgindx.tab' and 'srcindx.tab') that tabulate the contents of the CD, and documentation files. For more information on the contents and organization of the CD volume set refer to the "FILES, DIRECTORIES AND DISK CONTENTS" section of this document. The image files are organized according to NASA's Planetary Data System (PDS) standards. An image file (tile) is organized as a PDS labeled file containing an "image object".

Malin, Michael↗

Clementine High Resolution Camera Mosaicking Project: CL 6017; 0 deg to 80 deg S Latitude, 330 deg E Longitude - Volume 17

This compact disk (CD) is part of the Malin Space Science Systems (MSSS) effort to mosaic Clementine I high resolution (HiRes) camera lunar images. These mosaics were developed through calibration and semi-automated registration against the recently released geometrically and photometrically controlled Ultraviolet/Visible (UV/Vis) Basemap Mosaic, which is available through the PDS, as CD-ROM volumes CL_3001-3015. The HiRes mosaics are compiled from non-uniformity corrected, 750 nanometer ("D") filter high resolution observations from the HiRes imaging system onboard the Clementine Spacecraft. These mosaics are spatially warped using the sinusoidal equal-area projection at a scale of 20 m/pixel. The geometric control is provided by the 100 m/pixel U.S. Geological Survey (USGS) Clementine Basemap Mosaic compiled from the 750 nm Ultraviolet/Visible Clementine imaging system. Calibration was achieved by removing the image nonuniformity largely caused by the HiRes system's light intensifier. Also provided are offset and scale factors, achieved by a fit of the HiRes data to the corresponding photometrically calibrated UV/Vis basemap that approximately transform the 8-bit HiRes data to photometric units. The mosaics on this CD were compiled from sub-polar data (latitudes 80 degrees South to 80 degrees North; -80 to +80) within the longitude range 0-30 deg E. The mosaics are divided into tiles that cover approximately 1.75 degrees of latitude and span the longitude range of the mosaicked frames. Images from a given orbit are map projected using the orbit's nominal central latitude. This CD contains ancillary data files that support the HiRes mosaic. These files include browse images with UV/Vis context stored in a Joint Photographic Experts Group (JPEG) format, index files ('imgindx.tab' and 'srcindx.tab') that tabulate the contents of the CD, and documentation files. For more information on the contents and organization of the CD volume set refer to the "FILES, DIRECTORIES AND DISK CONTENTS" section of this document. The image files are organized according to NASA's Planetary Data System (PDS) standards. An image file (tile) is organized as a PDS labeled file containing an "image object".

Malin, Michael↗

Aerospace Nickel-cadmium Cell Verification

During the early years of satellites, NASA successfully flew "NASA-Standard" nickel-cadmium (Ni-Cd) cells manufactured by GE/Gates/SAFF on a variety of spacecraft. In 1992 a NASA Battery Review Board determined that the strategy of a NASA Standard Cell and Battery Specification and the accompanying NASA control of a standard manufacturing control document (MCD) for Ni-Cd cells and batteries was unwarranted. As a result of that determination, standards were abandoned and the use of cells other than the NASA Standard was required. In order to gain insight into the performance and characteristics of the various aerospace Ni-Cd products available, tasks were initiated within the NASA Aerospace Flight Battery Systems Program that involved the procurement and testing of representative aerospace Ni-Cd cell designs. A standard set of test conditions was established in order to provide similar information about the products from various vendors. The objective of this testing was to provide independent verification of representative commercial flight cells available in the marketplace today. This paper will provide a summary of the verification tests run on cells from various manufacturers: Sanyo 35 Ampere-hour (Ali) standard and 35 Ali advanced Ni-Cd cells, SAFr 50 Ah Ni-Cd cells and Eagle-Picher 21 Ali Magnum and 21 Ali Super Ni-CdTM cells from Eagle-Picher were put through a full evaluation. A limited number of 18 and 55 Ali cells from Acme Electric were also tested to provide an initial evaluation of the Acme aerospace cell designs. Additionally, 35 Ali aerospace design Ni-MH cells from Sanyo were evaluated under the standard conditions established for this program. Ile test program is essentially complete. The cell design parameters, the verification test plan and the details of the test result will be discussed.

