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At least 973 records · Page 54
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

SN 2018ijp: the explosion of a stripped-envelope star within a dense H-rich shell?

In this work, we discuss the outcomes of the follow-up campaign of SN 2018ijp, discovered as part of the Zwicky Transient Facility survey for optical transients. Its first spectrum shows similarities to broad-lined Type Ic supernovae around maximum light, whereas later spectra display strong signatures of interaction between rapidly expanding ejecta and a dense H-rich circumstellar medium, coinciding with a second peak in the photometric evolution of the transient. This evolution, along with the results of modeling of the first light-curve peak, suggests a scenario where a stripped star exploded within a dense circumstellar medium. The two main phases in the evolution of the transient could be interpreted as a first phase dominated by radioactive decays, and a later interaction-dominated phase where the ejecta collide with a pre-existing shell. We therefore discuss SN 2018jp within the context of a massive star depleted of its outer layers exploding within a dense H-rich circumstellar medium.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Modeling of tungsten filament in gas discharge in H - ion source

Sources of negative ions such as H - are essential elements of proton accelerators and tokamaks. They have limited lifetime. The replacement of an ion source is a costly process causing delays in the operation of the entire machine. The hot tungsten filament is the key element that limits the lifetime of the H - ion source at the Los Alamos Neutron Science Center (LANSCE) facility. An accurate model, which describes the filament physics and provides a reliable estimate on its lifetime, may significantly improve the operation of the facility. In this report we describe such a model, including a comprehensive list of relevant physical processes from first principles. The model can be used to describe different regimes of operation using diagnostics data as input parameters. It has been benchmarked against the data collected during the production cycle at LANSCE and shows good agreement with experimental data.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

H- ion source research and development at the Oak Ridge National Laboratory

The U.S. Spallation Neutron Source (SNS) is a state-of-the-art neutron scattering facility delivering the world's most intense pulsed neutron beams to a wide array of instruments which are used to conduct investigations in many fields of science and engineering. Neutrons are produced by spallation of liquid Hg due to bombardment of short (~1µs), intense (~35 A) pulses of protons delivered at 60 Hz from a storage ring which is fed by a high-intensity, 1 GeV H- LINAC. This facility has operated almost continuously since 2006, with ion source performance increasing over those years, and currently providing 50-60 mA of H- ions with a duty-factor of 6% for maintenance-free runs of ~120 days with near 100% availability. Ion source research and development at ORNL has played a key role in enabling and supporting these achievements: this report provides some historical highlights of this effort, describes our current ion source testing facilities, discusses the goals of the program and finally provides a snapshot of some of our ongoing R&D activities. In particular, we have recently simplified and improved the reliability of the plasma ignition gun for the external antenna ion source which is discussed in detail.

Welton, Robert F.↗
DOE OSTI2023

Experimental study of the edge radial electric field in different drift configurations and its role in the access to H-mode at ASDEX Upgrade

The formation of the equilibrium radial electric field (Er) has been studied experimentally at ASDEX Upgrade (AUG) in L-modes of “favorable” (ion ∇ B-drift toward primary X-point) and “unfavorable” (ion ∇ B-drift away from primary X-point) drift configurations, in view of its impact on H-mode access, which changes with drift configurations. Edge electron and ion kinetic profiles and impurity velocity and mean-field Er profiles across the separatrix are investigated, employing new and improved measurement techniques. The experimental results are compared to local neoclassical theory as well as to a simple 1D scrape-off layer (SOL) model. It is found that in L-modes of matched heating power and plasma density, the upstream SOL Er and the main ion pressure gradient in the plasma edge are the same for either drift configurations, whereas the Er well in the confined plasma is shallower in unfavorable compared to the favorable drift configuration. The contributions of toroidal and poloidal main ion flows to Er, which are inferred from local neoclassical theory and the experiment, cannot account for these observed differences. Furthermore, it is found that in the L-mode, the intrinsic toroidal edge rotation decreases with increasing collisionality and it is co-current in the banana-plateau regime for all different drift configurations at AUG. This gives rise to a possible interaction of parallel Pfirsch–Schlüter flows in the SOL with the confined plasma. Thus, the different H-mode power threshold for the two drift configurations cannot be explained in the same way at AUG as suggested by LaBombard et al. [Phys. Plasmas 12, 056111 (2005)] for Alcator C-Mod. Finally, comparisons of Er profiles in favorable and unfavorable drift configurations at the respective confinement transitions show that also the Er gradients are all different, which indirectly indicates a different type or strength of the characteristic edge turbulence in the two drift configurations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Convergent ab initio analysis of the multi-channel HOBr + H reaction

