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At least 973 records · Page 54

Pathway to tune sputter coated Nb$_3$Sn with Zr

Superconducting radio frequency (SRF) cavities are essential elements of many modern-day particle accelerators such as, European XFEL (DESY), LCLS II-HE (SLAC) and PIP II (Fermilab). Nb$_3$Sn superconducting material promises significant potential to exceed the performance of conventional niobium based SRF cavities. We aim to advance the ongoing R$&$D efforts to achieve Nb$_3$Sn coated cavities with high material quality. In this work, we have developed to achieve a route for effectively reducing the intrinsic defects in magnetron sputter coated Nb$_3$Sn SRF cavities and eventually improve the overall RF performance. We have observed that Zr is mainly being incorporated as ZrO$_2$ precipitates of average dimensions ranging from 20-100nm. By increasing the concentration of Zr, we have three major effects in the physical properties. Firstly, we noted that the density of the surface and bulk voids as well as their average dimensions are dramatically reduced on increasing the Zr content in Nb$_3$Sn. These surface voids are believed to be detrimental to cavity applications due to increase the local dissipation of electric and magnetic fields. These results indicate that inclusion of Zr in Nb$_3$Sn sputtered coating will improve the material quality and might help to reduce the overall RF power dissipation. Secondly, we observed that increasing Zr concentration from 0 to 2.4% substantially improves both superconducting transition temperature (Tc) and upper critical magnetic field (Hc2). However, on further increasing the Zr concentration to 24%, we noticed a small decrement in the Hc2 value. These results infer that the increase in Zr concentration up to an optimal concentration will be beneficial to enhance the superconducting properties. Increase in Tc promises lesser RF losses and improvement in accelerating gradient, whereas the increase in Hc2 suggests more efficient flux pinning which could give rise to high quality factors in presence of multi-Tesla magnetic field. Additionally, we also observed that increasing Zr concentration possibly prevents the oxygen diffusion and leads to thinner formation of primary surface oxide (Nb$_2$O$_5$ and SnO). This study gives a route to tune Zr fraction in Nb3Sn to modify the physical properties that control the high field performance of Nb3Sn RF cavities.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Evaluation of LANDSAT multispectral scanner images for mapping altered rocks in the east Tintic Mountains, Utah

The author has identified the following significant results. Positive findings of earlier evaluations of the color-ratio compositing technique for mapping limonitic altered rocks in south-central Nevada are confirmed, but important limitations in the approach used are pointed out. These limitations arise from environmental, geologic, and image processing factors. The greater vegetation density in the East Tintic Mountains required several modifications in procedures to improve the overall mapping accuracy of the CRC approach. Large format ratio images provide better internal registration of the diazo films and avoids the problems associated with magnifications required in the original procedure. Use of the Linoscan 204 color recognition scanner permits accurate consistent extraction of the green pixels representing limonitic bedrock maps that can be used for mapping at large scales as well as for small scale reconnaissance.

Rowan, L. C.↗

A search for interstellar scandium

The resonance line of Sc II at 3642.785 A has been sought in the interstellar spectrum of Zeta Oph, resulting in an upper limit N(Sc II) not greater than 8.6 billion/sq cm and a depletion of this element at least by a factor of 200, if Sc III contributes a negligible column density. The present upper limit may be somewhat below the level expected under the grain-formation model for interstellar depletions, and is consistent with the abundance expected if the depletions are due to gas-grain collisions. The new limit on this element helps to support the hypothesis that species within a specific range of ionization potential are preferentially depleted.

Snow, T. P., Jr.↗

Analysis of evaporative water loss in the Skylab astronauts

Daily evaporative water losses (EWL) during the three Skylab missions were measured using the indirect mass and water balance techniques. A mean inflight EWL of 860 ml/day-m 2 was obtained for nine men who averaged one hour of daily exercise. Although it was expected the EWL would increase in the hypobaric environment of Skylab (1/3 atmosphere), an average decrease from preflight sea level conditions of 11 percent was measured. The results suggest that weightlessness may have been a factor in modifying EWL primarily by decreasing sweat losses during exercise and possibly by reducing insensible skin losses as well. The weightless environment apparently promotes the formation of a sweat film on the skin surface both directly, by reducing heat and mass convective flow and sweat drippage, and perhaps indirectly by inducing measurable biochemical changes resulting in high initial sweating rates. It is proposed that these high levels of skin wettedness favor sweat suppression by a previously described mechanism.

