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At least 955 records · Page 53

Wavelength Dependence of the Absorption of Black Carbon Particles: Predictions and Results from the TARFOX Experiment and Implications for the Aerosol Single Scattering Albedo

Measurements are presented of the wavelength dependence of the aerosol absorption coefficient taken during the Tropical Aerosol Radiative Forcing Observational Experiment (TARFOX) over the northern Atlantic. The data show an approximate lamda(exp -1) variation between 0.40 and 1.0 micrometers. The theoretical basis of the wavelength variation of the absorption of solar radiation by elemental carbon [or black carbon (BC)] is explored. For a wavelength independent refractive index the small particle absorption limit simplifies to a lambda(exp -1) variation in relatively good agreement with the data. This result implies that the refractive indices of BC were relatively constant in this wavelength region, in agreement with much of the data on refractive indices of BC. However, the result does not indicate the magnitude of the refractive indices. The implications of the wavelength dependence of BC absorption for the spectral behavior of the aerosol single scattering albedo are discussed. It is shown that the single scattering albedo for a mixture of BC and nonabsorbing material decreases with wavelength in the solar spectrum (i.e., the percentage amount of absorption increases). This decease in the single scattering albedo with wavelength for black carbon mixtures is different from the increase in single scattering allied for most mineral aerosols (dusts). This indicates that, if generally true, the spectral variation of the single- scattering albedo can be used to distinguish aerosol types. It also highlights the importance of measurements of the spectral variation of the aerosol absorption coefficient and single scattering albedo.

Bergstrom, Robert W.↗

On the flaring of cometary plasma tails

Assuming that hypersonic pressure balance with the solar wind governs the shape of plasma tails, it is found that the gas pressure of tail ions and the magnetic field strength at the flanks of the ionopause control the flaring state. The gas pressure exhibits the larger effect: for constant pressures above a certain critical value, the tail flares essentially without limit, while for smaller values the tail flares only near the head (becoming cylindrical at greater distances). The influence of the magnetic field is that the tail flares to larger distances the higher the field strength at the flanks of the ionopause. The observed variability in flaring (and the implied differences in gas pressure and magnetic field) are throught to be the result of changes in the position and shape of the sunward cometary ionopause. Insertion of reasonable comet and solar wind parameters into the pressure balance equations is found to give good agreement with the observations.

Ershkovich, A. I.↗

Disorder-Tunable ZnGeP2 for Epitaxial Top Cells on Si

There has been a longstanding search for top cell materials for Si-based tandems. ZnGeP 2 is one material that could fit this need. It is lattice matched to Si and has the potential for tuning its band gap at fixed lattice constant via cation ordering. In this study, we investigate the effects of growth and annealing conditions on the structure of ZnGeP 2 thin films. Films were deposited amorphous and then annealed ex-situ. Using low anneal temperatures or short anneal times, we were able to kinetically trap the disordered phase. We also found composition to play a role in the degree of ordering in our films. Our findings support the hypothesis that ZnGeP 2 could be implemented as a material with tunable properties at fixed lattice constant through cation ordering.

14 SOLAR ENERGY↗

Modelling of polymer photodegradation for solar cell modules

A computer program developed to model and calculate by numerical integration the varying concentrations of chemical species formed during photooxidation of a polymeric material over time, using as input data a choice set of elementary reactions, corresponding rate constants and a convenient set of starting conditions is evaluated. Attempts were made to validate the proposed mechanism by experimentally monitoring the photooxidation products of small liquid alkane which are useful starting models for ethylene segments of polymers like EVA. The model system proved in appropriate for the intended purposes. Another validation model is recommended.

