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At least 973 records · Page 54

Data from Ethanol Production from Corn Fiber Separated after Liquefaction in the Dry Grind Process

Conversion of corn fiber to ethanol in the dry grind process can increase ethanol yields, improve coproduct quality and contribute to process sustainability. This work investigates the use of two physio-chemical pretreatments on corn fiber and effect of cellulase enzyme dosage to improve ethanol yields. Fiber separated after liquefaction of corn was pretreated using (1) hot water pretreatment (160°C for 5, 10 or 20 min); and (2) wet disk milling and converted to ethanol. The conversion efficiencies of hot water pretreated fiber were higher than untreated fiber, with highest increase in conversion (10.4%) achieved for 5-minute residence time at 160 °C. Disk milling was not effective in increasing conversion compared to other treatments. Hydrolysis and fermentation of untreated fiber with excess cellulase enzymes resulted in 33.3% higher conversion compared to untreated fiber. Note: in “Table1_Treatments.csv”, NA = Not applicable.

Conversion↗

Toward inverse backscatter absorption gas imaging: imaging a dry gas plume with ambient H 2 O absorption

This paper introduces inverse backscatter absorption gas imaging (iBAGI), a transparent gas imaging technique based on absorption spectroscopy of gases naturally present in ambient air being displaced by transparent gases. We demonstrate reconstruction of a 2-D image of a dry gas plume by measuring light of a raster-scanned diode laser tuned to an absorption line of atmospheric H 2 O. We quantify the performance depending on the distance to the backdrop and show that the key transmission metric is independent of absorption path length. We conclude with an outlook toward calibration-free, single-ended iBAGI using scattering from low-reflectivity backdrops.

Klug, Joseph C.↗

Dry etching of epitaxial InGaAs/InAlAs/InAlGaAs structures for fabrication of photonic integrated circuits

A dry etching process to transfer the pattern of a photonic integrated circuit design for high-speed laser communications is described. The laser stack under consideration is a 3.2-µm-thick InGaAs/InAlAs/InAlGaAs epitaxial structure grown by molecular beam epitaxy. The etching was performed using Cl2-based inductively-coupled-plasma and reactive-ion-etching (ICP-RIE) reactors. Four different recipes are presented in two similar ICP-RIE reactors, with special attention paid to the etched features formed with various hard mask compositions, in-situ passivations, and process temperatures. The results indicate that it is possible to produce high-aspect-ratio features with sub-micron separation on this multilayer structure. Additionally, the results of the etching highlight the tradeoffs involved with the corresponding recipes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhancing the performance of solvent-borne poly(ethyl methacrylate) coatings for high-power laser applications via low-temperature drying

Organic polymers are a versatile class of materials employed in a broad range of optical coating applications. However, their use as coatings in high-power laser applications, particularly in the UV spectral region, has been limited in scope due to their relatively low laser-induced damage thresholds (LIDTs), which decrease further with exposure to multiple pulses. This study explores the effect of post-deposition drying temperature and residual solvent on the LIDT of solvent-borne polymer coatings. In this work, poly(ethyl methacrylate) (PEMA) coatings were deposited by first spin coating solutions of PEMA (dissolved in 2,2,2-trichloroethanol (TCE)) onto fused silica substrates, then baking at temperatures of either 130°C (soft-bake) or 180°C (hard-bake). Analysis of the two coatings revealed that the soft-bake coating retained a significant amount of TCE within the polymer matrix, which functioned to plasticize the coating and reduce internal stress. The laser-induced damage resistance of the two coatings was evaluated using 351-nm, 1-ns laser pulses. The testing protocols included single-pulse (1-on-1), 1-pulse ramp (R-on-1), and a 1000-pulse ramp (1000R-on-1) test. The results showed that the plasticized, soft-bake coating exhibits a significantly increased LIDT, especially for multipulse irradiation conditions.

