Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “polyimide”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Toxicity of pyrolysis gases from some cellular polymers

Various samples of cellular polymers were evaluated for toxicity of pyrolysis gases, using the screening test method developed at the University of San Francisco. The cellular polymer samples included polyimide, polymethacrylimide, polybismaleimide, polyurethane, polyisocyanurate, polyethylene, polychloroprene, polyvinyl chloride, polystyrene, polysiloxane, and polyphosphazene. The cellular polymers exhibited varying levels of toxicity under these test conditions. Among the rigid cellular polymers, times to death were shortest with the imide type foams and longest with polyvinyl chloride and polystyrene. Among the flexible cellular polymers, times to death were shortest with polyimide and polyester, and longest with polychloroprene and polysiloxane. Increased char yield was not necessarily associated with reduced toxicity.

Hilado, C. J.↗
NASA NTRS1979

Effects of low-velocity impact on Gr/Pi compression laminates

The results of low velocity impact tests conducted on a graphite-polyimide laminate are presented. The 48-ply orthotropic laminate tested during this investigation is typical of laminates being proposed for heavily loaded aircraft wing skins. The nature of the damage is described as well as the effect of that damage on the compression strength of the 48-ply orthotropic laminate. The results obtained for the graphite-polyimide laminate are compared to existing results of similar tests conducted on other graphite-epoxy laminates.

Garcia, R.↗
NASA NTRS1979

Fabrication research for supersonic cruise aircraft

Advanced fabrication and joining processes for titanium and composite materials are being investigated by NASA to develop technology for the Supersonic Cruise Research (SCR) Program. Full-scale structural panels are being designed and fabricated to meet the criteria of an existing integrally stiffened shear panel on the upper wing surface of the NASA YF-12 aircraft. The program consists of laboratory testing and Mach 3 flight service of full-scale structural panels and laboratory testing of representative structural element specimens. Borsic/aluminum honeycomb-core, titanium clad Borsic/aluminum skin-stringer, graphite/PMR-15 polyimide honeycomb-core, and titanium superplastically formed/diffusion bonded panels have been designed, fabricated, and tested. Graphite/LARC-160 polyimide skin-stringer panels have been designed, and fabrication methods are being developed.

Hoffman, E. L.↗
NASA NTRS1980

Burning characteristics and fiber retention of graphite/resin matrix composites

Graphite fiber reinforced resin matrix composites were subjected to controlled burning conditions to determine their burning characteristics and fiber retention properties. Small samples were burned with a natural gas fired torch to study the effects of fiber orientation and structural flaws such as holes and slits that were machined into the laminates. Larger laminate samples were burned in a modified heat release rate calorimeter. Unidirectional epoxy/graphite and polyimide/graphite composites and boron powder filled samples of each of the two composite systems were burn tested. The composites were exposed to a thermal radiation of 5.3 Btu/sq ft-sec in air. Samples of each of the unfilled composite were decomposed anaerobically in the calorimeter. Weight loss data were recorded for burning and decomposition times up to thirty-five minutes. The effects of fiber orientation, flaws, and boron filler additives to the resins were evaluated. A high char forming polyimide resin was no more effective in retaining graphite fibers than a low char forming epoxy resin when burned in air. Boron powder additions to both the polyimide and the epoxy resins stabilized the chars and effectively controlled the fiber release.

Bowles, K. J.↗
NASA NTRS1980

Analyses of moisture in polymers and composites

A suitable method for the direct measurement of moisture concentrations after humidity/thermal exposure on state of the art epoxy and polyimide resins and their graphite and glass fiber reinforcements was investigated. Methods for the determination of moisture concentration profiles, moisture diffusion modeling and moisture induced chemical changes were examined. Carefully fabricated, precharacterized epoxy and polyimide neat resins and their AS graphite and S glass reinforced composites were exposed to humid conditions using heavy water (D20), at ambient and elevated temperatures. These specimens were fixtured to theoretically limit the D20 permeation to a unidirectional penetration axis. The analytical techniques evaluated were: (1) laser pyrolysis gas chromatography mass spectrometry; (2) solids probe mass spectrometry; (3) laser pyrolysis conventional infrared spectroscopy; and (4) infrared imaging thermovision. The most reproducible and sensitive technique was solids probe mass spectrometry. The fabricated exposed specimens were analyzed for D20 profiling after humidity/thermal conditioning at three exposure time durations.

