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Results for “SIDE EFFECTS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Suppressing proximity effects during rapid serial two-photon lithography through tuning of reaction–diffusion kinetics

The ability of two-photon lithography (TPL) to print deterministic nanoporous 3D structures is highly valuable for many applications. However, it is challenging to print such structures rapidly due to the proximity effects that cause closely spaced features to enlarge and merge. A key challenge is the limited understanding of the origins and spatiotemporal dynamics of the long-range proximity effects that extend beyond the optical focal spot. Here, we empirically investigate these proximity effects in serial TPL using custom-made acrylate-based photoresists. We demonstrate that the complex spatiotemporal dynamics of the proximity effects can be explained through the kinetics of the reaction–diffusion photopolymerization mechanisms that underlie the curing process. Specifically, we show that the proximity effects arise due to comparable timescales of reaction and diffusion of oxygen. Furthermore, we demonstrate that long-range proximity effects can be suppressed by introducing phenolic inhibitors, which reduce oxygen consumption through non-inhibiting side reactions and promote faster termination of curing reactions. These insights enabled improving the linewidths from >400 to 260 nm during printing of nanoporous 3D woodpiles at scanning speeds of 50 mm s −1 . Thus, the knowledge generated here can be applied to deterministically tune the proximity effects and enable rapid printing of high-resolution nanoporous 3D structures.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Direct regeneration of degraded LiFePO4 cathodes via a separator-enabled prelithiation strategy

A persistent challenge in lithium-ion batteries is the loss of active lithium due to the solid electrolyte interphase (SEI) formation and associated side reactions. While prelithiation employing lithium replenishment separator (LRS) has been proven effective in compensating for lithium loss, previous studies have largely been accompanied by gas evolution or solid residue formation during the prelithiation process. To surmount this challenge, we present a LRS based on 4-fluoro-1,2-dihydroxybenzene lithium salt (LiDF), capable of mitigating lithium loss while producing decomposition products that integrate directly into the electrolyte as functional additives which can assist with the stability of the SEI, free from gas or solid formation, thus establishing a sustainable and environmentally benign strategy for lithium compensation. Incorporation of the LRS enables the pristine LiFePO4||graphite (Gr) full cell to achieve 10.8% higher capacity than the cell with a polypropylene separator (PPS) after 200 cycles at 0.5C. Remarkably, the degraded LiFePO4 (D-LFP)||Gr full cell with the LRS exhibits a 135.8% capacity improvement over the PPS-based cell after 500 cycles. These findings establish the LRS as a powerful approach for both boosting high-performance lithium-ion batteries and recovering the capacity of degraded batteries.

Tao, Fujun↗
DOE OSTI2021

Energy use of piperazine with the advanced stripper from pilot plant testing

Here, piperazine with the Advanced Stripper (PZAS™) was tested at the National Carbon Capture Center (NCCC) at coal and NGCC conditions. Energy performance was measured with accounting for heat loss. The net heat duty was found to be identical at 2.45 GJ/tonne for both 4 and 12% CO 2 at 90% CO 2 removal. The average measured heat loss was 0.38 GJ/tonne and represented 30% of the gross heat rate. For PZAS, the warm rich piping before the control valve is the largest in surface area. Heat loss at this location increased heat duty by 80% of the heat loss value. Therefore, the total heat duty was decreased by 80% of the heat loss. The Independence™ model was validated using 112 steady-state pilot plant runs and predicted average net heat duty with an error of 9% and lean loading with an error of 10%. The model was used to simulate process impacts of heat loss for the PZAS and simple stripper configurations. For both strippers, heat loss was found to impact heat duty at locations other than just the steam heater. While heat loss in the steam heater was the most important for PZAS, heat loss in the column was the most important for the simple stripper due to a large top-side pinch and CO 2 reabsorption at the same location. CO 2 reabsorption in PZAS occurred only at high heat loss values (~0.14 GJ/hr), compared to low heat loss values (~ 0.03 GJ/hr) in the PZ-simple stripper. Excessive packing in the PZ-simple stripper caused a large top-side pinch at 0.23 mol/mol lean loading, making the column very sensitive to heat loss. Heat loss in the PZ-simple stripper increased heat duty by 120–150% at typical heat loss values and lean loading of 0.23 mol/mol. Heat loss in the MEA-simple stripper only increased heat duty by 1–13% in a typical lean loading range of 0.1–0.2 mol/mol. A large bottom side pinch at low lean loading for 7 m MEA made the effect of heat loss less pronounced.

