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At least 973 records · Page 54
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NASA NTRS1982

Chemistry and evolution of Titan's atmosphere

The chemistry and evolution of Titan's atmosphere are reviewed, in light of the scientific findings from the Voyager mission. It is argued that the present N2 atmosphere may be Titan's initial atmosphere, rather than one photochemically derived from an original NH3 atmosphere. The escape rate of hydrogen from Titan is controlled by photochemical production from hydrocarbons. CH4 is irreversibly converted to less hydrogen-rich hydrocarbons, which over geologic time accumulate on the surface to a layer thickness of about 0.5 km. Magnetospheric electrons interacting with Titan's exosphere may dissociate enough N2 into hot, escaping N atoms to remove about 0.2 of Titan's present atmosphere over geologic time. The energy dissipation of magnetospheric electrons exceeds solar EUV energy deposition in Titan's atmosphere by an order of magnitude, and is the principal driver of nitrogen photochemistry. The environmental conditions in Titan's upper atmosphere are favorable to building up complex molecules, particularly in the north polar cap region.

Strobel, D. F.↗
NASA NTRS1982

Observations and photochemistry of O/++/ in the daytime thermosphere

An analysis is conducted for the Atmosphere Explorer C observations of O(++) in the daytime thermosphere which supercedes that of Breig et al (1977) and restricts attention to five orbits of data from the high-grain mode of the magnetic ion-mass spectrometer. The present investigation adopts a model for O(++) ionospheric chemistry which has been revised in light of recent laboratory measurements of a fast loss rate for O(++) through reaction with N2. An improved procedure is also introduced which analyzes the basic ion currents recorded by the magnetic ion-mass spectrometer and has special application for the very low concentrations near and below 200 km. It is found that large scale features in the low altitude data are best represented with an additive term which is proportional to the N2 or O2 density, with the preferred interpretation as a contaminant signal induced by neutral particles impinging on instrument or spacecraft surfaces.

Breig, E. L.↗
NASA NTRS1983

The atmosphere of Titan - An analysis of the Voyager 1 radio occultation measurements

The equatorial atmosphere of Titan was probed by means of two coherently related radio signals transmitted from Voyager 1 at 13.0 and 3.6 cm wavelengths during the November 12, 1980 occultation of the spacecraft by the Saturn satellite. An analysis of the differential dispersive frequency measurements did not reveal any ionization layers in the upper atmosphere of Titan. The gas refractivity data, which extend from the surface to about 200 km altitude, were interpreted in two different ways. In the first, it is assumed that N2 makes up virtually all of the atmosphere, with small amounts of CH4 and other hydrocarbons present. In the second interpretation of the refractivity data, it is assumed that the 3.5 km altitude level corresponds to the bottom of a CH4 cloud layer and that N2 and CH4 were perfectly mixed below this level.

Lindal, G. F.↗
NASA NTRS1982

An integrated regenerative air revitalization system for spacecraft

Progress towards development of an air revitalization system (ARS) for spacecraft breathable atmosphere regeneration is assessed, and a preliminary design for a one-person ARS is described. The ARS is considered a necessary component of any permanently manned orbital station, and studies have demonstrated that penalties for expendable air supplies justify an ARS for missions longer than 40 days. CO2 must be removed and O2 returned along with N2, which can be extracted from hydrazine, with the H2 component returning to the operation of the CO2 reduction subsystem. An experimental ARS (ARX-1) features a cabin humidity control unit, a CO2 concentrator, an air-cooled CO2 reduction reactor, an oxygen generator (electrolysis), the hydrazine N2 generator, and a water handling unit. A 120-day test demonstrated one-button startup and 480 hr operation in a normal mode.

