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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

27 Al Pulsed Field Gradient, Diffusion–NMR Spectroscopy of Solvation Dynamics and Ion Pairing in Alkaline Aluminate Solutions

Here, pulsed field gradient nuclear magnetic resonance (PFG-NMR) measurements were successfully applied to the 27 Al (I = 5/2) nucleus in concentrated electrolytes to investigate the diffusion of aluminate ions [Al(OH) 4 – ] in simulant high-level nuclear waste (3 M NaOH) between 25 and 85 °C. The temperature-dependent diffusion coefficients obtained from 1 H, 23 Na, and 27 Al PFG-NMR were well fit by a Vogel–Fulcher–Tammann model and a power law equation. Comparison of 27 Al diffusion coefficients of 0.1 M Al(OH) 4 – in ~3 M MOH (where M = Na + , K + , (CH 3 ) 4 N + ) at room temperature varied in agreement with the expected changes in solution viscosity via Stokes–Einstein relationship, confirming that the dominant Al species at these conditions are Al(OH) 4 – monomers. This 27 Al PFG-NMR study extends an established methodology to a previously unexplored nucleus enabling this experimental technique to be leverage for exploring ion transport, speciation, and solution structure in concentrated electrolytes.

Diffusion↗
DOE OSTI2016

Highly Reversible Zinc-ion Intercalation with Chevrel Phase Mo6S8 Nanocubes and Applications for Advanced Zinc-ion Batteries

We demonstrate the application of the Chevrel phase Mo6S8 nanocubes as the anode material for rechargeable Zn-ion batteries. Mo6S8 can host Zn2+ ions reversibility both in aqueous and nonaqueous electrolytes with specific capacities around 90 mAh/g and exhibited remarkable intercalation kinetics as well as stability. Furthermore, we assembled full cells by integrating Mo6S8 anode with zinc-polyiodide (I-/I3-) based catholytes, and demonstrated that such fuel cells was also able to deliver outstanding rate performance and cyclic stability. This first demonstration of zinc intercalating anode could inspire the design of advanced Zn ion batteries.

Multivalent↗
DOE OSTI2020

Evaluation of Waveform Profiles for Traveling Wave Ion Mobility Separations in Structures for Lossless Ion Manipulations

Structures for lossless ion manipulations (SLIM) have recently enabled a powerful implementation of traveling wave ion mobility spectrometry (TWIMS) for ultra-high resolution separations. However, optimization of experimental parameters remains challenging. Most TWIMS separations have utilized square-shaped waveforms applied by time-dependent voltage stepping across a repeating sets of electrodes; however, alternative waveforms may provide further improvements to resolution. In this work, we characterize five waveforms (including square and sine) in terms of their transmission efficiency, IMS resolution, and resolving power, and explore the effects of TW amplitude and speed on the performance of each. We found, consistent with previous work, separations were generally improved with higher TW amplitudes, moderately improved by lower speeds (limited by ion ‘surfing’ with the waves), and found decreases in signal intensity at the extremes of operating conditions. The triangle and asymmetric ‘ramp forward’ shaped profiles were found to provide modestly greater resolution and resolving power, an observation we tentatively attribute to their relatively uniform fields and minimal low-field regions.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2013

Parametric coupling of lower hybrid wave with gyrating ion beam driven ion cyclotron instability in a plasma

A lower hybrid wave, launched into a tokamak for supplementary heating in the presence of neutral beam turned gyrating ion beam, is seen to excite some prominent channels of parametric decay. The beam driven deuterium cyclotron mode is further destabilized by the lower hybrid pump through the nonlinear 4-wave coupling, involving higher and lower frequency lower hybrid sidebands, when ω{sub 0}/k{sub 0z}v{sub 0z}=(1−ω{sub LH}{sup 2}/ω{sub 0}{sup 2}) , where ω{sub LH} is the lower hybrid frequency, ω{sub 0} and k{sub 0z} are the frequency and parallel wave number of the pump wave, and v{sub 0z} is the velocity of ion beam parallel to the magnetic field. The growth rate increases with parallel wave number of the ion-cyclotron mode. The pump is also susceptible to parametric upconversion into an upper sideband shifted by the frequency of the negative energy deuterium cyclotron mode. For typical parameters, the growth rate of this channel is around one fiftieth of deuterium cyclotron frequency and falls off with the transverse wave number of the mode.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2013

Cylindrically confined pair-ion-electron and pair-ion plasmas having axial sheared flow and radial gradients

The linear and nonlinear dynamics of pair-ion (PI) and pair-ion-electron plasmas (PIE) have been investigated in a cylindrical geometry with a sheared plasma flow along the axial direction having radial dependence. The coupled linear dispersion relation of low frequency electrostatic waves has been presented taking into account the Guassian profile of density and linear gradient of sheared flow. It is pointed out that the quasi-neutral cold inhomogeneous pure pair ion plasma supports only the obliquely propagating convective cell mode. The linear dispersion relation of this mode has been solved using boundary conditions. The nonlinear structures in the form of vortices formed by different waves have been discussed in PI and PIE plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Amplitude modulation of quantum-ion-acoustic wavepackets in electron-positron-ion plasmas: Modulational instability, envelope modes, extreme waves

