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At least 973 records · Page 54

The influence of line shape and band structure on temperatures in planetary atmospheres

Numerical experiments are performed to examine the effects of line shape and band structure on the radiative equilibrium temperature profile in planetary atmospheres. In order to accurately determine these effects, a method for calculating radiative terms is developed which avoids the usual approximations. It differs from the more commonly used methods in that it allows arbitrary dependence of the absorption coefficient on wave number, without requiring tedious line by line integration and without the constraints of band models. The present formulation is restricted to homogeneous atmospheres but the concept can be extended to the more general case. The numerical experiments reveal that the line shape and band structure of the absorbing gases have a large effect on temperatures in the higher layers of the atmosphere (corresponding to the stratosphere and mesosphere). The more nongrey the spectrum (that is, the higher the peaks and the deeper the troughs in the spectrum), the lower the temperature.

Arking, A.↗

Optical absorption in fused silica at elevated temperatures during 1.5-MeV electron irradiation

An experimental determination of the optical transmission of Corning 7940 UV and Suprasil 1 and 2 fused silica has been made during 1.5-MeV electron bombardment. The fused silica reached temperatures ranging from 150 to 1000 C. The Lewis Research Center dynamitron provided electron current densities which corresponded to a dose rate of 2.6 to 20 Mrad/sec. The irradiation induced absorption was measured at 215.0, 270.0, and 450.0 nm (2150, 2700, 4500 A). The length of each irradiation was sufficient so that an equilibrium between radiation induced coloration and high temperature annealing was reached. The experimental results indicate a significant optical absorption, with values of the induced absorption coefficient at 215.0 nm (2150 A) of 14.5 to 2.2/cm, at 270.0 nm (2700 A) of 9.7 to 3.0/cm and at 450.0 nm (4500 A) of 3.7 to 0.5/cm. This would make the use of fused silica as the separating wall material in the nuclear light bulb propulsion concept questionable.

Smith, A. B.↗

Microwave emission from the moon

Measurements of the microwave emission from the moon and their interpretation in terms of the thermophysics of that body are reviewed. Variations of the brightness temperatures of the moon during a lunation and during eclipses when combined with infrared and radar measurements yield a precise set of physical parameters for the upper few meters of the lunar soil. These parameters include the density, thermal conductivity, dielectric constant, radio absorption coefficients, and the mean temperature gradiant.

Muhleman, D. O.↗

Stark-effect modulation of a CO2 laser by NH2D.

Use of the molecular Stark effect in NH2D to modulate the 10.6-micron P(20) line of a CO2 laser, yielding a modulation depth of 40% from a 200-V/cm rms signal applied to a 19.7-cm gas cell external to the laser. NH2D was prepared by mixing ND3 and NH3. The absorption coefficient of the M = 4 Stark-split line was measured as a function of mixing ratio and pressure. The observed pressure-broadening coefficient was 32.5 MHz/torr.

Johnston, A. R.↗

Total radiative intensity calculations for 100% H2 and 87% H2-13% He.

Isothermal radiative intensity calculations for 100% H2 and 87% H2-13% He are presented for temperatures of 10,000-25,000 K, density ratios of .0001 to .1, and path lengths of 1.0-30.0 cm. The actual spectral details of the absorption coefficient were computed for 16,000 points from 240 to 30,000 A by summing the various line and continuum radiative processes at each point. This method should result in a very accurate calculation of radiative emission, including an accurate accounting for reabsorption due to overlapping lines.

Stickford, G. H., Jr.↗

Photodissociation of CS2 in the vacuum ultraviolet - Determination of bond dissociation energy from the lowest vibrational level of the ground state CS2.

