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At least 955 records · Page 53

Characterization of Asian Dust Properties Near Source Region During ACE-Asia

Asian dust typically originates in desert areas far from polluted urban regions. During transport, dust layers can interact with anthropogenic sulfate and soot aerosols from heavily polluted urban areas. Added to the complex effects of clouds and natural marine aerosols, dust particles reaching the marine environment can have drastically different properties than those from the source. Thus, understanding the unique temporal and spatial variations of Asian aerosols is of special importance in regional-to-global climate issues such as radiative forcing, the hydrological cycle, and primary biological productivity in the mid-Pacific Ocean. During ACE-Asia campaign, we have acquired ground- based (temporal) and satellite (spatial) measurements to infer aerosol physical/optical/radiative properties, column precipitable water amount, and surface reflectivity over this region. The inclusion of flux measurements permits the determination of aerosol radiative flux in addition to measurements of loading and optical depth. At the time of the Terra/MODIS, SeaWiFS, TOMS and other satellite overpasses, these ground-based observations can provide valuable data to compare with satellite retrievals over land. In this paper, we will demonstrate new capability of the Deep Blue algorithm to track the evolution of the Asian dust storm from sources to sinks. Although there are large areas often covered by clouds in the dust season in East Asia, this algorithm is able to distinguish heavy dust from clouds over the entire regions. Examination of the retrieved daily maps of dust plumes over East Asia clearly identifies the sources contributing to the dust loading in the atmosphe~~. We have compared the satellite retrieved aerosol optical thickness to the ground-based measurements and obtained a reasonable agreement between these two. Our results also indicate that there is a large difference in the retrieved value of spectral single scattering albedo of windblown dust between different sources in East Asia.

Tsay, Si-Chee↗

Factors governing water condensation in the Martian atmosphere

Modeling results are presented suggesting a diurnal condensation cycle at high altitudes at some seasons and latitudes. In a previous paper, the use of atmospheric optical depth measurements at the Viking lander site to show diurnal variability of water condensation at different seasons of the Mars year was described. Factors influencing the amount of condensation include latitude, season, atmospheric dust content and water vapor content at the observation site. A one-dimensional radiative-convective model is used herein based on the diabatic heating routines under development for the Mars General Circulation Model. The model predicts atmospheric temperature profiles at any latitude, season, time of day and dust load. From these profiles and an estimate of the water vapor, one can estimate the maximum occurring at an early morning hour (AM) and the minimum in the late afternoon (PM). Measured variations in the atmospheric optical density between AM and PM measurements were interpreted as differences in AM and PM condensation.

Colburn, David S.↗

Reconciling Simulated and Observed Views of Clouds: MODIS, ISCCP, and the Limits of Instrument Simulators in Climate Models

The properties of clouds that may be observed by satellite instruments, such as optical depth and cloud top pressure, are only loosely related to the way clouds are represented in models of the atmosphere. One way to bridge this gap is through "instrument simulators," diagnostic tools that map the model representation to synthetic observations so that differences between simulator output and observations can be interpreted unambiguously as model error. But simulators may themselves be restricted by limited information available from the host model or by internal assumptions. This work examines the extent to which instrument simulators are able to capture essential differences between MODIS and ISCCP, two similar but independent estimates of cloud properties. We focus on the stark differences between MODIS and ISCCP observations of total cloudiness and the distribution of cloud optical thickness can be traced to different approaches to marginal pixels, which MODIS excludes and ISCCP treats as homogeneous. These pixels, which likely contain broken clouds, cover about 15% of the planet and contain almost all of the optically thinnest clouds observed by either instrument. Instrument simulators can not reproduce these differences because the host model does not consider unresolved spatial scales and so can not produce broken pixels. Nonetheless, MODIS and ISCCP observation are consistent for all but the optically-thinnest clouds, and models can be robustly evaluated using instrument simulators by excluding ambiguous observations.

