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At least 973 records · Page 54

Super-Resolution Airy Disk Microscopy of Individual Color Centers in Diamond

Super-resolution imaging techniques enable nanoscale microscopy in fields such as physics, biology, and chemistry. However, many super-resolution techniques require specialized optical components, such as a helical-phase mask. In this work, we present a novel technique, super-resolution Airy disk microscopy, that can be used in a standard confocal microscope without any specialized optics. We demonstrate this technique, in combination with ground state depletion, to image and control nitrogen-vacancy (NV) centers in bulk diamond below the diffraction limit. A greater than 14-fold improvement in resolution compared to the diffraction limit is achieved, corresponding to a spatial resolution of 16.9(8) nm for a 1.3 NA microscope with 589 nm light. We make use of our enhanced spatial resolution to control the spins states of individual NV centers separated from each other by less than the diffraction limit, including pairs sharing the same orientation that are indistinguishable with a conventional electron spin resonance measurement.

36 MATERIALS SCIENCE↗

All-optical reconfiguration of single silicon-vacancy centers in diamond for non-volatile memories

Strain engineering is vital for tuning the optical and spin properties of solid-state color centers, enhancing spin coherence and compensating emission wavelength shift. Here, we develop an all-optical approach to directly modify the local strain of color centers at the nanoscale by migrating the nearby defect. High-power pulsed optical irradiation triggers defect migration, which subsequently leads to the redistribution of the local crystal lattice of the host material. This redistribution alters the strain experienced by nearby color centers. Using silicon-vacancy centers in diamond, we validate this method and demonstrate a ground state splitting enhancement of up to 1.8 THz. Unlike conventional methods, our approach requires no external fields or nanostructure modifications, enabling non-volatile strain control and optical memory functionality across wide temperature ranges. Its local, permanent nature offers a scalable path for enhancing spin coherence in large-scale quantum systems and has potential applications in photonic machine learning.

Nanoscale devices↗

Diamond detector for high rate monitors of fast neutrons beams

A fast neutron detection system suitable for high rate measurements is presented. The detector is based on a commercial high purity single crystal diamond (SDD) coupled to a fast digital data acquisition system. The detector was tested at the ISIS pulsed spallation neutron source. The SDD event signal was digitized at 1 GHz to reconstruct the deposited energy (pulse amplitude) and neutron arrival time; the event time of flight (ToF) was obtained relative to the recorded proton beam signal t{sub 0}. Fast acquisition is needed since the peak count rate is very high ({approx}800 kHz) due to the pulsed structure of the neutron beam. Measurements at ISIS indicate that three characteristics regions exist in the biparametric spectrum: i) background gamma events of low pulse amplitudes; ii) low pulse amplitude neutron events in the energy range E{sub dep}= 1.5-7 MeV ascribed to neutron elastic scattering on {sup 12}C; iii) large pulse amplitude neutron events with E{sub n} < 7 MeV ascribed to {sup 12}C(n,{alpha}){sup 9}Be and 12C(n,n')3{alpha}.

43 PARTICLE ACCELERATORS↗

Characterization of single crystal chemical vapor deposition diamond detectors for neutron spectrometry

Detectors made from artificial chemical vapor deposition single crystal diamond have shown great potential for fast neutron spectrometry. In this paper, we present the results of measurements made at the Physikalisch-Technische Bundesanstalt accelerator using neutron fields in the energy range from 7 MeV to 16 MeV. This study presents the first results of the characterization of the detector in this energy range.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Electron spin resonance shift and linewidth broadening of nitrogen-vacancy centers in diamond as a function of electron irradiation dose

A high-nitrogen-concentration diamond sample was subjected to 200-keV electron irradiation using a transmission electron microscope. The optical and spin-resonance properties of the nitrogen-vacancy (NV) color centers were investigated as a function of the irradiation dose up to 6.4 Multiplication-Sign 10{sup 21} e{sup -}/cm{sup 2}. The microwave transition frequency of the NV{sup -} center was found to shift by up to 0.6% (17.1 MHz) and the linewidth broadened with increasing electron-irradiation dose. Unexpectedly, the measured magnetic sensitivity is best at the lowest irradiation dose, even though the NV concentration increases monotonically with increasing dose. This is in large part due to a sharp reduction in optically detected spin contrast at higher doses.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Manufacturing of diamond windows for synchrotron radiation

A new diamond window construction is presented and explicit manufacturing details are given. This window will increase the power dissipation by about a factor of 4 over present day state of the art windows to absorb 600 W of power. This power will be generated by in-vacuum undulators with the storage ring ALBA operating at a design current of 400 mA. Extensive finite element (FE) calculations are included to predict the windows behavior accompanied by explanations for the chosen boundary conditions. A simple linear model was used to cross-check the FE calculations.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Engineering shallow spins in diamond with nitrogen delta-doping