Manzo, Michelle A.↗

Metal dynamics in Lake Vanda (Wright Valley, Antarctica)

Data are reported for Mn, Fe, Co, Ni, Cu and Cd in the Onyx River, and for Mn, Co, Ni, Cu and Cd in Lake Vanda, a closed-basin Antarctic lake. Oxic water concentrations for Co, Ni, Cu and Cd were quite low and approximate pelagic ocean values. Scavenging of these metals by sinking particles is strongly indicated. Deep-lake profiles reveal a sharp peak in the concentrations of Mn, Fe and Co at the oxic-anoxic boundary at 60 m. Maxima for Ni, Cu and Cd occur higher in the water column, in the vicinity of a Mn submaximum, suggesting early release of these metals from sinking manganese oxide-coated particles. A rough steady-state model leads to the conclusion that there is a large downward flux of Mn into the deep lake and that this flux is sufficient to explain the annual loss of Co, Ni, Cu and Cd. A pronounced geochemical separation between Fe and Mn apparently occurs in this system--Fe being best lost in near-shore environments and Mn being lost in deeper waters. Comparison of metal residence times in Lake Vanda with those in the oceans shows that in both systems Mn, Fe and Co are much more reactive than Ni, Cu and Cd. Energetically favorable inclusion of the more highly charged metals, Mn(IV), Fe(III) and Co(III), into oxide-based lattices is a plausible explanation.

NASA Center ARC↗

Airport Traffic Conflict Detection and Resolution Algorithm Evaluation

Two conflict detection and resolution (CD&R) algorithms for the terminal maneuvering area (TMA) were evaluated in a fast-time batch simulation study at the National Aeronautics and Space Administration (NASA) Langley Research Center. One CD&R algorithm, developed at NASA, was designed to enhance surface situation awareness and provide cockpit alerts of potential conflicts during runway, taxi, and low altitude air-to-air operations. The second algorithm, Enhanced Traffic Situation Awareness on the Airport Surface with Indications and Alerts (SURF IA), was designed to increase flight crew awareness of the runway environment and facilitate an appropriate and timely response to potential conflict situations. The purpose of the study was to evaluate the performance of the aircraft-based CD&R algorithms during various runway, taxiway, and low altitude scenarios, multiple levels of CD&R system equipage, and various levels of horizontal position accuracy. Algorithm performance was assessed through various metrics including the collision rate, nuisance and missed alert rate, and alert toggling rate. The data suggests that, in general, alert toggling, nuisance and missed alerts, and unnecessary maneuvering occurred more frequently as the position accuracy was reduced. Collision avoidance was more effective when all of the aircraft were equipped with CD&R and maneuvered to avoid a collision after an alert was issued. In order to reduce the number of unwanted (nuisance) alerts when taxiing across a runway, a buffer is needed between the hold line and the alerting zone so alerts are not generated when an aircraft is behind the hold line. All of the results support RTCA horizontal position accuracy requirements for performing a CD&R function to reduce the likelihood and severity of runway incursions and collisions.

Jones, Denise R.↗

Model predictive current profile control in tokamaks by exploiting spatially moving electron cyclotron current drives