Leonard, J. I.↗

Effect of patch borders on coercivity in amorphous rare earth-transition metal thin films

The coercivity at the micron scale is a very important property of magneto-optical media. It is a key factor that determines the magnetic domain wall movement and domain reversal. How the coercivity is influenced by a special type of patch borders is discussed. Patch formation is a general phenomenon in growth processes of amorphous rare earth transition metal thin films. Different patches may stem from different seeds and the patch borders are formed when they merge. Though little is known about the exact properties of the borders, we may expect that the exchange interaction at the patch border is weaker than that within a patch, since there is usually a spatial gap between two patches. Computer simulations were performed on a 2-D hexagonal lattice consisting of 37 complete patches with random shape and size. From the series of simulations we may conclude that the domain in the patch with borders of 30 percent exchange strength can expand most easily to the whole lattice, because the exchange strength can expand most easily to the whole lattice, because the exchange strength of the border is not too high to prevent the domain from growing within the patch and it is not too low to prevent the domain from expanding beyond the patch.

Patterson, G.↗

Light transmission and reflection in perennially ice-covered Lake Hoare, Antarctica

We have investigated the transmission and albedo of the perennial ice cover on Lake Hoare, Antarctica. Our database consists of year-round measurements of the photosynthetically active radiation (400-700 nm) under the ice, measurements of the spatial variation of the under-ice light in midsummer, and spectrally resolved measurements from 400 to 700 nm of the albedo and transmission of the ice cover in early (November) and in midsummer (January). Our results show that the transmission decreases in the first part of summer, dropping by a factor of approximately 4 from November to January. We suggest that this is due to heating in the upper layers of the ice cover and the formation of Tyndall figures. Later in the summer when a significant liquid water fraction occurs within the ice cover, the transmission increases. In the fall when the ice cover freezes solid the transmission drops markedly. The spectrally resolved measurements from 400 to 700 nm show that approximately 2-5% of the incident light in this spectral region penetrates the 3.5-m thick ice cover. We have analyzed the spectral data using a two-stream scattering solution to the radiative transfer equation with three vertical layers in the ice cover. A surficial glaze of scattering ice 1 cm thick overlies a layer of sandy, bubbly ice about a meter thick, and below this is a thick layer of sand-free ice with bubbles. We find that the ice cover is virtually opaque at wavelengths longer than 800 nm. The net transmission of solar energy is approximately 2%. Significant changes in the thickness of the ice cover have been reported at Lake Hoare. These are due primarily to changes in the thickness of the bottom layer only. Because this layer is relatively clear, the effect on the transmission through the ice cover from these changes is less than would be predicted assuming a homogeneous ice cover.

Mckay, C. P.↗

Observational Investigation of Solar Interior and Atmosphere

The Imaging Vector Magnetograph (IVM) has been modified to make it easier to observe at more than one spectral line. The cell holding the blocking filter has been replaced by a four-position filter wheel, so that changing to a different line is a matter of a few minutes rather than the several hours it used to take to disassemble the cell and install a new filter. Three new filters have been obtained, for Na 1589.6 nm, Fe 1630.25 nm, and H 1656.3 nm. The new filters have better bandpass profiles than the ones they replaced: somewhat wider, with flatter tops and steeper wings. This results in a reduction of parasitic light coming from adjacent Fabry-Perot orders, from seven percent to about two percent, and flattens the apparent continuum. The Mees CCD Imaging Spectrograph (MCCD) was upgraded under this grant, with a new control computer and data system. The camera was replaced with a faster, larger-format frame-transfer camera. Final integration of the upgrades is not yet complete, but tests indicate that the system cadence will be improved by a factor of five to ten, while increasing the spatial coverage by a factor of two (depending on observation options). Synoptic observations with the IVM and MCCD continue to be conducted daily, to the extent permitted by the fact that we have a single observer responsible for the observations. The older Haleakala Stokes Polarimeter is also used to make a daily vector magnetogram, normally of the region selected by the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) duty scientists. This instrument, however, is showing its age to the extent that its maintenance is becoming something of a challenge. We also run a white light full-disk imager and a video H alpha prominence camera, continuously during times of observations. Of particular interest, we obtained rapid-cadence observations of the 2003 July 15 white light flare with both the IVM and MCCD. The vector magnetograms show no obvious difference between the preflare and postflare configurations. The photospheric magnetogram sequence and H alpha spectra we obtained can be combined with spacecraft observations to construct a rather detailed picture of the events of this flare. Several papers are in preparation.

