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At least 973 records · Page 54

All sources NASA NTRS DOE OSTI

DOE OSTI2016

Integrated oil production and upgrading using molten alkali metal

A method that combines the oil retorting process (or other process needed to obtain/extract heavy oil or bitumen) with the process for upgrading these materials using sodium or other alkali metals. Specifically, the shale gas or other gases that are obtained from the retorting/extraction process may be introduced into the upgrading reactor and used to upgrade the oil feedstock. Also, the solid materials obtained from the reactor may be used as a fuel source, thereby providing the heat necessary for the retorting/extraction process. Other forms of integration are also disclosed.

02 PETROLEUM↗

DOE OSTI2017

Methods of analyzing crude oil

The invention generally relates to methods of analyzing crude oil. In certain embodiments, methods of the invention involve obtaining a crude oil sample, and subjecting the crude oil sample to mass spectrometry analysis. In certain embodiments, the method is performed without any sample pre-purification steps.

36 MATERIALS SCIENCE↗

DOE OSTI2015

Geomechanical Simulation to Predict the Oil Leak at the Wellbores in Big Hill Strategic Petroleum Reserve.

Oil leaks were found in wellbores of Caverns 105 and 109 at the Big Hill Strategic Petroleum Reserve site. According to the field observations, two instances of casing damage occurred at the depth of the interbed between the caprock bottom and salt top. A three dimensional finite element model, which contains wellbore element blocks and allows each cavern to be configured individually, is constructed to investigate the wellbore damage mechanism. The model also contains element blocks to represent interface between each lithology and a shear zone to examine the interbed behavior in a realistic manner. The causes of the damaged casing segments are a result of vertical and horizontal movements of the interbed between the caprock and salt dome. The salt top subsides because the volume of caverns below the salt top decrease with time due to salt creep closure, while the caprock subsides at a slower rate because the caprock is thick and stiffer. This discrepancy produces a deformation of the well. The deformed wellbore may fail at some time. An oil leak occurs when the wellbore fails. A possible oil leak date of each well is determined using an equivalent plastic strain failure criterion. A well grading system for a remediation plan is developed based on the predicted leak dates of each wellbore.

58 GEOSCIENCES↗

DOE OSTI2019

Methods of analyzing crude oil

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2019

Increasing the content of long chain fatty acids in seed oil

Provided are plants that express, or overexpress, a pPLAIIIδ protein. Constitutive or seed-specific expression of pPLAIIIδ protein in Arabidopsis increases seed oil content, the amount of C20 and C22 fatty acids, and the amount of C56, C58, and C60 triacylglycerols, effectively resulting in significantly higher oil yield per plant. Use of pPLAIIIδ is therefore an effective biotechnological tool to significantly increase plant yield, including oil, and the amount of high value long chain fatty acids in agricultural and horticultural crops, especially oilseed crops.

Wang, Xuemin↗

DOE OSTI2020

Methods of analyzing crude oil

02 PETROLEUM↗

DOE OSTI2021

Swell Behavior of Elastomers with a Hydrothermal Liquefaction Bio-Crude and a Fast Pyrolysis Bio-Oil

The compatibility of seventeen elastomer materials with two heavy biofuels (fast pyrolysis bio-oil and hydrothermal liquefaction (HTL) bio-crude) and diesel was assessed through volume change measurements. The elastomers included two fluorocarbons, six acrylonitrile rubbers (NBRs), and one each of fluorosilicone, neoprene, polyurethane, silicone, epichlorohydrin rubber (ECO), a blend of polyvinyl chloride and NBR (OZO), styrene butadiene rubber (SBR), hydrogenated NBR (HNBR) and ethylene propylene diene monomer (EPDM). The specimens were immersed in each test fuel for four weeks at 50°C and then measured for volume change. Afterwards, the specimens were dried, and the volume was remeasured. Ingeneral, the bio-oil produced unacceptable swelling in the fluoroelastomers, ECO, OZO, neoprene, polyurethane, SBR, HNBR, EPDM, silicone and five of the NBRs. In most cases, the HTL bio-crude produced lower (though still unacceptable) swelling than the bio-oil. Materials that showed good compatibility with the HTL biocrude were the fluoroelastomers, OZO, and silicone.

