Results for “volatility” — Page 53

NASA NTRSDate not supplied

Simulating Meteor Ablation at the Hypersonic Materials Environmental Test System

The ablation mechanisms of stony meteorite material and a terrestrial analog were investigated at the Hypersonic Materials Environmental Test System (HyMETS) facility at NASA’s Langley Research Center. The primary analyte (Tamdakht-H5) and arc-jet test conditions were chosen to simulate the entry of an ordinary chondrite through the Earth’s mesosphere. Basalt was selected to compare the meteorite response against material with enhanced polymerization and an elevated concentration of volatile species. The initial ablation process for each material commences with the vaporization of volatile species and germination of a viscous melt layer on the stagnation surface. However, each material exhibited distinct mass loss mechanisms, with basalt recessing at twice the rate of Tamdakht. Inspection of high-speed video and chemical analysis of the post-test melt layer suggests the dominant mode of mass loss of Tamdakht is expressed through the vaporization of volatile compounds. Vaporization rates of Tamdakht are 18x higher than basalt under the most severe test conditions which provides enhanced thermal shielding. Furthermore, Tamdakht produces a relatively stable melt flow, as evidenced by perpetual growth at the sidewall and the exiguous detachment of molten material into the flow. The ablation mechanism of basalt is markedly different from Tamdakht and is governed by volatile species in the virgin material. The dominant mode of mass loss for basalt is attributed to the detachment of large sections of the stagnation surface near the edge radius. An additional but subordinate mode of mass loss is assigned to the removal of melt flow as it passes over the edge radius, where shear forces overcome the rheological properties of the molten matter. Finally, mechanistic details will be discussed in terms of designing future test campaigns, developing meteorite-based materials response models, and impacting the broader scope of the Asteroid Threat Assessment Project (ATAP).

Meteor Ablation↗

NASA NTRS2022

Sodium Distribution on the Moon

The Moon is significantly depleted in volatile elements when compared to Earth, an observation that has resulted in various formation scenarios leading to the loss of volatiles. Sodium is a moderately volatile element that is a lithophile, which can be utilized as a tracer of the volatile history in planetary bodies. It is also well observed in the exosphere of several bodies in our solar system and exoplanetary systems. But lunar surface sodium abundances have so far been measured only in samples brought back to Earth. We report on results from the first effort to provide a global-scale measurement of sodium on the lunar surface using X-ray fluorescent spectra from Chandrayaan-2. A global average of 1.33 ± 0.03 wt% derived here is higher than previously known. Trends in the sodium abundance indicate a long-lived adsorbate component that could explain the higher abundances reported here, which would act as a reservoir that sustains the lunar sodium exosphere.

Surface composition↗

NASA NTRSDate not supplied

Lessons From Pluto for Uranus Moons

Introduction: Small patches of starkly different albedo on both Oberon and Umbriel may be evidence for frost segregation and volatile migration. The high obliquity of the Uranian system makes it a good candidate for volatile transport activity. CO 2 and ammonium species have been detected on some Uranian satellites, and CH 4 is at least theoretically viable as a resident volatile. The OWL-recommended UOP Orbiter spacecraft should be equipped with instruments capable of evaluating the nature and extent of volatiles in the Uranian satellite system.

J M Moore↗

NASA NTRSDate not supplied

VIPER Rover: Flight Build and Environmental Test Status

The NASA Artemis Program plans to return humans to the Moon to stay. Extended human stays on the Moon will require substantial resources to sustain human presence, requiring continuous supplies delivered from the Earth. However, if some of the resources were indigenously available, Earth logistical requirements could be substantially reduced by “living off the land” with in-situ lunar resources. Local volatiles could be processed into propellants and human life-supporting needs, reducing risk of maintaining a permanent human presence on the Moon. LCROSS, LRO and other missions have confirmed the presence of lunar volatiles resources in polar regions, so the next step is to understand the physical distribution of those resources, as well as the scientific basis for how water got there, and why it is still there. The Volatiles Investigating Polar Exploration Resource (VIPER) is a surface mobility scientific platform, designed to spend ~100 days mapping and surveying four different Ice Stability Regions to understand the scientific nature and distribution of water and other volatiles. VIPER will also provide scientific mineralogical context of the lunar regolith, such as the presence of silicon and light metals in lunar regolith, providing a composite picture of resource availability and sustainment. This paper will discuss VIPER’s completion of the flight rover build, as well as current progress in environmental testing, preparedness for mission operations, and overall readying for launch integration with our CLPS partner. VIPER is managed within NASA’s Science Mission Directorate (SMD), utilizing the Commercial Lunar Payload Services (CLPS) lunar delivery model.

