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At least 955 records · Page 53

O I concentration in Comet Halley

The present 200-mA spectral resolution and 1-inch spatial resolution long-slit spectra centered on Comet Halley's nucleus show an emission feature at the 5577 A wavelength of the green O I line whose spatial variation is very similar to that of the O I 6300-A line, but not the C2 bandhead nearby. On the assumption that the cometary O I 5577 A feature should share the cometary O I 6300-A line's spatial distribution, the 5577-A feature becomes at least partly attributable to oxygen; the ratio of the 6300-A line to the 5577-A line is then of the order of 10:1, which is consistent with the Festou and Feldman (1981) model in which water is the parent for the O I concentration features.

Smith, W. Hayden↗

Generating Vegetation Leaf Area Index Earth System Data Record from Multiple Sensors: Theory - Part 1

The generation of multi-decade long Earth System Data Records (ESDRs) of Leaf Area Index (LAI) and Fraction of Photosynthetically Active Radiation absorbed by vegetation (FPAR) from remote sensing measurements of multiple sensors is key to monitoring long-term changes in vegetation due to natural and anthropogenic influences. Challenges in developing such ESDRs include problems in remote sensing science (modeling of variability in global vegetation, scaling, atmospheric correction) and sensor hardware (differences in spatial resolution, spectral bands, calibration, and information content). In this paper, we develop a physically based approach for deriving LAI and FPAR products from the Advanced Very High Resolution Radiometer (AVHRR) data that are of comparable quality to the Moderate resolution Imaging Spectroradiometer (MODIS) LAI and FPAR products, thus realizing the objective of producing a long (multi-decadal) time series of these products. The approach is based on the radiative transfer theory of canopy spectral invariants which facilitates parameterization of the canopy spectral bidirectional reflectance factor (BRF). The methodology permits decoupling of the structural and radiometric components and obeys the energy conservation law. The approach is applicable to any optical sensor, however, it requires selection of sensor-specific values of configurable parameters, namely, the single scattering albedo and data uncertainty. According to the theory of spectral invariants, the single scattering albedo is a function of the spatial scale, and thus, accounts for the variation in BRF with sensor spatial resolution. Likewise, the single scattering albedo accounts for the variation in spectral BRF with sensor bandwidths. The second adjustable parameter is data uncertainty, which accounts for varying information content of the remote sensing measurements, i.e., Normalized Difference Vegetation Index (NDVI, low information content), vs. spectral BRF (higher information content). Implementation of this approach indicates good consistency in LAI values retrieved from NDVI (AVHRRmode) and spectral BRF (MODIS-mode). Specific details of the implementation and evaluation of the derived products are detailed in the second part of this two-paper series.

Ganguly, Sangram↗

Single Field-of-View Sounding Atmospheric Products

The Single Field-of-view Sounder Atmospheric Products (SiFSAP) answer the need for a novel high spatial resolution atmospheric data product for major hyper-spectral infrared (IR) sounder missions. SiFSAP include a complete set of atmospheric vertical profiles, cloud, and surface properties, which are physically retrieved from top-of-atmosphere (TOA) spectral radiances under all-sky conditions via a rigorously defined radiative transfer relationship. By using a state-of-art fast radiative transfer model and a carefully designed optimal estimation based physical retrieval scheme, the SiFSAP algorithm ensures both an ultra-fast data processing speed needed for operational weather applications and the radiometric consistency desired by long-term climate studies. SiFSAP supplement existing operational products by providing data at the native spatial resolution of the sounder instruments, the direct and accurate retrieval of cloud scattering properties, and the establishment of ‘radiance closure.’

single-field-of-view, retrieval, hyperspectral sou↗

Inter-Comparison of GOES-8 Imager and Sounder Skin Temperature Retrievals

Skin temperature (ST) retrievals derived from geostationary satellite observations have both high temporal and spatial resolutions and are therefore useful for applications such as assimilation into mesoscale forecast models, nowcasting, and diagnostic studies. Our retrieval method uses a Physical Split Window technique requiring at least two channels within the longwave infrared window. On current GOES satellites, including GOES-11, there are two Imager channels within the required spectral interval. However, beginning with the GOES-M satellite the 12-um channel will be removed, leaving only one longwave channel. The Sounder instrument will continue to have three channels within the longwave window, and therefore ST retrievals will be derived from Sounder measurements. This research compares retrievals from the two instruments and evaluates the effects of the spatial resolution and sensor calibration differences on the retrievals. Both Imager and Sounder retrievals are compared to ground-truth data to evaluate the overall accuracy of the technique. An analysis of GOES-8 and GOES-11 intercomparisons is also presented.