Pincus, Robert↗

Models of polarized infrared emission from bipolar nebulae

Many stars with circumstellar dust shells show a high degree of linear polarization (Sato et al. 1985). We are developing a model which assumes that the polarization arises from scattering by circumstellar dust. Our model assumes a geometry in which the star is surrounded by an optically thin spherical dust shell and embedded within an optically thick disk. This geometry is consistent with that proposed for objects with bipolar molecular outflow. This is important because many bipolar flow objects have also been observed to be highly polarized. The high degree of linear polarization is produced because the disk differentially attenuates the light from the star. The light incident from the point source is attenuated by a factor of exp(-tau/cos theta) where theta is the angle between a ray from the point source to the scatterer and a ray normal to the disk; tau is the optical depth at the wavelength of interest. Hence, the light scattered from the regions directly above and below the disk give the largest contribution to the total flux. The scattering angle for light from these regions is near 90 deg., so the light is strongly polarized and, in the Rayleigh scattering regime, is polarized parallel to the disk. The Stokes parameters for the scattered light from each particle in the shell are calculated by using the scattering matrix elements generated by a Mie scattering program. After the Stokes parameters for each particle are computed they are summed to give the Stokes parameters for the entire shell. Two graphs are presented which show the intensity and polarization spectrum generated by our model using the optical constants for astronomical silicates as defined by Draine and Lee (1984).

Burns, M. S.↗

Typical Types and Formation Mechanisms of Haze in an Eastern Asia Megacity, Shanghai

An intensive aerosol and gases campaign was performed at Shanghai in the Yangtze River Delta region over Eastern China from late March to early June 2009. This study provided a complementary picture of typical haze types and the formation mechanisms in megacities over China by using a synergy of ground-based monitoring, satellite and lidar observations. During the whole study period, several extreme low visibility periods were observed with distinct characteristics, and three typical haze types were identified, i.e. secondary inorganic pollution, dust, and biomass burning. Sulfate, nitrate and ammonium accounted for a major part of PM2.5 mass during the secondary inorganic pollution, and the good correlation between SO2/NOx/CO and PM2.5 indicated that coal burning and vehicle emission were the major sources. Large-scale regions with high AOD (aerosol optical depths) and low Angstrom exponent were detected by remote-sensing observation during the dust pollution episode, and this episode corresponded to coarse particles rich in mineral components such as Al and Ca contributing 76.8% to TSP. The relatively low Ca/Al ratio of 0.75 along with the air mass backward trajectory analysis suggested the dust source was from Gobi Desert. Typical tracers for biomass burning from satellite observation (column CO and HCHO) and from ground measurement (CO, particulate K+, OC, and EC) were greatly enhanced during the biomass burning pollution episode. The exclusive linear correlation between CO and PM2.5 corroborated that organic aerosol dominated aerosol chemistry during biomass burning, and the high concentration and enrichment degree of arsenic (As) could be also partly derived from biomass burning. Aerosol optical profile observed by lidar demonstrated that aerosol was mainly constrained below the boundary layer and comprised of spheric aerosol (depolarization ratio <5%) during the secondary inorganic and biomass burning episodes, while thick dust layer distributed at altitudes from near surface to 1.4 km (average depolarization ratio = 0.122+/-0.023) with dust accounting for 44-55% of the total aerosol extinction coefficient during the dust episode. This study portrayed a good picture of the typical haze types and proposed that identification of the complicated emission sources is important for the air quality improvement in megacities in China.

haze↗

Modeling the smoky troposphere of the southeast Atlantic: a comparison to ORACLES airborne observations from September of 2016

In the southeast Atlantic, well-defined smoke plumes from Africa advect over marine boundary layer cloud decks; both are most extensive around September, when most of the smoke resides in the free troposphere. A framework is put forth for evaluating the performance of a range of global and regional atmospheric composition models against observations made during the NASA ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) airborne mission in September 2016. A strength of the comparison is a focus on the spatial distribution of a wider range of aerosol composition and optical properties than has been done previously. The sparse airborne observations are aggregated into approximately 2° grid boxes and into three vertical layers: 3–6 km, the layer from cloud top to 3 km, and the cloud-topped marine boundary layer. Simulated aerosol extensive properties suggest that the flight-day observations are reasonably representative of the regional monthly average, with systematic deviations of 30 % or less. Evaluation against observations indicates that all models have strengths and weaknesses, and there is no single model that is superior to all the others in all metrics evaluated. Whereas all six models typically place the top of the smoke layer within 0–500 m of the airborne lidar observations, the models tend to place the smoke layer bottom 300–1400 m lower than the observations. A spatial pattern emerges, in which most models underestimate the mean of most smoke quantities (black carbon, extinction, carbon monoxide) on the diagonal corridor between 16° S, 6° E, and 10° S, 0° E, in the 3–6 km layer, and overestimate them further south, closer to the coast, where less aerosol is present. Model representations of the above-cloud aerosol optical depth differ more widely. Most models overestimate the organic aerosol mass concentrations relative to those of black carbon, and with less skill, indicating model uncertainties in secondary organic aerosol processes. Regional-mean free-tropospheric model ambient single scattering albedos vary widely, between 0.83 and 0.93 compared with in situ dry measurements centered at 0.86, despite minimal impact of humidification on particulate scattering. The modeled ratios of the particulate extinction to the sum of the black carbon and organic aerosol mass concentrations (a mass extinction efficiency proxy) are typically too low and vary too little spatially, with significant inter-model differences. Most models overestimate the carbonaceous mass within the offshore boundary layer. Overall, the diversity in the model biases suggests that different model processes are responsible. The wide range of model optical properties requires further scrutiny because of their importance for radiative effect estimates.

