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At least 973 records · Page 54

Life-Cycle Analysis of Greenhouse Gas Emissions and Water Consumption – Effects of Coal and Biomass Conversion to Liquid Fuels as Analyzed with the GREET Model

The vast reserves of coal in the U.S. provide a significant incentive for the development of processes for coal conversion to liquid fuels (CTL). Also, CTL using domestic coal can help move the U.S. toward greater energy independence and security. However, current conversion technologies are less economically competitive and generate greater greenhouse gas (GHG) emissions than production of petroleum fuels. Altex Technologies Corporation (Altex, hereinafter) and Pennsylvania State University have developed a hybrid technology to produce jet fuel from a feedstock blend of coal and biomass. Collaborating with Altex, Argonne National Laboratory has expanded and used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model to assess the life-cycle GHG emissions and water consumption of this hybrid technology. Biomass feedstocks include corn stover, switchgrass, and wheat straw. The option of biomass densification (bales to pellets) is also evaluated in this study. The results show that the densification process generates additional GHG emissions as a result of additional biomass process energy demand. This process coproduces a large amount of char, and this study investigates two scenarios to treat char: landfill disposal (Char-LF) and combustion for combined heat and power (CHP). Since the CHP scenarios export excess heat and electricity as coproducts, two coproduct handling methods are used for well-to-wake (WTWa) analysis: displacement (Char-CHP-Disp) and energy allocation (Char-CHP-EnAllo). When the feedstock contains 15 wt% densified wheat straw and 85 wt% lignite coal, WTWa GHG emissions of the coal-and-biomass-to-liquid pathways are 116, 97, and 137 gCO2e per megajoule (MJ) under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively, as compared to conventional jet fuel production at 84 gCO2e/MJ. WTWa water consumption values are 0.072, -0.046, and 0.044 gal/MJ for Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo, respectively, as compared to conventional jet fuel production at 0.028 gal/MJ. To reach the break-even point of 84 gCO2e/MJ, under the assumptions of constant product yields and energy demands regardless of the share of biomass and coal feedstocks, 31 wt%, 23 wt%, and 53 wt% of the feedstock blend need to be biomass under the Char-LF, Char-CHP-Disp, and Char-CHP-EnAllo scenarios, respectively.

09 BIOMASS FUELS↗

Algal Biomass Conversion to Fuels via Combined Algae Processing (CAP): 2020 State of Technology and Future Research

The annual State of Technology (SOT) assessment is an essential activity for platform research conducted under the Bioenergy Technologies Office. It allows for the impact of research progress to be quantified in terms of economic improvements in the overall biofuel production process for a particular biomass processing pathway, whether based on terrestrial or algal biomass feedstocks. As such, initial benchmarks can be established for currently demonstrated performance, and progress can be tracked towards out-year goals to ultimately demonstrate economically viable biofuel technologies. NREL's algae state of technology benchmarking efforts focus both on front-end algal biomass production and separately on back-end conversion to fuels through NREL's "combined algae processing" (CAP) pathway. The production model is based on outdoor long-term cultivation data, enabled by comprehensive algal biomass production trials conducted under the Development of Integrated Screening, Cultivar Optimization, and Verification Research consortium (DISCOVR) efforts, driven by data furnished by Arizona State University (ASU) at the Arizona Center for Algae Technology and Innovation (AzCATI) testbed site. The CAP model is based on experimental efforts conducted under NREL research and development projects. This report focuses on back-end conversion of algal biomass through the CAP pathway, highlighting the 2020 updates to minimum fuel selling price (MFSP). Notably, this analysis marks the first time that polyurethane (PU) is included as a value-added coproduct in the SOT case. Relative to prior 2019 benchmarks, the 2020 CAP SOT achieved further MFSP reductions of over $4/gallon gasoline equivalent, reflective of (a) the inclusion of PU co-production, (b) reduced SOT biomass production costs, and (c) higher pretreatment sugar yield data.

09 BIOMASS FUELS↗

Algal Biomass Conversion to Fuels via Combined Algae Processing (CAP) (2021 State of Technology and Future Research)