The plasma control systems in next-generation tokamaks like ITER will balance competing control objectives to achieve the desired level of performance in advanced scenarios while preventing magnetohydrodynamic instabilities and disruptions. During normal tokamak operation, the points of incidence of the electromagnetic waves generated by the electron cyclotron heating and current drives (EC H&CDs) are usually fixed in space. However, the points of incidence can be modified in real-time by changing the angles of the mirrors that reflect the EC H&CD waves. Altering the points of incidence, in turn, varies the ability of the plasma control system to regulate a plasma property. For instance, changing the EC H&CD wave incidence location may place the power demands necessary to achieve a particular plasma target within saturation limits. Therefore, using the EC H&CD deposition location, which is related to the EC H&CD mirror angle, as a supplementary controllable variable may facilitate access to a given target scenario. However, active scenario-control algorithms have not been designed so far to fully exploit this capability in real time. In this work, a model predictive controller that can handle actuation locations as control inputs is developed. In particular, the controller is designed to regulate both the auxiliary powers and the EC H&CD deposition locations in a pre-defined optimal sense to achieve the control objective of attaining and sustaining a target current profile. Further, the proposed controller is tested for a DIII-D tokamak scenario in nonlinear simulations using the Control Oriented Transport SIMulator (COTSIM).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Nonlinear control of safety factor gradient in tokamaks using spatially variable electron cyclotron current drives

Active control of plasma properties may be necessary to achieve stable operation of next-generation tokamaks over large time scales. Such control algorithms can regulate the plasma properties to avoid the onset of magnetohydrodynamic (MHD) instabilities. For instance, the global and local properties of the safety factor profile are linked to the onset of neoclassical tearing modes (NTMs). This work proposes a model-based control approach for deterring/delaying NTMs through active modulation of one of the safety factor properties - the gradient of the safety factor profile at a particular rational safety factor surface. In particular, a novel control-oriented model for the local safety factor gradient is developed. The nonlinear control model is governed by a nonautonomous ordinary differential equation that accounts for a given rational safety factor surface’s spatial variation over time. Further, to improve the controllability of the spatially evolving parameter, the control model treats ECH&CD positions, along with noninductive powers, as controllable variables. A nonlinear control algorithm based on feedback linearization with optimization is synthesized to achieve the objective of regulating the safety factor gradient around a given target. The proposed algorithm allocates optimal ECH&CD positions, in addition to auxiliary powers, at each time instant as the rational safety factor surface drifts to locations with a low control authority. Stability guarantees of the proposed control law are also discussed in this work. The proposed algorithm is tested for a DIII-D tokamak scenario in nonlinear simulations carried out using the Control Oriented Transport SIMulator (COTSIM). Both fixed and moving ECH&CD cases are studied, and their outcomes are compared. Simulation results demonstrate that enthusiastic regulation of the safety factor gradient can be achieved during the ramp-up and flat-top phases of tokamak operation in both fixed and moving ECH&CD cases. However, real-time updates of ECH&CD positions can prevent the saturation of auxiliary powers.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Materials Data on Li2CdPb by Materials Project

Li2CdPb crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Li sites. In the first Li site, Li is bonded to four equivalent Pb atoms to form distorted corner-sharing LiPb4 tetrahedra. All Li–Pb bond lengths are 3.03 Å. In the second Li site, Li is bonded to four equivalent Cd atoms to form distorted corner-sharing LiCd4 tetrahedra. All Li–Cd bond lengths are 3.03 Å. Cd is bonded in a body-centered cubic geometry to four equivalent Li and four equivalent Pb atoms. All Cd–Pb bond lengths are 3.03 Å. Pb is bonded in a body-centered cubic geometry to four equivalent Li and four equivalent Cd atoms.

36 MATERIALS SCIENCE↗

Materials Data on CdNi by Materials Project

NiCd crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. there are two inequivalent Ni sites. In the first Ni site, Ni is bonded in a 9-coordinate geometry to three equivalent Ni and six equivalent Cd atoms. All Ni–Ni bond lengths are 2.46 Å. There are three shorter (2.64 Å) and three longer (3.14 Å) Ni–Cd bond lengths. In the second Ni site, Ni is bonded in a 6-coordinate geometry to six equivalent Cd atoms. All Ni–Cd bond lengths are 2.53 Å. Cd is bonded in a 4-coordinate geometry to six Ni atoms.