Yohei Shinozuka↗

Eyjafjallajokull Volcano Plume Particle-Type Characterization from Space-Based Multi-angle Imaging

The Multi-angle Imaging SpectroRadiometer (MISR) Research Aerosol algorithm makes it possible to study individual aerosol plumes in considerable detail. From the MISR data for two optically thick, near-source plumes from the spring 2010 eruption of the Eyjafjallaj kull volcano, we map aerosol optical depth (AOD) gradients and changing aerosol particle types with this algorithm; several days downwind, we identify the occurrence of volcanic ash particles and retrieve AOD, demonstrating the extent and the limits of ash detection and mapping capability with the multi-angle, multi-spectral imaging data. Retrieved volcanic plume AOD and particle microphysical properties are distinct from background values near-source, as well as for overwater cases several days downwind. The results also provide some indication that as they evolve, plume particles brighten, and average particle size decreases. Such detailed mapping offers context for suborbital plume observations having much more limited sampling. The MISR Standard aerosol product identified similar trends in plume properties as the Research algorithm, though with much smaller differences compared to background, and it does not resolve plume structure. Better optical analogs of non-spherical volcanic ash, and coincident suborbital data to validate the satellite retrieval results, are the factors most important for further advancing the remote sensing of volcanic ash plumes from space.

Kahn, Ralph A.↗

Precipitable Water Vapor Variation in the Clear-Cloud Transition Zone From the ARM Shortwave Spectrometer

A new technique to retrieve precipitable water vapor (PWV)amount in the clear-cloud transition zone using ground-based zenith spectral radiance is developed. The method uses zenith radiances at the water vapor band at 720 nm and adjacent non-absorbing band at 750 nm.Radiative transfer calculations show that the relative difference in zenith radiance between the two bands depends on PWV and the variations in cloud optical depth introduce a small change in the relative difference which is independent of PWV amount. This allows us to retrieve PWV variations in the cloud-clear transition zone for clouds over dark ocean surface. We applied this method to a Cu cloud case with zenith radiance observations by the Shortwave Array Spectroradiometer-Zenith (SASZe) during the Marine ARM GPCI Investigation of Clouds (MAGIC) field campaign. We found that there is about 10% change in PWV amount from known-cloudy region to known-clear sky in cloud edges.

Atmosphere↗

Validation of satellite retrievals of cloud microsphysics and liquid water path using observations from FIRE

Cloud effective radii (r(sub e)) and cloud liquid water path (LWP) are derived from ISCCP spatially sampled satellite data and validated with ground-based pyranometer and microwave radiometer measurements taken on San Nicolas Island during the 1987 FIRE IFO. Values of r(sub e) derived from the ISCCP data are also compared to values retrieved by a hybrid method that uses the combination of LWP derived from microwave measurement and optical thickness derived from GOES data. The results show that there is significant variability in cloud properties over a 100 km x 80 km area and that the values at San Nicolas Island are not necessarily representative of the surrounding cloud field. On the other hand, even though there were large spatial variations in optical depth, the r(sub e) values remained relatively constant (with sigma less than or equal to 2-3 microns in most cases) in the marine stratocumulus. Furthermore, values of r(sub e) derived from the upper portion of the cloud generally are representative of the entire stratiform cloud. When LWP values are less than 100 g m(exp -2), then LWP values derived from ISCCP data agree well with those values estimated from ground-based microwave measurements. In most cases LWP differences were less than 20 g m(exp -2). However, when LWP values become large (e.g., greater than or equal to 200 g m(exp -2)), then relative differences may be as large as 50%- 100%. There are two reasons for this discrepancy in the large LWP clouds: (1) larger vertical inhomogeneities in precipitating clouds and (2) sampling errors on days of high spatial variability of cloud optical thicknesses. Variations of r(sub e) in stratiform clouds may indicate drizzle: clouds with droplet sizes larger than 15 microns appear to be associated with drizzling, while those less than 10 microns are indicative of nonprecipitating clouds. Differences in r(sub e) values between the GOES and ISCCP datasets are found to be 0.16 +/- 0.98 micron.

