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All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Modelling radionuclide transport in fractured media with a dynamic update of K d values

Radionuclide transport in fractured crystalline rocks is a process of interest in evaluating long term safety of potential disposal systems for radioactive wastes. Given their numerical efficiency and the absence of numerical dispersion, Lagrangian methods (e.g. particle tracking algorithms) are appealing approaches that are often used in safety assessment (SA) analyses. In these approaches, many complex geochemical retention processes are typically lumped into a single parameter: the distribution coefficient (Kd). Usually, the distribution coefficient is assumed to be constant over the time frame of interest. However, this assumption could be critical under long-term geochemical changes as it is demonstrated that the distribution coefficient depends on the background chemical conditions (e.g. pH, Eh, and major chemistry). In this study, we provide a computational framework that combines the efficiency of Lagrangian methods with a sound and explicit description of the geochemical changes of the site and their influence on the radionuclide retention properties.

58 GEOSCIENCES↗
DOE OSTI2015

Investigations for improved tank characterization and cleaning - 15454

In the process of tank closure, significant waste characterization and chemical cleaning occur. Costly characterization is performed at numerous processing stages. A need exists for new strategies and technologies to understand, optimize, scale, and speed up tank waste characterization with the end goal of reducing costs through implementation of programmatic changes that accelerate tank waste processing and tank closure schedules. This paper will explore a possible alternative to waste characterization methodologies and cleaning technologies to reduce costs and improve processing efficiency. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Deliquescence of Eutectic LiCl-KCl Diluted with NaCl for Interim Waste Salt Storage

Molten eutectic LiCl-KCl salt is a widely used electrolyte for electrorefining uranium from spent nuclear fuel. Due to the hygroscopic nature of this salt, such operations must be performed under controlled atmospheric conditions, and waste salts require careful storage to avoid deliquescence and corrosion of container materials. This study investigated a potential processing path for reducing the degree of deliquescence through dilution to varying extents with NaCl. Here, the hydration behavior of LiCl-KCl salts diluted with NaCl was evaluated in terms of mass gain due to water absorption, degree of deliquescence (including first appearances of standing water), and evidence of corrosion to stainless steel containers in a humid air environment (40°C, 20% relative humidity). In this humid air environment, pure eutectic LiCl-KCl exhibited a 50 mass % increase due to water absorption and showed evidence of standing water after 24 h. Waste salt diluted with NaCl required loadings of 89 mass % NaCl in order to prevent deliquescence and exhibited a 3 mass % increase due to water absorption. After periodic observation for 48 h, standing water was observed near all ingots with the exception of the 89 mass % NaCl samples. Dilution with 89% NaCl was also found to reduce evidence of corrosion when stored in stainless steel crucibles. While dilution with NaCl greatly decreases steady-state hydration, the storage volume is increased ~10× through this procedure.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Distinguishing Between Site Waste, Natural, and Other Sources of Contamination at Uranium and Thorium Contaminated Sites - 12274

Uranium and thorium processing and milling sites generate wastes (source, byproduct, or technically enhanced naturally occurring material), that contain contaminants that are similar to naturally occurring radioactive material deposits and other industry wastes. This can lead to mis-identification of other materials as Site wastes. A review of methods used by the US Army Corps of Engineers and the Environmental Protection Agency to distinguish Site wastes from potential other sources, enhanced materials, and natural deposits, at three different thorium mills was conducted. Real case examples demonstrate the importance of understanding the methods of distinguishing wastes. Distinguishing between Site wastes and enhanced Background material can be facilitated by establishing and applying a formal process. Significant project cost avoidance may be realized by distinguishing Site wastes from enhanced NORM. Collection of information on other potential sources of radioactive material and physical information related to the potential for other radioactive material sources should be gathered and reported in the Historical Site Assessment. At a minimum, locations of other such information should be recorded. Site decision makers should approach each Site area with the expectation that non site related radioactive material may be present and have a process in place to distinguish from Site and non Site related materials. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2024

