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At least 955 records · Page 53
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Chemomechanical origin of morphological disparity in lithium metal electrodeposition

The morphology of electrochemically deposited lithium (Li) critically governs the cycling stability and safety of Li metal batteries, yet the underlying controlling factors remain poorly understood. Even within the same coin cell, Li deposits can exhibit strikingly different morphologies, for example, sparse whiskers coexisting with particle-like deposits, indicting strong local variations in growth conditions. By combining cryogenic transmission electron microscopy with phase-field modeling, we here identify the root cause of this disparity. We reveal that the morphological divergence originates from the variations in structure and chemical composition of the initial SEI layer formed on the copper (Cu) substrate. These variations arise from substrate defects that induce localized electrochemical fields, driving selective dissociation of either solvent or salt, producing SEI layers with distinct chemomechanical properties. Solvent-derived organic SEI favors whisker growth, whereas salt-derived SEI promotes particle formation. This study establishes a direct mechanistic link between SEI chemomechanical properties and Li morphology, providing design principles for tailoring SEI layers to control Li deposition

energy storage↗
NASA NTRS1991

Acridine orange staining reaction as an index of physiological activity in Escherichia coli

The assumption that the acridine orange (AO) color reaction may be used as an index of physiological activity was investigated in laboratory grown Escherichia coli. Spectrofluorometric observations of purified nucleic acids, ribosomes and the microscopic color of bacteriophage-infected cells stained with AO confirmed the theory that single-stranded nucleic acids emit orange to red fluorescence while those that are double-stranded fluoresce green in vivo. Bacteria growing actively in a rich medium could be distinguished from cells in stationary phase by the AO reaction. Cells from log phase appeared red, whereas those in stationary phase were green. However, this differentiation was not seen when the bacteria were grown in a minimal medium or when a variation of the staining method was used. Also, shifting bacteria in stationary phase to starvation conditions rapidly changed their AO staining reaction. Boiling and exposure to lethal concentrations of azide and formalin resulted in stationary-phase cells that appeared red after staining but bacteria killed with chlorine remained green. These findings indicate that the AO staining reaction may be suggestive of physiological activity under defined conditions. However, variables in staining and fixation procedures as well as uncertainties associated with mixed bacterial populations in environmental samples may produce results that are not consistent with the classical interpretation of this reaction. The importance of validating the putative physiological implications of this staining reaction is stressed.

NASA Discipline Number 04-10↗
NASA NTRS2002

Are Solar Activity Variations Amplified by the QBO: A Modeling Study

Solar cycle activity effects (SCAE) in the lower and middle atmosphere, reported in several studies, are difficult to explain on the basis of the small changes in solar radiation that accompany the 11-year cycle. It is therefore natural to speculate that dynamical processes may come into play to produce a leverage. Such a leverage may be provided by the Quasi-Biennial Oscillation (QBO) in the zonal circulation of the stratosphere, which has been linked to solar activity variations. Driven primarily by wave mean flow interaction, the QBO period and its amplitude are variable but are also strongly influenced by the seasonal cycle in the solar radiation. This influence extends to low altitudes and is referred to as 'downward control'. Small changes in the solar radiative forcing may produce small changes in the period and phase of the QBO, but these in turn may produce measurable differences in the wind field. Thus, the QBO may be an amplifier of solar activity variations and a natural conduit of these variations to lower altitudes. To test this hypothesis, we conducted experiments with a 2D version of our Numerical Spectral Model that incorporates Hines' Doppler Spread Parameterization for small-scale gravity waves (GW). Solar cycle radiance variations (SCRV) are accounted for by changing the radiative heating rate on a logarithmic scale from 0.1% at the surface to 1% at 50 km to 10% at 100 km. With and without SCRV, but with the same GW flux, we then conduct numerical experiments to evaluate the magnitude of the SCAE in the zonal circulation. The numerical results indicate that, under certain conditions, the SCAE is significant and can extend to lower altitudes where the SCRV is small. For a modeled QBO period of 30 months, we find that the seasonal cycle in the solar forcing acts as a strong pacemaker to lock up the phase and period of the QBO. The SCAE then shows up primarily as a distinct but relatively weak amplitude modulation. But with a different QBO period between 30 and 34 (or less than 30, presumably) months, the seasonal phase lock is weak. Solar flux variations in the seasonal cycle then cause variations in the QBO period and phase. These amplify the SCAE to produce relatively large variations in the wind field. The SCAE in this case extends to mid-latitudes.