Rossow, W.↗

An Analysis of AERONET Aerosol Absorption Properties and Classifications Representative of Aerosol Source Regions

Partitioning of mineral dust, pollution, smoke, and mixtures using remote sensing techniques can help improve accuracy of satellite retrievals and assessments of the aerosol radiative impact on climate. Spectral aerosol optical depth (tau) and single scattering albedo (omega (sub 0) ) from Aerosol Robotic Network (AERONET) measurements are used to form absorption [i.e., omega (sub 0) and absorption Angstrom exponent (alpha(sub abs))] and size [i.e., extinction Angstrom exponent (alpha(sub ext)) and fine mode fraction of tau] relationships to infer dominant aerosol types. Using the long-term AERONET data set (1999-2010), 19 sites are grouped by aerosol type based on known source regions to: (1) determine the average omega (sub 0) and alpha(sub abs) at each site (expanding upon previous work); (2) perform a sensitivity study on alpha(sub abs) by varying the spectral omega (sub 0); and (3) test the ability of each absorption and size relationship to distinguish aerosol types. The spectral omega (sub 0) averages indicate slightly more aerosol absorption (i.e., a 0.0 < delta omega (sub 0) <= 0.02 decrease) than in previous work and optical mixtures of pollution and smoke with dust show stronger absorption than dust alone. Frequency distributions of alpha(sub abs) show significant overlap among aerosol type categories and at least 10% of the alpha(sub abs) retrievals in each category are below 1.0. Perturbing the spectral omega (sub 0) by +/- 0.03 induces significant alpha(sub abs) changes from the unperturbed value by at least approx. +/- 0.6 for Dust, approx. +/-0.2 for Mixed, and approx. +/-0.1 for Urban/Industrial and Biomass Burning. The omega (sub 0)440nm and alpha(sub ext) 440-870nm relationship shows the best separation among aerosol type clusters, providing a simple technique for determining aerosol type from surface- and future space-based instrumentation.

Giles, David M.↗

Cloud Remote Sensing with EPIC/DSCOVR Observations: A Sensitivity Study with Radiative Transfer Simulations

The Earth Polychromatic Imaging Camera (EPIC) onboard the Deep Space Climate Observatory (DSCOVR) views nearly the whole sunlit face of the Earth with 10 spectral bands ranging from the UV to the near-infrared, including two oxygen absorbing bands centered at 764 nm (A-band) and 687.75 nm (B-band). Clouds are among the primary remote sensing targets using EPIC images because of their important impacts on the Earth’s radiation budget. In order to facilitate the EPIC cloud data product development, we have built a radiative transfer simulator featuring flexible cloud microphysical parameters, gas absorptions, and the instrument line shape functions for each EPIC band. The radiative transfer simulator is used to explore the sensitivity of EPIC observations on liquid-phase cloud microphysical parameters, including optical depth, geometric thickness, and cloud top height. We found that the ratios of the reflectances in the oxygen A and B bands to their respective continuum measurements can be used to increase the confidence level of cloud masking over scenes with sun-glint. In addition, the 388 nm band can be used to differentiate low and high clouds with the uncertainty of roughly 2–3 km. Combining this information with the oxygen absorption bands, the cloud geometric thickness can be obtained with the rough uncertainty of 3–4 km.