High-level potential energy surfaces for three reactions of hypobromous acid with atomic hydrogen were computed at the CCSDTQ/CBS//CCSDT(Q)/complete basis set level of theory. Focal point analysis was utilized to extrapolate energies and gradients for energetics and optimizations, respectively. The H attack at Br and subsequent Br–O cleavage were found to proceed barrierlessly. The slightly submerged transition state lies −0.2 kcal mol−1 lower in energy than the reactants and produces OH and HBr. The two other studied reaction paths are the radical substitution to produce H2O and Br with a 4.0 kcal mol−1 barrier and the abstraction at hydrogen to produce BrO and H2 with an 11.2 kcal mol−1 barrier. The final product energies lie −37.2, −67.9, and −7.3 kcal mol−1 lower in energy than reactants, HOBr + H, for the sets of products OH + HBr, H2O + Br, and H2 + BrO, respectively. Additive corrections computed for the final energetics, particularly the zero-point vibrational energies and spin–orbit corrections, significantly impacted the final stationary point energies, with corrections up to 6.2 kcal mol−1.

Chemistry↗
DOE OSTI2020

Spatially separating redox centers on 2D carbon nitride with cobalt single atom for photocatalytic H 2 O 2 production

Redox cocatalysts play crucial roles in photosynthetic reactions, yet simultaneous loading of oxidative and reductive cocatalysts often leads to enhanced charge recombination that is detrimental to photosynthesis. This study introduces an approach to simultaneously load two redox cocatalysts, atomically dispersed cobalt for improving oxidation activity and anthraquinone for improving reduction selectivity, onto graphitic carbon nitride (C 3 N 4 ) nanosheets for photocatalytic H 2 O 2 production. Spatial separation of oxidative and reductive cocatalysts was achieved on a two-dimensional (2D) photocatalyst, by coordinating cobalt single atom above the void center of C 3 N 4 and anchoring anthraquinone at the edges of C 3 N 4 nanosheets. Such spatial separation, experimentally confirmed and computationally simulated, was found to be critical for enhancing surface charge separation and achieving efficient H 2 O 2 production. This center/edge strategy for spatial separation of cocatalysts may be applied on other 2D photocatalysts that are increasingly studied in photosynthetic reactions.

2D photocatalyst↗
DOE OSTI2021

Theoretical study of the HCS + –H 2 van der Waals complex: potential energy surface, rovibrational bound states, and rotationally inelastic collisional cross sections

An accurate ground-state intermolecular potential energy surface (PES) was calculated for the HCS + –H 2 complex. The surface was constructed from 3023 ab initio energies, computed with explicitly correlated coupled-cluster theory, CCSD(T)-F12b, with extrapolation to the complete basis set limit (VTZ-F12/VQZ-F12). The new 4D PES was used to compute rovibrational energies, rota- tional constants, and close-coupling quantum scattering calculations at low collision energies. A symmetry-adapted Lanczos algorithm was used to variationally compute the low-lying rovibrational bound states. Rotational constants for states of two isomers were determined from the energy levels and reported in hopes of motivating experiments. The rotationally inelastic state-to-state cross sections of HCS + by collision with para- and ortho-H 2 were computed and compared, and trends and propensities are discussed.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2023

High-resolution vibrational predissociation spectroscopy of I - ·H 2 O by single-mode CW infrared excitation in a 3D cryogenic ion trap

We describe the integration of a tunable, single-mode, continuous wave infrared laser into a cryogenic ion spectroscopy experiment to measure the rovibrational spectrum of the I - ∙H 2 O complex in the OH stretching region. These upper levels lie about 300 cm -1 above the dissociation threshold. The measurements are carried out by loading the ions in a radiofrequency ion trap at 10 Hz and cooling them to 5 K with pulsed He buffer gas. IR photodissociation (PD) of the I - ∙H 2 O complex is monitored by recording the I - product yield by time-of-flight mass spectrometry as a function of laser wavelength. Very narrow (Δν~75 MHz) rotational lines are observed throughout the spectrum, indicating long (ca. 2 ns) lifetimes for the excited metastable rovibrational levels. Rotational analysis of the band arising from the K”=1 to K’=2 transition of the free OH stretching fundamental yields the structure of the complex for the first time. Over 50% of the trapped ion ensemble in the trap can be photodissociated upon excitation of a single rotational line. This enables very high signal-to-noise in the PD spectrum, and is traced to a mechanism in which the ground state rotational levels are rapidly equilibrated by collisions with the buffer gas.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