Photolysis in the vacuum ultraviolet results almost exclusively in the production of S(super-3)P atoms, which is in apparent violation of spin conservation. The threshold energy of incident photons required to produce fluorescence was used to calculate the bond dissociation energy (from the lowest vibrational level of the ground state), and the result agrees with the value previously derived from the photoionization of CS2. The fluorescence excitation spectrum shows peaks corresponding to Rydberg series I and II, indicating that the observed photodissociation of CS2 in the vacuum ultraviolet is mainly the result of predissociation from Rydberg states. The absorption coefficient of CS2 was measured in the region of 1200 to 1400 A.

Okabe, H.↗

Gyrosynchrotron radiation and its transfer in a magnetoactive plasma.

Gyrosynchrotron radiation fields from mildly relativistic electrons in a magnetoactive plasma are asymptotically calculated by using the Green tensor and the Fourier transformation. These fields consist of the two components which correspond to the ordinary and extraordinary modes. Taking into account these fields, the emissivities and the absorption coefficients from an arbitrary distribution of electrons are calculated in order to discuss the intensity, spectrum, and polarization of gyrosynchrotron radiation. In general, the transfer of electromagnetic energy takes place along a direction different from that of the wave normal since the radiation fields have a nonvanishing component along the direction of the wave normal. A consideration is given on the problem of radiative transfer in relation to the Stokes parameters.

Sakurai, K.↗

A sealed titanium window proportional counter for the detection of .5-keV X rays.

A sealed Ti window proportional counter sensitive to X radiation in the energy range 0.35-0.45 keV and above 1.5 keV is described. Measurements of the Ti mass absorption coefficients and a graphical summary of the literature values are presented. For a proportional counter with a 930 microgram/sq cm (2.1-micron) Ti window, the peak efficiency at 0.45 keV is found to lie between 4.6% and 7.1%. An application in X-ray astronomy involving a rocket observation of Sco X-1 is discussed.

Mcclintock, J. E.↗

Vibrational relaxation of the bending mode of shock-heated CO2 by laser-absorption measurements.

Study of the vibrational relaxation characteristics of shock-heated CO2 using a tuned CO2 laser absorption technique. Absorption-coefficient histories were obtained for a single rotational state in each of the -10 0- and -02 0- levels over the temperature range from 500 to 2000 K, and for 21 rotational states of the -10 0- level at 1000 K. These histories have been combined with translational-rotational temperature histories based on interferometer measurements to calculate vibrational relaxation times for the bending mode. The results verify the mutual equilibrium of the bending and symmetric-stretch modes due to Fermi resonance. The bending mode relaxation times are approximately 10% shorter than predicted from interferometer results using the ratio of specific heats. Furthermore, relaxation times based on measurements of different rotational states at 1000 K show a variation with quantum number J, indicating a possible rotational nonequilibrium during the vibration relaxation process.

Eckstrom, D. J.↗

The composition of the Martian atmosphere - Minor constituents.

The Mariner 6 and 7 infrared spectrometers provided data which, in principle, determine upper limits on the possible atmospheric abundance of every gaseous substance that was undetected but which has recognized absorptions in the accessible spectral region, 1.9 to 14.4 microns. Through supporting laboratory determinations of curves of growth under pressure-broadening conditions appropriate to Mars, upper limits can be specified (expressed first in cm-atm, STP, for a vertical column and then in parts per million) for NO2, NH3, C3O2, SO2, OCS, NO, O3, CH4, N2O, HCL, HBr, and H2S. In addition, considerations of band contours, moments of inertia, and experimental absorption coefficients make it possible to place useful upper limits on 27 additional substances that were not detected and for which curves of growth have not been measured.

Horn, D.↗

The prospects for mineral analysis by remote infrared spectroscopy.

An investigation of the effects of physical parameters on the spectra of minerals has been carried out, and an attempt made to develop a comprehensive theory of the reflectance (or emittance) spectra of particulate surfaces. The theory involves the effects of particle size, surface roughness, porosity, and mixing ratios on the spectra of mineralogical assemblages. The true spectral information is represented by the refractive indices and absorption coefficients of the constituent minerals. The present theory and the Mie theory for a cloud of well separated quartz particles are compared, as well as theoretical and experimental reflectances of quartz powders, glass beads, and corundum powders. Experimental results of abrading sapphire are presented.