We demonstrate nanometer-precision depth control of nitrogen-vacancy (NV) center creation near the surface of synthetic diamond using an in situ nitrogen delta-doping technique during plasma-enhanced chemical vapor deposition. Despite their proximity to the surface, doped NV centers with depths (d) ranging from 5 to 100 nm display long spin coherence times, T{sub 2} > 100 {mu}s at d = 5 nm and T{sub 2} > 600 {mu}s at d {>=} 50 nm. The consistently long spin coherence observed in such shallow NV centers enables applications such as atomic-scale external spin sensing and hybrid quantum architectures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nano-hillock formation in diamond-like carbon induced by swift heavy projectiles in the electronic stopping regime: Experiments and atomistic simulations

The formation of surface hillocks in diamond-like carbon is studied experimentally and by means of large-scale molecular dynamics simulations with 5 Multiplication-Sign 10{sup 6} atoms combined with a thermal spike model. The irradiation experiments with swift heavy ions cover a large electronic stopping range between {approx}12 and 72 keV/nm. Both experiments and simulations show that beyond a stopping power threshold, the hillock height increases linearly with the electronic stopping, and agree extremely well assuming an efficiency of approximately 20% in the transfer of electronic energy to the lattice. The simulations also show a transition of sp{sup 3} to sp{sup 2} bonding along the tracks with the hillocks containing almost no sp{sup 3} contribution.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Effect of high-intensity x-ray radiation on Bragg diffraction in silicon and diamond

We simulated the Bragg reflection of high-intensity short x-ray pulses from single-crystal silicon and diamond by coupling tight-binding-molecular dynamics with a simple atomic kinetics model. We found that even when the pulse-averaged Bragg intensity degrades significantly, the reflectivity drops only slightly at the beginning of the pulse until the lattice is disordered by non-thermal melting. These results suggest that Bragg reflectors could produce shortened x-ray pulses through temporal slicing.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Note: Measurements of fast electrons in the TORE-SUPRA tokamak by means of modified Cherenkov-type diamond detector

The Note reports on experimental studies of ripple born fast electrons within the TORE-SUPRA facility, which were performed by means of a modified measuring head equipped with diamond detectors designed especially for recording the electron-induced Cherenkov radiation. There are presented signals produced by fast electrons in the TORE-SUPRA machine, which were recorded during two experimental campaigns performed in 2010. Shapes of these electron-induced signals are considerably different from those observed during the first measurements carried out by the prototype Cherenkov probe in 2008. An explanation of the observed differences is given.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Nonlinear ionization mechanism dependence of energy absorption in diamond under femtosecond laser irradiation

We present first-principles calculations for nonlinear photoionization of diamond induced by the intense femtosecond laser field. A real-time and real-space time-dependent density functional theory with the adiabatic local-density approximation is applied to describe the laser-material interactions in the Kohn-Sham formalism with the self-interaction correction. For a certain laser wavelength, the intensity dependence of energy absorption on multiphoton and/or tunnel ionization mechanisms is investigated, where laser intensity regions vary from 10{sup 12} W/cm{sup 2} to 10{sup 16} W/cm{sup 2}. In addition, the effect of laser wavelength on energy absorption at certain ionization mechanism is discussed when the Keldysh parameter is fixed. Theoretical results show that: (1) at the fixed laser wavelength, the relationship between the energy absorption and laser intensity shows a good fit of E = c{sub M}I{sup N} (N is the number of photons absorbed to free from the valence band) when multiphoton ionization dominates; (2) while when tunnel ionization becomes significant, the relationship coincides with the expression of E = c{sub T}I{sup n} (n < N).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

The potential application of ultra-nanocrystalline diamond films for heavy ion irradiation detection

The potential of utilizing the ultra-nanocrystalline (UNCD) films for detecting the Au-ion irradiation was investigated. When the fluence for Au-ion irradiation is lower than the critical value (f{sub c}= 5.0 Multiplication-Sign 10{sup 12} ions/cm{sup 2}) the turn-on field for electron field emission (EFE) process of the UNCD films decreased systematically with the increase in fluence that is correlated with the increase in sp{sup 2}-bonded phase ({pi}{sup *}-band in EELS) due to the Au-ion irradiation. The EFE properties changed irregularly, when the fluence for Au-ion irradiation exceeds this critical value. The transmission electron microscopic microstructural examinations, in conjunction with EELS spectroscopic studies, reveal that the structural change preferentially occurred in the diamond-to-Si interface for the samples experienced over critical fluence of Au-ion irradiation, viz. the crystalline SiC phase was induced in the interfacial region and the thickness of the interface decreased. These observations implied that the UNCD films could be used as irradiation detectors when the fluence for Au-ion irradiation does not exceed such a critical value.

