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At least 955 records · Page 53

Analysis of Dust Samples Collected from an Inland ISFSI Site (''Site B'').

In October of 2020, dust samples were collected from the surface of spent nuclear fuel (SNF) dry storage canisters during an inspection at an inland Independent Spent Fuel Storage Installation, the second inland site at which surface deposits have been sampled. The purpose of the sampling was to assess the composition and abundance of the soluble salts present on the canister surface, information which provides a metric for potential corrosion risks. The samples were delivered to Sandia National laboratories for analysis. At Sandia, the soluble salts were leached from the dust and quantified by ion chromatography. In addition, subsamples of the dust were taken for scanning electron microscopy to determine the texture and mineralogy of the dust and salts. The results of those analyses are presented in this report.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A once-molten, coarse-grained, Ca-rich inclusion in Allende

A compact, spheroidal Type B inclusion in Allende contains melilite laths that project radially inward from the inclusion edge which show interference growth textures. The combined textural and chemical features of this object cannot be explained by independent vapor-solid condensation of grains in space, followed by random aggregation of these grains into an inclusion. Instead, it probably formed from a once-molten droplet that crystallized in response to radiative cooling from its outer surface. The crystallization sequence in this and another similar inclusion in which oxygen isotopes have been measured is melilite-spinel-anorthite-fassaite; this sequence shows that oxygen isotopic heterogeneities in coarse-grained inclusions were formed after complete solidification of these objects by partial exchange with a less O-16-rich gas, and not during or before a melting event.

Macpherson, G. J.↗

Airborne and spaceborne radar images for geologic and environmental mapping in the Amazon rain forest, Brazil

Spaceborne and airborne radar image of portions of the Middle and Upper Amazon basin in the state of Amazonas and the Territory of Roraima are compared for purposes of geological and environmental mapping. The contrasted illumination geometries and imaging parameters are related to terrain slope and surface roughness characteristics for corresponding areas that were covered by each of the radar imaging systems. Landforms range from deeply dissected mountain and plateau with relief up to 500 m in Roraima, revealing ancient layered rocks through folded residual mountains to deeply beveled pediplain in Amazonas. Geomorphic features provide distinct textural signatures that are characteristic of different rock associations. The principle drainages in the areas covered are the Rio Negro, Rio Branco, and the Rio Japura. Shadowing effects and low radar sensitivity to subtle linear fractures that are aligned parallel or nearly parallel to the direction of radar illumination illustrate the need to obtain multiple coverage with viewing directions about 90 degrees. Perception of standing water and alluvial forest in floodplains varies with incident angle and with season. Multitemporal data sets acquired over periods of years provide an ideal method of monitoring environmental changes.

Ford, John P.↗

Eucrite Impact Melt NWA 5218 - Evidence for a Large Crater on Vesta

Northwest Africa (NWA) 5218 is a 76 g achondrite that is classified as a eucrite [1]. However, an initial classification [2] describes it as a "eucrite shock-melt breccia...(in which) large, partially melted cumulate basalt clasts are set in a shock melt flow...". We explore the petrology of this clast-bearing impact melt rock (Fig. 1), which could be a characteristic lithology at large impact craters on asteroid Vesta [3]. Methods: Optical microscopy, scanning electronmicroscopy, and Raman spectroscopy were used on a thin section (Fig. 1) for petrographic characterization. The impact melt composition was determined by 20 m diameter defocused-beam analyses with a Cameca SX-100 electron microprobe. The data from 97 spots were corrected for mineral density effects [4]. Constituent mineral phases were analyzed with a focusedbeam. Bidirectonal visible and near-infrared (VNIR) and biconical FT-IR reflectance spectra were measured on the surface of a sample slab on its central melt area and on an eucrite clast, and from 125-500 m and <125 m powders of melt. Results: General petrography: The sample specimen is a coherent, medium dark-grey (N4), melt rock. The thin section captures a central, subophitic-textured melt that contains ~1 cm to tens of m-size subangular to rounded, variably-shocked eucrite clasts. Clasts >100 m are coarse-grained with equigranular ~1 mm size plagioclase, quartz, and clinopyroxene (Fig. 1). Single crystals of chromite, ilmenite, zircon, Ca-Mg phosphate, Fe-metal, and troilite are embedded in the melt. Polymineralic clasts are mostly compositionally similar to the above mentioned larger clasts but scarce granulitic fragments are observed as well.