42 ENGINEERING↗
DOE OSTI2024

Electron transfer in a crystalline cytochrome with four hemes

Diffusion of electrons over distances on the order of 100 μm has been observed in crystals of a small tetraheme cytochrome (STC) from Shewanella oneidensis [J. Huang et al . J. Am. Chem. Soc. 142, 10459–10467 (2020)]. Electron transfer between hemes in adjacent subunits of the crystal is slower and more strongly dependent on temperature than had been expected based on semiclassical electron-transfer theory. Here, in this work, we explore explanations for these findings by molecular-dynamics simulations of crystalline and monomeric STC. New procedures are developed for including time-dependent quantum mechanical energy differences in the gap between the energies of the reactant and product states and for evaluating fluctuations of the electronic-interaction matrix element that couples the two hemes. Rate constants for electron transfer are calculated from the time- and temperature-dependent energy gaps, coupling factors, and Franck–Condon-weighted densities of states using an expression with no freely adjustable parameters. Back reactions are considered, as are the effects of various protonation states of the carboxyl groups on the heme side chains. Interactions with water are found to dominate the fluctuations of the energy gap between the reactant and product states. The calculated rate constant for electron transfer from heme IV to heme Ib in a neighboring subunit at 300 K agrees well with the measured value. However, the calculated activation energy of the reaction in the crystal is considerably smaller than observed. We suggest two possible explanations for this discrepancy. The calculated rate constant for transfer from heme I to II within the same subunit of the crystal is about one-third that for monomeric STC in solution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Soft x-ray detection for small satellites with a commercial CMOS sensor at room temperature

Recently CMOS (complementary metal-oxide-semiconductor) sensors have progressed to a point where they may offer improved performance in imaging x-ray detection compared to the CCDs often used in x-ray satellites. We demonstrate x-ray detection in the soft x-ray band (250-1700 eV) by a commercially available back-illuminated Sony IMX290LLR CMOS sensor using the Advanced Photon Source at the Argonne National Laboratory. Additionally, while operating the device at room temperature, we measure energy resolutions (FWHM) of 47 eV at 250 eV and and 77 eV 1700 eV which are comparable to the performance of the Chandra ACIS and the Suzaku XIS. Furthermore, we demonstrate that the IMX290LLR can withstand radiation up to 17.1 krad, making it suitable for use on spacecraft in low earth orbit.

47 OTHER INSTRUMENTATION↗
NASA NTRS1972

Propellant sidefeed-short pulse discharge thruster studies

The technique of feeding a solid propellant into the discharge from the sides of the discharge was evaluated. The thrust/power ratio could be significantly effected by the included angle of V-shaped propellants and by the electrode length. This result implies that when results are compared at the same specific impulse it is possible to obtain higher thrust efficiencies. In particular, it was found that for a given discharge energy the thrust/power ratio correlated with propellant mass. Increasing the integral simultaneously increases both the gas dynamic and electromagnetic thrust. An analytic expression was formulated for ablated mass which comprehensively describes experimental data in terms of geometry and electrical parameters. The correlation of the product impulse x specific impulse with discharge energy was also described. It is suggested that the reliability of dry energy storage capacitors does not equal the reliability of liquid impregnated units when the comparison is made at the same joules/Kg rating.

