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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

A combinatorial droplet microfluidic device integrated with mass spectrometry for enzyme screening

Mass spectrometry (MS) enables detection of different chemical species with a very high specificity; however, it can be limited by its throughput. Integrating MS with microfluidics has a tremendous potential to improve throughput and accelerate biochemical research. In this work, we introduce Drop-NIMS, a combination of a passive droplet loading microfluidic device and a matrix-free MS laser desorption ionization technique called nanostructure-initiator mass spectrometry (NIMS). This platform combines different droplets at random to generate a combinatorial library of enzymatic reactions that are deposited directly on the NIMS surface without requiring additional sample handling. The enzyme reaction products are then detected with MS. Drop-NIMS was used to rapidly screen enzymatic reactions containing low (on the order of nL) volumes of glycoside reactants and glycoside hydrolase enzymes per reaction. MS “barcodes” (small compounds with unique masses) were added to the droplets to identify different combinations of substrates and enzymes created by the device. We assigned xylanase activities to several putative glycoside hydrolases, making them relevant to food and biofuel industrial applications. Overall, Drop-NIMS is simple to fabricate, assemble, and operate and it has potential to be used with many other small molecule metabolites.

47 OTHER INSTRUMENTATION↗
NASA NTRS2006

Why Do T Tauri Disks Accrete?

Observations of T Tauri stars and young brown dwarfs suggest that the accretion rates of their disks scales roughly with the square of the central stellar mass. No dependence of accretion rate on stellar mass is predicted by the simplest version of the Gammie layered disk model, in which nonthermal ionization of upper disk layers allows accretion to occur via the magnetorotational instability. We show that a minor modification of Gaminie's model to include heating by irradiation from the central star yields a modest dependence of accretion on the mass of the central star. A purely viscous disk model could provide a strong dependence of accretion rate on stellar mass if the initial disk radius (before much viscous evolution has occurred) has a strong dependence on stellar mass. However, it is far from clear that at least the most massive pre-main-sequence disks can be totally magnetically activated by X-rays or cosmic rays. We suggest that a combination of effects are responsible for the observed dependence, with the lowest mass stars having the lowest mass disks, which can be thoroughly magnetically active, while the higher mass stars have higher mass disks that have layered accret,ion and relatively inactive or "dead" central zones at some radii. In such dead zones, we suggest that gravitational instabilities may play a role in allowing accretion to proceed. In this connection, we emphasize the uncertainty in disk masses derived from dust emission and argue that T Tauri disk masses have been systematically underestimated by conventional analyses. Furtlier study of accretion rates, especially in the lowest mass stars, would help to clarify the mechanisms of accretion in T Tauri stars.

Hartmann, Lee↗
NASA NTRS2016

The Effects of High Density on the X-ray Spectrum Reflected from Accretion Discs Around Black Holes

Current models of the spectrum of X-rays reflected from accretion discs around black holes and other compact objects are commonly calculated assuming that the density of the disc atmosphere is constant within several Thomson depths from the irradiated surface. An important simplifying assumption of these models is that the ionization structure of the gas is completely specified by a single, fixed value of the ionization parameter (xi), which is the ratio of the incident flux to the gas density. The density is typically fixed at n(sub e) = 10(exp 15) per cu cm. Motivated by observations, we consider higher densities in the calculation of the reflected spectrum. We show by computing model spectra for n(sub e) approximately greater than 10(exp 17) per cu cm that high-density effects significantly modify reflection spectra. The main effect is to boost the thermal continuum at energies 2 approximately less than keV. We discuss the implications of these results for interpreting observations of both active galactic nuclei and black hole binaries. We also discuss the limitations of our models imposed by the quality of the atomic data currently available.

accretion↗
NASA NTRS1995

Comparison of Yohkoh x-ray coronal events with Ulysses interplanetary events

The Yohkoh soft X-ray telescope (SXT) has observed several largescale eruptive events per year for the first three years of observations (Aug. 1991 - Nov. 1994) Such events are most prominent at high latitudes, but resemble long-duration flare events seen in active regions. Some of the high-latitude events have now been identified in the Ulysses/SWICS data base during the Ulysses south polar passage. There are puzzling examples of solar events with no interplanetary counterparts. A comparison of coronal and interplanetary events can lead to better models for mapping interplanetary disturbances back to their source location, especially by combining Yohkoh morphology with three-dimensional representations of the coronal magnetic field. In this paper we describe the parameters of the hot plasma seen by SXT. There is clear evidence for non radial motion in specific events. We present comparisons between the ionization temperature of the interplanetary plasma with that observed at the Sun in cases where this is possible.