Wittmann, Axel↗

Empirical Study of the Multiaxial, Thermomechanical Behavior of NiTiHf Shape Memory Alloys

An empirical study was conducted to characterize the multiaxial, thermomechanical responses of new high temperature NiTiHf alloys. The experimentation included loading thin walled tube Ni(sub 50.3)Ti(sub 29.7)Hf(sub 20) alloy samples along both proportional and nonproportional axial-torsion paths at different temperatures while measuring surface strains using stereo digital image correlation. A Ni(sub 50.3)Ti(sub 33.7)Hf(sub 16) alloy was also studied in tension and compression to document the effect of slightly depleting the Hf content on the constitutive responses of NiTiHf alloys. Samples of both alloys were made from nearly texture free polycrystalline material processed by hot extrusion. Analysis of the data shows that very small changes in composition significantly alter NiTiHf alloy properties, as the austenite finish (Af) temperature of the 16-at Hf alloy was found to be approximately 60 C less than the 20-at Hf alloy (approximately 120 C vs. 180 C). In addition, the 16-at Hf alloy exhibited smaller compressive transformation strains (2 vs. 2.5 percent). Multi-axial characterization of the 20-at % Hf alloy showed that while the random polycrystal transformation strains in tension (4 percent) and compression (2.5 percent) are modest in comparison with binary NiTi (6 percent, 4 percent), the torsion performance is superior (7 vs. 4 shear strain width to the pseudoelastic plateau).

tensile deformation↗

The Geology of Pluto and Charon Through the Eyes of New Horizons

NASA's New Horizons spacecraft has revealed the complex geology of Pluto and Charon. Pluto shows ongoing surface geological activity centered on a vast basin containing a thick layer of volatile ices that is involved in convection and advection, with a crater retention age no greater than 10 Ma. Surrounding terrains show active glacial flow, apparent transport and rotation of large buoyant water-ice crustal blocks, and pitting by sublimation erosion and/or collapse. More enigmatic features include tall mounds with central depressions that are conceivably cryovolcanic, and ridges with complex bladed textures. Pluto also has ancient cratered terrains up to 4 Ga old that are extensionally fractured and extensively mantled and eroded by glacial or other processes. Charon is not currently active, but experienced major extensional tectonism and resurfacing (probably cryovolcanic) nearly 4 billion years ago. Impact crater populations on Pluto and Charon are not consistent with the steepest proposed impactor size-frequency distributions.

New Horizons spacecraft↗

Reconstructing porous media using generative flow networks

One area of intense scientific interest for the study of sandstones, carbonates, and shale at the pore scale is the use of limited image and petrophysical data to generate multiple realizations of a rock’s pore structure. Such images aid efforts to quantify uncertainty in petrophysical properties, including porosity–permeability transforms. We develop and evaluate a deep learning-based method to synthesize porous media volumes using a so-called generative flow model trained on x-ray microscope images of rock texture and pore structure. These models are optimized on a log-likelihood objective and they synthesize large and realistic three-dimensional images. Further, we demonstrate the rapid generation of sandstone image volumes that display realism as gauged by quantitative comparison of topological features using Minkowski functionals of porosity, specific surface area, and the Euler–Poincaré characteristic (i.e., pore connectivity). We also evaluate the single-phase permeability using Navier–Stokes and lattice Boltzmann methods and show that transport properties of the generated samples match measured trends.