Ryan, L. E.↗
NASA NTRS1979

The structural behavior of a graphite-polymide honeycomb sandwich panel with quasi-isotropic face sheets and an orthotropic core

The results of a series of tests of graphite-polyimide honeycomb sandwich panels are presented. The panels were 1.22 m long, 0.508 m wide, and approximately 13.3 m thick. The face sheets were a T-300/PMR-15 fabric in a quasi-isotropic layup and were 0.279 mm thick. The core was Hexcel HRH 327-3/16 - 4.0 glass reinforced polyimide honeycomb, 12.7 mm thick. Three panels were used in the test: one was cut into smaller pieces for testing as beam, compression, and shear specimens; a second panel was used for plate bending tests; the third panel was used for in-plane stability tests. Presented are the experimental results of four point bending tests, short block compression tests, core transverse shear modulus, three point bending tests, vibration tests, plate bending tests, and panel stability tests. The results of the first three tests are used to predict the results of some of the other tests. The predictions and experimental results are compared, and the agreement is quite good.

Hyer, M. W.↗
NASA NTRS1981

A review of high-temperature adhesives

The development of high temperature adhesives and polyphenylquinoxalines (PPQ) is reported. Thermoplastic polyimides and linear PPQ adhesive are shown to have potential for bonding both metals and composite structures. A nadic terminated addition polyimide adhesive, LARC-13, and an acetylene terminated phenylquinoxaline (ATPQ) were developed. Both of the addition type adhesives are shown to be more readily processable than linear materials but less thermooxidatively stable and more brittle. It is found that the addition type adhesives are able to perform, at elevated temperatures up to 595 C where linear systems fail thermoplastically.

St.clair, A. K.↗
NASA NTRS1980

Screening of high temperature adhesives for large area bonding

High temperature-resistant adhesive systems were screened for processability, mechanical and physical properties, operational capability at 589 K (600 F), and the ability to produce large area bonds of high quality in fabricating Space Shuttle components. The adhesives consisted primarily of polyimide systems, including FM34B-18, NR-150B2 (DuPont), PMR-15, LARC-13, LARC-160, Thermid 600, and AI-1130L (AMOCA). The processing studies included preparation of polyimide resins, fabrication of film adhesives, development of lay-up and cure procedures, fabrication of honeycomb sandwich panels, and fabrication of mid-plane bonded panels in joints up to 30.5 cm (12 in.) wide. The screening program included tests for tack and drape properties, reticulation and filleting characteristics, ability to produce void-free or low porosity bonds in mid-plane bonded panels, out-time stability, lap shear strength, climbing drum peel strength, and glass transition temperature (Tg). This paper describes the processing methods developed and the test results.

Stenersen, A. A.↗
NASA NTRS1980

Hybridized composites for resistance to fiber release

Under certain conditions of combined fire and impact, graphite fibers are released to the atmosphere by graphite fiber composites. This investigation was conducted to improve the retention of graphite fiber in these situations. Hybrid combinations of graphite tape and cloth, glass cloth, and resin additives were studied with epoxy and polyimide resin systems. Polyimide resins formed the most resistant composites and resins based on simple novolac epoxies the least resistant of those tested. Great improvement in the containment of the fibers was obtained using graphite/glass hybrids, and nearly complete prevention of individual fiber release was made possible by the use of resin additives.

Stern, B. A.↗
NASA NTRS1983

High-Performance Matrix Resins

State-of-the-art PMR polyimides provide good strength and light weight in wide variety of critical applications. However, improved processability and elevated temperature thermo-oxidative stability are desired in such polyimide systems. Resins, intended for use in advanced composites, adhesives, and neat resin articles, show improvements in both processability and elevatedtemperature stability over state-of-the-art PMR-15 polymers.

Pater, R. H.↗
NASA NTRS1984

Shielded Aluminum Flat-Conductor Cable

Thin wiring harness stores compactly. Flat aluminum conductors glued between layers of polyimide. Aluminum shield surrounds insulated conductors. Outer layer polyimide. Aluminum shield reduces flexibility of cable and cable withstand only limited number of repetitions of sharp bending at same spot.