Kass, Michael↗

DOE OSTI2021

Increasing the content of long chain fatty acids in seed oil

Wang, Xuemin↗

DOE OSTI2022

History Matching and Prediction of a Polymer Flood Pilot in Heavy Oil Reservoir on Alaska North Slope

The first-ever polymer flood pilot to enhance heavy oil recovery on Alaska North Slope is ongoing. After more than 3 years of polymer injection, significant benefit has been observed from the decrease in water cut from 65% to less than 15% in the project producers. The primary objective of this study is to develop a robust history-matched reservoir simulation model capable of predicting future polymer flood performance. In this work, the reservoir simulation model has been developed based on the geological model and available reservoir and fluid data. In particular, four high transmissibility strips were introduced to connect the injector-producer well pairs, simulating short-circuiting flow behavior that can be explained by viscous fingering and reproducing the water cut history. The strip transmissibilities were manually tuned to improve the history matching results during the waterflooding and polymer flooding periods, respectively. It has been found that higher strip transmissibilities match the sharp water cut increase very well in the waterflooding period. Then the strip transmissibilities need to be reduced with time to match the significant water cut reduction. The viscous fingering effect in the reservoir during waterflooding and the restoration of injection conformance during polymer flooding have been effectively represented. Based on the validated simulation model, numerical simulation tests have been conducted to investigate the oil recovery performance under different development strategies, with consideration for sensitivity to polymer parameter uncertainties. The oil recovery factor with polymer flooding can reach about 39% in 30 years, twice as much as forecasted with continued waterflooding. Besides, the updated reservoir model has been successfully employed to forecast polymer utilization, a valuable parameter to evaluate the pilot test’s economic efficiency. All the investigated development strategies indicate polymer utilization lower than 3.5 lbs/bbl in 30 years, which is less than that of the same polymer used in a polymer pilot in Argentina.

Wang, Xindan↗

DOE OSTI2022

Methods of analyzing crude oil

Cooks, Robert Graham↗

DOE OSTI2022

Analyses of the C. Winter #10 Enhanced Open-hole Drill Stem Test of the Residual Oil Zone in the Cypress Sandstone

The objective of this report is to detail enhanced open-hole drill stem test (DST) of the Residual Oil Zone in the Cypress Sandstone. DST are 1) to confirm there is no mobile oil from the suspected residual oil zone (ROZ), 2) estimate vertical and horizontal permeability in the ROZ, and 3) test vertical communication between the Cypress main pay zone (MPZ) and the ROZ, across the upper calcite layer.

02 PETROLEUM↗

DOE OSTI2020

Corrosion Susceptibility of Cr–Mo Steels and Ferritic Stainless Steels in Biomass-Derived Pyrolysis Oil Constituents

In this work, to better understand and evaluate the corrosion performance of candidate structural steels and ferritic stainless steels for production, transport, and storage of biomass pyrolysis oils, corrosion studies were conducted in selected organic constituents of bio-oils, including catechol, formic acid, and their mixtures as well as lactobionic acid, using electrochemical impedance spectroscopy. R 2 , the resistance against corrosion reaction, was obtained by fitting measured impedance spectra into an equivalent circuit. The values of R 2 were then used to assess corrosion resistance of the steels in each organic constituent and mixture. Type 410 and 430 stainless steels were resistant to corrosion in all tested organic constituents, while 2.25Cr-1Mo steel was not. 9Cr-1Mo steel was corrosion resistant in catechol but not in the other mixtures that contained organic acids. On the basis of the results of this work, it is suggested that the corrosion resistance against organic acids is attributed to formation of a Cr-rich passive film that requires stainless steels with critical Cr levels in excess of approximately 11 wt %. In catechol-only solution, lower levels of Cr intermediate between that of 2.25Cr-1Mo steel and 9Cr-1Mo steel appeared sufficient.