58 GEOSCIENCES↗

Analysis of Dust Samples Collected from an Inland ISFSI Site (Site A)

In September of 2020, dust samples were collected from the surface of spent nuclear fuel (SNF) dry storage canisters during an inspection at an inland Independent Spent Fuel Storage Installation. The purpose of the sampling was to assess the composition and abundance of the soluble salts present on the canister surface, information which provides a metric for potential corrosion risks. The samples were delivered to Sandia National laboratories for analysis. At Sandia, the soluble salts were leached from the dust and quantified by ion chromatography. In addition, subsamples of the dust were taken for scanning electron microscope analysis to determine the texture and mineralogy of the dust and salts. The results of those analyses are presented in this report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Crack toughness evaluation of hot pressed and forged beryllium

Beryllium fracture toughness test specimens were fatigue cracked using reversed cycling with a compression load two to three times the tension load. In worked beryllium, textures may be produced which result in fatigue cracks that are out of plane with the starter notch. Specimens of hot pressed stock exhibited load displacement records which were nonlinear throughout their course. Fracture specimens of both hot pressed and forged stock showed essentially no reduction of thickness and the fracture surfaces were flat and normal to the load axis. However, the stress intensity factor at maximum load increased with decreasing thickness. Load-displacement and electric potential records for the hot pressed beryllium specimens exhibited several anomalies such as negative residual crack mouth displacements and a decrease in electrical potential with increasing load.

Jones, M. H.↗

Faults on Skylab imagery of the Salton Trough area, Southern California

The author has identified the following significant results. Large segments of the major high angle faults in the Salton Trough area are readily identifiable in Skylab images. Along active faults, distinctive topographic features such as scarps and offset drainage, and vegetation differences due to ground water blockage in alluvium are visible. Other fault-controlled features along inactive as well as active faults visible in Skylab photography include straight mountain fronts, linear valleys, and lithologic differences producing contrasting tone, color or texture. A northwestern extension of a fault in the San Andreas set, is postulated by the regional alignment of possible fault-controlled features. The suspected fault is covered by Holocene deposits, principally windblown sand. A northwest trending tonal change in cultivated fields across Mexicali Valley is visible on Skylab photos. Surface evidence for faulting was not observed; however, the linear may be caused by differences in soil conditions along an extension of a segment of the San Jacinto fault zone. No evidence of faulting could be found along linears which appear as possible extensions of the Substation and Victory Pass faults, demonstrating that the interpretation of linears as faults in small scale photography must be corroborated by field investigations.

Merifield, P. M.↗

Alteration of Sedimentary Clasts in Martian Meteorite Northwest Africa 7034

The martian meteorite Northwest Africa (NWA) 7034 and pairings represent the first brecciated hand sample available for study from the martian surface [1]. Detailed investigations of NWA 7034 have revealed substantial lithologic diversity among the clasts [2-3], making NWA 7034 a polymict breccia. NWA 7034 consists of igneous clasts, impact-melt clasts, and "sedimentary" clasts represented by prior generations of brecciated material. In the present study we conduct a detailed textural and geochemical analysis of the sedimentary clasts.

McCubbin, F. M.↗

Soil Evaporation Stress Determines Soil Moisture‐Evapotranspiration Coupling Strength in Land Surface Modeling

Model‐based estimates of soil moisture (SM)‐evapotranspiration (ET) coupling strength(ρ) vary widely and are prone to bias. Here we apply numerical modeling and remote sensing to identify the process‐level source of modeledρbias with the goal of improving the fidelity of current Earth system models. Results illustrate that modeledρis most strongly determined by soil evaporation (E) stress, and (generally positive)ρmodeling bias is attributable to the oversimplification of soil texture impacts on E stress. Based on new remotely sensed estimates ofρ, we demonstrate that removingρbias via a single optimized E stress parameter leads to improved ET accuracy and resolves a well‐known modeling bias in the partitioning of ET into E and T. As such, we highlight the importance of the stress function relating E and SM and its central role in regulating land‐atmosphere coupling processes impacting local climate.