Somersall, A. C.↗

Activation Energy for End-of-Life Solder Bond Degradation: Thermal Cycling of Field-Aged PV Modules

The longevity of solar photovoltaic modules depends on the durability and reliability of their components, one of which is the solder bonds in interconnect ribbons. The solder joints experience stresses from thermal cycling and constant elevated temperatures (40 °C-70 °C) in regular field operation leading to thermo-mechanical fatigue and intermetallic compound formation. To study the end-of-life wear-out mechanisms and to obtain activation energy of solder bond degradation, here two field-aged modules from Arizona-a 21-year-old Solarex MSX60 module (with Sn62Pb36Ag2 at the solder joints) and an 18-year-old Siemens M55 module (with Sn60Pb40 at the solder joints)-underwent 800 and 400 modified thermal cycles, respectively. Using three heating blankets, each module had three temperature zones maintained at 85, 95, and 105 °C during the 15-min hot dwell time of the thermal cycle. Cell-level series resistance data obtained from three temperature zones enabled the calculation of activation energy for solder bond degradation for the MSX60 and the M55 modules to be 0.12 eV and 0.35 eV, respectively. From each temperature zone in both modules, busbar-solder samples were obtained, imaged through SEM, and analyzed with energy-dispersive X-ray spectroscopy. In the MSX60 module with traces of Ag in the solder material, phase segregation and growth were primarily observed at high temperatures. For M55 modules without Ag in the solder material, major phase segregation was observed in all temperature zones. The IMC thickness for both modules increased with increasing module temperature. The beneficial effect of Ag in solder material on mitigating solder bond degradation is presented.

14 SOLAR ENERGY↗

Diurnal variation of nitric oxide in the upper stratosphere

Two recent measurements of the temporal variation of nitric oxide at constant altitude near 40 km are reported. The observations were made at float altitude with a balloon-borne chemiluminescence detector together with in situ ozone measurements. The first measurement was made at 44 N on September 17, 1987, at an altitude of 40 km from before sunrise until 1000 LT. The second observation was made at the same latitude on June 18, 1988, at 39 km from 0800 to 1230 LT. At an altitude of 40 km, nitric oxide was observed to start increasing very rapidly at sunrise when the solar zenith angle reached about 95 deg. After the rapid initial buildup, the rate of NO increase stabilized for 3 hours at about 1.2 ppbv/hour. Near 1100 LT at 39 km in summer, the NO mixing ratio was observed to become nearly constant. These features of the diurnal variation of NO are in accord with the temporal variation expected from a time-dependent zero-dimensional photochemical model.

Kondo, Y.↗

On the additivity of climate responses to the volcanic and solar forcing in the early 19th century

The early 19th century was the coldest period over the past 500 years, when strong tropical volcanic events and a solar minimum coincided. The 1809 unidentified eruption and the 1815 Tambora eruption happened consecutively during the Dalton minimum of solar irradiance; however, the relative role of the two forcing (volcano and solar) agents is still unclear. In this study, we examine the responses from a set of early 19th century simulations with combined and separated volcanic and solar forcing agents, as suggested in the protocol for the past1000 experiment of the Paleoclimate Modelling Intercomparison Project – Phase 4 (PMIP4). From 20-member ensemble simulations with the Max Planck Institute Earth system model (MPI-ESM1.2-LR), we find that the volcano- and solar-induced surface cooling is additive in the global mean/large scale, regardless of combining or separating the forcing agents. The two solar reconstructions (SATIRE (Spectral and Total Irradiance REconstruction-Millennia model) and PMOD (Physikalisch-Meteorologisches Observatorium Davos)) contribute to a cooling before and after 1815 of ~0.05 and ~0.15 K monthly average near-surface air cooling, respectively, indicating a limited solar contribution to the early 19th century cold period. The volcanic events provide the main cooling contributions, inducing a surface cooling that peaks at ~0.82 K for the 1809 event and ~1.35 K for Tambora. After the Tambora eruption, the temperature in most regions increases toward climatology largely within 5 years, along with the reduction of volcanic forcing. In the northern extratropical oceans, the temperature increases slowly at a constant rate until 1830, which is related to the reduction of seasonality and the concurrent changes in Arctic sea-ice extent. The albedo feedback of Arctic sea ice is found to be the main contributor to the Arctic amplification of the cooling signal. Several non-additive responses to solar and volcanic forcing happen on regional scales. In the atmosphere, the stratospheric polar vortex tends to strengthen when combining both volcano and solar forcing, even though the two forcing agents separately induce opposite-sign changes in stratospheric temperatures and zonal winds. In the ocean, when combining the two forcings, additional surface cold water propagates to the northern extratropics from the additional solar cooling in the tropics, which results in regional cooling along the propagation. Overall, this study not only quantifies the surface responses from combinations of the volcano and solar forcing, but also highlights the components that cannot be simply added from the responses of the individual forcing agents, indicating that a relatively small forcing agent (such as solar in early 19th century) can impact the response from the large forcing (such as the 1815 Tambora eruption) when considering regional climates.