Lemen, J. R.↗
NASA NTRS2012

Why Do Compact Active Galactic Nuclei at High Redshift Twinkle Less?

The fraction of compact active galactic.nuclei (AGNs) that exhibit interstellar scintillation (ISS) at radio wavelengths, as well as their scintillation amplitudes, have been found to decrease significantly for sources at redshifts z approx greater than 2. This can be attributed to an increase in the angular sizes of the mu-as-scale cores or a decrease in the flux densities of the compact mu-as cores relative to that of the mas-scale components with increasing redshift, possibly arising from (1) the space-time curvature of an expanding Universe, (2) AGN evolution, (3) source selection biases, (4) scatter broadening in the ionized intergalactic medium (IGM), or (5) gravitational lensing. We examine the frequency scaling of this redshift dependence of ISS to determine its origin, using data from a dual-frequency survey of ISS of 128 sources at 0 approx < z approx < 4. We present a novel method of analysis which accounts for selection effects in the source sample. We determine that the redshift dependence of ISS is partially linked to the steepening of source spectral indices (alpha (sup 8.4, sub 4.9)) with redshift, caused either by selection biases or AGN evolution, coupled with weaker ISS in the alpha (sup 8.4, sub 4.9) < -0.4 sources. Selecting only the -0.4 < alpha (sup 8.4, sub 4.9) < 0.4 sources, we find that the redshift dependence of ISS is still significant, but is not significantly steeper than the expected (1 + z)(exp 0.5) scaling of source angular sizes due to cosmological expansion for a brightness temperature and flux-limited sample of sources. We find no significant evidence for scatter broadening in the IGM, ruling it out as the main cause of the redshift dependence of ISS. We obtain an upper limit to IGM scatter broadening of approx. < 110 mu-as at 4.9 GHz with 99% confidence for all lines of sight, and as low as approx. < 8 mu-as for sight-lines to the most compact, approx 10 mu-as sources.

Koay, J. Y.↗
NASA NTRS1993

UV spectroscopy of low-redshift active galaxies

Ultraviolet spectra of bright Seyfert 1 galaxies will be obtained with the Hubble Space Telescope. Observations will be used to pursue the following goals: (1) Broad and narrow components of the strong emission lines will be deconvolved. (2) Broad-line profiles will be extracted for comparison with kinematic models; line ratios will be determined. (3) Many weak UV and emission lines from optical spectra will be compared for reddening along line of sight and chemical composition. (4) Absorption lines from Galactic halo, intergalactic medium and Seyfert galaxy will be used to establish physical conditions/chemical composition of the gas. (5) Strong emission Fe II in the UV will be used to determine FE II/L-alpha ratios for comparison with photoionization models. Other tasks relating to GTO 1170 program will be performed. It appears that NLR clouds in NGC 5548 experience much higher level of ionizing flux than those Seyfert 2 galaxies. Future observations will determine if this result extends to other Seyfert 1 galaxies.

Wu, C.-C.↗
NASA NTRS1995

The variability of the double-peaked Balmer lines in the active nucleus of NGC 1097