Farina, S.↗
NASA NTRS1984

Solar-Cell-Manufacturing System

Cost of manufacturing solar arrays minimized by using polyimide-ribbed substrates together with silver-plated coils of low-expansion nickel/iron ribbon on solar cells. Polyimide taped to ribbon protects cell from abrasion or from sticking to other tooling.

Kelly, F. G.↗
NASA NTRS1982

A thermoplastic polyimidesulfone

A polymer system has been prepared which has the excellent thermoplastic properties generally associated with polysulfones, and the solvent resistance and thermal stability of aromatic polyimides. This material, with improved processability over the base polyimide, can be processed in the 260-325 C range in such a manner as to yield high quality, tough unfilled moldings; strong, high-temperature-resistant adhesive bonds; and well consolidated, graphite-fiber-reinforced moldings (composities). The unfilled moldings have physical properties that are similar to aromatic polysulfones which demonstrates the potential as an engineering thermoplastic. The adhesive bonds exhibit excellent retention of initial strength levels even after thermal aging for 5000 hours at 232 C. The graphite-fiber-reinforced moldings have mechanical properties which makes this polymer attractive for the fabrication of structural composites.

St.clair, T. L.↗
NASA NTRS1982

A preliminary evaluation of a potential space worth encapsulant

A new polymer polyimide possessing optical and mechanical properties potentially suitable for space applications now exists. A preliminary evaluation of the material indicates that in its present state of development, the polyimide is not ready for space qualification. Further efforts to increase molecular weight and purify the consituents used to synthesize it are warranted. Activities addressing these needs are now being pursued. If these approaches prove successful, additional testing will take place with an emphasis on synergistic effects.

Scott-Monck, J.↗
NASA NTRS1983

Synthesis and characterization of a polyethersulfoneimide

Two similar polyimide systems were synthesized and characterized. The only structural difference was a sulfide linkage in the anhydride derived portion of the first system versus a sulfone linkage in the second. Their physical, mechanical, melt-flow and thermal properties were determined and also their resistance to some of the more common solvents. The flow properties of these polyimides indicate them to have potential for melt processability.

Burks, H. D.↗
NASA NTRS1983

A critical study of the role of the surface oxide layer in titanium bonding

Scanning electron microscope/X-ray photoelectron spectroscopy (SEM/XPS) analysis of fractured adhesively bonded Ti 6-4 samples is discussed. The text adhesives incuded NR 056X polyimide, polypheylquinoxaline (PPQ), and LARC-13 polyimide. Differentiation between cohesive and interfacial failure was based on the absence of presence of a Ti 2p XPS photopeak. In addition, the surface oxide layer on Ti-(6A1-4V) adherends is characterized and bond strength and durability are addressed. Bond durability in various environmental conditions is discussed.

Dias, S.↗
NASA NTRS1983

Resin characterization in cured graphite fiber reinforced composites using diffuse reflectance-FTIR

The feasibility of using diffuse reflectance in combination with Fourier transform infrared spectroscopy to obtain information on cured graphite fiber reinforced polymeric matrix resin composites was investigated. Several graphite/epoxy, polysulfone, and polyimide composites exposed to thermal or radiation environments were examined. An experimental polyimide-sulfone adhesive tape was also studied during processing. In each case, significant changes in resin molecular structure was observed due to environmental exposure. These changes in molecular structure were correlated with previously observed changes in material properties providing new insights into material behavior.

Young, P. R.↗
NASA NTRS1984

Off-axis tensile properties and fracture in a unidirectional graphite/polyimide composite (Celion 6000/PMR 15)

Tensile properties of unidirectional Celion 6000 graphite/PMR 15 polyimide composites prepared by hot molding and cold molding processes were measured at room temperature and 316 C, the upper use temperature of the polyimide resin, at both 45 and 90 deg to the fiber axis. The resulting fractures were characterized by scanning electron microscopy and materialographic techniques. Variation in tensile properties with processing history occurred in the elastic modulus and strain to failure for specimens loaded at 90 deg at 316 C, and in the fracture stress, and hence the in-plane shear stress, for those loaded at 45 deg at room temperature. Significant plastic deformation was observed in the 45 deg orientation at 316 C for material produced by both processing methods. In general, fracture occurred by both failure within the matrix and at the fiber-matrix interface; the degree of interfacial failure increased with temperature. Secondary cracking below the primary fracture surface was also observed.

Harper, J.↗