Kuhn, Jeffrey R.↗

Elemental Abundances in NGC 3516

We present Reflection Grating Spectrometer data from an XMM-Newton observation of the Seyfert 1 galaxy NGC 3516, taken while the continuum source was in an extremely low flux state. This observation offers a rare opportunity for a detailed study of emission from a Seyfert 1 galaxy as these are usually dominated by high nuclear continuum levels and heavy absorption. The spectrum shows numerous narrow emission lines (FWHM approximately less than 1300 kilometers per second) in the 0.3 - 2 keV range, including the H-like lines of C, N, and O and the He-like lines of N, O and Ne. The emission-line ratios and the narrow width of the radiative recombination continuum of CVI indicate that the gas is photoionized and of fairly low temperature (kT approximately less than 0.01 keV). The availability of emission lines from different elements for two iso-electronic sequences allows us to constrain the element abundances. These data show that the N lines are far stronger than would be expected from gas of solar abundances. Based on our photoionization models we find that nitrogen is overabundant in the central regions of the galaxy, compared to carbon, oxygen and neon by at least a factor of 2.5. We suggest that this is the result of secondary production of nitrogen in intermediate mass stars, and indicative of the history of star formation in NGC 3516.

Turner, T. J.↗

Lunar and Planetary Science XXXV: Ancient Mars Water and Landforms

Titles in this section include: 1) Giant Lowland Polygons: Relics of an Ancient Martian Ocean? 2) Lake Shorelines: Earth Analogs for Hypothesized Martian Coastal Features; 3) Complex Evolution of Paleolacustrine Systems on Mars: An Example from the Holden Crater; 4) Geomorphology and Hydraulics of Ma'adim Vallis, Mars, During a Noachian/Hesperian Boundary Paleoflood; 5) Geologic Evolution of Dao Vallis, Mars; 6) Advances in Reconstructing the Geologic History of the Chryse Region Outflow Channels on Mars; 7) Ravi Vallis, Mars - Paleoflood Origin and Genesis of Secondary Chaos Zones; 8) Walla Walla Vallis and Wallula Crater: Two Recently Discovered Martian Features Record Aqueous History; 9) Tharsis Recharge: a Source of Groundwater for Martian Outflow Channels; 10) Factors Controlling Water Volumes and Release Rates in Martian Outflow Channels; 11) Significance of Confined Cavernous Systems for Outflow Channel Water Sources, Reactivation Mechanisms and Chaos Formation; 12) Systematic Differences in Topography of Martian and Terrestrial Drainage Basins; 13) Waves on Seas of Mars and Titan: Wind-Tunnel Experiments on Wind-Wave Generation in Extraterrestrial Atmospheres.

Source record↗

Influence of antiorthostatic suspension on resistance to murine Listeria monocytogenes infection

The present study was designed to evaluate the influence of antiorthostatic suspension, a ground-based modeling system employed to simulate certain aspects of weightlessness that occur during space flight, on the capacity of mice to resist infection with the facultative intracellular bacterial pathogen Listeria monocytogenes. Female BDF1 mice were suspended by the tail in the orthostatic or antiorthostatic position and were infected with a sublethal dose of virulent L. monocytogenes at various times during the suspension. It was found that suspension did not influence the kinetics of bacterial growth in vivo if the infection was started concurrently with the suspension. However, mice that were antiorthostatically suspended 2, 4, or 7 days before the onset of infection exhibited an enhanced capacity to eliminate the challenge infection. Suspending mice on day 2 of the infection did not alter the kinetics of bacterial growth. Finally, the enhancement of resistance to the primary Listeria infection was accompanied by failure of the mice to generate long-term protective immunological memory to the challenge organism. Collectively, these results indicate that the stress of antiorthostatic suspension can influence the capacity of mice to resist bacterial infection.