Palumbo, D. J.↗
NASA NTRS1977

Static and wind-on tests of an upper-surface-blown jet-flap nozzle arrangement for use on the Quiet Clean Short-haul Experimental Engine (QCSEE)

The internal aerodynamic performance, the static turning characteristics, and the forward-speed characteristics of two 1/12-scale upper surface-blown jet-flap exhaust-nozzle arrangements designed for use on the Quiet Clean Short-Haul Experimental Engine (QCSEE) were investigated. The nozzles were equipped with interchangeable area-control side doors in the aft sidewalls of the nozzle so that the effective nozzle area could be varied over a wide range. A simulated wing was used to evaluate installation losses for the nozzles. A smoothly curved flap was attached to the trailing edge of the simulated wing to allow an evaluation of the static turning characteristics of the nozzle arrangement. Forward-speed effects on the jet turning characteristics of the QCSEE nozzles were evaluated by mounting a single engine on a semispan wing designed to be representative of a four-engine STOL transport configuration.

Phelps, A. E., III↗
NASA NTRS1978

The execution of systematic measurements on plane cascades

The present state of development of the experimental technique regarding the flow through cascades and several points to be specially observed in the design of cascade wind tunnels were discussed. The equations required for the evaluation of the momentum measurements in two dimensional flow through cascades were developed. Regarding the effect of the jet contraction due to the boundary layer along the side walls a simple method for correction was also given in order to obtain two dimensional flow characteristics. Also given were the equations for the evaluation of the pressure distribution measurements. Another contribution was made regarding the presentation of the test results in the form of nondimensional quantities. The results of systematic measurements of cascades with symmetrical aerofoil were reported, and the above suggested method was applied for the evaluation of the measurements.

Scholz, N.↗
NASA NTRS1978

Computer image processing: Geologic applications

Computer image processing of digital data was performed to support several geological studies. The specific goals were to: (1) relate the mineral content to the spectral reflectance of certain geologic materials, (2) determine the influence of environmental factors, such as atmosphere and vegetation, and (3) improve image processing techniques. For detection of spectral differences related to mineralogy, the technique of band ratioing was found to be the most useful. The influence of atmospheric scattering and methods to correct for the scattering were also studied. Two techniques were used to correct for atmospheric effects: (1) dark object subtraction, (2) normalization of use of ground spectral measurements. Of the two, the first technique proved to be the most successful for removing the effects of atmospheric scattering. A digital mosaic was produced from two side-lapping LANDSAT frames. The advantages were that the same enhancement algorithm can be applied to both frames, and there is no seam where the two images are joined.

Abrams, M. J.↗
NASA NTRS1981

Influence of hydrogen chemisorption kinetics on the interpretation of hydrogen transport through iron membranes

The influence of a specific surface reaction on the transport of gas-phase hydrogen through iron membranes has been investigated on the basis of model calculations. The surface reaction involves an adsorbed molecular hydrogen precursor between the gas phase and the dissociated chemisorbed state. The calculations demonstrate that the surface reaction for the H2/Fe system makes significant contributions to the time delay associated with the transient hydrogen transport through iron membranes, even under conditions where the steady-state hydrogen transport is independent of the surface reaction. These contributions to the time delay are interpreted in terms of an effective diffusivity, which is a function of the pressure on the entrance side and the thickness of the membrane.

Shanabarger, M. R.↗
NASA NTRS1984

Natural large-scale structures in the axisymmetric mixing layer

The present study is concerned with the optimization of conditional sampling techniques for eduction of naturally occurring large-scale structures in an axisymmetric mixing layer, and a comparison of the natural structure with that induced by means of controlled excitation. Questions regarding the sensitivity of the educed structure to the excitation amplitude are also explored. Aspects regarding the eduction with the high-speed-side reference signal are considered, taking into account structure identification, the smearing effect and a comparison with the structure under excitation, the effects of the threshold level, and the effect of a trigger-level window. Attention is given to structure characteristics and their dependence on Reynolds number and initial condition.