36 MATERIALS SCIENCE↗

DOE OSTI2014

A Review and Perspective of Recent Bio-Oil Hydrotreating Research

The pathway for catalytic hydrodeoxygenation of biomass derived fast pyrolysis oil represents a compelling route for production of liquid transportation fuels. There has been continued progress and advancements in both the public and private research areas towards driving this technology to completion. Published research and patent literature have demonstrated that continued development of HDO as a part of a processes for production liquid transportation using biomass is being advanced for both fuel blend stocks and for refinery intermediates for co-processing. Much of the research has still focused on “quality” metrics around single or groups of unit operations generating partially treated bio-oil streams without assessing upstream and downstream implications. However, there is an encouraging amount of research that is now being targeted and assessed with attempts to understand the impact on the final fuel product, regardless of the route. Much of the most important research is moving towards continuous, industrially relevant processes where data can be generated to adequately inform process and economic modeling. As the technology for producing liquid transportation fuels from pyrolysis/HDO/coprocessing is driving towards commercialization, further research should be prioritized on the basis of impact to a techno-economic analyses.

bio-oil↗

DOE OSTI2016

Evaluation of biosurfactants grown in corn oil by Rhodococcus rhodochrous on removing of heavy metal ion from aqueous solution

The potential application of biosurfactants to remove heavy metal ion from aqueous solution by batch technique was examined. The glycolipids type biosurfactants were grown in a media containing of 20% v/v corn oil with 7 days of fermentation by Rhodococcus rhodochrous. The biosurfactants reduced the surface tension of water of about 51% from 62 mN/m to 30 mN/m. The biosurfactant increased the E24 of water-palm oil emulsion of about 55% from 43% to 97% and could maintain this E24 value of above 50% for up to 9 days. Heavy metal ion removal, in this case cadmium ion, by crude and patially purified biosurfactants has been investigated from aqueous solution at pH 6. Adsorption capacity of Cd(II) ion by crude biosurfactant with 5 and 10 minutes of contact times were 1.74 and 1.82 mg/g, respectively. Additionally, the adsorption capacity of Cd(II) ion by partially purified biosurfactant with 5 and 10 minutes of contact times were 0.79 and 1.34 mg/g, respectively. The results demonstrated that the adsorption capacity of Cd(II) ion by crude biosurfactant was higher than that of by partially purified biosurfactant. The results suggested that the biosurfactant could be used in the removal of heavy metal ions from aqueous solution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2019

High marker density GWAS provides novel insights into the genomic architecture of terpene oil yield in Eucalyptus

Terpenoid-based essential oils are economically important commodities, yet beyond their biosynthetic pathways, little is known about the genetic architecture of terpene oil yield from plants. Transport, storage, evaporative loss, transcriptional regulation and precursor competition may be important contributors to this complex trait. Here, we associate 2.39 million single nucleotide polymorphisms derived from shallow whole-genome sequencing of 468 Eucalyptus polybractea individuals with 12 traits related to the overall terpene yield, eight direct measures of terpene concentration and four biomass-related traits. Our results show that in addition to terpene biosynthesis, development of secretory cavities, where terpenes are both synthesized and stored, and transport of terpenes were important components of terpene yield. For sesquiterpene concentrations, the availability of precursors in the cytosol was important. Candidate terpene synthase genes for the production of 1,8-cineole and α-pinene, and β-pinene (which comprised > 80% of the total terpenes) were functionally characterized as a 1,8-cineole synthase and a β/α-pinene synthase. Our results provide novel insights into the genomic architecture of terpene yield and we provide candidate genes for breeding or engineering of crops for biofuels or the production of industrially valuable terpenes.

