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At least 973 records · Page 54

Cycle life test and failure model of nickel-hydrogen cells

Six ampere hour individual pressure vessel nickel hydrogen cells were charge/discharge cycled to failure. Failure as used here is defined to occur when the end of discharge voltage degraded to 0.9 volts. They were cycled under a low earth orbit cycle regime to a deep depth of discharge (80 percent of rated ampere hour capacity). Both cell designs were fabricated by the same manufacturer and represent current state of the art. A failure model was advanced which suggests both cell designs have inadequate volume tolerance characteristics. The limited existing data base at a deep depth of discharge (DOD) was expanded. Two cells of each design were cycled. One COMSAT cell failed at cycle 1712 and the other failed at cycle 1875. For the Air Force/Hughes cells, one cell failed at cycle 2250 and the other failed at cycle 2638. All cells, of both designs, failed due to low end of discharge voltage (0.9 volts). No cell failed due to electrical shorts. After cell failure, three different reconditioning tests (deep discharge, physical reorientation, and open circuit voltage stand) were conducted on all cells of each design. A fourth reconditioning test (electrolyte addition) was conducted on one cell of each design. In addition post cycle cell teardown and failure analysis were performed on the one cell of each design which did not have electrolyte added after failure. Previously announced in STAR as N83-25038

Smithrick, J. J.↗

A new criterion for failure of materials by environment-induced cracking

A new criterion has been developed for predicting failure of materials by environment-induced cracking. The criterion has been developed by the use of fracture mechanics concepts and assumes that the relationship between crack-growth rate and stress intensity can be described by three separable regions of behavior as first suggested by Wiederhorn. The analytical form of the criterion relates failure time to the initial crack length and the critical crack length or alternatively, to the initial stress intensity and the fracture toughness for various conditions of stress and the environmental variables. The analytical expression is examined by the use of some experimental data on the hydrogen-induced cracking of Ti-5Al-2.5 Sn, and it is demonstrated that the expression predicts the general expected form of the relationship between the normalized stress intensity parameter and the failure time.

Williams, D. P.↗

Thermal-Mechanical Elastic-Plastic and Ductile Failure Model Calibrations for 304L Stainless Steel Alloy

Numerical simulations of metallic structures undergoing rapid loading into the plastic range require material models that accurately represent the response. In general, the material response can be seen as having four interrelated parts: the baseline response under slow loading, the effect of strain rate, the conversion of plastic work into heat and the effect of temperature. In essence, the material behaves in a thermal-mechanical manner if the loading is fast enough so when heat is generated by plastic deformation it raises the temperature and therefore influences the mechanical response. In these cases, appropriate models that can capture the aspects listed above are necessary. The material of interest here is 304L stainless steel, and the objective of this work is to calibrate thermal-mechanical models: one for the constitutive behavior and another for failure. The work was accomplished by first designing and conducting a material test program to provide data for the calibration of the models. The test program included uniaxial tension tests conducted at room temperature, 150 and 300 C and at strain rates between 10 –4 and 10 3 1/s. It also included notched tension and shear-dominated compression hat tests specifically designed to calibrate the failure model. All test specimens were extracted from a single piece of plate to maintain consistency. The constitutive model adopted was a modular $J_2$ plasticity model with isotropic hardening that included rate and temperature dependence. A criterion for failure initiation based on a critical value of equivalent plastic strain fitted the failure data appropriately and was adopted. Possible ranges of the values of the parameters of the models were determined partially on historical data from calibrations of the same alloy from other lots and are given here. The calibration of the parameters of the models were based on finite element simulations of the various material tests using relatively ne meshes and hexahedral elements. When using the model in structural finite element calculations, however, element formulations and sizes different from those in the calibration are likely to be used. A brief investigation demonstrated that the failure initiation predictions can be particularly sensitive to the element selection and provided an initial guide to compensate for the effect of element size in a specific example.

36 MATERIALS SCIENCE↗

Automatic recognition of intermittent failures - An experimental study of field data

A methodology is proposed for recognizing the symptoms of persistent problems in large systems. The system error rate is used to identify the error states among which relationships may exist. Statistical techniques are used to validate and quantify the strength of the relationship among these error states. As input, the approach takes the raw error logs containing a single entry for each error that is detected as an isolated event. As output, it produces a list of symptoms that characterize persistent errors. Thus, given a failure, it is determined whether the failure is an intermittent manifestation of a common fault or whether it is an isolated (transient) incident. The technique is shown to work on two CYBER systems and an IBM 3081 multiprocessor system. Comparisons to real failure/repair information obtained from field engineers show that, in about 85 percent of the cases, the error symptoms recognized by this approach correspond to real problems. The remaining 15 percent of the cases, although not directly supported by field data, are confirmed as being valid problems.