Summary of Savannah River Site FY23 Salt Waste Qualification Data

The Savannah River National Laboratory (SRNL) analyzed samples from Savannah River Site (SRS) Waste Tanks 41H and 21H to support qualification of Salt Waste Processing Facility (SWPF) Waste Batches 8 and 9 for processing (the FY23 Salt Batch Qualification samples). These Tanks (i.e. 41H and 21H) are blend tanks for feed to SWPF. None of the samples displayed any unusual or unexpected characteristics such as large amounts of solids, floating solids, or unusual color. Characterization of these samples confirmed similar chemical composition and characteristics to previous salt waste batches. The results for Batches 8 and 9 were provided by SRNL to Savannah River Mission Completion (SRMC), the Liquid Waste Operations subcontractor at SRS, as External Sample Results (Laboratory Information Management System (LIMS)) Reports. Additionally, a separate technical memo was issued by SRNL to report re-test data for Batch 8 for Cs-137 for filtered samples only which were run at the request of SWPF. For Batch 9, a set of samples was also analyzed in parallel by the SWPF-Analytical Laboratory (SWPF-AL). The SWPF-AL data is included herein for comparison with the SRNL data where applicable. The analytical results (both rapid, typically 4 weeks, and long term, typically 8 weeks) for Batches 8 and 9 are now summarized and discussed in this technical report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Evaluation of Iron‐Phosphate Glass–Ceramic Waste Form for Electrorefiner Salt Waste Simulant Dechlorinated With Phosphoric Acid

The importance of glass and glass–ceramic nuclear waste forms has been reaffirmed in recent years by the growing interest in nuclear power as a reliable energy source. Determination of processing methods for the disposal of halide-containing wastes will be essential for the advancement of nuclear technologies such as non-aqueous fuel reprocessing. Phosphate-based dechlorination and subsequent vitrification of radioactive salt waste into an iron-phosphate waste form have been identified as a potential processing scheme for electrochemical processing waste. The impact of H 3 PO 4 -based dechlorination of complex salt mixtures on the vitrification process and structure of the final iron-phosphate waste form has not yet been investigated. In this work, iron-phosphate glass–ceramics were made from simulant salt waste (48LiCl–33KCl–19NaCl mol%) dechlorinated with the H3PO4-based method. The glass-forming region was compared to that of traditionally prepared Na 2 O–Fe 2 O 3 –P 2 O 5 systems. For a candidate glass-forming composition, the processing scheme presented here was determined to favor Fe 3+ species. The O/P molar ratio was consistent for the candidate composition when dechlorinated at 400°C and 600°C in air and argon environments, indicating glass network connectivity was maintained despite variations in processing parameters. The results presented here validate processing schemes requiring iron-phosphate waste form synthesis following H 3 PO 4 -based dechlorination.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

A Preliminary Probabilistic Performance Assessment Model for Radiological and Chemical Contamination at the West Valley Site, New York - 19295