NASA Discipline Regulatory Physiology↗

MBARI-WEC September and October 2022 Field Data

This data is needed to simulate a model of the MBARI-WEC (Monterey Bay Aquarium Research Institute, Wave Energy Converter device) in a simulation environment (e.g. Gazebo) for 56 observation dates in the time between September and October 2022, and to compare the simulation outputs to the corresponding field data of the physical MBARI-WEC. There were 50 observations chosen in Sept and 6 observations in Oct. To help understand terms below, a summary of the system can be found at the github link in the downloads section below. The Gazebo MBARI-WEC model is also provided, should users wish to simulate using this platform. There are 4 *mat files included. ................................................................................................................................................................................................................................... Spectrum and Simulation Inputs: September2022_spectrum_siminputs.mat and October2022_spectrum_siminputs.mat has data needed for simulation inputs in table format. These include the ocean spectrum for an observation and operating parameters of the MBARI-WEC during that observation. They are organized as rows representing an observation and columns representing data. For example, for the September *mat there are 50 rows. The first 7 columns are Datetime, sig_waveheight, peak_period, mean_period, heaveconedoor_status, pistonpos_mean, and scale_factor: - Datetime is the date and time the observation occurred in PST - sig_waveheight is the significant wave height of the ocean spectrum during that observation in meters - peak_period is the peak period of the ocean spectrum during that observation in seconds - mean_period is the mean period of the ocean spectrum during that observation in seconds - heaveconedoor_status is the status of the heave cone doors where 0 represents the doors are open and 1 represents they are closed - pistonpos_mean is the mean position of the PTO ram (piston) in meters - scale_factor is an additional factor of 0.5 --1.4 applied to a default damping relationship The next columns are data needed to represent the ocean spectrum. First are the frequencies [Hz] labeled as "f0-f38", then the variance density [m2/Hz] labeled as "vardens0-vardens38". October2022_spectrum_siminputs.mat follows as a similar format as above, but includes a larger amount of ocean spectrum frequencies and variance density elements. ................................................................................................................................................................................................................................... Field data: The field data is found in MBARIWEC_septdata.mat and MBARIWEC_octdata.mat for the observations of September and October, respectively. These contain data in a struct format. The struct contains the following fields for each observation: PC_BattCurr, PC_LoadCurr, PC_RPM, PC_Voltage, SC_Range, SC_Velocity, DateTime, where: - PC_BattCurr is the current flowing to or from the onboard batteries in Amps - PC_LoadCurr is the current flowing to the load dump in Amps - PC_RPM is the electric/hydraulic motor shaft speed (directly coupled) in RPM - PC_Voltage is the bus voltage at the power converter in Volts - SC_Range is the PTO ram (piston) position in meters where 0 is fully retracted and 2.03 is fully extended - SC_Velocity is the PTO ram (piston) velocity in meters/sec - DateTime is the date and time of the sampled field data in each observation in PST - Electric Power is equal to: PC_Voltage*(PC_BattCurr + PC_LoadCurr) in Watts For example, upon loading MBARIWEC_octdata.mat, the aforementioned fields would be loaded, each with {6x1} cells for the 6 observations chosen in October. Within the first cell of e.g. SC_Range would be sampled data representing the field data of the MBARIWEC PTO piston position for say, one hour, of the first October observation. The corresponding field DateTime would...