The annual State of Technology (SOT) assessment is an essential activity for platform research conducted under the Bioenergy Technologies Office. It allows for the impact of research progress to be quantified in terms of economic improvements in the overall biofuel production process for a particular biomass processing pathway, whether based on terrestrial or algal biomass feedstocks. As such, initial benchmarks can be established for currently demonstrated performance, and progress can be tracked towards out-year goals to ultimately demonstrate economically viable biofuel technologies. NREL's algae state of technology benchmarking efforts focus both on front-end algal biomass production and separately on back-end conversion to fuels through NREL's "combined algae processing" (CAP) pathway. The production model is based on outdoor long-term cultivation data, enabled by comprehensive algal biomass production trials conducted under the Development of Integrated Screening, Cultivar Optimization, and Verification Research consortium (DISCOVR) efforts, driven by data furnished by Arizona State University (ASU) at the Arizona Center for Algae Technology and Innovation (AzCATI) testbed site. The CAP model is based on experimental efforts conducted under NREL research and development projects. This report focuses on back-end conversion of algal biomass through the CAP pathway, highlighting the 2021 updates to minimum fuel selling price (MFSP). This update maintains an important recent inclusion of polyurethane (PU) previously incorporated in the 2020 SOT as a value-added coproduct. Relative to the 2020 SOT case, this indicates a minimal increase of $0.10-$0.14/GGE (roughly 2%) for both the acids and BDO pathways, attributed to minimal increases in upstream algal biomass costs from slightly lower demonstrated cultivation productivities in the 2021 SOT.

09 BIOMASS FUELS↗

Radioisotope Power Systems: Considerations for use of Dynamic versus Static Conversion Technologies for NASA Missions

For more than five decades, Radioisotope Power Systems (RPS) have played a critical role in the exploration of space, enabling missions of scientific discovery to destinations across the solar system by providing electrical power to explore remote, challenging and extreme environments. In particular, RPS enable deep space missions where increased heliocentric distances reduce the ability of solar power to adequately meet spacecraft and instruments power requirements. Some previous notable missions that were enabled by RPS include Nimbus III, the Apollo Sur-face Experiments, the Pioneers 10 and 11, the Viking Mars Landers, Galileo, Ulysses, Cassini, New Horizons and Curiosity. The current operating set of missions that are enabled by RPS are Voyagers 1 and 2, Cassini, New Hori-zons, and Curiosity. The Multi-Mission Radioisotope Thermal Generator (MMRTG) is the current RPS used for mis-sions. An enhanced version of this generator outfitted with higher efficiency thermoelectrics is under development for potential use in the future. There are also current development efforts underway by NASA to explore dynamic power conversion systems such as Brayton and Stirling. This paper will compare and contrast the pros and cons of a generalized dynamic system with the current state-of-the-art thermoelectric static conversion system. The reason for this paper is to calmly analyze the pros and cons so that all the pertinent factors are placed under the same examination light with equal brightness. As with any purchase made the “newness” of certain items sometimes overrides a needed desire to fully vet all characteristics of the merchandise so that the best choice is made. The following areas will be specifically examined and discussed as they may impact the choice of radioisotope power system for a specific mission: • Projected power output to weight ratio (We/kg) • Amount of Pu-238 required per a fixed power output • Excess heat available to be rejected or used • Fueling operations during assembly by the Department of Energy (DOE) • Planetary protection protocol during fueling and testing of RPS • Transportation operations from DOE assembly site to Kennedy Space Center (KSC) • Remote operations at KSC prior to launch during Assembly Test and Launch Operations (ATLO) phase o Timing of the placement of the RPS onto spacecraft/rover o Off-normal operations at KSC

99 GENERAL AND MISCELLANEOUS↗

Conversion of Diesel Engines to a Gas and Gas–Diesel Cycle

The conversion of diesel engines to gas and gas–diesel cycles during the production process is analyzed. The requirements for conversion to natural-gas operation are presented. The power, efficiency, and environmental impact of diesel engines, natural-gas engines, and gas–diesel engines are compared.

42 ENGINEERING↗

Modeling of Liquid Hydrogen Tank Cooled with Para-Orthohydrogen Conversion

With the accelerating development of liquid-hydrogen storage facilities, the problem of boil-off hydrogen losses becomes very important. A promising method to reduce these losses is to utilize the endothermic para-orthohydrogen conversion of vented hydrogen, which can effectively decrease heat loads on a hydrogen tank. To model such a process, a hybrid computational model has been developed, based on the application of computational fluid dynamics for an ullage space, where knowledge of thermal stratification is important, and reduced-order models for other system elements. The simulation results for a spheroidal tank in selected conditions indicated a 10–25% reduction of boil-off losses due to cooling produced by vented hydrogen undergoing para-ortho-conversion.