A semirelativistic fluid model is employed to describe the nonlinear amplitude modulation of low-frequency (ionic scale) electrostatic waves in an unmagnetized electron-positron-ion plasma. Electrons and positrons are assumed to be degenerated and inertialess, whereas ions are warm and classical. A multiscale perturbation method is used to derive a nonlinear Schrödinger equation for the envelope amplitude, based on which the occurrence of modulational instability is investigated in detail. Various types of localized ion acoustic excitations are shown to exist, in the form of either bright type envelope solitons (envelope pulses) or dark-type envelope solitons (voids, holes). The plasma configurational parameters (namely, the relativistic degeneracy parameter, the positron concentration, and the ionic temperature) are shown to affect the conditions for modulational instability significantly, in fact modifying the associated threshold as well as the instability growth rate. In particular, the relativistic degeneracy parameter leads to an enhancement of the modulational instability mechanism. Furthermore, the effect of different relevant plasma parameters on the characteristics (amplitude, width) of these envelope solitary structures is also presented in detail. Finally, the occurrence of extreme amplitude excitation (rogue waves) is also discussed briefly. Our results aim at elucidating the formation and dynamics of nonlinear electrostatic excitations in superdense astrophysical regimes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Nonlinear hybrid simulation of internal kink with beam ion effects in DIII-D

In DIII-D sawteething plasmas, long-lived (1,1) kink modes are often observed between sawtooth crashes. The saturated kink modes have two distinct frequencies. The mode with higher frequency transits to a fishbone-like mode with sufficient on-axis neutral beam power. In this work, hybrid simulations with the global kinetic-magnetohydrodynamic (MHD) hybrid code M3D-K have been carried out to investigate the linear stability and nonlinear dynamics of the n = 1 mode with effects of energetic beam ions for a typical DIII-D discharge where both saturated kink mode and fishbone were observed. Linear simulation results show that the n = 1 internal kink mode is unstable in MHD limit. However, with kinetic effects of beam ions, a fishbone-like mode is excited with mode frequency about a few kHz depending on beam pressure profile. The mode frequency is higher at higher beam power and/or narrower radial profile consistent with the experimental observation. Nonlinear simulations have been performed to investigate mode saturation as well as energetic particle transport. The nonlinear MHD simulations show that the unstable kink mode becomes a saturated kink mode after a sawtooth crash. With beam ion effects, the fishbone-like mode can also transit to a saturated kink mode with a small but finite mode frequency. These results are consistent with the experimental observation of saturated kink mode between sawtooth crashes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Behavior of moving plasma in solenoidal magnetic field in a laser ion source

In a laser ion source, a solenoidal magnetic field is useful to guide the plasma and to control the extracted beam current. However, the behavior of the plasma drifting in the magnetic field has not been well understood. Therefore, to investigate the behavior, we measured the plasma ion current and the total charge within a single pulse in the solenoid by changing the distance from the entrance of the solenoid to a detector. We observed that the decrease of the total charge along the distance became smaller as the magnetic field became larger and then the charge became almost constant with a certain magnetic flux density. The results indicate that the transverse spreading speed of the plasma decreased with increasing the field and the plasma was confined transversely with the magnetic flux density. We found that the reason of the confinement was not magnetization of ions but an influence induced by electrons.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Uncovering the binding nature of thiocyanate in contact ion pairs with lithium ions

Ion pair formation is a fundamental molecular process that occurs in a wide variety of systems, including electrolytes, biological systems, and materials. In solution, the thiocyanate (SCN–) anion interacts with cations to form contact ion pairs (CIPs). Due to its ambidentate nature, thiocyanate can bind through either its sulfur or nitrogen atoms, depending on the solvent. This study focuses on the binding nature of thiocyanate with lithium ions as a function of the solvents using FTIR, 2D infrared spectroscopy (2DIR) spectroscopies, and theoretical calculations. The study reveals that the SCN– binding mode (S or N end) in CIPs can be identified through 2DIR spectroscopy but not by linear IR spectroscopy. Linear IR spectroscopy shows that the CN stretch frequencies are too close to one another to separate N- and S-bound CIPs. Moreover, the IR spectrum shows that the S–C stretch presents different frequencies for the salt in different solvents, but it is related to the anion speciation rather than to its binding mode. A similar trend is observed for the anion bend. 2DIR spectra show different dynamics for N-bound and S-bound thiocyanate. In particular, the frequency–frequency correlation function (FFCF) dynamics extracted from the 2DIR spectra have a single picosecond exponential decay for N-bound thiocyanate and a biexponential decay for S-bound thiocyanate, consistent with the binding mode of the anion. Lastly, it is also observed that the binding mode also affects the line shape parameters, probably due to the different molecular mechanisms of the FFCF for N- and S-bound CIPs.