VIPER↗

NASA NTRSDate not supplied

Developmental Hardware Testing Results and Forward Plans for the Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM)

We present testing results for developmental hardware of the Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM). SWIM-OWM will monitor spacecraft potable water and system water for trace organic contaminants. The system will detect and identify the specific organic chemical that makes up a given total organic carbon reading. We have built a first development unit (1DU) for SWIM-OWM, which directly injects aqueous water samples and detects chemicals with both a thermal conductivity detector and mass spectrometer sensor. The gas chromatography mass spectrometer (GCMS) system that comprises SWIM-OWM draws on the success of ISS-proven mass spectrometer hardware, and the demonstration of GCMS detection of trace organic contaminants in ISS cabin air. SWIM-OWM benefits from the excellent sensitivity and specificity afforded by GCMS. We have demonstrated detection of a set of chemicals relevant to both crew health and performance as well as system monitoring; these target chemicals range from light, volatile organics such as acetone and ethanol, to heavier, very non-volatile compounds such as dimethyl sulfone and o-phthalaldehyde. Direct aqueous injection was chosen for the general applicability of the technique to clean water sampling and to preclude sample pre-processing, which facilitates an on-line implementation of the SWIM-OWM when deployed in a spacecraft or habitation module. A specific advantage of direct aqueous injection when coupled with appropriate methods is that both the light, volatile organics and heavier non-volatiles can be detected from a single injection, in a single chromatogram. Results from 1DU testing will be discussed, and forward plans will be outlined for continued maturation of SWIM-OWM with the goal of implementing a technology demonstration for the purposes of maturing the engineering design and operations in an environment relevant to NASA’s future goals of exploring and setting up habitation on the Moon and Mars.

Water Monitoring↗

NASA NTRSDate not supplied

Developmental Hardware Testing Results and Forward Plans for Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM)

We present testing results for developmental hardware of the Spacecraft Water Impurity Monitor (SWIM) Organic Water Module (OWM). SWIM-OWM will monitor spacecraft potable water and system water for trace organic contaminants. The system will detect and identify the specific organic chemical that makes up a given total organic carbon reading. We have built a first development unit (1DU) for SWIM-OWM, which directly injects aqueous water samples and detects chemicals with both a thermal conductivity detector and mass spectrometer sensor. The gas chromatography mass spectrometer (GCMS) system that comprises SWIM-OWM draws on the success of ISS-proven mass spectrometer hardware, and the demonstration of GCMS detection of trace organic contaminants in ISS cabin air. SWIM-OWM benefits from the excellent sensitivity and specificity afforded by GCMS. We have demonstrated detection of a set of chemicals relevant to both crew health and performance as well as system monitoring; these target chemicals range from light, volatile organics such as acetone and ethanol, to heavier, very non-volatile compounds such as dimethyl sulfone and o-phthalaldehyde. Direct aqueous injection was chosen for the general applicability of the technique to clean water sampling and to preclude sample pre-processing, which facilitates an on-line implementation of the SWIM-OWM when deployed in a spacecraft or habitation module. A specific advantage of direct aqueous injection when coupled with appropriate methods is that both the light, volatile organics and heavier non-volatiles can be detected from a single injection, in a single chromatogram. Results from 1DU testing will be discussed, and forward plans will be outlined for continued maturation of SWIM-OWM with the goal of implementing a technology demonstration for the purposes of maturing the engineering design and operations in an environment relevant to NASA’s future goals of exploring and setting up habitation on the Moon and Mars.