08 HYDROGEN↗

EXPLAINING INVERTED-TEMPERATURE LOOPS IN THE QUIET SOLAR CORONA WITH MAGNETOHYDRODYNAMIC WAVE-MODE CONVERSION

Coronal loops trace out bipolar, arch-like magnetic fields above the Sun’s surface. Recent measurements that combine rotational tomography, extreme-ultraviolet imaging, and potential-field extrapolation have shown the existence of large loops with inverted-temperature profiles, i.e., loops for which the apex temperature is a local minimum, not a maximum. These “down loops” appear to exist primarily in equatorial quiet regions near solar minimum. We simulate both these and the more prevalent large-scale “up loops” by modeling coronal heating as a time-steady superposition of (1) dissipation of incompressible Alfvén wave turbulence and (2) dissipation of compressive waves formed by mode conversion from the initial population of Alfvén waves. We found that when a large percentage (>99%) of the Alfvén waves undergo this conversion, heating is greatly concentrated at the footpoints and stable “down loops” are created. In some cases we found loops with three maxima that are also gravitationally stable. Models that agree with the tomographic temperature data exhibit higher gas pressures for “down loops” than for “up loops,” which is consistent with observations. These models also show a narrow range of Alfvén wave amplitudes: 3 to 6 km s{sup -1} at the coronal base. This is low in comparison to typical observed amplitudes of 20–30 km s{sup -1} in bright X-ray loops. However, the large-scale loops we model are believed to compose a weaker diffuse background that fills much of the volume of the corona. By constraining the physics of loops that underlie quiescent streamers, we hope to better understand the formation of the slow solar wind.

79 ASTRONOMY AND ASTROPHYSICS↗

Thermoelectric Energy Conversion: Future Directions and Technology Development Needs

This viewgraph presentation reviews the process of thermoelectric energy conversion along with key technology needs and challenges. The topics include: 1) The Case for Thermoelectrics; 2) Advances in Thermoelectrics: Investment Needed; 3) Current U.S. Investment (FY07); 4) Increasing Thermoelectric Materials Conversion Efficiency Key Science Needs and Challenges; 5) Developing Advanced TE Components & Systems Key Technology Needs and Challenges; 6) Thermoelectrics; 7) 200W Class Lightweight Portable Thermoelectric Generator; 8) Hybrid Absorption Cooling/TE Power Cogeneration System; 9) Major Opportunities in Energy Industry; 10) Automobile Waste Heat Recovery; 11) Thermoelectrics at JPL; 12) Recent Advances at JPL in Thermoelectric Converter Component Technologies; 13) Thermoelectrics Background on Power Generation and Cooling Operational Modes; 14) Thermoelectric Power Generation; and 15) Thermoelectric Cooling.

theromelectric↗

Gas Turbine Energy Conversion Systems for Nuclear Power Plants Applicable to LiFTR Liquid Fluoride Thorium Reactor Technology

This panel plans to cover thermal energy and electric power production issues facing our nation and the world over the next decades, with relevant technologies ranging from near term to mid-and far term.Although the main focus will be on ground based plants to provide baseload electric power, energy conversion systems (ECS) for space are also included, with solar- or nuclear energy sources for output power levels ranging tens of Watts to kilo-Watts for unmanned spacecraft, and eventual mega-Watts for lunar outposts and planetary surface colonies. Implications of these technologies on future terrestrial energy systems, combined with advanced fracking, are touched upon.Thorium based reactors, and nuclear fusion along with suitable gas turbine energy conversion systems (ECS) will also be considered by the panelists. The characteristics of the above mentioned ECS will be described, both in terms of their overall energy utilization effectiveness and also with regard to climactic effects due to exhaust emissions.

Energy Conversion↗

Brayton Cycle Power Conversion Model for MW-Class Nuclear Electric Propulsion Mars Missions

A Brayton cycle based power conversion system for a nuclear electric propulsion application was modeled in Simulink as part of NASA’s space nuclear program in order to explore the impact of technology assumptions on the power conversion system performance and capabilities. The thermodynamic processes and algorithms within the model are documented, including a higher fidelity reactor model. Assumptions are chosen based on literature and subject matter expert review, and example results and capabilities of the model are shown. The effects of the turbine inlet and compressor inlet temperature on radiator area and thermal efficiency are discussed. For a He-Xe closed Brayton cycle, radiator areas as low as 650 m2/MWe are shown, with corresponding thermal efficiences at roughly 20% for the minimal radiator area solutions.