The New York State Energy Research and Development Authority (NYSERDA) is the owner of the Western New York Nuclear Service Center (WNYNSC), a 1,351-ha site located approximately 48 km south of Buffalo, New York. In 1962, Nuclear Fuel Services, Inc. (NFS) entered into agreements with the Atomic Energy Commission and New York State to construct the first commercial reprocessing plant of nuclear fuel in the United States at the WNYNSC. NFS built and operated the spent fuel reprocessing plant and waste disposal facilities, processing 640 Mg (640 metric tons) of spent nuclear fuel from 1966 to 1972 under an Atomic Energy Commission license. Nuclear fuel reprocessing operations halted in 1972 and never restarted, leaving behind radioactive and chemical wastes. The reprocessing wastes include high-level waste (HLW), so U.S. Department of Energy (DOE) was compelled to complete certain waste management activities under the West Valley Demonstration Project (WVDP) Act of 1980, including decommissioning of WVDP facilities. As collaborating agencies, NYSERDA and the DOE are tasked with making decisions about decommissioning and risk reduction for the West Valley Site. Neptune and Company, Inc. (Neptune) was contracted to develop a probabilistic performance assessment (PPA) model to assist the agencies in their decision making process for decommissioning the WVDP and WNYNSC. One important tool that is needed in order to inform the decision-making process is a science-based model of the contamination at the West Valley Site and its potential implications for human health and the environment. The West Valley PPA Model (the Model), developed using the GoldSim modeling software, is a tool intended to provide support for decision making with uncertainty, in a manner that is transparent, defensible, and robust. The PPA Model includes contaminant transport and health effects components, and is organized around geographically-organized contaminated facilities. These include the waste disposal areas licensed by the U.S. Nuclear Regulatory Commission and the State of New York, a waste tank farm for storage of HLW resulting from reprocessing operations, and several areas contaminated with radioactive and chemical constituents. The Model evaluates contaminant transport from these sources to points of exposure across the site and into receiving surface waters and sediments. Hypothetical people and wildlife are exposed to contamination at these locations, and the effects of these exposures are evaluated. Contaminant transport processes to be evaluated in the Model include groundwater and surface water transport, contaminant translocation by plants and animals, diffusion in subsurface air and water, and erosion of the Site. The evaluation of exposures to people in this preliminary model is limited to a resident farmer scenario, and ecological assessment is performed at the level of a screening analysis. The results of these preliminary evaluations inform future model developments. Model results are subjected to sensitivity analysis in order to determine those pathways and parameters that are most significant in influencing the results. This information allows analysts and decision makers to focus on those aspects of Site behavior and processes that contribute most to overall uncertainty. With this information, the Supplemental Environmental Impact Statement (SEIS) can inform defensible decisions regarding remediation of the Site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Deployment of Performance Management Methodology as part of Liquid Waste Program at Savannah River Site - 12178

In 2009, Savannah River Remediation LLC (SRR) assumed the management lead of the Liquid Waste (LW) Program at the Savannah River Site (SRS). The four SRR partners and AREVA, as an integrated subcontractor are performing the ongoing effort to safely and reliably: - Close High Level Waste (HLW) storage tanks; - Maximize waste throughput at the Defense Waste Processing Facility (DWPF); - Process salt waste into stable final waste form; - Manage the HLW liquid waste material stored at SRS. As part of these initiatives, SRR and AREVA deployed a performance management methodology based on Overall Equipment Effectiveness (OEE) at the DWPF in order to support the required production increase. This project took advantage of lessons learned by AREVA through the deployment of Total Productive Maintenance and Visual Management methodologies at the La Hague reprocessing facility in France. The project also took advantage of measurement data collected from different steps of the DWPF process by the SRR team (Melter Engineering, Chemical Process Engineering, Laboratory Operations, Plant Operations). Today the SRR team has a standard method for measuring processing time throughout the facility, a reliable source of objective data for use in decision-making at all levels, and a better balance between engineering department goals and operational goals. Preliminary results show that the deployment of this performance management methodology to the LW program at SRS has already significantly contributed to the DWPF throughput increases and is being deployed in the Saltstone facility. As part of the liquid waste program on Savannah River Site, SRR committed to enhance production throughput of DWPF. Beyond technical modifications implemented at different location of the facility, SRR deployed performance management methodology based on OEE metrics. The implementation benefited from the experience gained by AREVA in its own facilities in France. OEE proved to be a valuable tool in order to support the enhancement program in DWPF by providing unified metrics to measure plant performances, identify bottleneck location, and rank the most time consuming causes from objective data shared between the different groups belonging to the organization. Beyond OEE, the Visual Management tool adapted from the one used at La Hague were also provided in order to further enhance communication within the operating teams. As a result of all the initiatives implemented on DWPF, achieved production has been increased to record rates from FY10 to FY11. It is expected that thanks to the performance management tools now available within DWPF, these results will be sustained and even improved in the future to meet system plan targets. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Site Characterization and Adaptation - Lessons Learned from the Port Granby LLRW Project in Canada - 19255