Haines, Stephanie L.↗

The Sensitivity of Coded Mask Telescopes

Simple formulae are often used to estimate the sensitivity of coded mask X-ray or gamma-ray telescopes, but t,hese are strictly only applicable if a number of basic assumptions are met. Complications arise, for example, if a grid structure is used to support the mask elements, if the detector spatial resolution is not good enough to completely resolve all the detail in the shadow of the mask or if any of a number of other simplifying conditions are not fulfilled. We derive more general expressions for the Poisson-noise-limited sensitivity of astronomical telescopes using the coded mask technique, noting explicitly in what circumstances they are applicable. The emphasis is on using nomenclature and techniques that result in simple and revealing results. Where no convenient expression is available a procedure is given which allows the calculation of the sensitivity. We consider certain aspects of the optimisation of the design of a coded mask telescope and show that when the detector spatial resolution and the mask to detector separation are fixed, the best source location accuracy is obtained when the mask elements are equal in size to the detector pixels.

Skinner, Gerald K.↗

Effect of Landsat Thematic Mapper sensor parameters on land cover classification

Selected sensor parameter differences between TM and MSS were assessed through classification performance of a suburban/regional test site. Overall classification accuracy of a seven-band Landsat TM scene in comparison to MSS yielded an improvement in accuracy from 74.8 percent to 83.2 percent. To study the possible causes for the difference in classification performance, key sensor parameter differences between MSS and TM, including: (1) spatial resolution (30 m for TM versus 80 m for MSS), (2) quantization level (256 levels for TM versus 64 for MSS), and (3) spectral regions (seven bands in four major spectral regions for TM versus four bands in two regions for MSS), were evaluated. Landsat TM data were processed to stimulate all possible combinations of these MSS and TM parameters, yielding a three-factor design with two levels per factor. The results indicated that the added spectral regions (TM 1, TM 5, and TM 7) and to a lesser degree the increase in quantization level to eight bits produced the improved TM classification accuracy. However, in this study, the higher 30 m spatial resolution of TM contributed to a reduced classification accuracy from increased within-field variability or class heterogeneity.

Toll, D. L.↗

Ultra-Long Distance BOTDA Sensor System Employing Hybrid Amplification and Advanced Noise Reduction Techniques

Brillouin Optical Time Domain Analysis (BOTDA) sensor systems play a pivotal role in distributed sensing, which enables precise measurements of strain and temperature across extensive fiber lengths. This research offers a comprehensive strategy to extend the sensing range of BOTDA systems beyond tens of kilometers while maintaining high spatial resolutions. Such enhanced sensing is realized through the integration of distributed Raman amplification, inline amplification using erbium-doped fiber amplifiers (EDFA), and advanced noise reduction techniques. Optimizing Raman pump and probe wave profiles ensures the robustness of Brillouin scattering signals, effectively countering attenuation-induced losses. Additionally, enhancing weak Brillouin signals by strategically placing EDFAs at optimal fiber locations keeps sensor sensitivity high. Leveraging inherent redundancy in measured data as a function of frequency and fiber distance, the non-local means (NLM) filter removes noise while preserving essential physical information. In summary, this research has shown a holistic exploration of extending BOTDA’s distance sensing capabilities up to 150 km with spatial resolutions of 8 meters.

Bhatta, Hari↗

Detecting Magnon-phonon coupling in yttrium iron garnet with variable temperature STEM-EELS

Magnons, quanta of spin wave excitations in magnetically ordered materials, have been identified as candidates for several potentially transformative technologies in recent years. Macroscopic techniques, such as neutron scattering or Raman spectroscopy, can be used to identify and analyze magnons, but provide relatively delocalized information about the sample. Understanding how the bonding and local structure of a material interacts with, and influences, the magnon population in a material is a crucial step toward the ability to produce any real-world application utilizing magnons. By leveraging the combined spatial resolution of scanning transmission electron microscopy (STEM) and the energy resolution of monochromated electron energy-loss spectroscopy (EELS) nanoscale analysis of magnons can be performed. While the weak interaction of magnons with the electron beam makes magnon EELS challenging on reasonable timescales, magnon-phonon coupling can be leveraged to understand magnons through their effect on the more easily measured phonons. Here, we examine yttrium iron garnet (YIG) flakes, and demonstrate non-linear, temperature-dependent shifts in the phonon frequencies, consistent with previously described magnon-phonon coupling effects. The ability to measure the temperature-dependence of vibrational frequencies with high precision in individual nanoscale flakes, demonstrates the ability to study magnon-phonon coupling in the STEM with unprecedented spatial resolution.

