Influences of temperature on permeability changes of flow-paths altered by highly alkaline Ca-rich groundwater - 15192
Fractures (or cracks) in host rock around the geological repository are considered as main flow-paths for the migration of radionuclides. Such fractures would be altered by the alkaline components (Ca, Na, K) leaching from cementitious materials for the construction of the repository. While silicate minerals in fractures are dissolved by highly alkaline groundwater, secondary minerals would deposit on the surface of fractures because of the reaction between the alkaline components and silicate species. The authors' previous study showed the generation of CSH-gel and the clogging of micro flow-path under the condition of Ca-rich and high pH by flow experiments. The present study examined the permeability changes with temperature in micro flow-path flowing highly alkaline Ca-rich solution, considering temperature at the depth of geological disposal system. For the simulation of micro flow-path such as fractures, 'micro flow-cell', which nipped a thin Teflon sheet with a slit between granite chip and Teflon basement, were used for the experiments. Highly alkaline Ca-rich solution (pH>12 and 8.5 mM Ca(OH){sub 2}) were injected into micro flow-cell with 2.0 ml/h of flow rate under the given temperature conditions (278 K, 296 K or 313 K). As a result, the permeability became lower with the increase in temperature. In addition, the deposition rates of CSH-gel became larger with the increase in temperature, and the activation energy was estimated to be 32.0 kJ/mol. These results suggest that flow-paths around the geological repository would undergo the clogging with CSH-gel in a shorter time-period under a condition of higher temperature. (authors)