Brayton↗

Heat Pipe Heat Exchanger for Nuclear Electric Propulsion Power Conversion System

Heat pipe reactors have been considered by the Space Nuclear Propulsion program for Nuclear Electric Propulsion (NEP) power conversion systems and will require the use of heat exchangers to transfer heat via heat pipes to the Brayton working fluid from the reactor. Sodium (Na) and lithium (Li) were considered as viable working fluids inside the heat pipes which were assumed to have the same geometry based on studies and information from the Los Alamos National Laboratory. The heat exchanger was assumed to be a rectangular duct with heat pipes serving as tubes from previous NEP work and recommendations. Based on this geometry, Zukauskas correlations were used to model the convective heat transfer and pressure losses. Parametric sizing of the reactor component involved operational limits-based heat pipe thermal hydraulic modeling in cohesion with required user input geometry for the in-core lattice and various subcomponents. This work considered various power conversion inlet temperatures (PCIT) of 1100 K, 1150 K, and 1200 K for Na heat pipes and 1100 K, 1150 K, 1200 K, and 1400 K for Li heat pipes based on recommendations from prior work. Using these different PCITs, the subsystem masses and pressure losses were determined and analyzed. Na showed a lower overall operating temperature and about a fifth of the maximum heat throughput capability than that of Li for the same geometry. Due to this, the entire Na-based subsystem ended up being three times more massive than the Li-based subsystem given five times the required number of heat pipes. At the low PCIT of 1100 K, the Na-based subsystem exhibited the lowest pressure losses given the large overall cross sectional flow area and relatively low frictional pressure losses. However, as the PCIT increased, the frictional pressure losses increased resulting in higher pressure losses at the 1200 K PCIT than Li-based subsystem. However, the Li-based subsystem exhibited the largest pressure losses of all analyzed cases at the 1400 K PCIT due to the low density of the Brayton working fluid at this temperature.

electric↗

Data-Informed Environmental Conversion: Updating MIL-HDBK-217 and -338 with 50+ years of field data

Using over five decades of field data on electric and non-electric parts, we revisit the environmental conversion methodology described in MIL-HDBKs -217 and -338. These Reliability Engineering Handbooks’ predicted values are compared to new tables, developed using observed data. This observed data approach is also used to develop environmental conversion factors for non-electric parts, which were out of scope of MIL-HDBK-217 and -338.

reliability↗

Analysis of Thermoradiative Thermal Energy Conversion

The thermoradiative cell is a new method for converting heat energy to electrical power, first detailed by Strandberg in 2015. The cell is a p-n junction semiconductor device, similar to a photovoltaic cell but thermodynamically operating in the reverse direction, converting the thermal dark current into electrical power while radiating waste heat to space. The power and efficiency can be calculated as a function of bandgap in the Shockley-Queisser detailed-balance limit, in which the thermal emissivity of the cell is due to the recombination of electron-hole pairs, and all other recombination losses are ignored. The current produced is directly proportional to the recombination radiation. The fundamental loss mechanism for the thermoradiative cell is the energy carried by the infrared radiation into space from band-to-band recombination of carriers injected across the junction. In an ideal cell, to maximize the efficiency, the emission energy of these photons would precisely equal the bandgap. This can be achieved, for example, using dielectric filters or meta-material filters to recycle emission at other wavelengths back into the cell. The voltage is proportional to the external bias. These two constraints allow optimization of the optimum bias point for maximum power. Unlike photovoltaic cells, the maximum power operating point is not the same as the maximum efficiency point, and higher efficiency can be achieved at a higher (negative) bias in the ideal case. Incorporating non-ideal losses, however, shifts the maximum efficiency point toward lower bias. Unlike in photovoltaic cells, non-radiative recombination (e.g., Auger losses) will reduce the output current, but will not reduce the conversion efficiency, since the recombination energy is retained in the cell in the form of heat. Since a thermoradiative cell operates by radiating directly to space, the current produced by themoradiative cells will increase as Stefan-Boltzmann radiation; roughly the fourth power of the temperature. Thus, the power produced is highest at high operating temperatures, and, unlike conventional thermal conversion, increasing radiator temperature increases, the efficiency. Thus, the choice of technology will be toward semiconductors resistant to degradation at high temperature.

Thermoradiative↗

Development of CFD models to support LEU Conversion of ORNL s High Flux Isotope Reactor

The US Department of Energy s National Nuclear Security Administration (NNSA) is participating in the Global Threat Reduction Initiative to reduce and protect vulnerable nuclear and radiological materials located at civilian sites worldwide. As an integral part of one of NNSA s subprograms, Reduced Enrichment for Research and Test Reactors, HFIR is being converted from the present HEU core to a low enriched uranium (LEU) core with less than 20% of U-235 by weight. Because of HFIR s importance for condensed matter research in the United States, its conversion to a high-density, U-Mo-based, LEU fuel should not significantly impact its existing performance. Furthermore, cost and availability considerations suggest making only minimal changes to the overall HFIR facility. Therefore, the goal of this conversion program is only to substitute LEU for the fuel type in the existing fuel plate design, retaining the same number of fuel plates, with the same physical dimensions, as in the current HFIR HEU core. Because LEU-specific testing and experiments will be limited, COMSOL Multiphysics was chosen to provide the needed simulation capability to validate against the HEU design data and previous calculations, and predict the performance of the proposed LEU fuel for design and safety analyses. To achieve it, advanced COMSOL-based multiphysics simulations, including computational fluid dynamics (CFD), are being developed to capture the turbulent flows and associated heat transfer in fine detail and to improve predictive accuracy [2].