36 MATERIALS SCIENCE↗

Selection signatures in four lignin genes from switchgrass populations divergently selected for in vitro dry matter digestibility

Switchgrass is undergoing development as a dedicated cellulosic bioenergy crop. Fermentation of lignocellulosic biomass to ethanol in a bioenergy system or to volatile fatty acids in a livestock production system is strongly and negatively influenced by lignification of cell walls. This study detects specific loci that exhibit selection signatures across switchgrass breeding populations that differ in in vitro dry matter digestibility (IVDMD), ethanol yield, and lignin concentration. Allele frequency changes in candidate genes were used to detect loci under selection. Out of the 183 polymorphisms identified in the four candidate genes, twenty-five loci in the intron regions and four loci in coding regions were found to display a selection signature. All loci in the coding regions are synonymous substitutions. Selection in both directions were observed on polymorphisms that appeared to be under selection. Genetic diversity and linkage disequilibrium within the candidate genes were low. The recurrent divergent selection caused excessive moderate allele frequencies in the cycle 3 reduced lignin population as compared to the base population. As a result, this study provides valuable insight on genetic changes occurring in short-term selection in the polyploid populations, and discovered potential markers for breeding switchgrass with improved biomass quality.

09 BIOMASS FUELS↗

Permafrost Thaw, Uneven Subsidence and Projected Drying of Ice-wedge Polygon Tundra: Modeling Archive

This dataset is a model archive of the paper Permafrost Thaw, Uneven Subsidence and Projected Drying of Ice-wedge Polygon Tundra (in prep) to support a modeling study investigating how projected increases in Arctic temperature and precipitation will jointly influence hydrologic conditions in ice-rich tundra landscapes. With this dataset, this study is to address the research question: Will Arctic tundra landscapes become wetter or drier with increasing precipitation and temperature in the future when thaw-induced ground subsidence and associated microtopographic evolution are represented? The simulations focus on ice-wedge polygon tundra, a widespread form of ice-rich permafrost terrain that is highly sensitive to thaw-driven landscape change. This dataset contains model input and output data for four study watersheds in Alaska: Anaktuvuk, Utqiagvik (formerly Barrow), Brooks Foothills, and Prudhoe Bay. Simulations were performed using the Advanced Terrestrial Simulator (ATS, v1.5), a physics-rich integrated surface–subsurface hydrologic model. For each watershed, ten modeling cases were performed representing two landscape evolution conditions (with subsidence and without subsidence) combined with five climate forcing scenarios derived from Shared Socioeconomic Pathways (SSP5, SSP5 with precipitation trend, SSP2, SSP2 with precipitation trend, and SSP2 with double precipitation trend). Particularly, for each watershed under the forcing SSP2 with precipitation trend, there are two additional simulations considering spatially heterogeneous subsidence distributions: one assumes randomly distributed scaling and the other includes elevation dependent distribution scaling. These simulations span 1980–2099 and include spin-up runs (1980–2009) followed by transient projections (2010–2099). To facilitate reproducibility of simulations, all datasets are organized by watershed. For each study watershed, the dataset contains: (1) Pre-partitioned mesh files for 32-core modeling (.par.32.XX), located in EACH_WATERSHED/mesh/basin; and also a non-partitioned mesh file (.exo) located in EACH_WATERSHED/mesh; (2) Climate forcings corresponding to the five SSP scenarios (.h5), located in EACH_WATERSHED/data; (3) Final states (.h5) from column spin-up modeling used to initialize historical watershed-scale spin-up runs from 1980 to 2009, located in EACH_WATERSHED/PreSpinupHistorical; (4) Final states (.h5) of historical watershed-scale spin-up runs from 1980 to 2009 used to initialize projection runs, located in EACH_WATERSHED/Spinup_daymetERA5; (5) ATS modeling input files (.xml), located in EACH_WATERSHED/EACH_SIMULATION_SCENARIO/inputfiles; (6) ATS modeling output files (.dat), located in in EACH_WATERSHED/EACH_SIMULATION_SCENARIO/combined_obs; (7) For the Brooks Foothills watershed, additional spatial model outputs are provided (.h5) for selected years (2033 and 2093) used to generate spatial figures in this study, located in Brooksfoothills/EACH_SIMULATION_SCENARIO/results-WITH/WITHOUT_SUBSIDENCE-year2033/2093. All data files with suffix .h5 can be accessible through Python h5py, and all data files with suffix of .dat can be imported by Python pandas. Mesh file with .exo can be visualized through Paraview or read by Python netCDF. The Next-Generation Ecosystem Experiments in the Arctic (NGEE Arctic) project is a research effort to reduce uncertainty in the Department of Energy’s Energy Exascale Earth System Model (E3SM) by developing a predictive understanding of Arctic tundra ecosystems underlain by permafrost and to quantify feedbacks from the Arctic tundra to the Earth system. NGEE Arctic is supported by the Department of Energy's Office of Biological and Environmental Research. Over Phases 1–3, observations made by the NGEE Arctic team across a gradient of permafrost landscapes in Arctic Alaska improved the representation of tundra processes in the land surface component of E3SM (the E3SM Land Model, ELM). Model improvements emphasized unique aspects of permafrost environments and explored reductions in model complexity while retaining predictive power. The Arctic-informed ELM developed by NGEE Arctic has been used to make novel predictions on processes ranging from permafrost thaw to soil biogeochemical cycling to Earth system feedbacks associated with the unique characteristics of tundra plants. In Phase 4, the NGEE Arctic team is evaluating our new predictive understanding under novel conditions across the Arctic domain. In collaboration with partners at long-term pan-Arctic research sites we are examining whether an Arctic-informed ELM can faithfully simulate interactions among surface and subsurface processes at site, regional, and pan-Arctic scales. In turn, we are using variety of tools to dynamically extend and evaluate ELM inference, with an emphasis on data synthesis and pan-Arctic model evaluation, reintegration of code with an evolving E3SM, scaling across heterogeneous Arctic landscapes, and the appropriate representation of the impacts of increasingly frequent Arctic disturbances.