Water Monitoring↗

NASA NTRSDate not supplied

Viper Rover: Flight Build and Environmental Test Status

The NASA Artemis Program plans to return humans to the Moon to stay. Extended human stays on the Moon will require substantial resources to sustain human presence, requiring continuous supplies delivered from the Earth. However, if some of the resources were indigenously available, Earth logistical requirements could be substantially reduced by “living off the land” with in-situ lunar resources. Local volatiles could be processed into propellants and human life-supporting needs, reducing risk of maintaining a permanent human presence on the Moon. LCROSS, LRO and other missions have confirmed the presence of lunar volatiles resources in polar regions, so the next step is to understand the physical distribution of those resources, as well as the scientific basis for how water got there, and why it is still there. The Volatiles Investigating Polar Exploration Resource (VIPER) is a surface mobility scientific platform, designed to spend ~100 days mapping and surveying four different Ice Stability Regions to understand the scientific nature and distribution of water and other volatiles. VIPER will also provide scientific mineralogical context of the lunar regolith, such as the presence of silicon and light metals in lunar regolith, providing a composite picture of resource availability and sustainment. This paper will discuss VIPER’s completion of the flight rover build, as well as current progress in environmental testing, preparedness for mission operations, and overall readying for launch integration with our CLPS partner. VIPER is managed within NASA’s Science Mission Directorate (SMD), utilizing the Commercial Lunar Payload Services (CLPS) lunar delivery model.

rover↗

NASA NTRSDate not supplied

VIPER Rover Flight Build and Environmental Test Status

The NASA Artemis Program plans to return humans to the Moon to stay. Extended human stays on the Moon will require substantial resources to sustain human presence, requiring continuous supplies delivered from the Earth. However, if some of the resources were indigenously available, Earth logistical requirements could be substantially reduced by “living off the land” with in-situ lunar resources. Local volatiles could be processed into propellants and human life-supporting needs, reducing risk of maintaining a permanent human presence on the Moon. LCROSS, LRO and other missions have confirmed the presence of lunar volatiles resources in polar regions, so the next step is to understand the physical distribution of those resources, as well as the scientific basis for how water got there, and why it is still there. The Volatiles Investigating Polar Exploration Resource (VIPER) is a surface mobility scientific platform, designed to spend ~100 days mapping and surveying four different Ice Stability Regions to understand the scientific nature and distribution of water and other volatiles. VIPER will also provide scientific mineralogical context of the lunar regolith, such as the presence of silicon and light metals in lunar regolith, providing a composite picture of resource availability and sustainment. This paper will discuss VIPER’s completion of the flight rover build, as well as current progress in environmental testing, preparedness for mission operations, and overall readying for launch integration with our CLPS partner. VIPER is managed within NASA’s Science Mission Directorate (SMD), utilizing the Commercial Lunar Payload Services (CLPS) lunar delivery model.

rover↗

NASA NTRS1996

Photosynthetic photon flux, photoperiod, and temperature effects on emissions of (Z)-3-hexenal, (Z)-3-hexenol, and (Z)-3-hexenyl acetate from lettuce

To investigate the effects of environment on plant volatile emissions, 'Waldmann's Green' leaf lettuce was cultivated under different levels of photosynthetic photon flux (PPF), photoperiod, and temperature. A modified growth chamber was used to sample plant volatile emissions nondestructively, over time, and under controlled conditions. Total volatile emission rates were significantly higher from lettuce cultivated under PPF of 360 or 200 micromoles m-2 s-1 compared to 105 micromoles m-2 s-1, and significantly higher under a 16-h photoperiod than an 8-h photoperiod. No differences were detected among emission rates from different temperature treatments. In controlled environments, emissions could be regulated by adjusting environmental conditions accordingly.

NASA Program Advanced Life Support↗

NASA NTRS2013

The Pinnacles of Callisto

Many regions of Callisto feature an unusual landscape consisting of rolling dark plains with interspersed bright knobs (pinnacles) and ridges. In earlier work we interpreted the dark plains as dusty, mass-wasted residue from sublimation from volatile-rich bedrock and the bright knobs (often crater rims) as water ice accumulations at locations sheltered from thermal reradiation from the dusty residue. We simulated evolution of Callisto's craters as a combination of bedrock volatile sublimation, mass wasting of the dark, non-coherent residue, and redeposition of ice, and concluded that the ice pinnacles and ridges might be underlain by tens to hundreds of meters of ice. Here we report the initial work of a new study of pinnacles addressing additional questions: 1) Is there an evolutionary sequence starting, e.g., from a cratered initial surface through growth and formation of a dust mantle and pinnacles, to eventual loss of ice to sublimation resulting in just a dark, dusty surface? 2) What determines the areal density and spatial scale of pinnacles - volatile content of bedrock, crater density, surface age, broad-scale topographic setting? 3) Are pinnacles still forming? Several observations address these questions. In a few places scattered high-albedo blocks approx. 25-60 m in diameter occur in the vicinity of large icy pinnacles. We interpret these blocks to be remnants from the collapse of tall pinnacles that were undermined by mass wasting. Some high-relief icy knobs have developed a skeletonized planform due to mass wasting by avalanching, or perhaps to seeding of new sites of ice deposition on mass-wasted ice blocks. Some areas nearly lack fresh craters with well-defined ejecta and ice-free rims. This may imply rapid transformation of fresh craters by sublimation, mass wasting, and ice reprecipitation. In other areas small sharp-rimmed craters occur which lack ice pinnacles, but the craters nonetheless lack visible ejecta sheets. Our preliminary interpretation is that mass wasting is very efficient on Callisto, or alternatively the dust cover is very thick and lacks competent coarse materials.