Humidified single-scattering albedometer (H-CAPS-PM SSA ): Design, data analysis, and validation

In this work, we report the development and validation of a new humidified aerosol single-scattering albedometer to quantify the effects of water uptake on submicrometer particle optical properties. The instrument simultaneously measures in situ aerosol light extinction ( σ ep ) and scattering ( σ sp ) using a cavity-attenuated phase shift-single scattering albedo particulate matter (PM) monitor (CAPS-PM SSA , Aerodyne Research, Inc., Billerica, MA, USA). It retrieves by difference aerosol light absorption ( σ ap ) and directly quantifies aerosol single-scattering albedo (SSA), the aerosol “brightness.” We custom built a relative humidity (RH) control system using a water vapor-permeable membrane humidifier and coupled it to the CAPS-PM SSA to enable humidified aerosol observations. Our humidified instrument (H-CAPS-PM SSA ) overcomes problems with noise caused by mirror purge-flow humidification, heating, and characterizing cell RH. Careful angular truncation corrections in scattering, particularly for larger particles, were combined with empirical observations. Results show that the optimal operational size to be D p < 400 nm. The H-CAPS-PM SSA was evaluated with several pure single-component aerosols including ammonium sulfate ((NH 4 ) 2 SO 4 ), absorbing nigrosin, and levoglucosan, an organic biomass smoke tracer. The measured σ ep , σ sp , and the derived optical hygroscopicity parameter ( κ ) for size-selected ammonium sulfate are in good agreement with literature values. For dry size-selected nigrosin in the 100 < D p < 400 nm range, SSA values increased from ~0.3 to 0.65 with increasing D p . The enhancement in nigrosin σ ap at RH = 80% was a factor of 1.05–1.20 relative to dry conditions, with the larger particles showing greater enhancement. SSA increased with RH with the largest fractional enhancement measured for the smallest particles. For polydisperse levoglucosan, we measured an optical κ of 0.26 for both light extinction and scattering and negligible absorption. Our new instrument enables reliable observations of the effects of ambient humidity on mixed aerosol optical properties, particularly for light-absorbing aerosols whose climate forcing is uncertain due to measurement gaps.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Examination of OH and H 2 O 2 production by uniform and non-uniform modes of dielectric barrier discharge in He/air mixture

In this work we have carried out a parametrical study of hydroxyl radical (OH) generation in nanosecond dielectric barrier discharge (DBD) in He/air mixture using a laser-induced fluorescence approach. Specifically, the foci of the study are the investigation of differences between uniform and non-uniform modes of the discharges and the difference in production of OH and H 2 O 2 Nanosecond-time scale imaging of the discharge shows transition from streamer to diffuse mode when applied electric field to the discharge gap approaches ~90 kV cm –1 . The results show that both OH production in the gas phase and downstream H 2 O 2 delivery rates to liquid depend on the discharge mode operation and are respectively 30% and 3 times higher for the non-uniform DBD compared to the diffuse discharge.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Bayesian analysis of nuclear polarizability corrections to the Lamb shift of muonic H-atoms and He-ions

The extraction of nuclear charge radii from spectroscopy experiments in muonic atoms is currently limited by the large uncertainties associated with the theoretical evaluation of the nuclear polarizability effects. To facilitate calculations, these polarizability corrections are conventionally expressed as an expansion in a dimensionless parameter η, which has been argued in previous literature to hold an approximate value of 0.33 in light-nuclear systems. In this work, we check this claim by doing a Bayesian analysis of the nuclear-polarizability corrections to the Lamb shift in µ 2 H and µ 3 H atoms and in µ 3 He + and µ 4 He + ions at various orders in the η-expansion. As presented here, our analysis supports the claim that η $\ll$ 1 in these systems and finds truncation uncertainties that are similar to the previous estimate, the only exception being the truncation uncertainties in the µ 3 He + ion, which are found to be larger.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

The MIST-1 and MIST-2 multicusp ion sources for high-current $H$$^{+}_{2}$ beams

We present two iterations of the Multicusp Ion Source Technology at MIT (MIST) sources, designed to fulfill the requirements of the HCHC-XX cyclotron design. The HCHC-XX is a novel compact cyclotron accelerating $H$$^{+}_{2}$. Beam is injected through a radio-frequency quadrupole buncher-accelerator (embedded in the cyclotron yoke) and utilizes so-called vortex motion during acceleration. If successful, it will deliver 10 mA of protons at 60 MeV in CW mode. This scheme requires a low-emittance, high-current initial beam with high $H$$^{+}_{2}$ purity. We briefly summarize the design and previous results of the MIST-1 ion source and, for the first time, the detailed design of the new and improved MIST-2, including the mechanical, electrical, and control system design. We further show experimental results of using the MIST-2 backplate on the MIST-1 body, present a study using different types of permanent magnets for confinement (including no magnets), and finally, we present first results of the MIST-2 in full operation. In this first commissioning run, we were able to increase the total extracted current from the MIST-2 to 7 mA—a factor of 2 over the MIST-1.