Jianzhi Dong↗

Ubiquity and Causes of Soil Water Preferential Flow Across 17 Ecoregions

Abstract Preferential flow (PF) in soil causes the rapid transport of water, nutrients, and contaminants into the subsurface, influencing groundwater recharge and streamflow. Data scarcity has hindered the quantification of PF occurrence and the identification of its drivers across diverse ecoregions. We address this gap by analyzing high‐frequency, multi‐depth soil moisture data across 17 ecoregions in the USA, using ∼1,500 sensors at 40 sites. We discovered that PF is widespread, with sites experiencing PF in up to 60% of rainfall events ≥2 mm. Multiple approaches consistently show that PF is more likely to occur with increased peak rainfall intensity, finer textured material, low soil moisture variability, humid climate, and higher net primary productivity. This suggests that PF patterns could shift with projected climate changes, increasing uncertainty in predictions of groundwater recharge, water quality, and streamflow generation. Plain Language Summary Water can bypass part of the soil's matrix through a process called preferential flow (PF). This quick transport of water through the soil brings with it nutrients and contaminants and eventually makes it to groundwater and streams. To ensure ample amounts of good quality groundwater and surface water we need to understand when and where PF occurs. We inferred when PF occurred at 40 different sites across 17 ecoregions in the USA using soil moisture and rainfall data. We found that PF happened at all sites and in up to 60% of rainfall events ≥2 mm. Preferential flow was most likely at sites with high rainfall intensities, high clay content in soils, low variability in soil moisture, and high vegetation productivity. As rainfall intensities are predicted to increase due to climate change and vegetation becomes more productive, PF occurrence becomes more important for predicting groundwater recharge, water quality, and streamflow generation. Key Points Preferential flow (PF) is ubiquitous across the USA and occurs in up to 60% of all rainfall events ≥2 mm Rainfall intensity, soil texture, and antecedent soil moisture emerge as critical in generating PF across diverse ecoregions Two different PF detection approaches show similar relationships between key drivers and occurrence of PF

Li, Bonan↗

The Extraterrestrial Materials Simulation Laboratory

In contrast to fly-by and orbital missions, in situ missions face an incredible array of challenges in near-target navigation, landing site selection, descent, landing, science operations, sample collection and handling, drilling, anchoring, subsurface descent, communications, and contamination. The wide range of materials characteristics and environments threaten mission safety and success. For example, many physical properties are poorly characterized, including strength, composition, heterogeneity, phase change, texture, thermal properties, terrain features, atmospheric interaction, and stratigraphy. Examples of the range of materials properties include, for example: (1) Comets, with a possible compressive strength ranging from a light fluff to harder than concrete: 10(exp 2) to 10 (exp 8) Pa; (2) Europa, including a possible phase change at the surface, unknown strength and terrain roughness; and (3) Titan, with a completely unknown surface and possible liquid ocean. Additional information is contained in the original extended abstract.

Green, J. R.↗

Classification of Mars Pathfinder Rock Surfaces Using Quantitative Morphologic Indices

We have examined the morphology of rocks in two regions of the MPF landing site in terms of location, size and dimensions, sphericity sphericity and elongation, and have correlated this information with spectral data extracted from associated rock surfaces, with the goal of improving the likelihood of discerning between rock and rock surface types. We use four highly diverse Imager for Mars Pathfinder (IMP) images centered on Mini-Matterhorn and the Rock Garden because they are suited to demonstrate the wide morphologic variation of rocks at the site. A sampling of rocks was chosen at these locations that represented a range of shapes, textures and spectral signatures. In this initial analysis we focused upon the largest rocks that are situated in such a way as to allow easy viewing of most of the faces.

Yingst, R. A.↗

Irregular Mare Patches (IMPs): 100 Ma or 3 Ga?