Iyer, Ravishankar K.↗

Reliability and performance experience with flat-plate photovoltaic modules

Statistical models developed to define the most likely sources of photovoltaic (PV) array failures and the optimum method of allowing for the defects in order to achieve a 20 yr lifetime with acceptable performance degradation are summarized. Significant parameters were the cost of energy, annual power output, initial cost, replacement cost, rate of module replacement, the discount rate, and the plant lifetime. Acceptable degradation allocations were calculated to be 0.0001 cell failures/yr, 0.005 module failures/yr, 0.05 power loss/yr, a 0.01 rate of power loss/yr, and a 25 yr module wear-out length. Circuit redundancy techniques were determined to offset cell failures using fault tolerant designs such as series/parallel and bypass diode arrangements. Screening processes have been devised to eliminate cells that will crack in operation, and multiple electrical contacts at each cell compensate for the cells which escape the screening test and then crack when installed. The 20 yr array lifetime is expected to be achieved in the near-term.

Ross, R. G., Jr.↗

Reliability Issues with PME and BME Ceramic Capacitors

This work is a review of reliability issues specific for low-voltage precious metal electrode (PME) and base metal electrode (BME) multilayer ceramic capacitors (MLCC). A special attention is given to degradation and failures in capacitors with defects, in particular with cracks. Temperature and voltage reliability acceleration factors have been calculated based on approximation of distributions of degradation rates of leakage currents using a general log-linear Weibull model. Results show a substantial difference in behavior of BME and PME capacitors with defects. Mechanisms of degradation and failures in humid and dry environments and risks of overstressing capacitors during highly accelerated life testing (HALT) are discussed.

Teverovsky, Alexander↗

Leak Rate Performance of Silicone Elastomer O-Rings Contaminated with JSC-1A Lunar Regolith Simulant

Contamination of spacecraft components with planetary and foreign object debris is a growing concern. Face seals separating the spacecraft cabin from the debris filled environment are particularly susceptible; if the seal becomes contaminated there is potential for decreased performance, mission failure, or catastrophe. In this study, silicone elastomer O-rings were contaminated with JSC- 1A lunar regolith and their leak rate performance was evaluated. The leak rate values of contaminated O-rings at four levels of seal compression were compared to those of as-received, uncontaminated, O-rings. The results showed a drastic increase in leak rate after contamination. JSC-1A contaminated O-rings lead to immeasurably high leak rate values for all levels of compression except complete closure. Additionally, a mechanical method of simulant removal was examined. In general, this method returned the leak rate to as-received values.

leak rate↗

Polysulfide entrapment and retardation in gel electrolyte Li–S batteries: experiments and modeling

Gelling the electrolyte in lithium–sulfur (Li–S) batteries provides advantages in terms of safety and mitigating polysulfide shuttling leading to reduced side reactions and dendrite growth on the anode side. In the current study, organic and ceramic crosslinkers have been used to improve the entrapment of polysulfides and prevent them from shuttling to the anode side. However, the performance of gel electrolytes is still far from being on par with liquid electrolytes in terms of raw capacity. The discharge curves exhibit an extended first plateau for gel electrolyte batteries compared to liquid electrolytes, showing that polysulfides are better trapped in the gel system. Yet, in the conversion of soluble polysulfides into insoluble polysulfides, the second plateau was delayed. Qualitative and quantitative analysis of the polysulfide diffusion in the liquid electrolyte and gel electrolyte systems were also conducted to predict the relative diffusivity ratio between the liquid electrolyte and gel electrolyte for simulation. To probe what happens at the end of the discharge, where the mass transport in the gel electrolyte appears to be slow, a modified discharge procedure was used where the cell is first paused after discharge and then discharged a second time before recharging normally. Coin cell tests for two gel electrolytes in addition to liquid electrolyte show up to 7% capacity recovery after the pause, which indicates that the diffusion of species during the pause is responsible for the failure recovery. Additionally, the recovery is higher for gel electrolytes compared to liquid, for higher C-rates, and for longer pause times. To better understand this behavior, a Li–S numerical model with mass transport limited reactions was used to examine the polysulfide diffusion coefficients expected in different electrolyte systems. The model is able to reproduce the trends seen in experiments and yields a higher recovery for smaller Li 2 S 4 diffusion coefficients, suggesting that insufficient Li 2 S 4 mass transport is responsible for failure at the end of discharge. By identifying the effect that gel electrolytes have on the state of the battery during discharge using both experimental and simulation methods, this work is a step towards leveraging the advantages of gel electrolytes and mitigating their weaknesses.