EARTH SCIENCE > ATMOSPHERE > PRECIPITATION↗

A two-scale study on the influence of biopolymer enhancement on drying granular materials

Cracking resulting from drying (constrained dehydration) poses a significant challenge in geomaterials, impacting their mechanical performance. To address this problem, extensive efforts have been made to prevent or mitigate the occurrence of cracks, with recent attention focused on the utilisation of biopolymers. This letter investigates the influence of varying concentrations of the xanthan biopolymer on the mechanical response of granular materials, examining both macro and micro scales. The strength changes of the soil were evaluated through desiccation experiments, analysing the appearance and progression of failure on the macro scale. The findings of this study demonstrate that failure (cracking) progression is mitigated and eventually eliminated by increasing the concentration of the additive xanthan. Additionally, capillary experiments were conducted to assess the changes in attraction and the development of capillary bridges on the micro-scale. They indicate that the formation of hydrogel bridges significantly enhances particle attraction, thereby increasing its macro-resistance to cracking.

Engineering↗

AmeriFlux MX-Tes Tesopaco, secondary tropical dry forest

This is the AmeriFlux version of the carbon flux data for the site MX-Tes Tesopaco, secondary tropical dry forest. Site Description - This tower was located in the "Ejido la Estrella" where the eddy covariance tower is located 7.5 km east of the town Rosario de Tesopaco, in southeastern Sonora, Mexico. The tower was positioned in the center of a homogeneous flat terrain at the foothills of the Madre Occidental. This ecosystem lies in a highly seasonal region under the influence of the North American Monsoon that brings about 70% of the rains from July to September. The site is dominated by leguminous trees. Some of the dominant species are Lysiloma divaricatum, Ipomoea arborescens, Acacia cochliacantha, Haematoxylum brasiletto, and Celtis reticulata. The mean basal area at the study site is 14.83 ± 3.3m2 ha-1, and the aboveground biomass is estimated to be 43.20±9.5Mgha-1. These values and the high counts of Acacia cochliacantha indicate that the area is a secondary forest with significant management activities in the past.

Yepez, Enrico A.↗

Spatially Dependent Seismic Wavefield Scattering from an Underground Chemical Explosion: Analysis of the Source Physics Experiment Dry Alluvium Geology Large- N Array

