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At least 973 records · Page 54

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NASA NTRS1987

A vaporization model for iron/silicate fractionation in the Mercury protoplanet

A study has been carried out on the vaporization of a totally molten silicate magma of chondritic composition heated into the range 2500-3500 K. The motivation for this was to determine the changes in the composition of the mantle that would occur in the Mercury protoplanet should that body have been subjected to the high-temperature phase in the evolution of the primitive solar nebula, but the results are of more general interest. An empirical model based on ideal mixing of complex components was used to describe the nonideal magma. It is found that vaporization of about 70-80 percent of the original amount of silicate from a chondritic planet is required to produce an iron-rich body with a mean uncompressed density equal to that deduced for Mercury. At this point the silicate is depleted in the alkalis, FeO, and SiO2, and enriched in CaO, MgO, Al2O3, and TiO2 relative to chondritic material.

Fegley, Bruce, Jr.↗

NASA NTRS1988

Protective Coating For Laser Drilling Of Silicon

Sodium silicate prevents spattered silicon from fusing with surrounding material. Sodium silicate solution applied to wafer by dipping and draining or by spinning; application by spraying also works. When dried in oven, solution leaves thin coating of sodium silicate glass.

Shlichta, Paul J.↗

NASA NTRS1987

Mineralogy of chondritic interplanetary dust particles

This paper presents a synopsis of current investigations on the mineralogy of chondritic micrometeorites obtained from the lower stratosphere using flat-plate collection surfaces attached to high-flying aircraft. A compilation of detailed mineralogical analyses for 30 documented chondritic interplanetary dust particles indicates a wide variety of minerals present in assemblages which, as yet, are poorly defined. Two possible assemblages are: (1) carbonaceous phases and layer silicates and (2) carbonaceous and chain silicates or nesosilicates. Particles with both types of silicate assemblages are also observed.

Mackinnon, Ian D. R.↗

NASA NTRS1988

Raman observations on individual interplanetary dust particles

A Raman study of 20 representative interplanetary dust particles (IDPs) belonging to different infrared spectral classes is discussed. Six different groups of Raman spectra were discerned among the IDPs studied. Groups 1-5 exhibit the Raman signature of poorly crystallized carbonaceous material, with the degree of disorder of this material increasing from group 1 (most ordered) to group 5 (least ordered). Group 1 contains IDPs that have infrared spectra characteristic of olivines, and are deuterium depleted, while those in groups 2, 3, and 4 contain less ordered carbonaceous material and are deuterium enriched, suggesting different carbonaceous carrier phases for deuterium depletions and enrichments. Groups 5 and 6 contain little or no carbonaceous material, with an abundance of deuterium. No obvious relationship was found between Raman groups and infrared classes based on the 10 micron absorption band due to silicates. Because silicates are known to be present, but are not seen, it is presumed that silicate grains are coated with and/or imbedded in carbonaceous material. Several IDPs show broad visible laser-induced photoluminescence, probably produced by a carbonaceous component.

Wopenka, Brigitte↗

NASA NTRS1988

A multicomponent model of the infrared emission from Comet Halley

The 3-200-micron emission of Comet Halley is characterized theoretically by means of numerical simulations. Models with different populations of refractory dust grains are developed, applying compositional and spectral constraints based on ground-based and spacecraft observations. The results are presented in extensive graphs and discussed in detail. Best agreement between predicted and observed Halley emission is obtained for models with 8-40 times more crystalline silicate grains (by mass) than amorphous carbon grains. For the silicate grains, the predominance of large grains and thin carbonaceous coatings are found to account for the lack of a 10-micron silicate feature and the dark appearance of the comet, respectively.

Swamy, Krishna K. S.↗

NASA NTRS1988

The spectral properties of interplanetary dust particles

The observed spectral and mineralogical properties of interplanetary dust particles (IDP) allows the conclusion that: (1) the majority of IDP infrared spectra are dominated by olivine, pyroxene, or layer lattice silicate minerals, (2) to the first order the emission spectra of comets Halley and Kohoutek can be matched by mixtures of these IDP infrared types, implying that comets contain mixtures of these different crystalline silicates and may vary from comet to comet and perhaps even within a single comet, (3) do not expect to observe a single 20 micron feature in cometary spectra, (4) carbonaceous materials dominate the visible spectra properties of the IDPs even though the mass in these particles consists primarily of silicates, and (5) the particle characteristics summarized need to be properly accounted for in future cometary emission models.