atmospheric and ocean optics↗

Multifrequency Studies

The present report concerns the following projects 'Multifrequency observations of the BL Lacertae object MK 421"; "EUVE and multifrequency observations of the quasars 3C 273 and 3C 279"; "EUVE observations of the symbiotic star RAquarii"; and "Morphology of the local HI void and ionization of He in the local ISM". The common theme of the above projects is UV observations and analysis of a wide range of astrophysical classes or objects, from the diffuse interstellar medium, to symbiotic stars (R Aqr), to active galactic nuclei (AGNs). Understanding the local (primarily neutral hydrogen or HI) interstellar medium is of great importance to detecting nearby EUV sources. Specifically, the ionization of helium is strongly influencing the extinction in the extreme ultraviolet (EUV) and the optical depth can vary almost by an order of magnitude depending on the degree of ionization of various species including neutral helium Vel ) and singly ionized helium (Hell). The local interstellar medium (ISM) contains a giant void. Understanding the local ISM and the extent of the HI void engulfing the Sun is crucial to our understanding of the EUV emission from nearby strongly EUV-emitting stars like R Aqr, as well as subtracting local absorption effects from absorption effects in distant sources themselves such as quasars, BL Lacertae objects and AGNs in general. A compilation of known properties of the local ISM with appropriate references has been performed. R Aqr is a symbiotic stellar system comprised of a mass-losing approx.1 - 2 solar mass Mira- like long period variable with a 387 day period and a approx. solar mass,) hot companion/accretion disk that is believed to give rise to the symmetrical jet seen at UV, optical radio wavelengths. Recent observations of R Aqr have been conducted at continuum wavelengths with the Very Large Array (VLA) at 7 mm that have resolved the stellar components in RAqr and a geometrical distance of approx. 200pc has been obtained, confirming that R Aqr is the nearest symbiotic star system to the Sun. The status of the local ISM is, therefore, of great importance in attempting to understand the UV properties of the hot companion in R Aqr and its prominent jet. Here a multifrequency approach is required from both ground observations (e.g. with the VLA) as well as from space-borne observations (with the International Ultraviolet Explorer-IUE; and the Hubble Space Telescope-HST). The R Aqr jet has been observed with the VLA B-configuration at two epochs separated by approx. 13.2 yr. Comparison of the resulting 6 cm continuum images show that the radio jet has undergone a lateral counterclockwise rotation of approx. 6 deg - 12 deg on the plane of the sky. Comparison of the most recent radio image with a nearly contemporaneous HSTIFOC ultraviolet image at approx 2330 A suggests that the UV emission lies along the leading edge of the rotating radio jet.

Kafatos, Menas↗

The Vertical Distribution of Thin Features Over the Arctic Analysed from CALIPSO Observations: Aerosols - Part 2

Influx of aerosols from the mid-latitudes has a wide range of impacts on the Arctic atmosphere. In this study, the capability of the CALIPSO-CALIOP instrument to provide accurate observations of aerosol layers is exploited to characterize their vertical distribution, probability density functions (PDFs) of aerosol layer thickness, base and top heights, and optical depths over the Arctic for the 4-yr period from June 2006 to May 2010. It is shown that the bulk of aerosols, from about 65% in winter to 45% in summer, are confined below the lowermost kilometer of the troposphere. In the middle troposphere (3-5 km), spring and autumn seasons show slightly higher aerosol amounts compared to other two seasons. The relative vertical distribution of aerosols shows that clean continental aerosol is the largest contributor in all seasons except in summer, when layers of polluted continental aerosols are almost as large. In winter and spring, polluted continental aerosols are the second largest contributor to the total number of observed aerosol layers, whereas clean marine aerosol is the second largest contributor in summer and autumn. The PDFs of the geometrical thickness of the observed aerosol layers peak about 400-700 m. Polluted continental and smoke aerosols, which are associated with the intrusions from mid-latitudes, have much broader distributions of optical and geometrical thicknesses, suggesting that they appear more often optically thicker and higher up in the troposphere.

Devasthale, Abhya↗

Neural Network Reflectance Prediction Model for Both Open Ocean and Coastal Waters

Remote sensing of global ocean color is a valuable tool for understanding the ecology and biogeochemistry of the worlds oceans, and provides critical input to our knowledge of the global carbon cycle and the impacts of climate change. Ocean polarized reflectance contains information about the constituents of the upper ocean euphotic zone, such as colored dissolved organic matter (CDOM), sediments, phytoplankton, and pollutants. In order to retrieve the information on these constituents, remote sensing algorithms typically rely on radiative transfer models to interpret water color or remote-sensing reflectance; however, this can be resource-prohibitive for operational use due to the extensive CPU time involved in radiative transfer solutions. In this work, we report a fast model based on machine learning techniques, called Neural Network Reflectance Prediction Model (NNRPM), which can be used to predict ocean bidirectional polarized reflectance given inherent optical properties of ocean waters. This supervised model is trained using a large volume of data derived from radiative transfer simulations for coupled atmosphere and ocean systems using the successive order of scattering technique (SOS-CAOS). The performance of the model is validated against another large independent test dataset generated from SOS-CAOS. The model is able to predict both polarized and unpolarized reflectances with an absolute error (AE) less than 0.004 for 99% of test cases. We have also shown that the degree of linear polarization (DoLP) for unpolarized incident light can be predicted with an AE less than 0.002 for 99% of test cases. In general, the simulation time of SOS-CAOS depends on optical depth, and required accuracy. When comparing the average speeds of the NNRPM against the SOS-CAOS model for the same parameters, we see that the NNRPM is able to predict the Ocean BRDF 6000 times faster than SOS-CAOS. Both ultraviolet and visible wavelengths are included in the model to help differentiate between dissolved organic material and chlorophyll in the study of the open ocean and the coastal zone. The incorporation of this model into the retrieval algorithm will make the retrieval process more efficient, and thus applicable for operational use with global satellite observations.