25 ENERGY STORAGE↗

Critical design load case fatigue and ultimate failure simulation for a 10-m H-type vertical-axis wind turbine

While previous studies investigating critical VAWT design load cases have focused on large and relatively flexible Darrieus designs, the bulk of current commercial products seeking certification fall in the relatively small, stiff, and H-type configuration, such as the XFlow Energy Corporation turbine that this study compares against. Understanding the critical design load case impacts for both fatigue and ultimate failure for this size and type of VAWT are imperative for certification. The abil

Brownstein, Ian↗

NASA’s Identified Risks of Adverse Outcomes Due to Inadequate Human Systems Integration Architecture in Human Spaceflight

The NASA Human System Risk Board (HSRB) has the overall responsibility for tracking the evolution of the top ~30 human system risks that it has identified to be associated with human spaceflight. As part of this process, the Board is charged with maintaining a consistent, integrated process to mitigate those risks, and developing evidence-based risk posture recommendations. One of the identified risks is due to inadequate human systems integration architecture (HSIA) and a driving factor of this risk is that given decreasing real-time ground support for execution of complex operations during future exploration missions, there is a possibility of adverse performance outcomes including that crew are unable to adequately respond to unanticipated critical malfunctions or detect safety critical procedural errors. The HSRB uses Directed Acyclic Graphs (DAGs) as a communication tool for describing how astronaut exposure to spaceflight hazards leads to meaningful mission-level health and performance outcomes and as the basis for understanding intermediate causal relationships between risk contributing factors and countermeasures that link hazards to outcomes. The HSIA risk DAG will be presented and described. Historically, critical malfunctions requiring Crew/MCC management occurred at a rate of 1.7 times per year for ISS averaged over the lifetime and 3-4 times per year in the burn in phase for the vehicle. These averages do not include EVA data, which greatly increases the incident rate. Prior experience from the Apollo program showed 10/11 crewed missions experienced significant anomalies where crew relied heavily on MCC expertise in real-time. These failure patterns are in line with those observed in other complex engineered systems (e.g., oil rigs, launch systems, commercial aviation, etc.) It is likely that general malfunction and error rates are > 10% for short duration missions (<30 days), based on past and current spaceflight operations data. Likelihood of adverse outcomes has the potential to increase as crew conduct work with new, complex systems and with less ground support. For Low Earth Orbit missions and Lunar missions less than 30 days, assuming minimal comm delays, disruptions and bandwidth limitations, malfunctions and errors can affect mission objectives and crew health but may be mitigated by ground support. For Lunar missions greater than 30 days and any potential Mars mission malfunctions and errors can have Loss of Crew and Loss of Mission consequences due to reduced ground support (communication delays, constraints and blackouts) for more complex operations, as well as reduced resupply and evacuation options.

Daniel M Buckland↗

Classification of Photovoltaic Failures with Hidden Markov Modeling, an Unsupervised Statistical Approach

Failure detection methods are of significant interest for photovoltaic (PV) site operators to help reduce gaps between expected and observed energy generation. Current approaches for field-based fault detection, however, rely on multiple data inputs and can suffer from interpretability issues. In contrast, this work offers an unsupervised statistical approach that leverages hidden Markov models (HMM) to identify failures occurring at PV sites. Using performance index data from 104 sites across the United States, individual PV-HMM models are trained and evaluated for failure detection and transition probabilities. This analysis indicates that the trained PV-HMM models have the highest probability of remaining in their current state (87.1% to 93.5%), whereas the transition probability from normal to failure (6.5%) is lower than the transition from failure to normal (12.9%) states. A comparison of these patterns using both threshold levels and operations and maintenance (O&M) tickets indicate high precision rates of PV-HMMs (median = 82.4%) across all of the sites. Although additional work is needed to assess sensitivities, the PV-HMM methodology demonstrates significant potential for real-time failure detection as well as extensions into predictive maintenance capabilities for PV.

classification↗

A High-Voltage High-Current Benchtop Test Stand for Solid-State Switch Testing at the SNS

Solid-state switches already replaced thyratrons in the SNS extraction kicker power supplies, offering improved efficiency and reliability. However, recent supply chain disruptions, combined with a self-firing issue, led us to explore alternative solutions. A vendor-developed MOS-Gated Thyristor switch was introduced but ultimately failed during testing. To investigate the failure and assess possible improvements, a benchtop test stand was constructed to evaluate the performance of a single stage board. This test stand features a Pulse Forming Network (PFN) that operates at 6 kV and 6 kA, with a repetition rate exceeding 60 Hz, simulating real operational conditions. By utilizing this setup, we seek to gain a better understanding of the failure mechanisms, refine the switch designs, and ultimately develop a more reliable alternative for the extraction kicker power supplies.