Reifsnyder, Alexander [ORNL]↗

Spatial imaging of UV emission from Jupiter and Saturn

Spatial imaging with the IUE is accomplished both by moving one of the apertures in a series of exposures and within the large aperture in a single exposure. The image of the field of view subtended by the large aperture is focussed directly onto the detector camera face at each wavelength; since the spatial resolution of the instrument is 5 to 6 arc sec and the aperture extends 23.0 by 10.3 arc sec, imaging both parallel and perpendicular to dispersion is possible in a single exposure. The correction for the sensitivity variation along the slit at 1216 A is obtained from exposures of diffuse geocoronal H Ly alpha emission. The relative size of the aperture superimposed on the apparent discs of Jupiter and Saturn in typical observation is illustrated. By moving the planet image 10 to 20 arc sec along the major axis of the aperture (which is constrained to point roughly north-south) maps of the discs of these planets are obtained with 6 arc sec spatial resolution.

Clarke, J. T.↗

High-Frequency Density Oscillations from a Plasma Source Used for Simulating Low-Earth Orbit Plasma Environment

We present data from ground-based, vacuum-chamber tests demonstrating the ability to modulate the output of a plasma source capable of producing a low-Earth orbit (LEO) type plasma. We obtained plasma oscillations up to 2.5 kHz impingent on stationary test equipment, which corresponds to meter-level ionospheric structures in LEO. This plasma source is, therefore, suitable for developing scientific instruments that measure the LEO plasma environment, in situ, with meter-level spatial resolution. Measurements were made using a fixed-bias collector and an electrometer sampling at 40 kHz. A mechanical aperture was established at the output of the plasma source via two concentric grids. The outer grid was free to rotate in the azimuthal direction with respect to the fixed inner grid. An identical, alternating hole pattern in the two grids resulted in a variable aperture that cycles through 90 open/close cycles per revolution. The frequency of the plasma oscillations is limited by the mechanism used to spin the grids and the bearing assembly on which the grids rotate. Higher frequencies are obtainable by upgrading the drive mechanism, allowing the possibility of centimeter-level spatial resolution.

McTernan, Jesse K.↗

Direct Measurement Sensor of the Boundary Shear Stress in Fluid Flow

The flow fields and boundary erosion that are associated with scour at bridge piers are very complex. Direct measurement of the boundary shear stress and boundary pressure fluctuations in experimental scour research has always been a challenge and high spatial resolution and fidelity have been almost impossible. Most researchers have applied an indirect process to determine shear stress using precise measured velocity profiles. Laser Doppler Anemometry and Particle Image Velocimetry are common techniques used to accurately measure velocity profiles. These methods are based on theoretical assumptions to estimate boundary shear stress. In addition, available turbulence models cannot very well account for the effect of bed roughness which is fundamentally important for any CFD simulation. The authors have taken on the challenge to advance the magnitude level to which direct measurements of the shear stress in water flow can be performed. This paper covered the challenges and the efforts to develop a higher accuracy and small spatial resolution sensor. Also, preliminary sensor designs and test results are presented.

Badescu, Mircea↗

Vertical effective stress and temperature as controls of quartz cementation in sandstones: Evidence from North Sea Fulmar and Gulf of Mexico Wilcox sandstones

Here we present quantitative petrographic data, high spatial resolution oxygen isotope analyses of quartz cement, basin modelling and a kinetic model for quartz precipitation for two Paleocene-Eocene Wilcox Group sandstones from Texas and two Jurassic Fulmar Formation sandstones from the Central North Sea. At each location, one sandstone has been buried to ca. 145 °C and one to ca. 185 °C. A key difference between the Wilcox and Fulmar burial histories is that the Wilcox sandstones are currently at higher vertical effective stresses and, from basin modelling studies, have been subjected to generally higher vertical effective stresses through their burial history. The amounts of quartz cement in the Wilcox sandstones are between 12 and 18%, and between 2 and 6% in the Fulmar sandstones. High-spatial-resolution oxygen isotope data obtained from the quartz cements suggest temperature ranges for quartz precipitation from 60 to 80 °C to values approaching maximum burial temperature. Factors such as grain coatings or the timing of petroleum emplacement cannot explain the differences in the amounts of quartz cement. Petrographic data show that most of the silica for quartz cement can be derived from intergranular pressure dissolution. Although the sample set is small, we interpret the results to suggest that the differences in quartz cementation in Fulmar and Wilcox sandstones can be explained better by differences in their vertical effective stress history than their temperature history; in this case, the supply of silica rather than the precipitation of quartz becomes an important control on the rate and extent of cementation.