The Port Hope Area Initiative (PHAI) is a community-based solution for the long-term management of historic low level radioactive waste (LLRW) resulting from 60 years of uranium and radium processing operations in the Town of Port Hope, Ontario. The Eldorado refinery, on the shores of Lake Ontario, began refining radium-226 from pitchblende ore, later transitioning to the refining of uranium ore. Process residues were deposited at the Welcome Waste Management Facility in the Town of Port Hope until the mid-1950's switching to the Port Granby Waste Management Facility (PGWMF), which continued to accept waste until the late 1980's. The Port Granby Project is part of the broader PHAI being completed by Canadian Nuclear Laboratories (CNL). The scope of remediation activities at Port Granby includes: 1) constructing a new, secure long-term waste management facility (LTWMF) and supporting infrastructure, and 2) excavating and relocating LLRW and marginally contaminated soil from the Port Granby Waste Management Facility (PGWMF) to the newly constructed LTWMF. Remediation design required extensive site investigations of waste buried in unmarked and unlined trenches across the PGWMF area. Investigations included reviews of historical records, interviews with past staff of Eldorado and Atomic Energy Canada Limited (the entity managing the PHAI cleanup prior to CNL), radiological surveys, and the advancement of boreholes across the site to facilitate the physical sampling of soil and groundwater contaminants indicative of the presence of LLRW. This paper describes the challenges associated with characterizing and quantifying waste prior to remediation and lessons-learned to adjust procedural adaptations during the characterization phase of a project to better anticipate the unanticipated nature and growth of the contamination profile that often occurs during remediation. Despite substantial pre-remediation investigative efforts, current PGWMF remediation activities have resulted in growth of both the areal and vertical extent of contamination. The contamination profile was shown to be dramatically influenced by leaching of contaminants deeper into native soils. In addition, remedial excavation discovered specific waste types such as unidentified compressed gas cylinders outside of the location indicated by historical records, as well as a quantity of unknown liquids and unmarked drums. These discoveries have resulted in higher waste quantity estimates and have required a partial redesign of the LTWMF mound (a higher final elevation and steeper slopes) to accommodate the increased waste volume. In addition, the means and methods necessary to execute the remedial construction had to be modified to account for the new conceptual model developed from the new contamination data. Despite extensive historical review and site characterization to define the nature and extent of LLRW buried at the PGWMF, actual conditions encountered during remediation efforts necessitated taking an adaptive approach to both the design of the LTWMF and the means and methods used for excavation and transport of waste. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Remediation Residential Properties Contaminated with LLRW as Part of the Port Hope Area Initiative - The Importance of Effective Community Consultation - 18591

The Port Hope Area Initiative (PHAI) is a community-based solution for the long-term management of historic low level radioactive waste (LLRW) resulting from 60 years of uranium and radium processing operations in the urban setting of Port Hope, Ontario. The Eldorado refinery, on the shores of Lake Ontario, began refining radium-226 from pitchblende ore, later transitioning to the refining of uranium ore. Process residues were deposited at the Welcome Waste Management Facility in the Municipality of Port Hope until the mid-1950's switching to the Port Granby Waste Management Facility (PGWMF), which continued to accept waste until the late 1980's. Within the community of Port Hope, surveys are being conducted at approximately 4800 individual properties to identify the presence of LLRW resulting from fugitive emissions from the refinery and/or the use of refinery residue as construction backfill within the community. Identification of the presence of LLRW is based on multiple lines of evidence including reviews of historical information, gamma radiation surveys and physical sampling of soil for the presence of four signature contaminants. Of the 4800 properties being surveyed, it is expected that approximately 10% will contain some degree of LLRW requiring physical remediation. Many of the residences requiring remediation will require extensive soil removal, removal and restoration of outbuildings, fences and other structures, and the removal of mature trees, hedges and decorative gardens. For the property owners involved this phase represents the final and most intrusive aspect of the program. As such, the remedial designs must be sensitive to the needs of the community and individual property owners taking into consideration factors such as the need to minimize the disturbance to the neighborhood; maintaining geotechnical and structural stability of homes during excavations; removal and restoration of outbuildings affected by LLRW; removal and replacement of landscaping features (decks, fences, pools etc) and mature trees; radiation protection during earthworks; control of dust and noise; and maintaining safe access by residents. As Community satisfaction is a key metric for the success of the project, constant and effective communication at all stages of the project is necessary to ensure the residents understand the nature and extent of work to be undertaken; any and all inconveniences they can expect during the work; contingencies to deal with those inconveniences (e.g. parking, garbage collection etc); measures to protect their health and safety; scheduling; and what their property will look like at the completion of works. This paper provides an overview of the residential remediation program in Port Hope and describes the consultation efforts with property owners that are integral to the development of final designs. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Development of High Strength HEPA Filters for Use in Demanding Air and Gas Streams - 17644