Winklehner, D. [Massachusetts Institute of Technol↗
DOE OSTI2020

Impurity transport in the pedestal of H-mode plasmas with resonant magnetic perturbations

Experiments on DIII-D show that resonant magnetic perturbations (RMPs) reduce the impurity confinement time in the H-mode pedestal below that of naturally ELMy plasmas. STRAHL modeling of discharges with aluminum laser blow off (LBO) injection show increased diffusion in the pedestal of H-mode discharges with RMPs. The increased diffusion from the RMPs provides improved impurity control compared to the naturally ELMy discharges and prevents the buildup of impurities near the edge of the plasma. Tungsten LBO injection into discharges with and without RMPs led to striking differences in the evolution of the discharge. The naturally ELMy discharge became ELM free and showed an increase in edge radiation, leading to the eventual radiative collapse of the plasma. Injecting a similar number ofWparticles into discharges with RMPs, either with or without ELMs, led to a measurable accumulation of core W but did not significantly impact the evolution of the discharge. Furthermore, these results indicate that RMPs are beneficial for controlling the buildup of impurities in the pedestal region of the plasma.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2022

Investigation of the compatibility of pellet fueling with ELM-free H-mode plasmas in EAST tokamak

Abstract Experiments on pellet fueling have been carried out in edge localized mode (ELM)-free high-confinement mode (H-mode) plasmas with q 95 ∼ 6 in the EAST tokamak. Cryogenic deuterium pellets were injected into the ELM-free plasmas at a frequency of 10 or 5 Hz from ∼45 cm above the mid-plane on the low-field side. It is found that the ELM-free H-mode plasmas are still sustained even if both the edge and core plasma are impacted by the pellet injections (PIs). Several small ELMs would appear and the edge coherent mode accompanying the ELM-free phase fades or even disappears just after the pellet events, but the plasma would rapidly recover to the ELM-free state. Although the ELMing phase is very short, it may be an issue that still needs to be resolved in the future. Meanwhile, the 3/2 tearing mode often appearing in ELM-free discharges would be stabilized by the PIs, and the high-Z impurity concentration would be reduced during the PIs. All these results will be meaningful to International Thermonuclear Experimental Reactor and future fusion reactors.

Physics↗
DOE OSTI2021

Plasma-droplet interaction study to assess transport limitations and the role of • OH, O • ,H • ,O 2 (a 1 Δ g ),O 3 , He(2 3 S) and Ar(1s 5 ) in formate decomposition

Plasmas interacting with liquid microdroplets are gaining momentum due to their ability to significantly enhance the reactivity transfer from the gas phase plasma to the liquid. This is, for example, critically important for efficiently decomposing organic pollutants in water. In this contribution, the role of •OH as well as non-•OH-driven chemistry initiated by the activation of small water microdroplets in a controlled environment by diffuse RF glow discharge in He with different gas admixtures (Ar, O 2 and humidified He) at atmospheric pressure is quantified. The effect of short-lived radicals such as O• and H• atoms, singlet delta oxygen (O 2 (a 1 Δ g )), O 3 and metastable atoms of He and Ar, besides •OH radicals, on the decomposition of formate dissolved in droplets was analyzed using detailed plasma diagnostics, droplet characterization and ex situ chemical analysis of the treated droplets. The formate decomposition increased with increasing droplet residence time in the plasma, with ~70% decomposition occurring within ~15 ms of the plasma treatment time. The formate oxidation in the droplets is shown to be limited by the gas phase •OH flux at lower H 2 O concentrations with a significant enhancement in the formate decomposition at the lowest water concentration, attributed to e – /ion-induced reactions. However, the oxidation is diffusion limited in the liquid phase at higher gaseous •OH concentrations. Here, the formate decomposition in He/O 2 plasma was similar, although with an order of magnitude higher O• radical density than the •OH density in the corresponding He/H 2 O plasma. Using a one-dimensional reaction–diffusion model, we showed that O 2 (a 1 Δ g ) and O 3 did not play a significant role and the decomposition was due to O•, and possibly •OH generated in the vapor containing droplet-plasma boundary layer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Outer midplane neutral density measurements and H-mode fueling studies in NSTX-U