36 MATERIALS SCIENCE↗

Laser-driven 1 GeV carbon ions from preheated diamond targets in the break-out afterburner regime

Experimental data are presented for laser-driven carbon C{sup 6+} ion-acceleration, verifying 2D-PIC studies for multi-species targets in the Break-Out Afterburner regime. With Trident's ultra-high contrast at relativistic intensities of 5 × 10{sup 20} W/cm{sup 2} and nm-scale diamond targets, acceleration of carbon ions has been optimized by using target laser-preheating for removal of surface proton contaminants. Using a high-resolution wide angle spectrometer, carbon C{sup 6+} ion energies exceeding 1 GeV or 83 MeV/amu have been measured, which is a 40% increase in maximum ion energy over uncleaned targets. These results are consistent with kinetic plasma modeling and analytic theory.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Increased negatively charged nitrogen-vacancy centers in fluorinated diamond

We investigated the effect of fluorine-terminated diamond surface on the charged state of shallow nitrogen vacancy defect centers (NVs). Fluorination is achieved with CF{sub 4} plasma, and the surface chemistry is confirmed with x-ray photoemission spectroscopy. Photoluminescence of these ensemble NVs reveals that fluorine-treated surfaces lead to a higher and more stable negatively charged nitrogen vacancy (NV{sup −}) population than oxygen-terminated surfaces. NV{sup −} population is estimated by the ratio of negative to neutral charged NV zero-phonon lines. Surface chemistry control of NV{sup −} density is an important step towards improving the optical and spin properties of NVs for quantum information processing and magnetic sensing.

36 MATERIALS SCIENCE↗

Radiation-assisted Frenkel-Poole transport in single-crystal diamond

The measurement of the density of occupied states as a function of the applied electric field, performed on single-crystal chemical vapour deposition diamond by x-ray modulated photocurrent technique, is reported. Two regimes of non-linear charge transport were observed: a classical Frenkel-Poole (FP) process at high electric fields (>6800 V/cm), and a radiation-assisted transport mechanism at intermediate electric fields (2000 to 6800 V/cm), consisting of a double-step process in which the direct re-emission into the extended band occurs following multiple photo-induced FP-like hopping transitions.

36 MATERIALS SCIENCE↗

Three-dimensional diamond detectors: Charge collection efficiency of graphitic electrodes

Implementation of 3D-architectures in diamond detectors promises to achieve unreached performances in the radiation-harsh environment of future high-energy physics experiments. This work reports on the collection efficiency under β-irradiation of graphitic 3D-electrodes, created by laser pulses in the domains of nanoseconds (ns-made-sensors) and femtoseconds (fs-made-sensors). Full collection is achieved with the fs-made-sensors, while a loss of 25%–30% is found for the ns-made-sensors. The peculiar behaviour of ns-made sensors has been explained by the presence of a nano-structured sp{sup 3}-carbon layer around the graphitic electrodes, evidenced by micro-Raman imaging, by means of a numerical model of the charge transport near the electrodes.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

High stability electron field emitters made of nanocrystalline diamond coated carbon nanotubes

We report enhanced life-time stability for the electron field emitters prepared by coating nanocrystalline diamond (NCD) on carbon nanotubes (CNTs). Upon overcoming the problem of poor stability in CNTs, the NCD-CNTs exhibit excellent life-time stability of 250 min tested at different applied voltages of 600 and 900 V. In contrast, the life-time stability of CNTs is only 33 min even at relatively low voltage of 360 V and starts arcing at 400 V. Hence, the NCD-CNTs with improved life-time stability have great potential for the applications as cathodes in flat panel displays and microplasma display devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Creation of quantum entanglement with two separate diamond nitrogen vacancy centers coupled to a photonic molecule

We explore the entanglement generation and the corresponding dynamics between two separate nitrogen-vacancy (NV) centers in diamond nanocrystal coupled to a photonic molecule consisting of a pair of coupled photonic crystal (PC) cavities. By calculating the entanglement concurrence with readily available experimental parameters, it is found that the entanglement degree strongly depends on the cavity-cavity hopping strength and the NV-center-cavity detuning. High concurrence peak and long-lived entanglement plateau can be achieved by properly adjusting practical system parameters. Meanwhile, we also discuss the influence of the coupling strength between the NV centers and the cavity modes on the behavior of the concurrence. Such a PC-NV system can be employed for quantum entanglement generation and represents a building block for an integrated nanophotonic network in a solid-state cavity quantum electrodynamics platform. In addition, the present theory can also be applied to other similar systems, such as two single quantum emitters positioned close to a microtoroidal resonator with the whispering-gallery-mode fields propagating inside the resonator.

77 NANOSCIENCE AND NANOTECHNOLOGY↗