bedrock volatile sublimation↗

NASA NTRS2015

Field Testing Near-IR and Neutron Spectrometer Prospecting: Applications to Resource Prospector on the Moon

While we know there are volatiles sequestered at the poles of the Moon, the detailed 3-D distribution, abundance, and physical and chemical form are largely unknown. The next giant leap, Resource Prospector (RP), will use landed assets to fully characterize the volatile composition and distribution at scales of tens to hundreds of meters. To achieve this range of scales, mobility is required. Near real-time operation of surface assets is desirable, with a concept of operations very different from that of rovers on Mars. For RP, new operational approaches are required to carry out real-time robotic exploration. The Mojave Volatiles Project (MVP) is a Moon- Mars Analog Mission Activities (MMAMA) program effort aimed at (1) determining effective approaches to operating a real-time but short-duration lunar surface robotic mission, and (2) performing prospecting science in a natural setting, as a test of these approaches. Here we describe some results from the first such test, carried out in the Mojave Desert between 16 and 24 October, 2014. The test site was an alluvial fan just E of the Soda Mountains, SW of Baker, California. This site contains desert pavements, ranging from the late Pleistocene to early-Holocene in age. These pavements are dissected by the ongoing development of washes. A principal objective was to determine the hydration state of different types of desert pavement and bare ground features. The mobility element of the test was the KREX-2 rover, designed and operated by the Intelligent Robotics Group at NASA Ames Research Center.

Mojave Volatiles Project (MVP)↗

NASA NTRS2014

Infrared Spectral Observations While Drilling into a Frozen Lunar Simulant

Past and continuing observations indicate an enrichment of volatile materials in lunar polar regions. While these volatiles may be located near the surface, access to them will likely require subsurface sampling, during which it is desirable to monitor the volatile content. In a simulation of such activities, a multilayer lunar simulant was prepared with differing water content, and placed inside a thermal vacuum chamber at Glenn Research Center (GRC). The soil profile was cooled using liquid nitrogen. In addition to the soil, a drill and infrared (IR) spectrometer (~1600-3400 nm) were also located in the GRC chamber. We report the spectral observations obtained during a sequence where the drill was repeatedly inserted and extracted, to different depths, at the same location. We observe an overall increase in the spectral signature of water ice over the duration of the test. Additionally, we observe variations in the water ice spectral signature as the drill encounters different layers.

volatile content↗

NASA NTRSDate not supplied

A New Era of H-O-C-S Magma Solubility Modeling: Better, Faster, Stronger

H 2 O, CO 2 , and S are the most abundant volatiles in magmatic systems and are critical to understanding magma storage, phase equilibria, and volcanic eruptions. Models that consider all three of these components, however, may not allow for critical examination and adjustment of assumptions underlying the model, or provide benchmark testing or extensible interfaces. Thus, understanding why models produce different results can be challenging. We have gathered authors of established (D-Compress) and recent (VolFe, EVo, Sulfur_X, MAGEC) H-O-C-S volatile solubility models to work together to understand how and why our models diverge. We present a series of benchmark basalt degassing scenarios revealing that often understated model assumptions such as fO 2 buffer equations, fO 2 -Fe 3+ /ΣFe relationships, and even major element normalization routines have outsized effects on model results. All models consider S 2- and S 6+ melt species but with different approaches to sulfate/sulfide capacities, partition coefficients, and species fugacities, leading to divergence in the evolution of modeled gas compositions, melt S and Fe speciation, and fO 2 , with the extent of divergence depending on melt composition. Such scenarios enable meaningful intercomparison of existing models and lay the groundwork for a user-friendly yet powerful solubility modeling framework. Given our wealth of existing solubility literature, we suggest that the field of magmatic volatiles should focus now on the creation of modern tools and the modular implementation of existing model equations or methods, and that the evaluation of code usability, transparency, and benchmarking should be codified pillars of the peer-review process. As an example of such an endeavor, we present early work coupling these sulfur solubility models with VESIcal, an extensible and rigorously tested python library containing seven existing H 2 O-CO 2 solubility models. VESIcal includes the ability to extract, edit, and even interchange assumptions underlying any model. For example, users may combine or swap separately published H 2 O, CO 2 , and S models, as well as underlying model choices, such as Equations of State and redox models.