We present spectroscopic observations of the nucleus of the Seyfert/low-ionization nuclear emission-line region galaxy NGC 1097 spanning the period 1991-1994. The goal was to monitor anticipated variations of the broad, double-peaked Balmer lines which appeared abruptly in 1991. We find that the broad Balmer lines have varied significantly over the monitoring period, both in their integrated fluxes and in their profile shapes. The integrated H-alpha flux has decreased by a factor of 2, the (H-alpha)/(H-beta) ratio has increased, and the originally asymmetric H-alpha profile has become symmetric. The decline of the H-alpha flux and the change in the (H-alpha)/(H-beta) ratio can be interpreted as consequences of either increased obscuration along the line of sight, or a decline in the ionizing continuum, but neither of these scenarios can account for the change in profile shapes. A model attributing the line emission to a precessing elliptical ring around a 10(exp 6) solar mass nuclear black hole can reproduce the observed profile variations. In this scenario, the line-emitting ring is the result of the tidal disruption of a star by the black hole. Alternative scenarios associating the broad-line emission with a collimated bipolar outflow also remain viable, but binary black holes and inhomogeneous accretion disks are disfavored by the observed pattern of variability.

Storchi-Bergmann, Thaisa↗
NASA NTRS1992

Characterization of radiation-induced damage in high performance polymers by electron paramagnetic resonance imaging spectroscopy

The potential for long-term human activity beyond the Earth's protective magnetosphere is limited in part by the lack of detailed information on the effectiveness and performance of existing structural materials to shield the crew and spacecraft from highly penetrating space radiations. The two radiations of greatest concern are high energy protons emitted during solar flares and galactic cosmic rays which are energetic ions ranging from protons to highly oxidized iron. Although the interactions of such high-energy radiations with matter are not completely understood at this time, the effects of the incident radiation are clearly expected to include the formation of paramagnetic spin centers via ionization and bond-scission reactions in the molecular matrices of structural materials. Since this type of radiation damage is readily characterized by Electron Paramagnetic Resonance (EPR) spectroscopy, the NASA Langley Research Center EPR system was repaired and brought on-line during the 1991 ASEE term. A major goal of the 1992 ASEE term was to adapt the existing core of the LaRC EPR system to meet the requirements for EPR Imaging--a powerful new technique which provides detailed information on the internal structure of materials by mapping the spatial distribution of unpaired spin density in bulk media. Major impetus for this adaptation arises from the fact that information derived from EPRI complements other methods such as scanning electron microscopy which primarily characterize surface phenomena. The modification of the EPR system has been initiated by the construction of specially designed, counterwound Helmholtz coils which will be mounted on the main EPR electromagnet. The specifications of the coils have been set to achieve a static linear magnetic field gradient of 10 gauss/mm/amp along the principal (Z) axis of the Zeeman field. Construction is also in progress of a paramagnetic standard in which the spin distribution is known in all three dimensions. This sample will be used to assess the linearity of the magnetic field gradient and to ensure authentic image reconstruction. A second major task was to secure the computer capability to enable image reconstruction from projection data generated by the magnetic field gradients. To this end, commercially available and public domain software packages which perform inverse Fourier Transform and convoluted (filtered) back projection functions are being integrated into the existing EPR data processing system.

Suleman, Naushadalli K.↗
NASA NTRS2017

The Weak Fe Fluorescence Line and Long-Term X-Ray Evolution of the Compton-Thick Active Galactic Nucleus in NGC7674

We present NuSTAR X-ray observations of the active galactic nucleus (AGN) in NGC7674.The source shows a flat X-ray spectrum, suggesting that it is obscured by Compton-thick gas columns. Based upon long-term flux dimming, previous work suggested the alternate possibility that the source is a recently switched-off AGN with the observed X-rays being the lagged echo from the torus. Our high-quality data show the source to be reflection-dominated in hard X-rays, but with a relatively weak neutral Fe K(alpha) emission line (equivalent width [EW] of approximately 0.4 keV) and a strong Fe XXVI ionized line (EW approximately 0.2 keV).We construct an updated long-term X-ray light curve of NGC7674 and find that the observed 2-10 keV flux has remained constant for the past approximately 20 yr, following a high-flux state probed by Ginga. Light travel time arguments constrain the minimum radius of the reflector to be approximately 3.2 pc under the switched-off AGN scenario, approximately 30 times larger than the expected dust sublimation radius, rendering this possibility unlikely. A patchy Compton-thick AGN (CTAGN) solution is plausible, requiring a minimum line-of-sight column density (N(sub H)) of 3 x 10(exp 24) cm(exp -2) at present, and yields an intrinsic 2-10 keV luminosity of (3-5) x 10(exp 43) erg s(exp -1). Realistic uncertainties span the range of approximately (1-13) x 10(exp 43) erg s1. The source has one of the weakest fluorescence lines amongst bona fide CTAGN, and is potentially a local analogue of bolometrically luminous systems showing complex neutral and ionized Fe emission. It exemplifies the difficulty of identification and proper characterization of distant CTAGN based on the strength of the neutral Fe K line