Noyes, G. P.↗
NASA NTRS1983

Day and night models of the Venus thermosphere

A model atmosphere of Venus for altitudes between 100 and 178 km is presented for the dayside and nightside. Densities of CO2, CO, O, N2, He, and O2 on the dayside, for 0800 and 1600 hours local time, are obtained by simultaneous solution of continuity equations. These equations couple ionospheric and neutral chemistry and the transport processes of molecular and eddy diffusion. Photodissociation and photoionization J coefficients are presented to facilitate the incorporation of chemistry into circulation models of the Venus atmosphere. Midnight densities of CO2 CO, O, N2, He, and N are derived from integration of the continuity equations, subject to specified fluxes. The nightside densities and fluxes are consistent with the observed airglow of NO and O2(1 Delta). The homopause of Venus is located near 133 km on both the dayside and nightside.

Massie, S. T.↗
NASA NTRS1983

Pulsed laser photolysis study of the reaction between O(3P) and HO2

It is pointed out that bimolecular reactions involving two free radicals are of great interest because both reactants have unpaired electrons and hence could interact at distances longer than those typical of radical-molecule encounters. A method based on laser photolysis is being developed to produce selectively free radicals in the homogeneous gas phase. This is to be done in such a way as to isolate the reaction of interest and subsequently follow the course of the reaction using spectroscopic techniques. The present investigation is concerned with a study in which the rate coefficient for the reaction of O(3P) with HO2, has been measured at N2 pressures ranging from 10 to 500 torr, taking into account the reaction O(3P)+HO2 yields OH-O2. In the described study, O(3P) and HO2 were produced by cophotolysis of O3 and H2O2 in N2 at 248.5 nm using a KrF excimer laser.

Ravishankara, A. R.↗
NASA NTRS1983

Coherent anti-Stokes Raman spectroscopic modeling for combustion diagnostics

The status of modelling the coherent anti-Stokes Raman spectroscopy (CARS) spectra of molecules important in combustion, such as N2, H2O, and CO2, is reviewed. It is shown that accurate modelling generally requires highly precise knowledge of line positions and reasonable estimates of Raman linewidths, and the sources of these data are discussed. CARS technique and theory is reviewed, and the status of modelling the phenomenon of collisional narrowing at pressures well above atmospheric for N2, H2O, and CO2 is described. It is shown that good agreement with experiment can be achieved using either the Gordon rotational diffusion model or phenomenological models for inelastic energy transfer rates.

Hall, R. J.↗
NASA NTRS1983

Rotational CARS application to simultaneous and multiple-point temperature and concentration determination in a turbulent flow

Coherent anti-Stokes Raman scattering (CARS) from the pure rotational Raman lines of N2 is employed to measure the instantaneous (approximately 10 ns) rotational temperature of N2 gas at room temperature and below with good spatial resolution (0.2 x 0.2 x 3.0 cu mm). A broad bandwidth dye laser is used to obtain the entire rotational spectrum from a single laser pulse; the CARS signal is then dispersed by a spectrograph and recorded on an optical multichannel analyzer. A best fit temperature is found in several seconds with the aid of a computer for each experimental spectrum by a least squares comparison with calculated spectra. The model used to calculate the theoretical spectra incorporates the temperature and pressure dependence of the pressure-broadened rotational Raman lines, includes the nonresonant background susceptibility, and assumes that the pump laser has a finite linewidth. Temperatures are fit to experimental spectra recorded over the temperature range of 135 to 296 K, and over the pressure range of .13 to 15.3 atm.

Snow, J. B.↗
NASA NTRS1983

Measurement of heat pump processes induced by laser radiation

A series of experiments was performed in which a suitably tuned CO2 laser, frequency doubled by a Tl3AsSe37 crystal, was brought into resonance with a P-line or two R-lines in the fundamental vibration spectrum of CO. Cooling or heating produced by absorption in CO was measured in a gas-thermometer arrangement. P-line cooling and R-line heating could be demonstrated, measured, and compared. The experiments were continued with CO mixed with N2 added in partial pressures from 9 to 200 Torr. It was found that an efficient collisional resonance energy transfer from CO to N2 existed which increased the cooling effects by one to two orders of magnitude over those in pure CO. Temperature reductions in the order of tens of degrees Kelvin were obtained by a single pulse in the core of the irradiated volume. These measurements followed predicted values rather closely, and it is expected that increase of pulse energies and durations will enhance the heat pump effects. The experiments confirm the feasibility of quasi-isentropic engines which convert laser power into work without the need for heat rejection. Of more immediate potential interest is the possibility of remotely powered heat pumps for cryogenic use, such applications are discussed to the extent possible at the present stage.