Bullman, Austin [ORNL]↗

BISON validation of FeCrAl cladding mechanical failure during simulated reactivity-initiated accident conditions*

Here, a reactivity-initiated accident (RIA) is a postulated design basis accident in light water reactors (LWRs) in which a rapid reactivity insertion induces a fission rate increase and a fuel pellet temperature rise. During RIA, the fuel pellet thermally expands and may cause pellet-cladding mechanical interaction (PCMI). Separate effects PCMI tests were performed on C26M FeCrAl cladding tube samples, introducing biaxial stress via a well understood modified burst test (MBT) system. A high-speed camera in the MBT system captured the projections, covering a 360° view of the cladding deformation and enabling a digital image correlation (DIC) method to quantify the surface strains with high fidelity. Representative hot zero-power RIA mechanical loading conditions were applied to the sample, and the test duration ranged from 20 to 500 ms at an average temperature of 573 K. BISON finite element–based fuel performance code modeling was performed against the high-fidelity DIC data produced from the MBTs. Validation calculations were conducted with 2D models and systematically compared with test data of the burst time, burst pressure, burst hoop strains, and hoop strain rates. Based on the behaviors from the separate effects test, BISON calculations satisfactorily predicted the cladding deformation behaviors. Sensitivity analysis was conducted to identify highly influential mechanical properties responsible for the cladding failure behavior during the MBT experiments. The results highlight the significance of the cladding's mechanical strength in governing cladding strain, followed by the significance of the mechanical interactions between the pellet and the cladding.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Testing of Gyroless Estimation Algorithms for the FUSE Spacecraft

The Far Ultraviolet Spectroscopic Explorer (FUSE) is equipped with two ring laser gyros on each of the spacecraft body axes. In May 2001 one gyro failed. It is anticipated that all of the remaining gyros will also fail based on intensity warnings. In addition to the gyro failure, two of four reaction wheels failed in late 2001. The spacecraft control now relies heavily on magnetic torque to perform the necessary science maneuvers and hold on target. The only sensor consistently available during slews is a magnetometer. This paper documents the testing and development of magnetometer-based gyroless attitude and rate estimation algorithms for FUSE. The results of two approaches are presented, one relies on a kinematic model for propagation, a method used in aircraft tracking, and the other is a pseudo-linear Kalman filter that utilizes Euler's equations in the propagation of the estimated rate. Both algorithms are tested using flight data collected over a few months before and after the reaction wheel failure. Finally, the question of closed-loop stability is addressed. The ability of the controller to meet the science slew requirements, without the gyros, is tested through simulations.

Thienel, Julie↗

Multiscale electro-chemo-mechanical model of high-capacity amorphous silicon anode material in sodium-ion batteries

The growing interest in sodium-ion batteries (SIBs) is fueled by their abundant resources and environmentally friendly nature, with amorphous silicon (a-Si) emerging as a promising anode material for enhancing capacity. However, the key challenge lies in sustaining reversible capacity during cycling. Here, in this work, we developed a multiscale electrochemical model incorporating an a-Si anode to elucidate the performance parameters of SIBs. Additionally, we integrated an electro-chemo-mechanical model at the particle level to capture stress generation, an essential factor in the degradation of high-capacity electrodes. Unlike existing models, our approach accounts for large-deformation chemo-mechanics at the particle scale and includes simulations under varying charge rates to explore multiscale behavior. The results reveal that coupled sodiation significantly prolongs complete cycling times and influences discharge dynamics, indicating that neglecting this coupling leads to an underestimation of actual capacity. Furthermore, we observed pronounced polarization effects at higher charge rates, resulting in heterogeneous stress distributions across the anode. With the identification of critical failure parameters for both active particles and binder materials, offering novel insights for mitigating degradation in high-capacity electrode systems.

Amorphous silicon anode↗

Comparing the deformation mechanism in 316 L stainless steel fabricated by hybrid and additive manufacturing

This study rationalizes the relatively higher elongation with minimal strength drop of 316L stainless steel (316LSS) manufactured using the hybrid approach in comparison to a fully additive approach followed by machining. It was found that twinning was the dominant deformation mechanism in 316LSS produced by both additive and hybrid approaches. Additionally, the relatively lower fraction of twins in the as-fabricated state of hybrid approach compared to a fully additive approach resulted in delaying the onset of steady-state strain hardening rate to higher strain levels, thereby resulting in an overall increase in elongation to failure.

36 MATERIALS SCIENCE↗

Limiting Rotation Rate of Neutron Stars from Crust Breaking and Gravitational Waves

Abstract Neutron stars are not observed to spin faster than about half their breakup rate. This limiting rotational frequency may be related to the strength of their crusts. As a star spins up from accretion, centrifugal forces stress the crust. We perform finite-element simulations of rotating neutron stars and find that the crust fails at rotation rates about half the breakup rate. Given uncertainties in microphysics, we have not determined the crust configuration after this failure. Instead, we argue that the crust may fail in an asymmetric way and could produce a configuration with a significant ellipticity (fractional difference in moments of inertia). If the ellipticity is large, a rotating star will radiate gravitational waves that may limit further spin-up. These stars may be promising sources for LIGO/VIRGO and next-generation gravitational-wave detectors.

Morales, J. A.↗