25 ENERGY STORAGE↗
DOE OSTI2026

Observation of Charmonium Sequential Suppression in Heavy-Ion Collisions at the Relativistic Heavy Ion Collider

We report measurements of charmonium sequential suppression in Ru+Ru and Zr+Zr collisions at $\sqrt{s_{NN}}$ =200 GeV with the STAR experiment at the Relativistic Heavy Ion Collider (RHIC). The inclusive yield ratio of 𝜓⁡(2⁢S) to J/𝜓 as a function of transverse momentum is reported, along with the centrality dependence of the double ratio, defined as the 𝜓⁡(2⁢S) to J/𝜓 ratio in heavy-ion collisions relative to that in 𝑝 +𝑝 collisions. In the 0–80% centrality class, the double ratio is found to be 0.41±0.10 (stat)±0.03 (syst)±0.02 (ref), lower than unity with a significance of 5.6 standard deviations. This provides experimental evidence that 𝜓⁡(2⁢S) is significantly more suppressed than J/𝜓 in heavy-ion collisions at RHIC. This sequential suppression pattern seems to increase from peripheral to central collisions, but with no significant dependence on the transverse momentum.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2018

Effect of the QCD equation of state and strange hadronic resonances on multiparticle correlations in heavy ion collisions

The QCD equation of state at zero baryon chemical potential is the only element of the standard dynamical framework to describe heavy ion collisions that can be directly determined from first principles. Continuum extrapolated lattice QCD equations of state have been computed using 2+1 quark flavors (up/down and strange) as well as 2+1+1 flavors to investigate the effect of thermalized charm quarks on QCD thermodynamics. Lattice results have also indicated the presence of new strange resonances that not only contribute to the equation of state of QCD matter but also affect hadronic afterburners used to model the later stages of heavy ion collisions. We investigate how these new developments obtained from first principles calculations affect multiparticle correlations in heavy ion collisions. We compare the commonly used equation of state S95n-v1, which was constructed using what are now considered outdated lattice results and hadron states, to the current state-of-the-art lattice QCD equations of state with 2+1 and 2+1+1 flavors coupled to the most upto-date hadronic resonances and their decays. New hadronic resonances lead to an enhancement in the hadronic spectra at intermediate p T . Using an outdated equation of state can directly affect the extraction of the shear viscosity to entropy density ratio, η/s , of the quark-gluon plasma and results for different flow observables. The effects of the QCD equation of state on multiparticle correlations of identified particles are determined for both AuAu √ sNN = 200 GeV and PbPb √ sNN = 5.02 TeV collisions. New insights into the v 2 {2} to v 3 {2} puzzle in ultracentral collisions are found. Flow observables of heavier particles exhibit more non-linear behavior regardless of the assumptions about the equation of state, which may provide a new way to constrain the temperature dependence of η/s .

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Influence of ion-to-atom ratio on the microstructure of evaporated molybdenum thin films grown using low energy argon ions

The authors report the effect of argon ion to molybdenum atom ratio (r) on the microstructure of low energy (70 eV) argon ion assisted electron beam evaporated Mo thin films. Surface roughness, morphology, and crystallinity of Mo films are found to strongly depend on “r.” Increase of “r” from 0 to 100 induces gradual loss in crystallinity, reduction in surface roughness and systematic increase in density of the film. For “r” ∼ 100, average atomic density of the film approaches the bulk value (97%) with lowest surface roughness. Further, increasing “r” up to 170 reduces the atomic density, increases roughness, and increase in crystallinity induced by low energy Ar ion beam. The observed surface roughness and grain size determined by x-ray reflectivity and glancing incidence x-ray diffraction correlate well with atomic force microscopy measurements. This study demonstrates that for r = 100 one gets lowest roughness Mo film with highest density and nearly amorphous microstructure. The growth model is discussed by structural zone model.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Dust-ion-acoustic double layers in multi-ion dusty plasma

A theoretical investigation has been made on nonplanar (cylindrical and spherical) dust-ionacoustic (DIA) double layers (DLs) in a multi-ion dusty plasma system containing inertial positive and negative ions and arbitrarily charged stationary dust. The dust particles have been considered as arbitrarily (either positively or negatively) charged in order to observe the effects of the dust polarity on the DIA DLs. The ion species were considered to be at different temperatures to observe the effects of the temperatures on that waves. The modified Gardner equation, which has been derived by employing the reductive perturbation method, has been used to analyze time-dependent nonplanar and planar DIA DLs. It has been found that the time evolution of DIA DLs is significantly modified not only by the nonplanar geometry, but also by the polarity, temperature, and mass ratio of the constituent particles. It has been also found that the amplitude of cylindrical DIA DL structures is larger than that of 1D planar ones, but smaller than that of the spherical ones.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