Explosion sources have been observed to generate significant shear‐wave energy despite their isotropic nature. To investigate this phenomenon, we conduct an analysis of the seismic data collected as part of the Source Physics Experiment (SPE): Dry Alluvium Geology (DAG) and investigate the generation of shear‐wave energy via scattering. The data were produced by three underground chemical explosions and consist of three‐component seismograms, which were recorded by the DAG Large‐N array. Synthetic tests suggest that for the DAG experiments, small‐scale stochastic heterogeneities, defined as features with correlation lengths of 10–100s of meters, are more effective than large‐scale geologic structure (scales >1–10 km) at reproducing the scattering of explosion generated wavefields observed at DAG. We analyze the seismic data for spatially variable ratios between transversely and radially polarized seismic energy, and then estimate the mean free path of P and S waves. All analyses are conducted within a frequency band of 5–50 Hz. The ratio of transversely to radially polarized energy is the highest in the east and west portion of the Large‐N array. In addition, the magnitude of the estimated S‐wave mean free path is shorter in the eastern portion of the Large‐N array. This variation indicates that the eastern area of the DAG array is where more scattering is occurring, suggesting azimuthal dependence of P‐to‐P and P‐to‐S scattering. Furthermore, this azimuthal dependence of P‐to‐S scattering can have implications for explosion discrimination based on spectral ratios of seismic wave types, because the general assumption is that explosions do not generate shear‐wave energy. Synthetic tests modeling only larger‐scale geologic structure had lower transversely polarized energy (only four stations showing a transversely to radially polarized energy ratio greater than 1) and fewer stations (<10) displaying shorter (<300 m) mean free paths than what was observed in the DAG data results.

Darrh, Andréa Nicole↗

Characterization of inter-seasonal climatic variability through dry-season rice productivity in the north-west region of Bangladesh

Inter-annual climatic variability in Bangladesh is critical and the probability of occurrence of extreme episodic/ climatic events has increased in the last couple of decades and thus threatening food security. Impact of inter-seasonal climatic va riability on Boro rice (dry season) yield in north-western parts of Bangladesh was analyzed using the historic weather datasets for 1971 to 2010 and MAKESENS model. Boro rice yield increased from 1980 onwards and the growth rate picked up with time. Inter-annual and inter-seasonal climatic variability was noticed through maximum and minimum temperatures, rainfall and sunshine hours. Typically, temperatures and rainfall showed increasing trends but sunshine hours were decreasing gradually during the study period. Growth rates in average annual maximum, minimum and mean air temperatures were 0.001, 0.016 and 0.009°C year-1, respectively. On regional scale, Boro-rice seasonal maximum temperature was decreasing by 0.013°C year-1 yet minimum and mean temperatures were increasing by 0.024 and 0.006°C year-1, respectively. Annual average sunshine hours in the study location were in decreasing trend by 0.027 hr year-1, but reduction in seasonal sunshine hours was 0.035 hr year-1. Inter-seasonal climatic variability was characterized through the Boro-rice yields in four test regions of north-west region of Bangladesh. Trend line equations were evolved for assessing the impact of climatic variations on Bororice yield. If maximum temperature changes by 1oC, Boro rice yield could be increased by 0.13 t ha-1, but it would reduce by 0.34 t ha-1 with one degree rise in minimum temperature. If sunshine hour decreases by 1 hr, Boro rice yield would decrease by 0.70 t ha-1 in study locations. Combined effects of maximum and minimum temperatures and sunshine hours showed significant influence on grain yields of Boro rice. These imply that temperature tolerant and solar radiation use-efficient rice varieties need to be bred for combating climate change impact in Bangladesh. There is a need to identify optimum sowing/transplanting window for the region, choice of suitable cultivars/ideo-types, and adoption of appropriate water and nutrients management strategies and adoption of appropriate resource conservation technologies for sustainable Boro rice production in Bangladesh.

54 ENVIRONMENTAL SCIENCES↗

Analysis of Dose Consequences Arising from the Release of Spent Nuclear Fuel from Dry Storage Casks

The resulting dose consequences from releases of spent nuclear fuel (SNF) residing in a dry storage casks are examined parametrically. The dose consequences are characterized by developing dose versus distance curves using simplified bounding assumptions. The dispersion calculations are performed using the MELCOR Accident Consequence Code System (MACCS2) code. Constant weather and generic system parameters were chosen to ensure that the results in this report are comparable with each other and to determine the relative impact on dose of each variable. Actual analyses of site releases would need to accommodate local weather and geographic data. These calculations assume a range of fuel burnups, release fractions (RFs), three exposure scenarios (2 hrs and evacuate, 2 hrs and shelter, and 24 hrs exposure), two meteorological conditions (D-4 and F-2), and three release heights (ground level – 1 meter (m), 10 m, and 100 m). This information was developed to support a policy paper being developed by U.S. Nuclear Regulatory Commission (NRC) staff on an independent spent fuel storage installation (ISFSI) and monitored retrievable storage installation (MRS) security rulemaking.