radiative transfer↗

Reconciling Simulated and Observed Views of Clouds: MODIS, ISCCP, and the Limits or Instrument Simulators

The properties of clouds that may be observed by satellite instruments, such as optical depth and cloud top pressure, are only loosely related to the way clouds m-e represented in models of the atmosphere. One way to bridge this gap is through "instrument simulators," diagnostic tools that map the model representation to synthetic observations so that differences between simulator output and observations can be interpreted unambiguously as model error. But simulators may themselves be restricted by limited information available from the host model or by internal assumptions. This paper considers the extent to which instrument simulators are able to capture essential differences between MODIS and ISCCP, two similar but independent estimates of cloud properties. The authors review the measurements and algorithms underlying these two cloud climatologies, introduce a MODIS simulator, and detail data sets developed for comparison with global models using ISCCP and MODIS simulators, In nature MODIS observes less mid-level doudines!> than ISCCP, consistent with the different methods used to determine cloud top pressure; aspects of this difference are reproduced by the simulators running in a climate modeL But stark differences between MODIS and ISCCP observations of total cloudiness and the distribution of cloud optical thickness can be traced to different approaches to marginal pixels, which MODIS excludes and ISCCP treats as homogeneous. These pixels, which likely contain broken clouds, cover about 15 k of the planet and contain almost all of the optically thinnest clouds observed by either instrument. Instrument simulators can not reproduce these differences because the host model does not consider unresolved spatial scales and so can not produce broken pixels. Nonetheless, MODIS and ISCCP observation are consistent for all but the optically-thinnest clouds, and models can be robustly evaluated using instrument simulators by excluding ambiguous observations.

Ackerman, Steven A.↗

Evaluating the Assumptions of Surface Reflectance and Aerosol Type Selection Within the MODIS Aerosol Retrieval Over Land: The Problem of Dust Type Selection

Aerosol Optical Depth (AOD) and Angstrom exponent (AE) values derived with the MODIS retrieval algorithm over land (Collection 5) are compared with ground based sun photometer measurements at eleven sites spanning the globe. Although, in general, total AOD compares well at these sites (R2 values generally over 0.8), there are cases (from 2 to 67% of the measurements depending on the site) where MODIS clearly retrieves the wrong spectral dependence, and hence, an unrealistic AE value. Some of these poor AE retrievals are due to the aerosol signal being too small (total AOD<0.3) but in other cases the AOD should have been high enough to derive accurate AE. However, in these cases, MODIS indicates AE values close to 0.6 and zero fine model weighting (FMW), i.e. dust model provides the best fitting to the MODIS observed reflectance. Yet, according to evidence from the collocated sun photometer measurements and back-trajectory analyses, there should be no dust present. This indicates that the assumptions about aerosol model and surface properties made by the MODIS algorithm may have been incorrect. Here we focus on problems related to parameterization of the land-surface optical properties in the algorithm, in particular the relationship between the surface reflectance at 660 and 2130 nm.