High-efficiency particulate air (HEPA) filters are used in a wide variety of applications, including the removal of radioactive particulate from process off-gas streams and the venting of waste storage containers. Porvair Filtration Group, specializing in the design and manufacture of robust filters in numerous industries, has worked to develop HEPA filter designs for use in such high-demand nuclear process-gas and air streams. Using the requirements of section FK of the American Society of Mechanical Engineers AG-1 Code on Nuclear Air and Gas Treatment (ASME AG-1) as a guide, Porvair Filtration Group has designed filters which can withstand upset conditions to include elevated temperatures, high relative humidity, high particle-loading, and an unconventionally high differential pressure across the filter media; while maintaining excellent removal efficiencies. The process by which Porvair Filtration Group has reached optimized designs was based upon an extended test and development program. Design, manufacture, and testing of flat sheet media samples, geometrically equivalent model filters, and full-scale prototypes was performed at several Porvair Filtration Group facilities located in the United States and the United Kingdom. The methods and results of this development program are outlined in the following paper. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Port Hope Are Initiative Port Granby Project - Water Management in Extreme Weather Conditions - 19257

The Port Granby Project is part of the Port Hope Area Initiative (PHAI) through which Canadian Nuclear Laboratory (CNL) is managing long-term historic low level radioactive waste (LLRW) resulting from 60 years of uranium and radium processing operations in the urban setting of Port Hope, Ontario. Port Granby remediation scope includes 1) constructing a new, secure long-term waste management facility (LTWMF) and supporting infrastructure, and 2) excavating and relocating LLRW and marginally contaminated soil from the Port Granby Waste Management Facility (PGWMF), which accepted waste until the 1980's, to the newly constructed LTWMF. This paper provides an overview of the challenges of water management (control of storm and groundwater at the LTWMF and PGWMF) on a large-scale construction project with changing and unpredictable weather patterns. Consistent with increased observations of extreme weather events, over two consecutive construction seasons, weather changed from one of the driest on record (high temperatures, dry conditions and strong wind) to one of the wettest on record (short duration high-intensity rainfall that flooded the LTWMF, excavations and on-site PGWMF and LTWMF retention ponds). This paper describes the collaborative approach among Wood (Constructor), AECOM (Engineer of Record), and CNL to adjust to extremes in weather to control dust and excessive water during construction. The summer of 2016, one of the driest summers on record in southern Ontario, was followed by one of the wettest in 2017. In 2016, the project team used water from the uncontaminated on-site storm water ponds, applied a polymer product for dust control across the site to augment water applications, obtained a Permit to Take Water from the provincial government to pump water from Lake Ontario, procured large tanks for storage of Lake Ontario water to meet peak demand, and retained additional water trucks/operators for day to day site operations. In stark contrast, to accommodate heavy rains in 2017 the project team installed ∼6 million liter aboveground storage tanks with secondary containment for contaminated water storage; procured 100+ mobile water storage tanks to supplement the on-site storage, utilized LTWMF cells sumps, excavations and retention ponds to store and manage onsite water; and adjusted additional staff resources (more staff and longer shifts) during anticipated periods of high-intensity rainfall, at times managing water around the clock. Recognizing the need to minimize the release of contaminated soil and water from the construction site at all times, these efforts illustrate the importance of anticipating and reacting to extreme weather events on a more regular basis. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Characterization of undissolved solids from the dissolution of North Anna reactor fuel

Here, samples of undissolved solids (UDS) from the dissolution of North Anna reactor fuel were characterized to investigate the effects of using air or oxygen as the oxidant during tritium removal. The UDS composition data also support the development of a waste form for disposal. There was no discernible effect of the oxidant used during the tritium removal process or the size fraction on the UDS composition. Scanning electron microscopy (SEM) and energy dispersive (x-ray) spectroscopy were used to estimate the oxygen content of the UDS and it was found to be potentially significant, on the order of 30% by mass and 80% by atom.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

