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At least 973 records · Page 54

A Warm Garage for a Lunar Rover

Approach: One approach to heating a rover during the lunar night is the so-called thermal wadis concept [1]. This involves heating the regolith with solar concentrators and placing the rover on the heated surface for the night. Since the regolith is heated by a relatively weak heat flux, a high thermal conductivity is required for heating a sufficiently large mass of regolith. However, lunar regolith has a low thermal conductivity. Therefore, the concept involves increasing the conductivity by sintering the regolith, which requires a significant energy input and complex procedures. Here we propose an alternative approach where the low thermal conductivity of regolith is an advantage. Specifically, we propose to use a highly exothermic combustible mixture for heat generation. The mixture pellets are placed in the surface layer of regolith and ignited. The combustion forms condensed products and releases heat, which then slowly spreads to the surrounding regolith. Heat can also be transferred, for example, by heat pipes, into radiant heating surfaces installed on the ground. A greenhouse that transmits sunlight during the day and decreases the radiative heat losses during the night can also be installed. Selection of the Heat-generating Mixture: The reactive mixture should have a high specific energy and generate only condensed products since gases could disturb the regolith layer, carry enthalpy out of the system, and lead to an explosion. There are mixtures, (sometimes called pyrolants) that possess very high specific energies. One example is magnesium-Teflon-Viton mixtures used in flares. However, they produce gases and may cause explosions. Other mixtures that include magnesium cannot be used either because of the high vapor pressure of Mg at temperatures well below the combustion temperature. Recently, mixtures that involve lithium peroxide (Li2O2) have been proposedfor using in space power systems [2]. However, they produce lithium oxide (Li2O), which boils at 2800 K at 1 atm and hence at a lower temperature in vacuum. Fortunately, there exist many mixtures that release a lot of heat and form only condensed products during the combustion. Many such mixtures have been used for self-propagating high-temperature synthesis (SHS) of various materials [3, 4]. For the application discussed here, t itanium/boron (1:2 mole ratio) mixture appears to be particularly promising. The specific energy is 4.0 MJ/kg (1.1 kWh/kg), the adiabatic flame temperature is about 3200 K, and the reaction forms solid titanium diboride (TiB2, melting point: 3500 K). The mixture can be ignited easily with a heated tungsten wire, and it has been used widely as a booster to ignite the main mixture in the SHS process.Estimates: Assuming that specific heat of regolith is 500 J/(kg∙K) [5] and all generated heat is transferred to regolith, 12.5 kg of the Ti/B mixture would increase the temperature of 1000 kg of regolith by 100 K. To evaluate the rate of heat transfer in the regolith, a spherical model was analyzed where the heat released by a 12.5 kg Ti/B core propagates by thermal conduction through a 1000 kg regolith shell with no heat loss from its outer surface. At a bulk density of 1500 kg/m3 [5], the radius of the shell was 54 cm, while the radius of the core was about 11 cm. The calculations were conducted using Thermal Desktop SINDA/FLUINT (Cullimore and Ring Technologies) software at two constant values of bulk thermal conductivityk of the regolith: 0.001 and 0.01 W/(m∙K). The results show that after 14.5 days the core lost 31% of the released heat at the lower k and 77% at the higher k. At a distance of 20 cm from the core surface, the temperature of the regolith increased by only 1 K at the lower k and by 132 K at the higher k. In reality, the regolith near the heat source will be melted, so its thermal conductivity will increase significantly. Nevertheless, the conducted estimates indicate that combustion-based heat generators, placed directly in the regolith, could provide heat during a rather long period such as the lunar night.Conclusion: Heat generators based on gasless combustion of highly energetic reactive mixtures could be installed directly in the surface layer of lunar regolith. Because of the low thermal conductivity of the regolith, such generators would keep thermal energy for days and gradually supply heat to a rover/lander.Acknowledgment: The material presented in this work is based upon the work supported by National Aeronautics and Space Administration (NASA) under Grant #80NSSC20K0293.References: [1] Balasubramaniam R. et al. (2011) J. Thermophys. Heat Trans., 25,130−139. [2] Blair R.G. and Vasu S.S. (2022) Conf. Advanced Power Systems for Deep Space Exploration. [3] Varma A. et al. (1998) Adv. Chem. Eng., 24,79−226. [4] Levashov E.A. et al. (2017) Int. Mater. Rev., 62,203−239. [5] Wood-Robinson R. et al. (2019) J. Geophys. Res. Planets, 124, 1989−2011.