58 GEOSCIENCES↗

Combining Spatial and Temporal Resolution in Cryo-TEM of Device Materials: Preprint

Cryogenic transmission electron microscopy (cryo-TEM) has been instrumental to reducing the effects of electron-beam sample interactions and enabling higher spatial resolution studies of beam sensitive materials. However, the process of thinning and freezing samples for cryo-TEM characterization is often complex and frequently involves removing materials from their environment or stimuli of interest for extended times. This can allow for structural relaxation, diffusion, and other dynamic processes to occur prior to characterization; for energy materials like battery electrodes, this makes it difficult to precisely correlate the imaged structure with native structures that evolve in-situ during device processing, operation, or aging. Here, we present methods to prepare cryo-TEM samples from energy materials during these critical processes in the relevant device lifetimes. This offers insights into improving the temporal resolution of cryo-TEM, while still exploiting its ability to achieve high spatial resolutions in characterizing beam sensitive materials.

BASIC BIOLOGICAL SCIENCES,MATERIALS SCIENCE↗

X-ray linear dichroic tomography of crystallographic and topological defects

Abstract The functionality of materials is determined by their composition 1–4 and microstructure, that is, the distribution and orientation of crystalline grains, grain boundaries and the defects within them 5,6 . Until now, characterization techniques that map the distribution of grains, their orientation and the presence of defects have been limited to surface investigations, to spatial resolutions of a few hundred nanometres or to systems of thickness around 100 nm, thus requiring destructive sample preparation for measurements and preventing the study of system-representative volumes or the investigation of materials under operational conditions 7–15 . Here we present X-ray linear dichroic orientation tomography (XL-DOT), a quantitative, non-invasive technique that allows for an intragranular and intergranular characterization of extended polycrystalline and non-crystalline 16 materials in three dimensions. We present the detailed characterization of a polycrystalline sample of vanadium pentoxide (V 2 O 5 ), a key catalyst in the production of sulfuric acid 17 . We determine the nanoscale composition, microstructure and crystal orientation throughout the polycrystalline sample with 73 nm spatial resolution. We identify and characterize grains, as well as twist, tilt and twin grain boundaries. We further observe the creation and annihilation of topological defects promoted by the presence of volume crystallographic defects. The non-destructive and spectroscopic nature of our method opens the door to operando combined chemical and microstructural investigations 11,18 of functional materials, including energy, mechanical and quantum materials.

Science & Technology - Other Topics↗

Integrating collapsible plasmonic gaps on near-field probes for polarization-resolved mapping of plasmon-enhanced emission in 2D material

Scanning near-field optical microscopy (SNOM) is an important technique used to study the optical properties of material systems at the nanoscale. In previous work, we reported on the use of nanoimprinting to improve the reproducibility and throughput of near-field probes including complicated optical antenna structures such as the ‘campanile’ probe. However, precise control over the plasmonic gap size, which determines the near-field enhancement and spatial resolution, remains a challenge. Here, we present a novel approach to fabricating a sub-20 nm plasmonic gap in a near-field plasmonic probe through the controlled collapse of imprinted nanostructures using atomic layer deposition (ALD) coatings to define the gap width. The resulting ultranarrow gap at the apex of the probe provides a strong polarization-sensitive near-field optical response, which results in an enhancement of the optical transmission in a broad wavelength range from 620 to 820 nm, enabling tip-enhanced photoluminescence (TEPL) mapping of 2-dimensional (2D) materials. We demonstrate the potential of this near-field probe by mapping a 2D exciton coupled to a linearly polarized plasmonic resonance with below 30 nm spatial resolution. This work proposes a novel approach for integrating a plasmonic antenna at the apex of the near-field probe, paving the way for the fundamental study of light-matter interactions at the nanoscale.