IMPs exhibit a perplexing combination of characteristics that are consistent with either an approximately 100 Ma or 3 Ga formation. Dozens of small-area IMPs have crisp morphologies and crater size-frequency distributions (SFDs) that denote relatively recent geologic activity (less than 100 Ma); however, the apparently well-developed regolith on portions of the IMPs are in conflict with such a young age [1]. To test possible formation hypotheses (e.g., [1-5]), which range from ancient volcanism to contemporary outgassing, we examined IMP morphology at the meter-scale with LROC NAC images and derived elevation models. We focused on the largest IMPs (Ina, Sosigenes, Cauchy, Maskelyne, and Nubium), where contacts between deposits are best developed. Most of our observations are consistent with multiple generations of inflation and breakouts (or squeeze-ups) of basaltic lavas that were affected by local slopes. Some of the extrusions coalesced into larger mounds or filled pre-existing craters. We did not observe evidence of large-scale void space (e.g., fissures, fractures, linear depressions, or pits) within or beneath the mounds or rougher deposits (e.g., [5]). But, small-scale voids may be signified by isolated pitted textures. We also did not detect evidence of the cooling fractures or lava plates expected in young lava flows and observed in lunar impact melt deposits. The smooth texture of the mounds is enigmatic. Block-less craters suggest at least 5 m of friable or poorly-cohesive material (such as regolith), yet mound margins exhibit slopes greater than 30 deg requiring significant material strength. Blocks are not common on the mounds, but are sometimes excavated by impacts (usually excavated from beneath the mounds). The uneven deposits are equally enigmatic and texturally varied (blocky, pitted, and crenulated). They are deficient in superposed craters compared to the mounds. If the mounds are indeed of similar age to the rougher units, then their different superposed crater morphologies and SFDs need to be explained by factors other than their ages. Any mounds originally composed of friable surface materials would evolve differently from more coherent deposits (e.g., [6-7]).

Stopar, Julie↗

The Impact of Freeze‐Thaw History on Soil Carbon Response to Experimental Freeze‐Thaw Cycles

Abstract Freeze‐thaw is a disturbance process in cold regions where permafrost soils are becoming vulnerable to temperature fluctuations above 0°C. Freeze‐thaw alters soil physical and biogeochemical properties with implications for carbon persistence and emissions in Arctic landscapes. We examined whether different freeze‐thaw histories in two soil systems led to contrasting biogeochemical responses under a laboratory‐controlled freeze‐thaw incubation. We investigated controls on carbon composition through Fourier‐transform ion cyclotron resonance mass spectrometry (FT‐ICR‐MS) to identify nominal carbon oxidation states and relative abundances of aliphatic‐type carbon molecules in both surface and subsurface soils. Soil cores (∼60 cm‐depth) were sampled from two sites in Alaskan permafrost landscapes with different in situ freeze‐thaw characteristics: Healy (>40 freeze‐thaw cycles annually) and Toolik (<15 freeze‐thaw cycles annually). FT‐ICR‐MS was coupled with in situ temperature data and soil properties (i.e., soil texture, mineralogy) to assess (a) differences in soil organic matter composition associated with previous freeze‐thaw history and (b) sensitivity to experimental freeze‐thaw in the extracted cores. Control (freeze‐only) samples showed greater carbon oxidation in Healy soils compared with Toolik, even in lower mineral horizons where freeze‐thaw history was comparable across both sites. Healy showed the most loss of carbon compounds following experimental freeze‐thaw in the lower mineral depths, including a decrease in aliphatics. Toolik soils responded more slowly to freeze‐thaw as shown by intermediary carbon oxidation distributed across multiple carbon compound classes. Variations in the response of permafrost carbon chemistry to freeze‐thaw is an important factor for predicting changes in soil function as permafrost thaws in high northern latitudes.

Rooney, Erin C.↗

Beam impingement angle effects on secondary electron emission characteristics of textured pyrolytic graphite

Experimentally determined values of true secondary electron emission and relative values of reflected primary electron yield for untreated and ion-textured pyrolytic graphite over a range of primary electron energy levels and electron beam impingement angles are presented. Information required to develop high efficiency multistage depressed collectors (MDC's) for microwave amplifier traveling-wave tubes for space communication and aircraft applications is provided. To attain the highest possible MDC efficiencies, the electrode surfaces must have low secondary electron emission characteristics. Pyrolytic graphite, a chemically vapor-deposited material, is a particularly promising candidate for this application. The pyrolytic graphite surfaces studied were tested over a range of primary electron beam energies and beam impingement angles from 200 to 2000 eV and direct (0 deg) to near-grazing angles (85 deg), respectively. Surfaces both parallel to and normal to the planes of material deposition were examined. The true secondary electron emission and reflected primary electron yield characteristics of the pyrolytic graphite surfaces are compared to those of sooted control surfaces.

Curren, A. N.↗