lunar↗

Detecting Surface Changes from an Underground Explosion in Granite Using Unmanned Aerial System Photogrammetry

Efficient detection and high-fidelity quantification of surface changes resulting from underground activities are important national and global security efforts. In this investigation, a team performed field-based topographic characterization by gathering high-quality photographs at very low altitudes from an unmanned aerial system (UAS)-borne camera platform. The data collection occurred shortly before and after a controlled underground chemical explosion as part of the United States Department of Energy’s Source Physics Experiments (SPE-5) series. The high-resolution overlapping photographs were used to create 3D photogrammetric models of the site, which then served to map changes in the landscape down to 1-cm-scale. Separate models were created for two areas, herein referred to as the test table grid region and the nearfield grid region. The test table grid includes the region within ~40 m from surface ground zero, with photographs collected at a flight altitude of 8.5 m above ground level (AGL). The near-field grid area covered a broader area, 90–130 m from surface ground zero, and collected at a flight altitude of 22 m AGL. The photographs, processed using Agisoft Photoscan® in conjunction with 125 surveyed ground control point targets, yielded a 6-mm pixel-size digital elevation model (DEM) for the test table grid region. This provided the ≤3 cm resolution in the topographic data to map in fine detail a suite of features related to the underground explosion: uplift, subsidence, surface fractures, and morphological change detection. The near-field grid region data collection resulted in a 2-cm pixel-size DEM, enabling mapping of a broader range of features related to the explosion, including: uplift and subsidence, rock fall, and slope sloughing. This study represents one of the first works to constrain, both temporally and spatially, explosion-related surface damage using a UAS photogrammetric platform; these data will help to advance the science of underground explosion detection.

54 ENVIRONMENTAL SCIENCES↗

Elasticity of crystalline molecular explosives

Crystalline molecular explosives are key components of engineered explosive formulations. In precision applications a high degree of consistency and predictability is desired under a range of conditions to a variety of stimuli. Prediction of behaviors from mechanical response and failure to detonation initiation and detonation performance of the material is linked to accurate knowledge of the material structure and first stage of deformation: elasticity. The elastic response of pentaerythritol tetranitrate (PETN), cyclotrimethylene trinitramine (RDX), and cyclotetramethylene tetranitramine (HMX), including aspects of material and measurement variability, and computational methods are described in detail. Experimental determinations of elastic tensors are compared, and an evaluation of sources of error is presented. Furthermore, computed elastic constants are also compared for these materials and for triaminotrinitrobenzene (TATB), for which there are no measurements.

36 MATERIALS SCIENCE↗

Explosion Source Models

Explosive detonations produce shocked transients with highly nonlinear pressure signatures in the near field. Here, this chapter presents the properties and defining characteristics of a suite of theoretical source pressure functions representative of detonations and deflagrations, and constructs criteria for defining reference blast pulses. Both the primary positive overpressure and the negative underpressure phases contribute to the temporal and spectral features of a blast pulse.

Blast Pulse↗

Particle Acceleration by Magnetic Reconnection in Geospace

Particles are accelerated to very high, non-thermal energies during explosive energy-release phenomena in space, solar, and astrophysical plasma environments. While it has been established that magnetic reconnection plays an important role in the dynamics of Earth’s magnetosphere, it remains unclear how magnetic reconnection can further explain particle acceleration to non-thermal energies. Here we review recent progress in our understanding of particle acceleration by magnetic reconnection in Earth’s magnetosphere. With improved resolutions, recent spacecraft missions have enabled detailed studies of particle acceleration at various structures such as the diffusion region, separatrix, jets, magnetic islands (flux ropes), and dipolarization front. With the guiding-center approximation of particle motion, many studies have discussed the relative importance of the parallel electric field as well as the Fermi and betatron effects. However, in order to fully understand the particle acceleration mechanism and further compare with particle acceleration in solar and astrophysical plasma environments, there is a need for further investigation of, for example, energy partition and the precise role of turbulence.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Can a Photosensitive Oxide Catalyze Decomposition of Energetic Materials?