COMSOL↗

Electrocatalysts for carbon dioxide conversion

Electrocatalysts for carbon dioxide conversion include at least one catalytically active element with a particle size above 0.6 nm. The electrocatalysts can also include a Helper Catalyst. The catalysts can be used to increase the rate, modify the selectivity or lower the overpotential of electrochemical conversion of CO.sub.2. Chemical processes and devices using the catalysts also include processes to produce CO, HCO.sup.-, H.sub.2CO, (HCO.sub.2).sup.-, H.sub.2CO.sub.2, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.-, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, or (COO.sup.-).sub.2, and a specific device, namely, a CO.sub.2 sensor.

30 DIRECT ENERGY CONVERSION↗

Bringing Fenton Hill into the Digital Age: Data Conversion in Support of the Geothermal Technologies Office Code Comparison Study Challenge Problems

The Geothermal Technologies Office Code Comparison Study (GTO-CCS) was established by the U.S. Department of Energy to facilitate collaboration among members of the geothermal modeling community and to evaluate and improve upon the ability of existing codes to simulate thermal, hydrological, mechanical, and chemical processes associated with complex enhanced geothermal systems (EGS). The first stage of the project, which has been completed, involved comparing simulations for seven benchmark problems that were primarily designed using well-prescribed, simplified data sets. In the second stage, the participating teams are tackling two challenge problems based on the EGS research conducted in hot dry rock (HDR) at Fenton Hill, near Los Alamos, New Mexico. The Fenton Hill project, conducted by Los Alamos National Laboratory (LANL) from 1970 to 1995, was the world’s first HDR demonstration project. One of the criteria for selecting this experiment as the basis for the challenge problems was the amount and availability of data for generating model inputs. The Fenton Hill HDR system consisted of two reservoirs – an earlier Phase I reservoir tested from 1974 to 1981 and a deeper Phase II reservoir tested from 1980 to 1995. Detailed accounts of both phases of the HDR project have been presented in a number of books and reports, including a recently published summary of the lessons learned and a final report with a chronological description of the Fenton Hill project, prepared by LANL. Project documents and records have been archived and made public through the National Geothermal Data System (NGDS). Some of the data acquired from Phase II are available in electronic format readable on modern computers. These include the microseismic data from some of the important experiments (e.g. the massive hydraulic fracturing test conducted in 1983) and the injection/production wellhead data from the circulation tests conducted between 1992-1995. However, much of the data collected during the project, while publicly available, currently only exist in the form of tables or graphs within scanned documents. Therefore, in support of the GTO-CCS, the data needed for developing simulation inputs are being compiled and converted to platform independent, open readable formats so that all participating teams will have access to the same electronic data set. In some cases this requires conversion using optical character recognition, digitizing existing images, and generating the appropriate metadata from project documents. The GTO-Velo knowledge management framework, developed by Pacific Northwest National Laboratory (PNNL), was used for the benchmark problem stage of the comparison study and will also be used as the data repository for the challenge problem data sets. It is staggering and impractical to convert all published data for the Fenton Hill site, so the focus is on data that supports simulations for the three topical areas defined by the study for the challenge problems: 1) reservoir creation/stimulation, 2) reactive and passive transport, and 3) thermal recovery. Conversion of these data provide value not only to GTO-CCS participants, but also to members of the geothermal community at large who may be interested in revisiting the Fenton Hill experiment in the future.

Code Comparison Study↗

Electrocatalytic process for carbon dioxide conversion

An electrocatalytic process for carbon dioxide conversion includes combining a Catalytically Active Element and a Helper Polymer in the presence of carbon dioxide, allowing a reaction to proceed to produce a reaction product, and applying electrical energy to said reaction to achieve electrochemical conversion of said carbon dioxide reactant to said reaction product. The Catalytically Active Element can be a metal in the form of supported or unsupported particles or flakes with an average size between 0.6 nm and 100 nm. The reaction products comprise at least one of CO, HCO.sup.-, H.sub.2CO, (HCO.sub.2).sup.-, H.sub.2CO.sub.2, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.-, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, (COO.sup.-).sub.2, and CF.sub.3COOH.

30 DIRECT ENERGY CONVERSION↗