galaxies: Seyfert –X-rays: individual (NGC 7674)↗
NASA NTRS1988

A magnetic loop model for structure and activity in the Galactic center

A simple model for the production and propagation of magnetized loops in the Galactic center is developed. It is found that a magnetized model can reproduce the filamentary, asymmetric structures on all scales from 100 pc to subparsec scales in the Galactic center. The radio and molecular gas morphology on all scales inside the Galactic center lobe may be explained in terms of the expansion of strongly magnetized loops and their interaction with the 2-5 pc torus and 30-50 pc portion of the center lobe. The magnetic loops have a toroidal field which explains the braided appearance of the radio continuum emission on the 2 pc scale. The barlike feature on the 2 pc radio continuum maps can be viewed as a piece of a magnetic loop with field strength about 0.01 G which is colliding and reconnecting with the ionized inner edge of the 2 pc molecular torus. The loop-torus interaction feeds energetic particles and shear Alfven waves into the torus, and deposits mass and energy.

Heyvaerts, Jean↗
NASA NTRS2003

The Nature of the UV/X-ray Absorber In PG 2302+029

We present Chandra X-ray observations of the radio-quiet QSO PG 2302+029. This quasar has a rare system of ultra-high velocity (-56,000 km s(exp -1) UV absorption lines that form in an outflow from the active nucleus. The Chandra data indicate that soft X-ray absorption is also present. We perform a joint UV and X-ray analysis, using photoionization calculations, to determine the nature of the absorbing gas. The UV and X-ray datasets were not obtained simultaneously. Nonetheless, our analysis suggests that the X-ray absorption occurs at high velocities in the same general region as the UV absorber. There are not enough constraints to rule out multi-zone models. In fact, the distinct broad and narrow UV line profiles clearly indicate that multiple zones are present. Our preferred estimates of the ionization and total column density in the X-ray absorber (logU = 1.6, N(sub eta) = 10(exp 22.4) cm (exp -2) over predict the O VI lambda lambda1032,1038 absorption unless the X-ray absorber is also outflowing at approximately 56,000 km s(exp-l), but they over predict the Ne VIII lambda lambda 770,780 absorption at all velocities. If we assume that the X-ray absorbing gas is outflowing at the same velocity of the UV-absorbing wind and that the wind is radiatively accelerated, then the outflow must be launched at a radius of less than or equal to 10(exp 15) cm from the central continuum source. The smallness of this radius casts doubts on the assumption of radiative acceleration.

Sabra, Bassem M.↗
NASA NTRS2016

Evidence for the Thermal Sunyaev Zeldovich Effect Associated with Quasar Feedback

Using a radio-quiet subsample of the Sloan Digital Sky Survey spectroscopic quasar catalogue, spanning redshifts 0.5-3.5, we derive the mean millimetre and far-infrared quasar spectral energy distributions (SEDs) via a stacking analysis of Atacama Cosmology Telescope and Herschel-Spectral and Photometric Imaging REceiver data. We constrain the form of the far-infrared emission and find 3 sigma-4 sigma evidence for the thermal Sunyaev-Zel'dovich (SZ) effect, characteristic of a hot ionized gas component with thermal energy (6.2 plus or minus 1.7) × 10 (exp 60) erg. This amount of thermal energy is greater than expected assuming only hot gas in virial equilibrium with the dark matter haloes of (1-5) × 10(exp 12) h(exp −1) solar mass that these systems are expected to occupy, though the highest quasar mass estimates found in the literature could explain a large fraction of this energy. Our measurements are consistent with quasars depositing up to (14.5 +/- 3.3)tau (sub 8)(exp -1) per cent of their radiative energy into their circumgalactic environment if their typical period of quasar activity is tau(sub 8) x 108 yr. For high quasar host masses, approximately 10(exp 13) h(exp −1) solar mass, this percentage will be reduced. Furthermore, the uncertainty on this percentage is only statistical and additional systematic uncertainties enter at the 40 per cent level. The SEDs are dust dominated in all bands and we consider various models for dust emission. While sufficiently complex dust models can obviate the SZ effect, the SZ interpretation remains favoured at the 3 sigma-4 sigma level for most models.