16 TIDAL AND WAVE POWER↗

Propellant-Less Spacecraft Formation-Flying and Maneuvering with Photonic Laser Thrusters

The present NIAC Phase II program explored an amplified photon thruster, Photonic Laser Thruster (PLT), as a means of enabling unprecedented maneuverability of small spacecraft, such as cubesats, and reducing space system SWaP for future NASA missions and other commercial and DoD space endeavors. In addition to its propellantless operation capability, PLT can provide orders of magnitude more precise controls in thrust magnitude and vector than conventional thrusters. Furthermore, PLT promises to enable innovative CONOPS (Concept of Operations) to change how some NASA missions are conceived and to represent a revolutionary departure from the "all-in-one" single-spacecraft approach, where a primary factor that dominates spacecraft design is a heavy and risk-intolerant mission-critical payload. Instead, the PLT CONOPS has evolved from a different path based on interbody dynamics via thrust and power beaming. As interbody atomic dynamics unfolds completely new classes of molecular structures that cannot be formed by solo acting atoms alone, the PLT interbody dynamics is predicted to unfold unprecedented multibody spacecraft structures. Therefore, the revolutionary path of the PLT CONOPS represents a technology push rather than a mission pull, and will enable an entirely new generation of planetary, heliospheric, and Earth-centric missions. The chief accomplishments of the present Phase II program are: 1) achievement of photon thrust up to 3.5 mN (100 times scaling up of Phase I PLT) and amplification factor up to 1,500 (15 times enhancement of Phase I PLT), 2) laboratory demonstration of propelling, slowing and stopping a 1U cubesat on an air track with PLT, 3) proof of feasibility on persistent out-of-plane formation flying with PLT in simulation studies, 4) preliminary SolidWorks designs of 1-mN class PLT, 5) establishment of SWaP for flight-ready PLT, 6) designs for proof-ofconcept missions of precision formation flying with cubesats, 7) definition of PLT-based NASA missions, such as Virtual Telescope. In sum, the present study conclusively demonstrated the potential of PLT to revolutionize future space endeavors by drastically enhancing maneuverability of spacecraft, reducing future space system SWaP by exploiting small spacecraft multi-system, and enabling innovative CONOPS.

Bae, Young K.↗

Designing silicon carbide heterostructures for quantum information science: challenges and opportunities

Abstract Silicon carbide (SiC) can be synthesized in a number of different structural forms known as polytypes with a vast array of optically active point defects of interest for quantum information sciences. The ability to control and vary the polytypes during SiC synthesis may offer a powerful methodology for the formation of new material architectures that expand our ability to manipulate these defects, including extending coherence lifetimes and enhancing room temperature operation. Polytypic control during synthesis presents a significant challenge given the extreme conditions under which SiC is typically grown and the number of factors that can influence polytype selection. In situ monitoring of the synthesis process could significantly expand our ability to formulate novel polytype structures. In this perspective, we outline the state of the art and ongoing challenges for precision synthesis in SiC. We discuss available in situ x-ray characterization methods that will be instrumental in understanding the atomic scale growth of SiC and defect formation mechanisms. We highlight optimistic use cases for SiC heterostructures that will become possible with in situ polytypic control and end by discussing extended opportunities for integration of ultrahigh quality SiC materials with other semiconductor and quantum materials.