Mengel, J. G.↗
NASA NTRS1987

Evidence for periodic radial velocity variations in Arcturus

Evidence for periodic radial velocity variation in Arcturus based on Doppler accelerometer studies is reported. The most likely period and amplitude for these variations are 1.842 + or - 0.005 days and 160 + or - 10 m/s, respectively. Epoch-folding of 31 nights of Arcturus data taken between December 21, 1985 and March 31, 1986 reveals a sawtooth phase diagram. Two physical mechanisms as potential causes of this variation are briefly discussed.

Smith, P. H.↗
DOE OSTI2023

Two Marine Heatwave (MHW) Variants under a Basinwide MHW Conditioning Mode in the North Pacific and Their Atlantic Associations

Abstract During 2013–16 and 2018–22, marine heatwaves (MHWs) occurred in the North Pacific, exhibiting similar extensive coverage, lengthy duration, and significant intensity but with different warming centers. The warming center of the 2013–16 event was in the Gulf of Alaska (GOA), while the 2018–22 event had warming centers in both the GOA and the coast of Japan (COJ). Our observational analysis indicates that these two events can be considered as two MHW variants induced by a basinwide MHW conditioning mode in the North Pacific. Both variants were driven thermodynamically by atmospheric wave trains propagating from the tropical Pacific to the North Pacific, within the conditioning mode. The origin and propagating path of these wave trains play a crucial role in determining the specific type of MHW variant. When a stronger wave train originates from the tropical central (western) Pacific, it leads to the GOA (COJ) variant. The cross-basin nature of the wave trains enables the two MHW variants to be accompanied by a tripolar pattern of sea surface temperature anomalies in the North Atlantic but with opposite phases. The association of these two MHW variants with the Atlantic Ocean also manifests in the decadal variations of their occurrence. Both variants tend to occur more frequently during the positive phase of the Atlantic multidecadal oscillation but less so during the negative phase. This study underscores the importance of cross-basin associations between the North Pacific and North Atlantic in shaping the dynamics of North Pacific MHWs.

Meteorology & Atmospheric Sciences↗
DOE OSTI2022

Correlation between the gas-phase metallicity and ionization parameter in extragalactic H II regions

The variations of the metallicity and ionization parameter in H II regions are usually thought to be the dominant factors that produce the variations we see in the observed emission line spectra. There is an increasing amount of evidence that these two quantities are physically correlated, although the exact form of this correlation is debatable in the literature. Simulated emission line spectra from photoionized clouds provide important clues about the physical conditions of H II regions and are frequently used for deriving metallicities and ionization parameters. Through a systematic investigation on the assumptions and methodology used in applying photoionization models, we find that the derived correlation has a strong dependence on the choice of model parameters. On the one hand, models that give consistent predictions over multiple emission-line ratios yield a positive correlation between the metallicity and ionization parameter for the general population of H II regions or star-forming galaxies. On the other hand, models that are inconsistent with the data locus in high-dimensional line ratio space yield discrepant correlations when different subsets of line ratios are used in the derivation. The correlation between the metallicity and ionization parameter has a secondary dependence on the surface density of the star formation rate (SFR), with the higher SFR regions showing a higher ionization parameter but weaker correlations. The existence of the positive correlation contradicts the analytical wind-driven bubble model for H II regions. We explore assumptions in both dynamical models and photoionization models, and conclude that there is a potential bias associated with the geometry. However, this is still insufficient to explain the correlation. Mechanisms that suppress the dynamical influence of stellar winds in realistic H II regions might be the key to solving this puzzle, though more sophisticated combinations of dynamical models and photoionization models to test are required.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1989

Miranda - Color and albedo variations from Voyager photometry

Voyager 0.48-micron images of Miranda covering phase angles of 13-39 deg, together with 0.35-micron 0.41-micron, and 0.56-micron data at 16-deg phase angle, are the bases of the Minnaert parameters from which the present albedo/color maps are derived. Color ratios are found to be essentially constant over all terrain types and albedo ranges on the satellite; spectrally, Miranda is gray. The color data are noted to conform with a model in which varying amounts of materials spectrally resembling the asteroidal F-material are mixed with an icy component.