Sunyaev-Zeldovich (SZ)↗
DOE OSTI2022

Many-body effects for the Mg 2s XPS of MgO

The energy separation of the higher lying cation XPS binding energies, BEs, for MgO is examined. It is shown that the Hartree–Fock BEs overestimate the separation of the Mg BE(2s) and BE(2p), because an important many-body effect is neglected in the determination of the Hartree–Fock BEs. Once the many-body effect is taken into account, there is good agreement between theory and the XPS measurement. The character of this atomic many-body effect is established in terms of a nearly degenerate configuration that is needed to describe the wavefunction when an Mg 2s electron is ionized. Further, the results provide additional evidence of the ionic character of the MgO crystal. Given the atomic character of the many-body effect, it is likely to apply also to the BE separations of other closed shell oxides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1984

Hydrogen line ratios in Seyfert galaxies and low redshift quasars

New observations of the Lymal alpha radiation/hydrogen alpha radiation ratio in a set of X-ray selected active galactic nuclei and an archival study of International Ultraviolet Explorer (IUE) observations of Lymal alpha low redshift quasars and Seyfert galaxies have been used to form a large sample for studying the influence of soft X-rays on the enhancement of Balmer emission in the broad line region. In common models of broad line clouds, the Balmer lines are formed deep in the interior, largely by collisional excitation. Heating within the clouds is provided by soft X-ray radiation, while Lymal alpha is formed mainly by recombination after photoionization. The ratio Lymal alpha/Halpha is expected to depend weakly on the ratio of ionizing ultraviolet luminosity to X-ray luminosity (L sub UV/l sub x). If the Lymal alpha luminosity is used as a measure of L sub UV' a weak dependence of Lymal/H alpha on the X-ray luminosity is found similar to previous results.

Kriss, G. R.↗
NASA NTRS2003

Introduction to Radiation Issues for International Space Station Extravehicular Activities

The International Space Station (ISS) provides significant challenges for radiation protection of the crew due to a combination of circumstances including: the extended duration of missions for many crewmembers, the exceptionally dynamic nature of the radiation environment in ISS orbit, and the necessity for numerous planned extravehicular activities (EVA) for station construction and maintenance. Radiation protection requires accurate radiation dose measurements and precise risk modeling of the transmission of high fluxes of energetic electrons and protons through the relatively thin shielding provided by the space suits worn during EVA. Experiments and analyses have been performed due to the necessity to assure complete radiation safety for the EVA crew and thereby ensure mission success. The detailed characterization described of the material and topological properties of the ISS space suits can be used as a basis for design of space suits used in future exploration missions. In radiation protection practices, risk from exposure to ionizing radiation is determined analytically by the level of exposure, the detrimental quality of the radiation field, the inherent radiosensitivity of the tissues or organs irradiated, and the age and gender of the person at the time of exposure. During low Earth orbit (LEO) EVA, the relatively high fluxes of low-energy electrons and protons lead to large variations in exposure of the skin, lens of the eye, and tissues in other shallow anatomical locations. The technical papers in this publication describe a number of ground-based experiments that precisely measure the thickness of the NASA extravehicular mobility unit (EMU) and Russian Zvezda Orlan-M suits using medical computerized tomography (CT) X-ray analysis, and particle accelerator experiments that measure the minimum kinetic energy required by electrons and photons to penetrate major components of the suits. These studies provide information necessary for improving the understanding of the current ISS space suits and provide insights into improved approaches for the design of future suits. This chapter begins with a summary of the dynamic ionizing radiation environment in LEO space and introduces the concepts and quantities used to quantify exposure to space radiation in LEO. The space suits used for EVA and the experimental partial human phantom are described. Subsequent chapters report results from measured charged particle fields before and after incident protons and secondary particles are transported through the space suits and into organs and tissues.