Durbin, Samuel G.↗

Data sharing report characterization of population 7: Personal protective equipment, dry active waste, and miscellaneous debris, surveillance and maintenance project Oak Ridge National Laboratory Oak Ridge, Tennessee

The U.S. Department of Energy (DOE) Oak Ridge Office of Environmental Management (EM-OR) requested that Oak Ridge Associated Universities (ORAU), working under the Oak Ridge Institute for Science and Education (ORISE) contract, provide technical and independent waste management planning support under the American Recovery and Reinvestment Act (ARRA). Specifically, DOE EM-OR requested that ORAU plan and implement a sampling and analysis campaign targeting certain URS|CH2M Oak Ridge, LLC (UCOR) surveillance and maintenance (S&M) process inventory waste. Eight populations of historical and reoccurring S&M waste at the Oak Ridge National Laboratory (ORNL) have been identified in the Waste Handling Plan for Surveillance and Maintenance Activities at the Oak Ridge National Laboratory, DOE/OR/01-2565&D2 (WHP) (DOE 2012) for evaluation and processing to determine a final pathway for disposal. Population 7 (POP 7) consists of 56 containers of aged, low-level and potentially mixed S&M waste that has been staged in various locations around ORNL. Several of these POP 7 containers primarily contain personal protective equipment (PPE) and dry active waste (DAW), but may contain other miscellaneous debris. This data sharing report addresses the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) specified waste in a 13-container subpopulation (including eight steel boxes, three 55-gal drums, one sealand, and one intermodal) that lacked sufficient characterization data for possible disposal at the Environmental Management Waste Management Facility (EMWMF) using the approved Waste Lot (WL) 108.1 profile.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Structural Sensitivity of Dry Storage Canisters

This LS-DYNA modeling study evaluated a generic used nuclear fuel vertical dry storage cask system under tip-over, handling drop, and seismic load cases to determine the sensitivity of the canister containment boundary to these loads. The goal was to quantify the expected failure margins to gain insight into what material changes over the extended long-term storage lifetime could have the most influence on the security of the containment boundary. It was determined that the tip-over case offers a strong challenge to the containment boundary, and identifies one significant material knowledge gap, the behavior of welded stainless steel joints under high-strain-rate conditions. High strain rates are expected to increase the material’s effective yield strength and ultimate strength, and may decrease its ductility. Determining and accounting for this behavior could potentially reverse the model prediction of a containment boundary failure at the canister lid weld. It must be emphasized that this predicted containment failure is an artifact of the generic system modeled. Vendor specific designs analyze for cask tip-over and these analyses are reviewed and approved by the Nuclear Regulatory Commission.

Klymyshyn, Nicholas A.↗

Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal (Final Technical Report)

The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

01 COAL, LIGNITE, AND PEAT↗

Performance of a Hot-Dry Climate Whole-House Retrofit

The Stockton house retrofit is a two-story tudor style single family deep retrofit in the hot-dry climate of Stockton, CA. The home is representative of a deep retrofit option of the scaled home energy upgrade packages offered to targeted neighborhoods under the pilot Large-Scale Retrofit Program (LSRP) administered by the Alliance for Residential Building Innovation (ARBI). Deep retrofit packages expand on the standard package by adding HVAC, water heater and window upgrades to the ducting, attic and floor insulation, domestic hot water insulation, envelope sealing, lighting and ventilation upgrades. Site energy savings with the deep retrofit were 23% compared to the pre-retrofit case, and 15% higher than the savings estimated for the standard retrofit package. Energy savings were largely a result of the water heater upgrade, and a combination of the envelope sealing, insulation and HVAC upgrade. The HVAC system was of higher efficiency than the building code standard. Overall the financed retrofit would have been more cost effective had a less expensive HVAC system been selected and barriers to wall insulation remedied. The homeowner experienced improved comfort throughout the monitored period and was satisfied with the resulting utility bill savings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