Hillier, J.↗
NASA NTRS1997

[Petrological Analysis of Astrophysical Dust Analog Evolution]

This project "Petrological analysis of astrophysical dust analog evolution" was initiated to try to understand the vapor phase condensation, and the nature of the reaction products, in circumstellar environments, such as the solar nebula 4,500 Myrs ago, and in the interstellar medium. Telescope-based infrared [IR] spectroscopy offers a broad-scale inventory of the various types of dust in these environments but no details on small-scale variations in terms of chemistry and morphology and petrological phase relationships. Vapor phase condensation in these environments is almost certainly a non-equilibrium process. The main challenge to this research was to document the nature of this process that, based on astrophysical observations, seems to yield compositionally consistent materials. This observation may suggest a predictable character during non-equilibrium condensation. These astrophysical environments include two chemically distinct, that is, oxygen-rich and carbon-rich environments. The former is characterized by silicates the latter by carbon-bearing solids. According to cosmological models of stellar evolution circumstellar dust accreted into protoplanets wherein thermal and/or aqueous processes will alter the dust under initially, non-equilibrium conditions.

Rietmeijer, Frans J. M.↗
NASA NTRS1985

Spectral analysis of the Forbush decrease of 13 July 1982

The maximum entropy method has been applied in the spectral analysis of high-energy cosmic-ray intensity during the large Forbush event of July 13, 1982. An oscillation with period of about 2 hours and amplitude of 1 to 3% was found to be present during the decrease phase. This oscillation can be related to a similar periodicity in the magnetospheric field. However, the variation was not observed at all neutron monitor stations. In the beginning of the recovery phase, the intensity oscillated with a period of about 10 hours and amplitude of 3%.

Vainikka, E.↗
DOE OSTI2026

Effect of 316 stainless steel powder processing conditions on microstructure

One parameter that has both economic and performance effects in the manufacturing of steel parts is the powder feedstock used. 316 L steel powder can be produced through water atomization or gas atomization, where both the powder size and the atomization process determine the cost of powder feedstock. Gas atomized powder is spherical and has a lower oxygen content than water atomized powder, making it the preferred choice for performance, but comes at a higher financial cost. Here, in this study, various 316 L powder batches are characterized to understand physical properties and microstructural variations. Density and flowability were determined using gas pycnometry and Hall flow tests. Powder morphology and porosity were qualitatively analyzed via optical microscopy and scanning electron microscopy, Finally, transmission electron microscopy was used to determine changes in phases present. Spherical gas atomized powder of 30–100 μm contained Mn$-$Si rich oxides both on the surface and within the matrix. Meanwhile, irregular water atomized powder 30 μm in diameter contained silicon oxides without manganese. All powder particles contained a nickel rich cellular structure which was shown to support the formation of additional phases. While literature has observed general microstructural features across 316 L powder particles, transmission electron microscopy (TEM) in this study has identified variations in precipitation and cell structures. Information regarding morphology, flowability, density, and phase distributions can be applied to understand variations in part consolidation, which will in turn show which powder aspects are significant for production.

Chemical segregation↗
DOE OSTI2023

Source apportionment of soot particles and aqueous-phase processing of black carbon coatings in an urban environment

Abstract. The impacts of soot particles on climate and human health depend on the concentration of black carbon (BC) as well as the thickness and composition of the coating material, i.e., organic and inorganic compounds internally mixed with BC. In this study, the size-resolved chemical composition of BC-containing aerosol was measured using a high-resolution soot particle aerosol mass spectrometer (SP-AMS) during wintertime in Fresno, California, a location influenced by abundant combustion emissions and frequent fog events. Concurrently, particle optical properties were measured to investigate the BC absorption enhancement. Positive matrix factorization (PMF) analysis was performed on the SP-AMS mass spectral measurements to explore the sources of soot particles and the atmospheric processes affecting the properties of BC coatings. The analysis revealed that residential woodburning and traffic are the dominant sources of soot particles. Alongside primary soot particles originating from biomass burning (BBOABC) and vehicles (HOABC) two distinct types of processed BC-containing aerosol were identified: fog-related oxidized organic aerosol (FOOABC) and winter-background OOABC (WOOABC). Both types of OOABC showed evidence of having undergone aqueous processing, albeit with differences. The concentration of FOOABC was substantially elevated during fog events, indicating the formation of aqueous secondary organic aerosol (aqSOA) within fog droplets. On the other hand, WOOABC was present at a relatively consistent concentration throughout the winter and was likely related to the formation of secondary organic aerosol (SOA) in both the gas phase and aerosol liquid water. By comparing the chemical properties and temporal variations in FOOABC and WOOABC, we gain insights into the key aging processes of BC aerosol. It was found that aqueous-phase reactions facilitated by fog droplets had a significant impact on the thickness and chemical composition of BC coatings, thereby affecting the light absorption and hygroscopic properties of soot particles. These findings underscore the important role of chemical reactions occurring within clouds and fogs and influencing the climate forcing of BC aerosol in the atmosphere.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