Organic–inorganic interfaces provide both intrigues and opportunities for designing systems that possess properties and functionalities inaccessible by each individual component. In particular, the electronic, catalytic, and defect properties of inorganic surfaces can significantly affect the adsorption, decomposition, and photoresponse of organic molecules. Here, we choose the formulation of TiO 2 and trinitrotoluene (TNT), a highly catalytic oxide and a prominent explosive, as a prototypical example to explore the effect of a catalytic oxide additive on the photosensitivity of energetic materials. We show that whether or not a catalytic oxide additive can help molecular decompositions under light illumination depends largely on the band alignment between the oxide surface and the energetic molecule. For the composite of TiO 2 and TNT, the lowest unoccupied molecular orbitals (LUMOs) of TNT merge within the conduction band (CB) of TiO 2 . As such, no optical transition corresponding to available laser energies is observed. However, oxygen vacancy can lead to electron density transfer from the surface to the energetic molecules, causing an enhancement of the bonding between molecules and surface and a reduction of the molecular decomposition activation barriers. Therefore, when other (than optical) forms of energy (shock, heat, etc.) flow into molecules, molecular decompositions may be triggered more easily.

36 MATERIALS SCIENCE↗

Large sensitivity enhancement in semiconducting organic field effect transistor sensors through incorporation of ultra-fine platinum nanoparticles

We report remarkable improvement in sensitivity of pentacene-based field effect transistor devices towards trace nitro-aromatic explosive vapors through the incorporation of high density, sub-2 nm platinum nanoparticles (NPs) within these structures. Exploiting the unique electronic properties of these NPs, we have demonstrated a detection limit of 56.6 parts per billion of 2,4-dinitrotoluene (DNT) vapor while control samples without any embedded NPs showed no observable sensitivity to DNT vapor. We attribute this remarkable enhancement in sensitivity to the ability of these NPs to function as discrete nodes, participating in the charge transfer with adsorbed nitro-aromatic molecules.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A new principle for low-cost hydrogen sensors for fuel cell technology safety

Hydrogen sensors are of paramount importance for the safety of hydrogen fuel cell technology as result of the high pressure necessary in fuel tanks and its low explosion limit. I present a novel sensor principle based on thermal conduction that is very sensitive to hydrogen, highly specific and can operate on low temperatures. As opposed to other thermal sensors it can be operated with low cost and low power driving electronics. On top of this, as sensor element a modified standard of-the shelf MEMS thermopile IR-sensor can be used. The sensor principle presented is thus suited for the future mass markets of hydrogen fuel cell technology.S.

42 ENGINEERING↗

Suppression of shunting current in a magnetically insulated coaxial vacuum diode

Real-time investigations of the dynamics of explosive electron emission from a high-voltage cathode holder made of nonmagnetic stainless steel in a magnetically insulated coaxial vacuum diode have been performed. It has been shown that aging the cathode with several tens of voltage pulses at a field of 1–2 MV/cm provides a stray emission delay ranging from hundreds of picoseconds to a nanosecond or more. In addition, the magnetic field must be configured so that the magnetic lines would not cross the vacuum gap between the diode case and the cathode holder in the region behind the emitting edge of the cathode. These efforts provide conditions for stable emission of the working beam from a graphite cathode with a sharp emitting edge.

36 MATERIALS SCIENCE↗

Influence of emission threshold of explosive emission cathodes on current waveform in foilless diodes

The emission threshold of explosive emission cathodes (EECs) is an important factor for beam quality. It can affect the explosive emission delay time, the plasma expansion process on the cathode surface, and even the current amplitude when the current is not fully space-charge-limited. This paper researches the influence of the emission threshold of an annular EEC on the current waveform in a foilless diode when the current is measured by a Rogowski coil. The particle-in-cell simulation which is performed under some tolerable and necessary simplifications shows that the long explosive emission delay time of high-threshold cathodes may leave an apparent peak of displacement current on the rise edge of the current waveform, and this will occur only when the electron emission starts after this peak. The experimental researches, which are performed under a diode voltage of 1 MV and a repetitive frequency of 20 Hz, demonstrate that the graphite cathode has a lower emission threshold and a longer lifetime than the stainless steel cathode according to the variation of the peak of displacement current on the rise edge of the current waveform.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Power and energy of exploding wires

Exploding wires are used in many high-energy applications, such as initiating explosives. Previous work analyzing gold wire burst in detonator applications has shown burst current and action metrics to be inconsistent with burst phenomenon across multiple firing-sets. Energy density better captures the correlation between different wire geometries, different electrical inputs, and explosive initiation. This idea has been expanded upon, to analyze the burst properties in power-energy space. Further inconsistencies in the understanding of wire burst and its relation to peak voltage have been found. An argument will be made for redefining the definition of burst. The result is a more broad understanding of rapid metal phase transition and the initiation of explosives in EBW applications.