Neutral density profiles are measured on the outboard midplane of the National Spherical Torus Experiment Upgrade (NSTX-U) using a two dimensional camera (ENDD, edge neutral density diagnostic) filtered for deuterium Balmer α (D α ) emission interpreted via simulations using the Monte Carlo neutral transport code DEGAS 2. Deuterium atomic densities n D are calculated by inverting the line-integrated D α brightness and using local measurements of electron density ne and temperature T e to determine atomic rate coefficients. The assumptions used in the derivation of n D from D α emissivity are validated using DEGAS 2 to estimate contributions to emissivity due to electron impact excitation and molecular processes. In this work, experimental measurements and DEGAS 2 simulations are compared over a database of L- and H-mode discharges, showing good agreement in D α emissivity profiles. Residual disagreement between experiment and simulations is suggestive of the possible role of intermittent transport and uncertainties in the molecular data. DEGAS 2 simulations are further used to complement the ENDD diagnostic, extracting neutral (atomic and molecular) densities at locations where the ENDD measurement are not made or where the assumptions used in the ENDD analysis are not valid. Deuterium atomic densities and ionization profiles on the outer midplane are compared for L-mode and H-mode discharges in NSTX-U. One-way coupling of DEGAS 2 to UEDGE multi-fluid simulations constrained by experimental data is used to study edge fueling and neutral penetration in NSTX-U discharges.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Identifying the microtearing modes in the pedestal of DIII-D H-modes using gyrokinetic simulations

Recent evidence points toward the microtearing mode (MTM) as an important fluctuation in the H-mode pedestal for anomalous electron heat transport. A study of the instabilities in the pedestal region carried out using gyrokinetic simulations to model an ELMy H-mode DIII-D discharge (USN configuration, 1.4 MA plasma current, and 3 MW heating power) is presented. The simulations produce MTMs, identified by predominantly electromagnetic heat flux, small particle flux, and a substantial degree of tearing parity. The magnetic spectrogram from Mirnov coils exhibits three distinct frequency bands—two narrow bands at lower frequency (~35–55 kHz and ~70–105 kHz) and a broader band at higher frequency (~300–500 kHz). Global linear GENE simulations produce MTMs that are centered at the peak of the ω* profile and correspond closely with the bands in the spectrogram. The three distinctive frequency bands can be understood from the basic physical mechanisms underlying the instabilities. For example (i) instability of certain toroidal mode numbers (n) is controlled by the alignment of their rational surfaces with the peak in the ω* profile, and (ii) MTM instabilities in the lower n bands are the conventional collisional slab MTM, whereas the higher n band depends on curvature drive. While many features of the modes can be captured with the local approximation, a global treatment is necessary to quantitatively reproduce the detailed band gaps of the low-n fluctuations. Notably, the transport signatures of the MTM are consistent with careful edge modeling by SOLPS.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

Radiative divertor detachment and impurity transport with nitrogen and neon seeding in KSTAR H-mode plasmas

Achieving core-edge compatible divertor detachment is a critical requirement for stable operation in future fusion devices. This study compares nitrogen and neon seeding in KSTAR H-mode plasmas with carbon walls, combining experiments and SOLPS-ITER modelling to evaluate their radiative dissipation and core-edge compatibility. Experimentally, N seeding achieved stronger divertor detachment, with larger reductions in target particle and heat fluxes, a higher divertor radiation fraction, and a lower core radiation fraction than Ne. In contrast, Ne seeding triggered a significant rise in core radiation followed by H–L back transitions, limiting the maximum total radiated power fraction to roughly half that of N. SOLPS-ITER simulations reproduced the experimental trends and revealed that the better core-edge compatibility of N arises from its higher divertor retention in addition to its higher cooling factor. The relative positions of the stagnation points of impurity poloidal velocity and ionization sources did not explain the different divertor compression. Instead, in the present modelling, the higher impurity parallel particle flux, resulting from the higher parallel impurity velocity, explains the stronger nitrogen impurity compression in the divertor region. The parallel temperature distribution with N was more favourable for achieving higher impurity parallel velocity than with Ne, because the impurity velocity is governed by modifications of the main ion flow due to friction and thermal forces, both of which strongly depend on the temperature. Ultimately, this behaviour is attributed to the strongly divertor-localized radiation of N. These results demonstrate that N is more effective than Ne in achieving radiative divertor detachment while maintaining low core contamination in KSTAR, consistent with observations in other present tokamaks.

KSTAR↗