Mielonen, T.↗

Modeling and Evaluation of the Global Sea-Salt Aerosol Distribution: Sensitivity to Emission Schemes and Resolution Effects at Coastal/Orographic Sites

One of the major sources of uncertainty in model estimates of the global sea-salt aerosol distribution is the emission parameterization. We evaluate a new sea-salt aerosol life cycle module coupled to the online multi-scale chemical transport model NMMB/BSC-CTM. We compare 5 year global simulations using five state-of-the-art sea-salt open-ocean emission schemes with monthly averaged coarse aerosol optical depth (AOD) from selected AERONET sun photometers, surface concentration measurements from the University of Miami's Ocean Aerosol Network, and measurements from two NOAA/PMEL cruises (AEROINDOEX and ACE1). Model results are highly sensitive to the introduction of sea-surface-temperature (SST)-dependent emissions and to the accounting of spume particles production. Emission ranges from 3888 teragrams per year to 8114 teragrams per year, lifetime varies between 7.3 hours and 11.3 hours, and the average column mass load is between 5.0 teragrams and 7.2 teragrams. Coarse AOD is reproduced with an overall correlation of around 0.5 and with normalized biases ranging from +8.8 percent to +38.8 percent. Surface concentration is simulated with normalized biases ranging from minus 9.5 percent to plus 28 percent and the overall correlation is around 0.5. Our results indicate that SST-dependent emission schemes improve the overall model performance in reproducing surface concentrations. On the other hand, they lead to an overestimation of the coarse AOD at tropical latitudes, although it may be affected by uncertainties in the comparison due to the use of all-sky model AOD, the treatment of water uptake, deposition and optical properties in the model and/or an inaccurate size distribution at emission.

Bias↗

HST WFC3 Observations of Uranus' 2014 Storm Clouds and Comparison with VLT/SINFONI and IRTF/Spex Observations

In November 2014 Uranus was observed with the Wide Field Camera 3 (WFC3) instrument of the Hubble Space Telescope as part of the Hubble 2020: Outer Planet Atmospheres Legacy program, OPAL. OPAL annually maps Jupiter, Uranus and Neptune (and will also map Saturn from 2018) in several visible near- infrared wavelength filters. The Uranus 2014 OPAL observations were made on the 89th November at a time when a huge cloud complex, first observed by de Pater et al. (2015) and subsequently tracked by professional and amateur astronomers (Sayanagi et al., 2016), was present at 30-40deg N. We imaged the entire visible atmosphere, including the storm system, in seven filters spanning 467924 nm, capturing variations in the coloration of Uranus clouds and also vertical distribution due to wavelength dependent changes in Rayleigh scattering and methane absorption optical depth. Here we analyse these new HST observations with the NEMESIS radiative-transfer and retrieval code in multiple-scattering mode to determine the vertical cloud structure in and around the storm cloud system. The same storm system was also observed in the H-band (1.4-1.8 micrometers) with the SINFONI Integral Field Unit Spectrometer on the Very Large Telescope (VLT) on 31st October and 11th November, reported by Irwin et al. (2016, 10.1016j.icarus.2015.09.010). To constrain better the cloud particle sizes and scattering properties over a wide wavelength range we also conducted a limb-darkening analysis of the background cloud structure in the 30-40deg N latitude band by simultaneously fitting: a) these HSTOPAL observations at a range of zenith angles; b) the VLTSINFONI observations at a range of zenith angles; and c) IRTFSpeX observations of this latitude band made in 2009 at a single zenith angle of 23deg, spanning the wavelength range 0.8-1.8 micrometers (Irwin et al., 2015, 10.1016j.icarus.2014.12.020). We find that the HST observations, and the combined HSTVLTIRTF observations at all locations are well modelled with a three-component cloud comprised of: 1) a vertically thin, but optically thick deep tropospheric cloud at a pressure of approximately 2 bars; 2) a methane-ice cloud based at the methane-condensation level of approximately 1.23 bar, with variable vertical extent; and 3) a vertically extended tropospheric haze, also based at the methane-condensation level of 1.23 bar. We find that modelling both haze and tropospheric cloud with particles having an effective radius of approximately 0.1 micron provides a good fit the observations, although for the tropospheric cloud, particles with an effective radius as large as 1.0 micron provide a similarly good fit. We find that the particles in both the tropospheric cloud and haze are more scattering at short wave- lengths, giving them a blue color, but are more absorbing at longer wavelengths, especially for the tropospheric haze. We find that the spectra of the storm clouds are well modelled by localized thickening and vertical extension of the methane-ice cloud. For the particles in the storm clouds, which we assume to be composed of methane ice particles, we find that their mean radii must lie somewhere in the range 0. 1 1. 0 m. We find that the high clouds have low integrated opacity, and that streamers reminiscent of convective thunderstorm anvils are confined to levels deeper than 1 bar. These results argue against vigorous moist convective origins for the cloud features.

atmospheres↗