GeoMelt{sup R} In-Container Vitrification (ICV){sup TM} for Fukushima Daiichi Water Treatment Secondary Wastes - 20212

The Japanese government is supporting development work implemented jointly by Veolia subsidiaries Kurion Japan, K.K., Veolia Nuclear Solutions (VNS), Inc., and Veolia Nuclear Solutions Federal Services, LLC for treating radioactive waste generated from Fukushima Daiichi Nuclear Power Station (NPS) water treatment using the GeoMelt{sup TM} In-Container Vitrification (ICV){sup TM} technology. The initial work consisted of glass formulation and engineering-scale testing which was completed in 2018, in the frame of an IRID (International Research Institute for Nuclear Decommissioning) program as part of a project subsidized by Japan's Ministry of Economy, Trade and Industry (METI). The Fukushima Daiichi NPS Mid- and Long-Term Road-map requires investigation of methods to stabilize solid wastes (and to immobilize radioisotopes in the wastes) generated as a result of emergency response and decommissioning activities. Cooling water treatment has resulted in a significant amount of solid and slurry secondary wastes (mostly adsorbents and ion-exchange materials) which will require processing at some point. GeoMelt{sup R} ICV{sup TM} is a joule-heated melter technology which uses a refractory-lined single-use container combining the melter and disposal container. There is no pouring required nor concerns with refractory corrosion which allows the process to accommodate a wide range of waste chemistries and high waste loadings. The testing described here consisted of three engineering-scale melts, each processing between 212 kg and 240 kg of waste simulants, glass formers, and non-radioactive cesium (Cs) and strontium (Sr) tracers. Continuous isokinetic stack sampling of off-gas emissions was performed for each test in order to calculate Cs and Sr retention in the glass wasteform. Single-pass retention of Cs in the final glass wasteform ranged from 91.46 to 99.30%, and single-pass retention of Sr ranged from 99.76 to 100%. Planned particulate recycle will increase these retention levels. Melt 1 processed a mixture of KUR-EH (a zeolite-based ion-exchange material), simulated Advanced Liquid Processing System (ALPS) Carbonate and Iron Slurries, and glass additives. Melt 2 processed a mixture of KUR-EH, KUR-TSG (a titanate-based adsorbent), and glass additives. Melt 3 processed a mixture of KUR-EH, simulated barium sulfate/iron ferrocyanide sludge (AREVA sludge), and glass additives. Waste loadings for these melts ranged from 70 weight percent (wt%) to 82 wt%. Vitrification produces a waste form much denser than the stored water treatment secondary waste wastes, resulting in significant volume reduction. Volume reductions for the three tests ranged from 74 to 79 vol%. Vitrification produces a chemically durable wasteform. Pacific Northwest National Laboratory (PNNL) tested three glass samples from each engineering-scale melt) by the Materials Characterization Center 1 (MCC-1) test, an international standard leach test of the chemical durability of nuclear waste glasses. PNNL also obtained one U.S. reference glass (EA Glass) and two Japan reference glasses P0798) and tested these under the same MCC-1 conditions (90 deg. C, 10 m-1, DIW, and 7, 14, 28-day) as the GeoMelt{sup R} ICV{sup TM} glasses. The GeoMelt{sup R} ICV{sup TM} glasses exhibited lower total normalized releases and 14- to 28-day normalized release rates than the three reference glasses. These results suggest that the GeoMelt{sup R} ICV{sup TM} glasses have durabilities on par with high-level waste glasses under standard test conditions. Post-melt process sampling and analysis indicated no Cs migration into the melter refractory materials and very little deposition of Cs or Sr onto the melter hood or off-gas piping internals. The results of the testing indicated good Cs retention in the glass, high volume reduction and waste loadings, and excellent chemical durability. These factors are important to minimize treatment costs and to protect workers and the environment. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Ion Exchange Processing of AW-105 Hanford Tank Waste through Crystalline Silicotitanate in a Staged 2- then 3-Column System