36 MATERIALS SCIENCE↗

Materials Data on BaCdGe by Materials Project

BaCdGe is hexagonal omega structure-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Ba is bonded to six equivalent Cd and six equivalent Ge atoms to form a mixture of face and edge-sharing BaCd6Ge6 cuboctahedra. All Ba–Cd bond lengths are 3.66 Å. All Ba–Ge bond lengths are 3.66 Å. Cd is bonded in a distorted trigonal planar geometry to six equivalent Ba and three equivalent Ge atoms. All Cd–Ge bond lengths are 2.75 Å. Ge is bonded in a 3-coordinate geometry to six equivalent Ba and three equivalent Cd atoms.

36 MATERIALS SCIENCE↗

Materials Data on Ce2CdPt2 by Materials Project

Ce2Pt2Cd crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Ce is bonded in a 6-coordinate geometry to six equivalent Pt and four equivalent Cd atoms. There are two shorter (2.90 Å) and four longer (3.04 Å) Ce–Pt bond lengths. All Ce–Cd bond lengths are 3.47 Å. Pt is bonded in a 9-coordinate geometry to six equivalent Ce and two equivalent Cd atoms. Both Pt–Cd bond lengths are 3.08 Å. Cd is bonded to eight equivalent Ce and four equivalent Pt atoms to form a mixture of face and corner-sharing CdCe8Pt4 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on Ce2CdPd2 by Materials Project

Ce2Pd2Cd crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Ce is bonded in a 6-coordinate geometry to six equivalent Pd and four equivalent Cd atoms. There are two shorter (2.91 Å) and four longer (3.07 Å) Ce–Pd bond lengths. All Ce–Cd bond lengths are 3.47 Å. Pd is bonded in a 9-coordinate geometry to six equivalent Ce, one Pd, and two equivalent Cd atoms. The Pd–Pd bond length is 2.89 Å. Both Pd–Cd bond lengths are 3.07 Å. Cd is bonded to eight equivalent Ce and four equivalent Pd atoms to form a mixture of face and corner-sharing CdCe8Pd4 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on Pr2CdNi2 by Materials Project

Pr2Ni2Cd crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Pr is bonded in a 6-coordinate geometry to six equivalent Ni and four equivalent Cd atoms. There are two shorter (2.93 Å) and four longer (2.98 Å) Pr–Ni bond lengths. All Pr–Cd bond lengths are 3.39 Å. Ni is bonded in a 9-coordinate geometry to six equivalent Pr, one Ni, and two equivalent Cd atoms. The Ni–Ni bond length is 2.48 Å. Both Ni–Cd bond lengths are 3.03 Å. Cd is bonded to eight equivalent Pr and four equivalent Ni atoms to form a mixture of face and corner-sharing CdPr8Ni4 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on Nd2CdNi2 by Materials Project

Nd2Ni2Cd crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Nd is bonded in a 6-coordinate geometry to six equivalent Ni and four equivalent Cd atoms. There are two shorter (2.91 Å) and four longer (2.96 Å) Nd–Ni bond lengths. All Nd–Cd bond lengths are 3.37 Å. Ni is bonded in a 9-coordinate geometry to six equivalent Nd, one Ni, and two equivalent Cd atoms. The Ni–Ni bond length is 2.48 Å. Both Ni–Cd bond lengths are 3.01 Å. Cd is bonded to eight equivalent Nd and four equivalent Ni atoms to form a mixture of corner and face-sharing CdNd8Ni4 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on CeCdNi4 by Materials Project

CeNi4Cd is Hexagonal Laves-derived structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Ce is bonded in a 12-coordinate geometry to twelve equivalent Ni and four equivalent Cd atoms. All Ce–Ni bond lengths are 2.93 Å. All Ce–Cd bond lengths are 3.06 Å. Ni is bonded to three equivalent Ce, six equivalent Ni, and three equivalent Cd atoms to form a mixture of face, edge, and corner-sharing NiCe3Cd3Ni6 cuboctahedra. There are three shorter (2.48 Å) and three longer (2.52 Å) Ni–Ni bond lengths. All Ni–Cd bond lengths are 2.93 Å. Cd is bonded in a 4-coordinate geometry to four equivalent Ce and twelve equivalent Ni atoms.

36 MATERIALS SCIENCE↗