Zhou, Junze (ORCID:000000020682767X)↗

Protocols for x-ray transient grating pump/optical probe experiments at x-ray free electron lasers

Abstract Transient grating spectroscopy is a specialized application of the four-wave-mixing methodology and constitutes a versatile technique for investigating the dynamics of vibrational, magnetic and electronic degrees of freedom of matter in a background-free fashion. Recent developments in free-electron laser sources have enabled the extension of this technique into the extreme ultraviolet range. Ongoing efforts to expand transient grating spectroscopy into the x-ray regime promise numerous advantages: (1) substantial penetration depths that allow for probing bulk material properties, (2) element specificity via specific core-excited states, and (3) short wavelengths that allow for excitation gratings with higher momentum transfer and improved spatial resolution. In this study, we comprehensively outline the procedures for conducting x-ray transient grating pump/optical probe experiment. The process encompasses the design and alignment of the experimental setup, as well as the subsequent steps involved in data acquisition and analysis. This paper is intended as a comprehensive guide for researchers interested in implementing x-ray transient grating spectroscopy, providing valuable insights into the intricacies of the experimental workflow required for this novel technique. Furthermore, we discuss the potential for extending this methodology to an x-ray pump/x-ray probe scheme, envisioning a future direction that holds promise for enhancing the capabilities and scope of x-ray transient grating spectroscopy, opening new opportunities for studying ultrafast processes with unprecedented temporal and spatial resolutions.

Optics↗

Spatially Resolved Domicile Charging Demands for Light-, Medium-, and Heavy-Duty Electric Vehicles in Virginia

The use of plug-in electric vehicles (PEVs) and resulting grid impacts are likely to grow rapidly, and evaluation of optimal smart charge management and grid integration strategies is warranted now. Evaluating distribution grid impacts requires fine-grained models of PEV operations to estimate charging loads across diverse vehicles at high spatial resolution. We propose such a model and consider a high-electrification scenario in Richmond and Newport News, Virginia. Our framework considers four categories of vehicle that are amenable to early aggressive electrification: light-duty passenger vehicles (LDV), trucks and vans with a focus on delivery or other local operations, school buses, and transit buses. These vehicles have a relatively consistent domicile, reducing the need for public charging infrastructure rollout to electrify. We apply a recent LDV model and propose new models for each vocation of medium- and heavy-duty vehicle, leveraging telematics data. We demonstrate our framework in Virginia and find energy demands in the region may total 15 GWh day, with most consumed by LDV. However, considering power demand at high spatial resolution reveals a different trend: LDVs have relatively small peak loads at specific sites (peak site demand around 800 kW) compared to average and high demand medium- and heavy-duty vehicle charging sites (peak site demand around 6,000 kW at a transit bus depot, 1,500 kW at a local freight hub, and 1,000 kW at a school). Our framework yields insights on the relative impacts of each vocation and enables future work to tailor grid integration strategies to each vehicle category.

33 ADVANCED PROPULSION SYSTEMS↗

Chandra ACIS Observations of Jovian X-Ray Emission

On November 25 and 26, 1999, the Chandra X-ray spacecraft conducted a set of four 19,000 sec observations of Jupiter. The ACIS-S instrument configuration was used for its good low energy efficiency and spatial resolution. An anomalous response was obtained which was subsequently attributed to strong jovian infrared radiation penetrating the detector and piling up spurious events across the entire X-ray range. However, the pre-observation establishment of an offsetting bias field has allowed the recovery of data from that portion of Jupiter's disc which remained within the elevated portion of the bias field during the observation. This ranges from fewer than 3000 sec to the entire observing time for about 10% of the planet. Auroral emission is seen near both poles in each observation. The northern aurora ia overall more intense than the southern, consistent with prior Einstein and ROSAT Observatory results. The southern aurora shows more modulation with Jupiter's rotation than the northern. Spatial resolution has been improved by at least a factor of two over prior measurements but convincing evidence of structure has not been seen. Lower latitude emission, first observed by ROSAT, is confirmed with flux levels averaging more than a factor of five below peak auroral values. Pronounced variation in the observed emission has occurred over the observing period. The spectral response extends from 0.24 keV, below which noise dominates, to about 1.2 keV. For all four observations the spectrum is clearly enhanced between 0.45 and 0.85 keV. This is apparently unequivocal evidence that Jupiter's X-ray emission is the result of oxygen and perhaps sulfur ions precipitating into the planet's atmosphere, where they undergo charge exchange interactions. The identification of specific transitions lines in the spectrum is among the ongoing efforts. A bremsstrahlung component has not yet been identified.

Garmire, Gordon↗