Harmon, K. J. (ORCID:0000000164277971)↗

Methyl formate oxidation kinetics up to 100 atm

Methyl formate (MF, CH3OCHO), the simplest ester, is a representative oxygenated fuel with high oxygen content, and low sooting tendency. However, its oxidation behavior under high-pressure and intermediate-temperature conditions remains insufficiently understood, especially where low-temperature peroxy radical chemistry, methanol chemistry, and pressure-dependent reaction pathways play a critical role. In this study, MF oxidation experiments were conducted in the Princeton supercritical-pressure jet-stirred reactor (SP-JSR) at 20 and 100 atm over the temperature range of 400–950 K under both fuel-lean and fuel-rich conditions. Based on the experimental results, an updated HP-Mech was developed by incorporating previous MF sub-mechanisms, expanded low-temperature peroxy pathways, and evaluated pressure-dependent decomposition kinetics. The newly updated HP-Mech shows greatly improved performance in predicting the onset temperature, the key intermediate species fractions, methanol formation, and the progression of MF oxidation across all the experimental conditions. Path flux analysis indicates that MF consumption at the onset stage is dominated by H-abstraction at the methyl site, forming CH2OCHO radicals that lead to the formation and isomerization of O2CH2OCHO, driving low-temperature chain propagation. Moreover, H-abstraction at the formate site forms CH3OCO radicals that preferentially decompose to CH3, initiating the methanol formation pathway linked to CH3O2 and HO2 chemistry. At the same time, HO2 formation is strongly coupled to MF oxidation through multiple MF-derived radical pathways. HCO originates from MF oxidation and acts as a key coupling species linking fuel consumption to HO2 buildup, especially under high-pressure and intermediate-temperature conditions. In addition to this dominant channel, supplementary HO2 formation pathways involving CH3, CH3O, CH2OH, and CH3O2 reacting with O2 further connect methanol chemistry and oxygenated radical chemistry to the HO2 pool, indicating the central role of HO2 in governing MF oxidation. Sensitivity analysis identifies MF with OH/HO2/CH3O2 reactions and the HO2/H2O2/OH sequence as the key factors controlling reactivity in the high-pressure and intermediate-temperature regime. MF directly reacts with OH/HO2/CH3O2 to consume the fuel and produce reactive radicals like CH2OCHO and CH3OCO that undergo subsequent oxidation pathways. Moreover, HO2 recombination suppresses oxidation at lower temperatures, while thermal decomposition of H2O2 accelerates OH production and promotes fuel consumption as temperature increases. The direct formation of active OH from HO2 radicals further completes the mechanism, improving its prediction especially during the oxidation onset stage.

Low-temperature Chemistry↗

Large Eddy Simulation of the Diurnal Cycle of Shallow Convection in the Central Amazon

Climate models often face challenges in accurately simulating the daily precipitation cycle over tropical land areas, particularly in the Amazon. One contributing factor may be the incomplete representation of the diurnal evolution of shallow cumulus (ShCu) clouds. This study aimed to enhance the understanding of the diurnal cycles of ShCu clouds—from formation to maturation and dissipation—over the Central Amazon (CAMZ). Using observational data from the Green Ocean Amazon 2014 (GoAmazon) campaign and large eddy simulation (LES) modeling, we analyzed the diurnal cycles of six selected pure ShCu cases and their composite behavior. Our results revealed a well-defined cycle, with cloud formation occurring between 10 and 11 local time (LT), maturity from 13 to 15 LT, and dissipation by 17–18 LT. The vertical extent of the liquid water mixing ratio and the intensity of the updraft mass flux were closely associated with increases in turbulent kinetic energy (TKE), enhanced buoyancy flux within the cloud layer, and reduced large-scale subsidence. We further analyzed the diurnal cycles of the convective available potential energy (CAPE), the convective inhibition (CIN), the Bowen ratio (BR), and the vertically integrated TKE in the mixed layer (ITKE-ML), exploring their relationships with the cloud base mass flux (Mb) and cloud depth across the six ShCu cases. ITKE-ML and Mb exhibited similar diurnal trends, peaking at approximately 14–15 LT. However, no consistent relationships were found between CAPE (or BR) and Mb. Similarly, comparisons of the cloud depth with CAPE, BR, ITKE-ML, CIN, and Mb revealed no clear relationships. Smaller ShCu clouds were sometimes linked to higher CAPE and lower CIN. It is important to emphasize that these findings are preliminary and based on a limited sample of ShCu cases. Further research involving an expanded dataset and more detailed analyses of the TKE budget and synoptic conditions is necessary. Such efforts would yield a more comprehensive understanding of the factors influencing ShCu clouds’ vertical development.