Zaman, K. B. M. Q.↗
NASA NTRS1989

Analysis of vibrations of the National Transonic Facility model support system using a 3-D aeroelastic code

Vibrations of the National Transonic Facility model support system were analyzed using Computational Aeroelasticity Program-Transonic Small Disturbance, a three-dimensional transonic small disturbance code designed for aeroelastic analysis of complete aircraft. The model support system was represented as a tunnel-spanning flexible wing whose structural properties were obtained from measured responses. Aeroelastic transients were calculated and analyzed to obtain modal stability characteristics. The results show that there is tendency to exhibit a hump mode instability in one of the modes, and that there are other weakly damped or unstable modes. Most of the motion is in the aft section of the model support system. The close proximity of the solid wind-tunnel diffuser side walls to the model support system is shown to have adverse effects on its aeroelastic stability characteristics. When the effects of the wind-tunnel walls are modeled, the analyses indicate the presence of wind-tunnel resonance modes which are not present when free-air boundary conditions are used.

Whitlow, Woodrow, Jr.↗
NASA NTRS1989

Characteristics of type III bursts in the solar wind from simultaneous observations on board ISEE-3 and Voyager

The properties of solar type III bursts observed aboard ISEE-3 and Voyager that originate behind the sun are analyzed and compared to those originating on the near side. The measurement of the burst parameters and the correction for proximity effects are described. The diminution of flux densities, the increase of source sizes, the difference of source azimuths and elevations, the change of spectral properties, and the anomalous delays in burst arrival time at one spacecraft relative to another are determined. Many of the observations imply that the beaming of type III radiation is much more widespread at all frequencies than has been derived from statistical studies. The effective beam appears to consist of at least two components: a Gaussian core of half width about 60 deg, and a very broad halo that extends to 180 deg with an amplitude of a few percent.

Lecacheux, A.↗
NASA NTRS1991

Analysis of cryogenic propellant behavior in microgravity and low thrust environments

Predictions of a CFD program calculating a fluid-free surface shape and motion as a function of imposed acceleration are validated against the drop-tower test data collected to support design and performance assessments of the Saturn S-IVB stage liquid-hydrogen tank. The drop-tower facility, experimental package, and experiment procedures are outlined, and the program is described. It is noted that the validation analysis confirms the program's suitability for predicting low-g fluid slosh behavior, and that a similar analysis could examine the effect of incorporating baffles and screens to impede initiation of any unwanted side loads due to slosh. It is concluded that in actual vehicle applications, the engine thrust tailoff profile should be included in computer simulations if the precise interface versus time definition is needed.

Fisher, Mark F.↗
NASA NTRS1991

Measurements of condensation nuclei above the jet stream - Evidence for cross jet transport by waves and new particle formation at high altitudes

Condensation nuclei were used as a tracer in midlatitude NASA Stratosphere-Troposphere Exchange Project (STEP) experiments in April and May 1984 in order to study transport in the stratosphere. The very large scale, mean CN distribution was distorted by waves which had the effect of transporting air with anticyclonic properties several degrees to the cyclonic side of the jet and created a strongly layered structure in the CN distribution. Unfiltered CN data revealed short-wavelength oscillations in the CN distribution at the interface between the transported anticyclonic air parcel and the adjacent cyclonic air mass. These oscillations were also seen in the ozone data and increase the potential for mixing along that interface. If the mixing does occur, a wave mechanism for cross-jet transport has been observed.

Wilson, J. C.↗
NASA NTRS1992

Lunar radiator shade

An apparatus for rejecting waste heat from a system located on or near the lunar equator is presented. The system utilizes a reflective catenary shaped trough deployed about a vertical radiator to shade the radiator from heat emitted by the hot lunar surface. The catenary shaped trough is constructed from a film material and is aligned relative to the sun so that incoming solar energy is focused to a line just above the vertical radiator and can thereby isolate the radiator from the effects of direct sunlight. The film is in a collapsed position between side by side support rods, all of which are in a transport case. To deploy the film and support rods, a set of parallel tracks running perpendicular to length of the support rods are extended out from the transport case. After the support tracks are deployed, the support rods are positioned equidistant from each other along the length of the support tracks so that the flexible film shade between adjacent support rods is unfolded and hangs in a catenary shaped trough. A heat radiator is supported between each pair of support rods above each hanging reflective trough.

Ewert, Michael K.↗