54 ENVIRONMENTAL SCIENCES↗

The spacecraft power supply system

The power supply system in the Telstar spacecraft consists of a solar cell plant to convert solar radiation to electrical energy when the satellite is illuminated by the sun, a 19-cell nickel-cadmium battery to store energy, and a regulation circuit to supply constant output voltages over a wide variation in input voltages. Additionally, the power supply system provides switching to conserve power and allow battery recharging during periods between communications experiments.

POWER SUPPLY↗

Spatially resolved infrared observations of Saturn. III - 10- and 20-micron disk scans at B prime = -11.8 deg

Disk scans of Saturn at 10 and 20 microns were obtained when the Saturnicentric solar declination B prime was -11.8 deg. The scans show little change from scans obtained when B prime was -16.3 deg. This could result from the long radiative time constant of the Saturnian atmosphere. The observations at 20 microns, in the H2 continuum, show positively that the temperature inversion at the south pole has a higher temperature than at any other point on the disk. In addition, the 12.1- and 20-micron scans indicate that the temperature of the inversion region is higher at the equator compared to the temperate zone. The data also suggest that enhanced 20-micron emission is correlated with the strength of the ultraviolet absorption.

Tokunaga, A. T.↗

Design data package and operating procedures for MSFC solar simulator test facility

Design and operational data for the solar simulator test facility are reviewed. The primary goal of the facility is to evaluate the performance capacibility and worst case failure modes of collectors, which utilize either air or liquid transport media. The facility simulates environmental parameters such as solar radiation intensity, solar spectrum, collimation, uniformity, and solar attitude. The facility also simulates wind conditions of velocity and direction, solar system conditions imposed on the collector, collector fluid inlet temperature, and geometric factors of collector tilt and azimuth angles. Testing the simulator provides collector efficiency data, collector time constant, incident angle modifier data, and stagnation temperature values.

Source record↗

Metal-halide mixtures for latent heat energy storage

Some candidates for alkali metal and alkali halide mixtures suitable for thermal energy storage at temperatures 600 C are identified. A solar thermal system application which offer advantages such as precipitation of salt crystals away from heat transfer surfaces, increased thermal conductivity of phase change materials, corrosion inhibition, and a constant monotectic temperature, independent of mixture concentrations. By using the lighters, metal rich phase as a heat transfer medium and the denser, salt rich phase as a phase change material for latent heat storage, undesirable solidification on the heat transfer surface may be prevented, is presented.

Chen, K.↗

The high latitude circulation and temperature structure of the thermosphere near solstice

NCAR thermospheric-general-circulation-model (TGCM) computations of solar-maximum thermospheric neutral-gas temperature and circulation around the December solstice are presented and discussed. The TGCM uses a 5 x 5-deg grid and 24 constant-pressure layers, corresponding to altitudes of about 97-500 km. The results are mapped as electron-density contours, polar plots, cylindrical equidistant projections, meridional cross sections, and F-region polar plots comparing the TGCM predictions with DE-2 satellite observations. The significant differences between summer and winter high-latitude F-region winds are attributed to the ion drag momentum associated with magnetospheric convection. The TGCM wind predictions follow the same pattern as the satellite measurements but are too small; possible model corrections are considered.

Roble, R. G.↗

Testing for a cosmological influence on local physics using atomic and gravitational clocks

The existence of a possible influence of the large-scale structure of the universe on local physics is discussed. A particular realization of such an influence is discussed in terms of the behavior in time of atomic and gravitational clocks. Two natural categories of metric theories embodying a cosmic infuence exist. The first category has geodesic equations of motion in atomic units, while the second category has geodesic equations of motion in gravitational units. Equations of motion for test bodies are derived for both categories of theories in the appropriate parametrized post-Newtonian limit and are applied to the Solar System. Ranging data to the Viking lander on Mars are of sufficient precision to reveal (1) if such a cosmological influence exists at the level of Hubble's constant, and (2) which category of theories is appropriate for a descripton of the phenomenon.