54 ENVIRONMENTAL SCIENCES↗

High-z galaxies with JWST and local analogues – it is not only star formation

ABSTRACT I present an analysis of the JWST NIRSpec data of SMACS 0723 released as Early Release Observations. As part of this three new redshifts are provided, bringing the total of reliable redshifts to 14. I propose a modification to the direct abundance determination method that reduces sensitivity to flux calibration uncertainties by a factor of ∼3 and show that the resulting abundances are in good agreement with Bayesian photoionization models of the rest-frame optical spectrum. I also show that 6355 is most likely a narrow-line active galactic nucleus (AGN) with $M_*\lt 10^9\, \mathrm{M}_\odot$ at z = 7.66 and argue that 10 612 might also have an AGN contribution to its flux through comparison to photoionization models and low-redshift analogues. Under the assumption that the lines come from star formation, I find that the galaxies have gas depletion times of ∼107 yr, comparable to similar galaxies locally. I also identify a population of possibly shock-dominated galaxies at z < 3, whose near-IR emission lines plausibly come nearly all from shocks and discuss their implications. I close with a discussion of the potential for biases in the determination of the mass–metallicity relation using samples defined by detected [O iii]4363 and show using low-z galaxies that this can lead to biases of up to 0.5 dex with a systematic trend with mass.

Brinchmann, Jarle (ORCID:0000000343598797)↗

Levitation Experiments on ISS: Science and Applications

Levitation experiments on the International Space Station (ISS) are ongoing. The European Space Agency (ESA) Materials Science Laboratory Electromagnetic Levitator (MSL-EML) has been in operation since 2015. US investigators are on several of the European Topical Teams and have been heavily involved with the experiments since 2009. The experiments include magneto-hydrodynamic (MHD) modeling of macro-convection, the effects of convection on microstructure, investigation of metallic glass formation, and much more. Recently NASA selected four proposals to the MaterialsLab NASA Research Announcement (NRA) for experiments on the Japan Aerospace eXploration Agency (JAXA) Electrostatic Levitation Furnace (ELF), which was launched to the ISS in 2015. It is estimated that the four US investigators will have flight experiments on ELF within the next few years. The experiments range from a novel method to measure interfacial tension to investigations of thermophysical properties of metals, metal oxides, and non-linear optical materials. Using the MSL-EML and ELF, US investigators are studying a wide range of NASA exploration-relevant materials. Levitation experiments enable exploration in many ways. For example, high quality thermophysical properties of high-temperature materials are critical to develop accurate models of casting, welding, and metal additive manufacturing, which could lead to more efficient and more reliable production of metallic parts for exploration, commercial, and industrial applications. High-quality thermophysical properties could also lead to the development of functional oxide glass and optical materials. In many cases, the accuracy of available property data is the limiting factor in the predictive capabilities of the models. Many thermophysical properties can be measured in a levitator on Earth, but with convective contamination. This contamination plays a significant role in the formation of the intermediate phases. In particular, nucleation and viscosity measurements demand quiescent conditions that can only be attained in microgravity-based levitation systems. A brief overview of the ongoing and planned levitation experiments on the ISS will be presented, followed by the exploration-relevance.

SanSoucie, Michael P.↗

Impact of Urban Pollution on Organic-Mediated New-Particle Formation and Particle Number Concentration in the Amazon Rainforest

A major challenge in assessing the impact of aerosols on climate change is to understand how human activities change aerosol loading and properties relative to the pristine-preindustrial baseline. Here we combine chemical transport simulation and field measurements to investigate the effect of anthropogenic pollution from an isolated metropolis on particle number concentration over the preindustrial-like Amazon rainforest through various new-particle formation (NPF) mechanisms and primary particle emissions. To represent organic-mediated NPF, we employ a state-of-the-art model that systematically simulates the formation chemistry and thermodynamics of extremely low volatility organic compounds as well as their roles in NPF processes, and further update the model to improve organic NPF simulations under human-influenced conditions. Results show that urban pollution from the metropolis increases particle number concentration by a factor of 5–25 over the downwind region (within 200 km from city center) compared to background conditions. Overall, our model indicates that NPF contributes over 70% of the total particle number in the downwind region except immediately adjacent to the sources. Among different NPF mechanisms, the ternary NPF involving organics and sulfuric acid overwhelmingly dominates. The improved understanding of particle formation mechanisms will help better quantify anthropogenic aerosol forcing from pristine-preindustrial times to present day.

54 ENVIRONMENTAL SCIENCES↗