Propulsion evaluation for orbit-on-demand vehicles

Future earth-to-orbit vehicles may be required to reach orbit within hours or even minutes of a decision. A study has been conducted to consider vehicles with such a capability. In Phase I of the study, 11 vehicles were designed to deploy 5000 lb to a polar orbit. Changes in the designs were examined parametrically for increased on-orbit maneuvers, increased payload, and other mission variations. Based on the results, two concepts were selected for Phase II design work: a vertical-takeoff, two-stage system and a horizontal-takeoff, two-stage system with an airbreathing subsonic first stage. The results of several propulsion evaluations are presented, including liftoff thrust-to-weight effects, dual-fuel propulsion for a horizontal-takeoff concept, and the effect of using fluorine.

Martin, J. A.↗
NASA NTRS1985

The Feinheit method: A phase-independent formulation of the period-luminosity relation for Cephids

The tight correlation between color and luminosity during the cyclical variation of a Cepheid is calibrated and shown to be a direct means by which most of the phase-dependent temperature-induced amplitude of the variable can be transformed away. The resulting Feinheit function, F = V - alpha (B-V) gives rise to a random-phase period-luminosity relation with an rms scatter of less than 0.20 mag. A comparison shows that the blue Feinheit method for distance determinations method from single-phase observations is as accurate as near-infrared photometry but has the added advantage of being able to use panoramic detectors for the data acquisition. The Feinheit function is identified as the surface area variation of the Cepheid during its cycle.

Madore, B. F.↗
NASA NTRS1988

Acoustic imaging of subtle porosity variations in ceramics

Acoustic images of silicon carbide ceramic disks were obtained using a precision scanning contact pulse-echo technique. Phase and cross-correlation velocity and attenuation maps were used to form color images of microstructural variations. These acoustic images reveal microstructural variations not observable with X-radiography.

Generazio, E. R.↗
DOE OSTI2024

Local lattice distortions and electronic phases in perovskite manganite Pr 0.5 Sr 0.5 MnO 3

We use variable temperature and magnetic field total x-ray scattering to study the crystal structure of the strongly correlated Pr 0.5 Sr 0.5 MnO 3 perovskite, which is a paramagnetic insulator at room temperature, becomes a ferromagnetic metal at 272 K and, upon further decreasing the temperature, turns into an antiferromagnetic insulator at 105 K. We find that a model featuring a monoclinic symmetry captures the structure and its temperature and field evolution well, eliminating the need to evoke a phase segregation scenario as done in prior studies. It appears that coupled variations in Mn–oxygen bonding distances and angles from their values in an undistorted perovskite lattice, i.e., coupled local lattice distortions, assist the phase transitions in Pr 0.5 Sr 0.5 MnO 3 , contributing to its unique physical properties. Local structural distortions thus emerge as an important degree of freedom in strongly correlated systems, in particular perovskite manganates, and, therefore, they should be fully accounted for when their fascinating physics is considered.