1,8‐cineole↗

DOE OSTI2022

Separating Oil-Water Mixtures Using Bump Arrays

Particle separation is an important process step across many fields. One technique being applied for separating solids such as blood components or sand particles from carrier fluids is the use of arrays of aligned posts called deterministic lateral arrays to bump particles to one side in the flow stream to enhance separation. This technique may be useful for separation of deformable particles. The ability to efficiently separate two-phase industrial (oil/water) mixtures is key for future use of valuable resources. Over 1 trillion gallons of petroleum production water could be reclaimed annually for reuse in the drought-ridden western US states. The ability to reclaim this petroleum production water may be critical for the Central High Plains (Colorado, Kansas, Oklahoma, Texas, and New Mexico). Trends in just the High Plains area already lost 20 to 25% of the irrigated farming area due to insufficient ground water storage to irrigate, and farmland losses are expected to grow to 40%. Proving this technology is key to reuse of petroleum production water for crop irrigation or to replace water from currently failing aquifers in rich agricultural lands of the Central High Plains. We conducted experiments applying mesofluidic separation for flowing two-phase (oil/water) mixtures. Experiments were conducted using oils of differing viscosities with water as the carrier fluid; separation was achieved over a range of oil-water concentrations. We describe the results of these experiments in this paper.

oil-water separation, micelle, droplet separation,↗

DOE OSTI2014

Draft Genome Sequence of Pseudoalteromonas sp. Strain ND6B, an Oil-Degrading Isolate from Eastern Mediterranean Sea Water Collected at a Depth of 1,210 Meters

We report the draft genome of Pseudoalteromonas sp. strain ND6B, which is able to grow with crude oil as a carbon source. Strain ND6B was isolated from eastern Mediterranean Sea deep water at a depth of 1,210 m. The genome of strain ND6B provides insight into the oil-degrading ability of the Pseudoalteromonas species.

02 PETROLEUM↗

DOE OSTI2016

Compositional simulation of hydrocarbon recovery from oil shale reservoirs with diverse initial saturations of fluid phases by various thermal processes

We have studied the hydrocarbon production from oil shale reservoirs filled with diverse initial saturations of fluid phases by implementing numerical simulations of various thermal in-situ upgrading processes. We use our in-house fully functional, fully implicit, and non-isothermal simulator, which describes the in-situ upgrading processes and hydrocarbon recovery by multiphase-multicomponent systems. We have conducted two sets of simulation cases—five-spot well pattern problems and Shell In-situ Conversion Process (ICP) problems. In the five-spot well pattern problems, we have analyzed the effects of initial fluid phase that fills the single-phase reservoir and thermal processes by four cases—electrical heating in the single-phase-aqueous reservoir, electrical heating in the single-phase-gaseous reservoir, hot water injection in the single-phase-aqueous reservoir, and hot CO 2 -injection in the single-phase-gaseous reservoir. In the ICP problems, we have analyzed the effects of initial saturations of fluid phases that fill two-phase-aqueous-and-gaseous reservoir by three cases—initial aqueous phase saturations of 0.16, 0.44, and 0.72. Through the simulation cases, system response and production behavior including temperature profile, kerogen fraction profile, evolution of effective porosity and absolute permeability, phase production, and product selectivity are analyzed. In the five-spot well pattern problems, it is found that the hot water injection in the aqueous phase reservoir shows the highest total hydrocarbon production, but also shows the highest water-oil-mass-ratio. Productions of phases and components show very different behavior in the cases of electrical heating in the aqueous phase reservoir and the gaseous phase reservoir. In the ICP problems, it is found that the speed of kerogen decomposition is almost identical in the cases, but the production behavior of phases and components is very different. It is found that more liquid organic phase has been produced in the case with the higher initial saturation of aqueous phase by the less production of gaseous phase.

04 OIL SHALES AND TAR SANDS↗