Adams, P. J.↗

Concepts used in the preparation of the document - Space and planetary environment criteria guidelines for use in space vehicle development 1982 revision

The NASA/Marshall Space Flight Center has developed a series of documents concerning space and planetary environments for use in the formulation of aerospace vehicle and spacecraft design criteria. For the earth above 90km altitude, and for the moon, planets, and other bodies in the Solar System; information is provided in disciplinary area of importance to the spacecraft designer such as planetary geology and morphology, atmospheric and ionospheric structures, radiation, particles, geomagnetic fields, astrodynamic constants, and meteoroids. This paper presents the philosophy used in the preparation of the current (1982) version of the document. Specific topics will be discussed in relation to their significance for aerospace vehicle and spacecraft development and mission analysis.

Davis, M. H.↗

Observed rate of ionization in shaped-charge releases of barium in the ionosphere

Data from 36 Ba shaped-charge releases carried out at an angle of less than 25 deg to the magnetic field, by the technique of Wescott et al. (1972) and Michel (1974), were examined for evidence of a sustained rate of ionization in excess of that attributable to sunlight. In four of the experiments, the time constant for the decay of the neutrals was measured using an ultrasensitive color TV camera and was found to have a value of about 30 sec, consistent with slow (solar) ionization. Although the qualitative appearance of most jets was found to be consistent with a slow process of ionization, some releases produced a thin confined jet that was suggestive of rapid ionization. Two of these jets were analyzed in detail, but no evidence of anomalous ionization was produced. The data obtained in this work agree with the geometrical predictions of the Swift model.

Hallinan, Thomas J.↗

Current Regulator For Sodium-Vapor Lamps

Regulating circuit maintains nearly-constant alternating current in sodium-vapor lamp. Regulator part of dc-to-ac inverter circuit used to supply power to street lamp from battery charged by solar-cell array.

Mclyman, W. T.↗

Rotational enhancement of line asymmetries in F9-G2 dwarfs

Disk integration of solar intensity profiles suggests that rotation enhances intermediate strength line asymmetries up to v sin i of about 6 km/s, after which the slope of the line bisector remains constant. Observed stellar line profiles do not show such a simple relation. Fast rotators exhibit large variations, owing presumably to stellar activity. Caution is advised with respect to the use of slow rotating or inactive star line profiles to determine the broadening of faster rotators.

Bruning, David H.↗

GOME Calibration and Validation Using Backscatter UV Techniques

GOME radiance, irradiance, and ozone products were validated by NASA Goddard Space Flight Center through three tasks which included, pre-launch calibration comparisons with SBUV and TOMS radiometric standards, validation of GOME Level-1 irradiance and radiance and Level 2 total ozone data products using SBUV/2 and TOMS algorithms and data, and studies of GOME data using the Goddard radiative transfer code. The prelaunch calibration using the NASA large aperture integrating sphere was checked against that provided by TPD. Agreement in the calibration constants, derived in air, between the Goddard and TPD system were better than 3%. Validation of Level-1 irradiance data included comparison of GOME and SSBUV and the UARS solar irradiances measurements. Large wavelength dependent differences, as high as 10%, were noted between GOME and the US instruments. This discrepancy has now been attributed to radiometric sensitivity changes experienced by GOME when operating in a vacuum. GOME Earth radiance data were then compared to the NOAA-14 SBUV/2 radiances. These results show that between 340 and 400 nm the differences in GOME and SBUV/2 data are less than 5% with some wavelength dependence. At wavelengths shorter than 300 nm, differences are of the order of 10% or more where the GOME radiances are larger. To test GOME DOAS retrieved total ozone values, these values were compared with ozone amounts retrieved using GOME radiances in the TOMS version-7 algorithm. The differences showed a solar zenith angle dependence ranging from 0 to 10% where the TOMS algorithm values were higher. GOME radiances below 300 nm were further validated by selecting radiances at wavelengths normally used by SBUV and processing them through the SBUV ozone profile algorithm and then compared to climatological values. The GOME ozone profiles ranged from 10-30% lower over altitude compared to climatological values. This is consistent with the offsets detected in the SBUV/2 radiance comparisons at wavelengths shorter than 300 nm.

Hilsenrath, E.↗