volatiles in magmas↗

NASA NTRS1972

Gas-liquid chromatography in lunar organic analysis.

Gas-liquid chromatography (GLC) is a powerful and sensitive method for the separation and detection of organic compounds at nanogram levels. The primary requirement for successful analyses is that the compounds of interest must be volatile under the chromatographic conditions employed. Nonvolatile organic compounds must be converted to volatile derivatives prior to analysis. The derivatives of choice must be both amenable to chromatographic separation and be relatively stable. The condition of volatility necessitates the development of efficient derivatization reactions for important groups of compounds as amino acids, carbohydrates, nucleosides, etc. Trimethylsilylation and trifluoroacetylation represent specific areas of recent prominence. Some relevant practical aspects of GLC are discussed.

Gehrke, C. W.↗

NASA NTRS1973

Evaporation rate and vapor pressure of selected polymeric lubricating oils.

A recently developed ultrahigh-vacuum quartz spring mass sorption microbalance has been utilized to measure the evaporation rates of several low-volatility polymeric lubricating oils at various temperatures. The evaporation rates are used to calculate the vapor pressures by the Langmuir equation. A method is presented to accurately estimate extended temperature range evaporation rate and vapor pressure data for polymeric oils, incorporating appropriate corrections for the increases in molecular weight and the change in volatility of the progressively evaporating polymer fractions. The logarithms of the calculated data appear to follow linear relationships within the test temperature ranges, when plotted versus 1000/T. These functions and the observed effusion characteristics of the fluids on progressive volatilization are useful in estimating evaporation rate and vapor pressure changes on evaporative depletion.

Gardos, M. N.↗

NASA NTRS1974

The study of electrical conduction mechanisms

The dielectric response of lunar fines 74241,2 is presented in the audio-frequency range and under lunarlike conditions. Results suggest that volatiles are released during storage and transport of the lunar sample. Apparently, subsequent absorption of volatiles on the sample surface alter its dielectric response. The assumed volatile influence disappear after evacuation. A comparison of the dielectric properties of lunar and terrestrial materials as a function of density, temperature, and frequency indicates that if the lunar simulator analyzed were completely devoid of atmospheric moisture it would present dielectric losses smaller than those of the lunar sample. It is concluded that density prevails over temperature as the controlling factor of dielectric permittivity in the lunar regolith and that dielectric losses vary slowly with depth.

Morrison, H. F.↗

NASA NTRS1973

Monitoring systems for evaluation of terrestrial contamination in a lunar sample transfer facility

The lunar sample transfer facility used consists of two tandem glove boxes and an entrance vacuum antechamber. Monitoring systems were used to evaluate the contamination levels of water, permanent gases, and lower volatility organic compounds in the glove box atmosphere. The experimental procedures are considered, taking into account the glove box atmosphere, aspects of volatile gas analysis, and lower volatility organic contaminants. The value of high resolution mass spectrometry in the monitoring scheme is illustrated with the aid of an example.

Wszolek, P. C.↗

NASA NTRS1973

How to lose Rb, K, and change the K/Rb ratio - An experimental study

Thermal volatilization studies on Apollo 16 soils and crystalline rocks have been carried out to measure the depletion of K, Rb, and Na and changes in K/Rb ratios during heating under vacuum. Rubidium can be lost from both soils and rocks at temperatures as low as 1000 C. Because of the greater volatility of Rb as compared to K, the K/Rb ratio can be changed from normal values of 330-360 for the Apollo 16 samples to values as high as 1100 by thermal volatilization. Rapid heating experiments on soil samples were carried out to approximate agglutinate formation conditions in order to measure changes in alkali element abundances. Equal changes in K/Rb ratios can be produced with longer heating at lower temperatures or heating at higher temperatures for shorter times.

Gibson, E. K., Jr.↗