Aronson, J. R.↗

Approximate temperature distribution for a diffuse, highly reflecting material.

The application of a 'two-flux' technique is considered for determining the reflective characteristics and approximate temperature distribution in highly backscattering materials characterized by a very small absorption coefficient. With respect to the transmitted internal radiation fields, the internal radiative emission is assumed to be negligible. A comparison of theory and experiment is presented.

Weston, K. C.↗

Microwave emission from granular silicates

Experimental finding is that mass absorption coefficient is independent of frequency but highly dependent on moisture content; effective conductivity increases with frequency, and low tangent is independent of frequency. Computed values of electrical properties are in rough numerical agreement with extrapolated laboratory values on other silicate materials.

Conel, J. E.↗

UV photography of the earth and moon

This experiment obtained imagery of the earth and the moon at a series of wavelength intervals in the near ultraviolet. These photographs were used to aid in the interpretation of the UV appearance of other planets in the solar system, especially mars and venus. The filter and film characteristics are described, as well as the ozone absorption coefficient curve.

Owen, T. C.↗

The application of far IR lasers to the investigation of the optical properties of materials

The effect of diffusion on the saturation and absorption properties of molecular gases is considered. The analysis starts with a simple derivation of the multi-level rate equations. Incorporating the diffusion term, calculations are carried out both for the homogeneous and inhomogeneous broadening cases. Both graphical and analytical solutions are obtained for the absorption coefficient and the saturation intensity. It is shown that the effect of diffusion is characterized by a diffusion function, which varies inversely with the radius of the beam at low pressures and small beam sizes. The analysis is done in terms of two parameters k1a and k2a, which are simple functions of the intensity of the beam I, the effective relaxation rate w, and the effective diffusion constant D the a is designated as the radius of the beam.

Stafsudd, O. M.↗

Net radiation method for enclosure systems involving partially transparent walls

The net radiation method is developed for analyzing radiation heat transfer in enclosure systems involving partially transparent walls. One such system is an enclosure with windows in it. The conventional net radiation method was developed for enclosures having opaque walls. If a partially transparent wall is present, it will permit radiation to enter and leave the enclosure. The net radiation equations are developed here for gray and semigray enclosures with one or more windows. Another system of interest, such as in a flat plate solar collector, consists of a series of parallel transparent layers. The transmission characteristics of such window systems are obtained by the net radiation method, and the technique appears to be more convenient than the ray tracing method which has been used in the past. Relations are developed for windows consisting of any number of parallel layers having differing absorption coefficients and differing surface reflectivities, and for systems composed of parallel transmitting layers and opaque plates.

Siegel, R.↗

An interative solution of an integral equation for radiative transfer by using variational technique

An effective iterative technique is introduced to solve a nonlinear integral equation frequently associated with radiative transfer problems. The problem is formulated in such a way that each step of an iterative sequence requires the solution of a linear integral equation. The advantage of a previously introduced variational technique which utilizes a stepwise constant trial function is exploited to cope with the nonlinear problem. The method is simple and straightforward. Rapid convergence is obtained by employing a linear interpolation of the iterative solutions. Using absorption coefficients of the Milne-Eddington type, which are applicable to some planetary atmospheric radiation problems. Solutions are found in terms of temperature and radiative flux. These solutions are presented numerically and show excellent agreement with other numerical solutions.

Yoshikawa, K. K.↗

An electrophotometer operating in a photon-counting regime

A photon counter photometer constructed allows one to carry out the UBV - photometry of stars from 6.0 to 14.0 stellar magnitude with the accuracy of 0.007 to 0.017 stellar magnitude. The absorption coefficients in U, B, V are determined and the color equations for transferring the observed magnitude differences to the UBV system are found.

Pugach, A. F.↗