The Hanford Site stores an estimated 56 million gallons of mixed radioactive and chemically hazardous waste in large underground tanks. In support of the Direct Feed Low-Activity Waste (DFLAW) Program for expediting Hanford tank waste supernate treatment, laboratory-scale ion exchange processing using prototypic unit operations was conducted on AW-105 tank waste at the Pacific Northwest National Laboratory Radiochemical Processing Laboratory. This report describes the small-scale ion exchange testing with 9.2 L of diluted and filtered supernate from Tank 241-AW-105 (hereafter referred to as AW-105) at 16 °C (62 °F). One of the waste acceptance criteria (WAC) for the Waste Treatment Plant (WTP) Low-Activity Waste Facility is that the waste must contain less than 3.18×10 -5 Ci 137 Cs per mole of Na. For the AW-105 tank waste to meet this criterion, only 0.225% of the influent 137 Cs concentration may be delivered to the WTP; this requires a Cs decontamination factor of 445. Testing with AW-105 matched current Tank Side Cesium Removal (TSCR) facility prototypic operations where a lead-lag configuration was used until the lag column reached the WAC limit, then a polish column was brought online for continued processing in a lead-lag-polish column configuration. Feed was processed at 1.9 bed volumes (BVs) per hour; the flowrate, in terms of contact time with the crystalline silicotitanate (CST) bed, matched the expected flowrate at TSCR. The Cs-decontaminated product was retained for vitrification testing (to be reported separately). The lead column reached 83% Cs breakthrough after processing ~1500 BVs of feed; the 50% Cs breakthrough was interpolated from the breakthrough data and occurred at 1041 BVs. Despite the AW-105 having a significantly higher K concentration (0.55 M compared to 0.10 M), testing compared to previous AP-107 ion exchange column testing at 16 °C showed no difference in BVs processed to reach the WAC on the lead column and only an approximate ~20 BV decrease in volume processed to reach the WAC limit on the lag column. The negligible differences in capacity despite the 5x concentration differences in K was determined to be due to the significantly lower NO3 concentration in the AW-105 supernate compared to the AP-107 tank waste matrix. A comparison in breakthrough curves for the two tests also indicated slightly faster kinetic behavior in the AW-105, with the variations in feed matrices (lower NO3 concentration) likely responsible for the deviation. The Cs effluent from the lag column reached the WAC limit after processing 772 BVs. Anticipating this breakthrough point, the polish column was preemptively installed around 675 BVs. Cs breakthrough from the lag column began at 300 BVs, reaching 1.10×10 1 µCi/mL, or 14.13 % Cs breakthrough, after processing all 1500 BVs of feed. The polish column processed nominally 830 BVs and reached 2.10×10 -1 µCi/mL, or 0.27 % Cs breakthrough at the conclusion of the test. Table S.1 and Figure S.1 summarize the observed column performance and relevant Cs loading characteristics.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Tank 48H Tetraphenylborate Mitigation: Simulant Studies using Sodium Permanganate

Tank 48H currently holds legacy material containing organic tetraphenylborate (TPB) compounds from the operation of the In-Tank Precipitation (ITP) process. TPB was added during the ITP process to precipitate the otherwise soluble cesium as insoluble cesium TPB (CsTPB), but excessive benzene generation from TPB degradation curtailed this treatment method. The contents of Tank 48H, which include approximately 26.000 kg of potassium TPB (KTPB) and trace CsTPB, are not compatible with the waste treatment facilities at the Savannah River Site (SRS) since the organic content and the associated flammability issues pose a challenge to the salt processing and sludge processing facilities within the liquid waste system. An in-tank process to remove (or decompose) TPB safely would be of great value. Previous testing at Savannah River National Laboratory (SRNL) demonstrated the destruction of glycolate via chemical oxidation using sodium permanganate with simulated and radioactive waste. Scoping tests were performed to study the destruction of TPB to determine if the contents of Tank 48H would be amenable to the same type of destruction. Partial destruction of TPB was observed in Tank 48H simulants under mild conditions (e g., pH 11, room temperature) with no definitive indication of benzene generation. To build upon the success of the scoping tests, an additional study was requested to provide a better understanding of the underlying chemistry for Tank 48H content destruction using sodium permanganate. Three experiments were performed with Tank 48H simulants at 40 °C to determine the efficacy of using sodium permanganate for TPB destruction. Three starting pH values were selected: 1) pH 11 for comparison with the previous work at room temperature, 2) pH 10 as the minimum pH recommended by the Corrosion Control Program (CCP) for in-tank processing, and 3) pH 8 to determine the effectiveness of TPB destruction at near neutral pH. While below the allowable pH for the CCP, the experiment at pH 8 was performed to study the TPB-Permanganate reaction under more extreme conditions and further verify the potential for out-of-tank processing.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