Shavers, M. R.↗
NASA NTRS2022

Evidence for a Significant Kuiper Belt Dust Contribution to the Zodiacal Cloud

Interplanetary dust particles (IDPs) are important samples of dust-producing objects in the solar system including many primitive and organic-rich bodies that are not sampled by known meteorites. IDPs spiral in towards the Sun under the influence of Poynting-Robertson (P-R) drag forces and are exposed to solar energetic particles (SEPs) that leave tracks of ionization damage in anhydrous silicate grains. We determined the exposure ages of track-rich IDPs using a new calibration of the SEP track production rate and show that track-rich IDPs have long exposure ages (>1 My) that preclude an origin from main-belt asteroids (MBAs) and Jupiter-family comets (JFCs). We propose that track-rich IDPs represent samples of dust produced by collisions among Edgeworth-Kuiper Belt objects (EKBOs) and that appreciable amounts of EKBO dust are contributing to the Zodiacal cloud. Many track-rich IDPs also contain abundant secondary minerals that provide direct evidence for past aqueous activity on some EKBOs.

Lindsay P. Keller↗
DOE OSTI2025

Evaluation of Properties for Microsample Identification

A study was conducted to determine if individual particle characteristics could be used to identify particles of interest, sub-samples, from bulk post-detonation debris. Three archived post-detonation debris samples were used for this effort. Particles from these samples were identified as active (produced fission tracks), and inactive (did not produce fission tracks), as the first defining characteristic. Morphology was the secondary characteristic to select particles for further study, i.e. spherical/non-spherical. Once particles were identified and isolated, they were characterized by optical microscopy for size in µm, number of fission tracks, morphology, transmitted light color, and reflected light color. Particles were then analyzed by scanning electron microscopy for morphology, elemental content, and compound identification. Raman spectroscopy was attempted on five particles with indeterminate results due to environmental mixing (heterogeneity) during the events of particle formation. Once all non-destructive analyses were completed all particles were analyzed by thermal ionization mass spectrometry to determine isotopic atom percents of plutonium and uranium, and an estimate of atoms of plutonium and uranium in each particle. An estimate of the ratio of uranium to plutonium was also obtained (U/Pu). Data analytics of the data from the particles showed that combining characteristics of the particles have a high probability of identifying particles of interest from bulk post-detonation debris samples. Please note that this version of the report is an abridged version of the full report (Wagnon et al. 2025) that has been edited to be appropriate for public release.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
NASA NTRS2001

Far Ultraviolet Spectroscopic Explorer Observations of the Seyfert 1.5 Galaxy NGC 5548 in a Low State

We present far-ultraviolet spectra of the Seyfert 1.5 galaxy NGC 5548 obtained in 2000 June with the Far Ultraviolet Spectroscopic Explorer (FUSE). Our data span the observed wavelength range 915-1185 A at a resolution of approximately 20 km s(exp -1). The spectrum shows a weak continuum and emission from O VI (lambda)(lambda)1032, 1038, C III (lambda)977, and He II (lambda)1085. The FUSE data were obtained when the AGN (Active Galactic Nuclei) was in a low state, which has revealed strong, narrow O VI emission lines. We also resolve intrinsic, associated absorption lines of O VI and the Lyman series. Several distinct kinematic components are present, spanning a velocity range of approximately 0 to -1300 km s(exp -1) relative to systemic, with kinematic structure similar to that seen in previous observations of longer wavelength ultraviolet (UV) lines. We explore the relationships between the far-UV (ultraviolet) absorbers and those seen previously in the UV and X-rays. We find that the high-velocity UV absorption component is consistent with being low-ionization, contrary to some previous claims, and is consistent with its non-detection in high-resolution X-ray spectra. The intermediate velocity absorbers, at -300 to -400 km s(exp -1), show H I and O VI column densities consistent with having contributions from both a high-ionization X-ray absorber and a low-ionization UV absorber. No single far-UV absorbing component can be solely identified with the X-ray absorber.

Brotherton, M. S.↗