Sandford, Scott A.↗

NASA NTRS1987

Kinetics of mineral condensation in the solar nebula

A natural extension of the type of gas-mineral-melt condensation experiments is to study the gas-mineral-melt reaction process by controlling the reaction times of appropriate gas compositions with silicate materials. In a condensing and vaporizing gas-solid system, important processes that could influence the composition of and speciation in the gas phase are the kinetics of vaporization of components from silicate crystals and melts. The high vacuum attainable in the space station would provide an environment for studying these processes at gas pressures much lower than those obtainable in experimental devices operated at terrestrial conditions in which the gas phase and mineral or melt would be allowed to come to exchange equilibrium. Further experiments would be performed at variable gas flow rates to simulate disequilibrium vapor fractionation. In this type of experiment it is desirable to analyze directly the species in the gas phase in equilibrium with the condensed silicate material. This analytical method would provide a direct determination of the species present in the gas phase. Currently, the notion of gas speciation is based on calculations from thermodynamic data. The proposed experiments require similar furnace designs and use similar experimental starting compositions, pressures, and temperatures as those described by Mysen.

Grove, T. L.↗

NASA NTRS1988

The spectral properties of collected interplanetary dust particles

Sandford, S. A.↗

NASA NTRS1989

Shock-implanted noble gases. II - Additional experimental studies and recognition in naturally shocked terrestrial materials

The process by which ambient gases can be implanted into silicates by shocks was investigated by analyzing the noble-gas content of several experimentally and naturally shocked silicate samples. The retentivity of shock-implanted gas during stepwise heating in the laboratory was defined in terms of two parameters, namely, the activation energy for diffusion and the extraction temperature at which 50 percent of the gas is released, both of which correlate with the shock pressure. The experiments indicate that, with increasing shock pressure, gas implantation occurs through an increasing production of microcracks/defects in the silicate lattice. The degree of annealing of these defects control the degree of diffusive loss of implanted gas.

Bogard, Donald↗

NASA NTRS1989

On the size distribution of newly formed grains in red supergiant atmospheres

Theoretical ultraviolet extinction curves have been calculated for comparison with observed curves for circumstellar dust in M supergiants. The theoretical curves assume a silicate grain composition, because silicate grains are expected in the oxygen-rich environments that are observed. Calculations were performed with and without the inclusion of scattering into the beam, with largely similar results. A comparison of the computed curves with the observed ultraviolet extinction curve for circumstellar dust in Alpha Scorpii indicates that the size distribution of the circumstellar grains must cut off near 800 A; that is, there are few or no grains smaller than this. The conclusion is that smaller interstellar silicate grains, where they exist, must come from other sources such as grain fragmentation in shocks.

Seab, C. Gregory↗

NASA NTRS1990

Reflectance spectra of 'featureless' materials and the surface mineralogies of M- and E-class asteroids

In a search for diagnostic spectral parameters which can be used to distinguish different materials on the surface of asteroids and to provide information on the detection limits for mafic silicates, the 0.3- to 2.6-micron reflectance spectra of meteoritic enstatite (nearly pure MgSiO3), iron meteorite metal, magnetite, and amorphous carbon as well as various mixtures of these materials with mafic silicates were examined. Results are presented on the dependence of the spectral detectability of mafic silicates associated with metal, carbon, and magnetite on the particle sizes of the phases, their chemistries, crystal structures, and abundances. It is shown that the observational data for a representative M-class asteroid, (16) Psyche, are largely consistent with a fine-grained metal-rich surface assemblage, whereas data for the E-class asteroid (44) Nysa indicate that its surface is composed of fine-grained material similar to enstatite achondrites, with a small amount of material comparable to the chondritic inclusions found in the Cumberland Falls aubrite.

Cloutis, Edward A.↗

NASA NTRS1990

Cobalt and nickel concentrations in the 'komatiite component' of Apollo 16 polymict samples

Some estimates for the concentrations of Co and Ni in the primitive mafic component of Apollo 16 breccias and soils are large, comparable to concentrations in terrestrial komatiites. These estimates may be erroneously high because the contribution from meteoritic contamination of the samples has been underestimated. However, even if the correction for meteoritic Co and Ni is valid and the calculated residual Ni is not of meteoritic origin, the Ni is presently carried by Fe-Ni metal while the Fe and Mg are carried by mafic silicates. If any large-scale separation of metal and silicate phases has occurred, the concentration ratio of Ni to Fe + Mg in the mafic silicates of the ancient crust in the vicinity of the Apollo 16 site has not been preserved by Apollo 16 rocks. Apollo 16 polymict breccias and soils contain much higher concentrations of siderophile elements and Fe-Ni metal than other nonmare samples from the Moon. Thus, it is likely that the Ni/(Mg + Fe) ratio estimated for the komatiite component from Apollo 16 samples is high compared to the actual ratio for the lunar crust.