Garbuny, M.↗
NASA NTRS1984

Rotational cars application to simultaneous and multiple-point temperature and concentration determination in a turbulent flow

Coherent Anti-stokes Raman Scattering (CARS) from the pure rotational Raman lines of N2 is employed to measure the instantaneous rotational temperature of N2 gas at room temperature and below with good spatial resolution. A broad-bandwidth dye laser is used to obtain the entire rotational spectrum from a signal laser pulse; the CARS signal is then dispersed by a spectrograph and recorded on an optical multichannel analyzer. A best-fit temperature is found in several seconds with the aid of a computer for each experimental spectrum by a least squares comparison with calculated spectra. The model used to calculate the theoretical spectra incorporates the temperature and pressure dependence of the pressure-broadened rotational Raman lines, includes the nonresonant background susceptibility, and assumes that the pump laser has a finite linewidth. Temperatures are fit to experimental spectra recorded over the temperature range of 135 to 296K, and over the pressure range of 0.13 to 15.3 atm. In addition to the spatially resolved single point work, we have used multipoint CARS to obtain information from many spatially resolved volume elements along a cylindrical line (0.1 x 0.1 x 2.0 mm). We also obtained qualitative information on the instantaneous species concentration and temperature at 20 spatially resolved volume elements (0.1 x 0.1 x 0.1 mm) along a line.

Snow, J. B.↗
NASA NTRS1984

Cryogenic wind tunnel technology. A way to measurement at higher Reynolds numbers

The goals, design, problems, and value of cryogenic transonic wind tunnels being developed in Europe are discussed. The disadvantages inherent in low-Reynolds-number (Re) wind tunnel simulations of aircraft flight at high Re are reviewed, and the cryogenic tunnel is shown to be the most practical method to achieve high Re. The design proposed for the European Transonic Wind tunnel (ETW) is presented: parameters include cross section. DISPLAY 83A46484/2 = 4 sq m, operating pressure = 5 bar, temperature = 110-120 K, maximum Re = 40 x 10 to the 6th, liquid N2 consumption = 40,000 metric tons/year, and power = 39,5 MW. The smaller Cologne subsonic tunnel being adapted to cryogenic use for preliminary studies is described. Problems of configuration, materials, and liquid N2 evaporation and handling and the research underway to solve them are outlined. The benefits to be gained by the construction of these costly installations are seen more in applied aerodynamics than in basic research in fluid physics. The need for parallel development of both high Re tunnels and computers capable of performing high-Re numerical analysis is stressed.

Beck, J. W.↗
NASA NTRS1983

Thermal infrared lines of methane broadened by nitrogen at low temperatures

Measurements of spectral transmittance in the nu4-fundamental band of (C-12)H4 have been performed at low temperatures using a Fourier transform spectrometer with apodized spectral resolution of 0.06 per cm. With applications to lines formed in the atmospheres of Titan and earth in mind, N2 has been used as the broadening gas. Comparisons of observed and computed spectral transmittances on a line-by-line basis have yielded line strengths, N2-broadened half-widths and their variation with temperature. Best agreement between measured and computed spectra was obtained when the absolute intensity of the band was taken as 128 per (sq cm-atm) at 296 K. Line widths were found to vary as T to the n power with n = -1.0 for lines of the F-species and 0.63 for the A-species. The measured line widths are considerably larger than those used in the AFGL compilation.

Varanasi, P.↗
NASA NTRS1983

A laboratory study of the 8.65 micron fundamental of (C-12)H3D at temperatures relevant to Titan's atmosphere

Spectral transmittance measurements have been performed in the nu6-fundamental of (C-12)H3D at 153 K. Relevant to the studies of the emission spectra of Titan recorded by the IRIS instruments on board Voyagers 1 and 2, N2 has been used as the broadening gas. Excellent agreement between experimental and theoretical spectral transmittance has been the result of using N2-broadened line widths and their dependence upon temperature measured in the nu2-fundamental and S = 63.6 per(sq cm atm) for the absolute intensity of the nu6-fundamental.