The evaluation of aluminum and iron metal oxide settling behaviors for Hanford insoluble solids waste preprocessing

The Hanford site is currently one of the largest and most expensive cleanup sites for hazardous, radioactive waste. Over 20% of the waste found at the Hanford site is in the form of a high activity sludge. The insoluble solids in the sludge will need to be concentrated prior to vitrification in the high-level waste (HLW) melter. This will minimize the amount of liquid that will be evaporated during the melting process and expedite the melter processing rate. One proposed option for concentrating the insoluble solids is gravity settling in the storage tanks. Metal oxide compounds containing aluminum and iron make up the majority of the insoluble solids in the sludge, therefore understanding the behavior of these compounds in various tank waste matrices can facilitate sludge pretreatment options. A study of non-radioactive slurry solutions containing Al(OH) 3 (gibbsite), AlO(OH) (boehmite), and Fe 2 O 3 (iron (III) oxide) was conducted to determine the time dependent interface behavior and settling rates of these compounds. Variations in solids loading and sodium concentration were evaluated to represent waste processing conditions and the results of these settling studies were compared with prior tank waste settling tests. Information gathered from these studies can be used to inform future decisions on sludge treatment processes of the insoluble solids processed at the Hanford site.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

A Perspective on Long-Term Recovery Following the Fukushima Nuclear Accident - 12075

The tragic events at the Fukushima Daiichi Nuclear Power Station began occurring on March 11, 2011, following Japan's unprecedented earthquake and tsunami. The subsequent loss of external power and on-site cooling capacity severely compromised the plant's safety systems, and subsequently, led to core melt in the affected reactors and damage to spent nuclear fuel in the storage pools. Together with hydrogen explosions, this resulted in a substantial release of radioactive material to the environment (mostly Iodine-131 and Cesium- 137), prompting an extensive evacuation effort. The latest release estimate places the event at the highest severity level (Level 7) on the International Nuclear Event Scale, the same as the Chernobyl accident of 1986. As the utility owner endeavored to stabilize the damaged facility, environmental contamination continued to propagate and affect every aspect of daily life in the affected region of Japan. Elevated levels of radioactivity (mostly dominated by Cs-137 with the passage of time) were found in soil, drinking water, vegetation, produce, seafood, and other foodstuffs. An estimated 80,000 to 90,000 people were evacuated; more evacuations are being contemplated months after the accident, and a vast amount of land has become contaminated. Early actions were taken to ban the shipment and sale of contaminated food and drinking water, followed by later actions to ban the shipment and sale of contaminated beef, mushrooms, and seafood. As the event continues to evolve toward stabilization, the long-term recovery effort needs to commence - a process that doubtless will involve rather complex decision-making interactions between various stakeholders. Key issues that may be encountered and considered in such a process include (1) socio-political factors, (2) local economic considerations, (3) land use options, (4) remediation approaches, (5) decontamination methods, (6) radioactive waste management, (7) cleanup levels and options, and (8) government policies, among others. This paper offers a perspective on this likely long and arduous journey toward establishing a 'new normal' that will ultimately take shape. Toward this end, it is important to evaluate the 'optimization' process advocated by the international community in achieving long-term recovery from this particularly fateful event in Fukushima. In the process, experience and lessons learned from past events will be fully evaluated and considered. (author)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