Korotev, Randy L.↗

NASA NTRS1990

Constraints on the subsurface structure of Europa

The wedge-shaped bands appearing near the anti-Jovian point on Europa are tension cracks which, after formation on an intact lithosphere, have facilitated the rotation of ice-lithosphere sections decoupled from the silicate interior. Such factors as fluid pressure, surface temperature, silicate impurities in the ice, and strain rates, would have affected the processes in question. A minimum degree of differentiation is required for Europa to mechanically decouple the rotated ice lithosphere from the underlying, predominantly silicate mantle.

Golombek, M. P.↗

NASA NTRS1990

Microwave dielectric properties of dry rocks

A combination of techniques was used to measure the dielectric properties of 80 rock samples in the microwave region. The real part (RP) of the relative dielectric constant was measured in 0.1-GHz steps from 0.5 to 18 GHz, and the imaginary part (IP) was measured at five frequencies between 1.6 and 16 GHz. The bulk density rho(b) was also measured for all the samples, and the bulk chemical composition (BCC) was determined for 56 of the samples. RP is found to be frequency-independent at 0.5-18 GHz for all samples, and rho(b) accounts for about 50 percent of the observed variance. For silicate rocks, as much as 78 percent of the variance is explained by the combination of rho(b) and the fractional contents of oxides when the silicates are subgrouped by genesis. In contrast, IP decreases with increasing frequency for most rock samples, and no statistically significant relationships are found between IP and rho(b). For subgrouped silicate rocks, 60 percent of the variance in IP can be explained by BCC.

Ulaby, Fawwaz T.↗

NASA NTRS1989

Si3N4 emissivity and the unidentified infrared bands

Infrared spectroscopy of warm (about 150 to 750 K), dusty astronomical sources has revealed a structured emission spectrum which can be diagnostic of the composition, temperature, and in some cases, even size and shape of the grains giving rise to the observed emission. The identifications of silicate emission in oxygen rich objects and SiC in carbon rich object are two examples of this type of analysis. Cometary spectra at moderate resolution have similarly revealed silicate emission, tying together interstellar and interplanetary dust. However, Goebel has pointed out that some astronomical sources appear to contain a different type of dust which results in a qualitatively different spectral shape in the 8 to 13 micron region. The spectra shown make it appear unlikely that silicon nitride can be identified as the source of the 8 to 13 micron emission in either NGC 6572 or Nova Aql 1982. The similarity between the general wavelength and shape of the 10 micron emission from some silicates and that from the two forms of silicon nitride reported could allow a mix of cosmic grains which include some silicon nitride if only the 8 to 13 micron data are considered.

Russell, Ray W.↗

NASA NTRS1989

Grain growth, optical polarisation, and extinction in interstellar clouds

Increases in the wavelength of maximum polarization and the ratio of total to selective extinction are generally assumed to be the result of grain growth in interstellar clouds. Using a grain model in which the interstellar extinction is explained by amorphous carbon (a-C) and hydrogenated amorphous carbon (a-C:H) mantles on silicate cores the effects of these absorbing carbonaceous mantles on the polarizing properties of large (500 to 2500 A radius) silicate grains were theoretically studied. The polarization model of Mathis was adopted and it was shown that carbon-coated silicate grains can explain the relationship between the wavelength of maximum polarization and R observed toward dark clouds.

Jones, A. P.↗

NASA NTRS1989

New circumstellar dust component in oxygen rich environments

Spectra of oxygen rich stars in the IRAS low-resolution spectra (LRS) catalog were found to display two distinct classes of curcumstellar excess emission. The first group has the normal silicate with emission peaking at 10 and 18 microns. The second group has an emission spectrum peaking at 13 and 20 microns. There are also spectra with a mixture of the above types. Generally the continuum temperature associated with the second group is much warmer than that associated with the normal silicate group. Laboratory spectra are compared with the new excess which associates the emission with a class of materials represented by hydrated aluminates and silicates. Possible interpretations include equilibrium condensation sequences and peculiar metal abundance ratios.

Goebel, John H.↗

NASA NTRS1989

Continuous infrared emission of proto- and young-planetary nebulae

Evolutionary sequences of planetary nebulae (PNe) were calculated beginning from the moment of shell ejection to its dissipation and IR spectra of the outgoing radiation were obtained for different stages of the evolution. To solve the coupled hydrodynamical and radiation transfer problem a computer code was used in which gas and dust are treated as two separate hydrodynamical components. The models, which are calculated for two grain materials (graphite and silicate) have a size distribution of particles based on that found for the interstellar medium. In the computations, the recent optical properties of graphite and astronomical silicate grains tabulated by Draine (1987) were employed. It was assumed that silicate of graphite grains exist below some critical temperature equal to 1300 or to 1700 K, respectively. Infrared model spectra are compared with the IR radiation emitted by some proto- and some young-planetary nebulae. The observed IR continua can be quite well matched with our models with grains having a reasonable size range.

Szczerba, Ryszard↗