Varanasi, P.↗
NASA NTRS1984

Constraints on bulk composition, seasonal variation, and global dynamics of Pluto's atmosphere

The potential seasonal variation of Pluto's atmosphere is investigated by considering the behavior of the candidate atmospheric constituents Ne, N2, CO, O2, and Ar when individually mixed with CH4. The effects of diurnal and latitudinal variation of insolation and eclipses on the atmosphere are also studied. Seasonal effects are shown to dominate. It is shown that the atmospheric bulk may not be a minimum near aphelion but rather at intermediate distances from the sun during summer/winter where inadequate ice deposits may allow the atmosphere to collapse by freezing out over winter latitudes. The likely global circulation regimes for each model atmosphere are investigated as a function of temperature, and it is concluded that if CH4, O2, or CO dominates the atmosphere, Pluto will exhibit cyclic variations between an axially symmetric circulation system at perihelion and a baroclinic wave regime at aphelion. If N2 dominates the wave regime should hold continuously.

Stern, S. A.↗
NASA NTRS1984

Ionospheric chemistry of NO(+)

An investigation is described of the behavior of NO(+) in the daytime F region, with basic ion concentration measurements from the Atmosphere Explorer C satellite. The data set was acquired along select orbits at low latitudes and exhibits substantial variations in the NO(+) concentration, both along and between nearby orbits. An excellent consistency is demonstrated between these observations and current chemical equilibrium theory, in contrast to differences that have been reported for the related N2(+) ion. Large variations in the concurrently observed electron temperature permit a relevant comparison between different laboratory determinations of the dissociative recombination rate coefficient. Contributions to the NO(+) production from several secondary sources are also evaluated. Results strengthen the basis for the current theoretical ionospheric chemistry of NO(+) and establish important constraints on resolution of the difficulties with N2(+).

Breig, E. L.↗
NASA NTRS1984

Laser measurements of the effects of vibrational energy on the reactions of CN

Pulsed laser photolysis of C2N2 at 193 nm has been used as a source of CN radicals in both the v-double-prime = 0 and v-double-prime = 1 levels. Individual rovibronic levels of these radicals were measured as a function of time with a tunable dye laser. From these measurements the rate constants for the reaction of each of these vibrational levels with H2, O2, CO, CO2, N2, HCN, C2N2, and CH4 have been determined. Some enhancement in the rate constant with vibrational energy which could not be ascribed to quenching was observed for O2, CH4, and H2. Only vibrational quenching was observed for HCN, N2, CO2, CO and C2N2. In the CO case the vibrational quenching rate appears to be significantly enhanced by complex formation during the quenching process.

Sayah, N.↗
NASA NTRS1984

Axisymmetric electromagnetic field influence on the characteristic velocity of an arc-jet

Tests for determining the influence of an axisymmetric EM field on the characteristic velocity of an arc jet are presented. The experimental set up is briefly described. Tests were performed with rotation induced by the centrifugal and magnetic fields in the same sense. The fuels used were HE and N2 and the results are discussed. It is found that by variation of the induction, current, and arc jet strength, the behavior is determined essentially by the shape of the cathodic and anodic blobs on the electrodes together with their movement under the combined effect of the aerodynamic and magnetic fields. In view of the different characteristics of He and N2 in respect to the dissociation heat and ionization, it is expected that the regime of the arc jet when used with H2 fuel will be similar to that with He.

Oggero, M.↗
NASA NTRS1985

Scaling blackbody laser to high powers

Lasers pumped by solar heated blackbody cavities have potential for multimegawatt power beaming in space. There are two basic types of blackbody lasers; cavity pumped and transfer system. The transfer system is judged to be more readily scalable to high power. In this system, either N2 or CO is heated by the blackbody cavity then transferred into the laser cavity where CO2 is injected. The N2-CO2 system was demonstrated, but probably has lower efficiency than the CO-CO system. The characteristics of potential transfer laser systems are outlined.

Deyoung, R. J.↗