42 ENGINEERING↗

Comparing the shock sensitivity of insensitive energetic materials

We present a tabletop method to study the shock sensitivity of plastic-bonded explosives that are considered shock insensitive using high dynamic range optical emission spectroscopy with laser-launched km/s flyer plate impacts (2, 3, and 4 km/s), which measures the spectral radiance (the emission spectrum vs a calibrated intensity standard) every 0.8 ns in the nanosecond and microsecond regimes. The explosives were TATB (1,3,5 trinitro, 2,4,6 triamino benzene), FOX-7 (1,1-diamino-2,2-dinitroethylene), LLM-105 (2,6-diamino-3,5-dinitropyrazine-1-oxide), and NTO (nitrotriazolone), all with 20% Sylgard 182 binder. Time resolving emission from shocked explosives produces a unique fingerprint at each shock pressure, and the emission temporal profile can be used to understand each material's shock response and the underlying mechanisms within the framework of the well-known shock ignition and growth models. Ignition was characterized by the emission intensity during nanosecond hot spot ignition. The growth process, which occurs after the shock has unloaded, was characterized by the time derivative of microsecond emission intensity. Singular-value decomposition was used to determine a characteristic spectral radiance over the entire time range, and this radiance was fit to a graybody model to determine a characteristic temperature Tc. Even though these insensitive explosives have similar shock sensitivities, our method can clearly distinguish their shock response. FOX-7 and NTO were the most sensitive, with FOX-7 having the greatest shock ignition sensitivity, growth rate, and Tc. LLM-105 was much less sensitive than FOX-7 and NTO, and TATB consistently showed the lowest sensitivity by any measure.

Akhtar, Meysam (ORCID:0000000243897837)↗

The general relativistic instability supernova of a supermassive population III star

The formation of supermassive Population III stars with masses ≳10,000 M{sub ☉} in primeval galaxies in strong ultraviolet backgrounds at z ∼ 15 may be the most viable pathway to the formation of supermassive black holes by z ∼ 7. Most of these stars are expected to live for short times and then directly collapse to black holes, with little or no mass loss over their lives. However, we have now discovered that non-rotating primordial stars with masses close to 55,000 M{sub ☉} can instead die as highly energetic thermonuclear supernovae powered by explosive helium burning, releasing up to 10{sup 55} erg, or about 10,000 times the energy of a Type Ia supernova. The explosion is triggered by the general relativistic contribution of thermal photons to gravity in the core of the star, which causes the core to contract and explosively burn. The energy release completely unbinds the star, leaving no compact remnant, and about half of the mass of the star is ejected into the early cosmos in the form of heavy elements. The explosion would be visible in the near infrared at z ≲ 20 to Euclid and the Wide-Field Infrared Survey Telescope, perhaps signaling the birth of supermassive black hole seeds and the first quasars.

79 ASTRONOMY AND ASTROPHYSICS↗

Constraining Type Ia supernova explosions and early flux excesses with the Zwicky Transient Factory

In the new era of time-domain surveys, Type Ia supernovae are being caught sooner after explosion, which has exposed significant variation in their early light curves. Two driving factors for early-time evolution are the distribution of 56 Ni in the ejecta and the presence of flux excesses of various causes. We perform an analysis of the largest young SN Ia sample to date. We compare 115 SN Ia light curves from the Zwicky Transient Facility to the turtls model grid containing light curves of Chandrasekhar mass explosions with a range of 56 Ni masses, 56 Ni distributions, and explosion energies. We find that the majority of our observed light curves are well reproduced by Chandrasekhar mass explosion models with a preference for highly extended 56 Ni distributions. We identify six SNe Ia with an early-time flux excess in our gr-band data (four ‘blue’ and two ‘red’ flux excesses). We find an intrinsic rate of 18 ± 11 percent of early flux excesses in SNe Ia at z < 0.07, based on three detected flux excesses out of 30 (10 percent) observed SNe Ia with a simulated efficiency of 57 percent. This is comparable to rates of flux excesses in the literature but also accounts for detection efficiencies. Two of these events are mostly consistent with circumstellar material interaction, while the other four have longer lifetimes in agreement with companion interaction and 56 Ni-clump models. We find a higher frequency of flux excesses in 91T/99aa-like events (44 ± 13 percent).