36 MATERIALS SCIENCE↗
NASA NTRS2000

Polar Spacecraft Based Comparisons of Intense Electric Fields and Poynting Flux Near and Within the Plasma Sheet-Tail Lobe Boundary to UVI Images: An Energy Source for the Aurora

In this paper, we present measurements from two passes of the Polar spacecraft of intense electric and magnetic field structures associated with Alfven waves at and within the outer boundary of the plasma sheet at geocentric distances of 4-6 R(sub E), near local midnight. The electric field variations have maximum values exceeding 100 mV/m and are typically polarized approximately normal to the plasma sheet boundary. The electric field structures investigated vary over timescales (in the spacecraft frame.) ranging front 1 to 30 s. They are associated with strong magnetic field fluctuations with amplitudes of 10-40 nT which lie predominantly ill the plane of the plasma sheet and are perpendicular to the local magnetic field. The Poynting flux associated with the perturbation fields measured at these altitudes is about 1-2 ergs per square centimeters per second and is directed along the average magnetic field direction toward the ionosphere. If the measured Poynting flux is mapped to ionospheric altitudes along converging magnetic field lines. the resulting energy flux ranges up to 100 ergs per centimeter squared per second. These strongly enhanced Poynting fluxes appear to occur in layers which are observed when the spacecraft is magnetically conjugate (to within a 1 degree mapping accuracy) to intense auroral structures as detected by the Polar UV Imager (UVI). The electron energy flux (averaged over a spatial resolution of 0.5 degrees) deposited in the ionosphere due to auroral electron beams as estimated from the intensity in the UVI Lyman-Birge-Hopfield-long filters is 15-30 ergs per centimeter squared per second. Thus there is evidence that these electric field structures provide sufficient Poynting flux to power the acceleration of auroral electrons (as well as the energization of upflowing ions and Joule heating of the ionosphere). During some events the phasing and ratio of the transverse electric and magnetic field variations are consistent with earthward propagation of Alfven surface waves with phase velocities of 4000-10000 kilometers per second. During other events the phase shifts between electric and magnetic fields suggest interference between upward and downward propagating Alfven waves. The E/B ratios are about an order of magnitude larger than typical values of C/SIGMA(sub p), where SIGMA(sub p), is the height integrated Pedersen conductivity. The contribution to the total energy flux at these altitudes from Poynting flux associated with Alfven waves is comparable to or larger than the contribution from the particle energy flux and 1-2 orders of magnitude larger than that estimated from the large-scale steady state convection electric field and field-aligned current system.

Wygant, J. R.↗
DOE OSTI2023

Simulating scalar field theories on quantum computers with limited resources

Here we present a quantum algorithm for implementing φ 4 lattice scalar field theory on qubit computers. The field is represented in the discretized field amplitude basis. The number of qubits and elementary gates required by the implementation of the evolution operator is proportional to the lattice size. The algorithm allows efficient φ 4 state preparation for a large range of input parameters in both the normal and broken-symmetry phases. The states are prepared using a combination of variational and adiabatic evolution methods. First, the ground state of a local Hamiltonian, which includes the φ 4 self-interaction, is prepared using short variational circuits. Next, this state is evolved by switching on the coupling between the lattice sites adiabatically. The parameters defining the local Hamiltonian are adjustable and constitute the input of our algorithm. We present a method to optimize these parameters in order to reduce the adiabatic time required for state preparation. For preparing broken-symmetry states, the adiabatic evolution problems caused by crossing the phase transition critical line and by the degeneracy of the broken-symmetry ground state can be addressed using an auxiliary external field which gradually turns off during the adiabatic process. We show that the time dependence of the external field during the adiabatic evolution is important for addressing the broken-symmetry ground state degeneracy. The adiabatic time dependence on the inverse error tolerance can be reduced from quadratic to linear by using a field strength that decreases exponentially in time relative to one that decreases linearly.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2002

Fabrication of Fiber-Optic Tilted Bragg Grating Filter in 40 nm Range with A Single Phase Mask

Fiber-optic Bragg grating filters are fabricated with a range of Bragg wavelength between 1296 and 1336 nm, using a single phase mask. 30 mW of continuous-wave light at 244 nm is used from a frequency-doubled argon-ion laser having an intracavity etalon. Gratings are fabricated by tilting the photosensitive fiber with respect to the phase mask up to an angle of 15 degrees. The variation of Bragg wavelength with the fiber-tilt is explained with a simple formula. High spatial coherence of 244 nm light makes it possible to displace the fiber as much as 6 mm in front of the phase mask and tilt the fiber by as much as 15 degrees. This results in nearly constant band-width and near 100% reflectively for all gratings throughout the 40 nm range.

Grant, Joseph↗