79 ASTRONOMY AND ASTROPHYSICS↗

Electrospun core-shell microfiber separator with thermal-triggered flame-retardant properties for lithium-ion batteries

Although the energy densities of batteries continue to increase, safety problems (for example, fires and explosions) associated with the use of highly flammable liquid organic electrolytes remain a big issue, significantly hindering further practical applications of the next generation of high-energy batteries. We have fabricated a novel “smart” nonwoven electrospun separator with thermal-triggered flame-retardant properties for lithium-ion batteries. The encapsulation of a flame retardant inside a protective polymer shell has prevented direct dissolution of the retardant agent into the electrolyte, which would otherwise have negative effects on battery performance. Furthermore, during thermal runaway of the lithium-ion battery, the protective polymer shell would melt, triggered by the increased temperature, and the flame retardant would be released, thus effectively suppressing the combustion of the highly flammable electrolytes.

25 ENERGY STORAGE↗

Visualizing the strong field–induced molecular breakup of C 60 via x-ray diffraction

Laser-driven dynamics in polyatomic molecules poses a complex many-body problem. Understanding intense light-matter interaction is crucial for steering intramolecular quantum dynamical processes. Here, we record time-resolved x-ray diffraction images of C 60 molecules during and after their interaction with intense near-infrared fields, giving direct access to structural changes of the molecules and their fragmentation in real time. Tuning the intensity of the excitation pulses, we uncover a transition from a weak-field regime of excited but stable molecules to a high-field regime dominated by Coulomb explosion. In the transition region, the molecules expand by up to 50% of their initial size within just 140 fs, with major fragmentation only setting in afterward. This work demonstrates that x-ray diffractive imaging is capable of retrieving time-resolved structural information of large molecules reshaped by intense laser fields. Laser-driven fragmentation is a first step toward observing molecular processes modified by laser fields of increasing intensity.

Schnorr, Kirsten [Paul Scherrer Inst. (PSI), Villi↗

Nuclear Quadrupole Resonance (NQR) for Stand-off Detection of Contraband

NQR is based on an interaction between the nuclear quadrupole moment of a spin ≥ 1 nucleus (commonly 14N) and the gradient of the electric field from electrons. This causes energy level splitting similar to NMR but with no requirement of an external field. NQR is highly sensitive to chemical structure. Most explosives and drugs have NQR signals (typically in the 1-6 MHz range), thus it is an excellent candidate for detection of concealed contraband (i.e. IEDs, smuggling) but it does have issues with low SNR and long detection times.

36 MATERIALS SCIENCE↗

Year-end report on FY13 activities for J8A6

The Russian-3 (R3) HANE, a 60 km high-latitude burst with yield estimated at 300 kt, was chosen for the demonstration. This test was selected because it allowed LLNL to leverage existing funding, which was directed at extending LLNL’s capability to simulate HANEs at atmospheric altitudes (<100 km). David Larsen (LLNL) developed a new particle-tracing code that tracks monoenergetic electrons of various energies from a point source as they interact with the atmosphere, losing energy and ‘pitch-angle scattering’ as they are transported. A relatively large fraction of the initial electrons are able to escape the atmosphere and were handed off to LANL for further processing to calculate the effect on space based assets. LANL binned the electrons into a phase-space density as a function of energy and equatorial pitch-angle and showed that all of the electrons would travel along field lines to the conjugate point in the Southern hemisphere, where they would likely be absorbed, because their equatorial pitch-angles were too field-aligned to permit them to ‘mirror’ above the atmosphere and be ‘trapped’. Thus, the initial LLNL output did not produce any trapped electrons to input into LANL’s diffusion code and so no study of the long-term evolution of the trapped population and its effect on space-based assets could be performed. It was recognized that LLNL’s calculation did not properly model the low-probability, large-angle scattering associated with a single Coulomb interaction between a beta-decay electron and the nucleus of the neutral particles in the high atmosphere, which would be the dominant interaction above some altitude (>100 km) and might allow the electrons to be pitch-angle scattered sufficiently to become trapped. A second LLNL calculation that properly included this single interaction probability was conducted and the output processed by LANL. It was shown that a small fraction of the initial population (~0.01%) would be ‘locally trapped’; however, even this small population would likely be absorbed within a few minutes as the electrons drifted around earth and eventually ended up on field lines where they would be absorbed in the atmosphere. The output of the second LLNL calculation was found to produce about 4x fewer backscattered electrons than previous work (Selesnick et al 2012), and so the remainder of the FY13 LANL effort on the project was aimed at trying to resolve this discrepancy. LANL implemented a stochastic differential equation to simulate the backscatter process so that the results could be compared to Larsen and Selesnick. Initial results from this capability have been obtained, but no quantitative comparison to Larsen or Selesnick has been done yet.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