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At least 955 records · Page 53

Chemical reactivity of hydrogen, nitrogen, and oxygen atoms at temperatures below 100 k

The synthesis of unusual compounds by techniques employing cryogenic cooling to retard their very extreme reactivity was investigated. Examples of such species that were studied are diimide (N2H2), cyclobutadiene (C4H4), cyclopropanone (C3H4O), oxirene (C2H2O), and many others. Special purpose cryogenically cooled inlet arrangements were designed such that the analyses incurred no warm-up of the cold, and frequently explosively unstable, compounds. Controlled energy electron impact techniques were used to measure critical potentials and to develop the molecular energetics and thermodynamics of these molecules and to gain some insight into their kinetic characteristics as well. Three and four carbon strained ring molecules were studied. Several reactions of oxygen and hydrogen atoms with simple molecules of H, N, C, and O in hard quench configurations were studied. And the quench stabilization of BH3 was explored as a model system in cryochemistry.

Mcgee, H. A., Jr.↗

Rotor aeroelastic stability coupled with helicopter body motion

A 5.5-foot-diameter, soft-in-plane, hingeless-rotor system was tested on a gimbal which allowed the helicopter rigid-body pitch and roll motions. Coupled rotor/airframe aeroelastic stability boundaries were explored and the modal damping ratios were measured. The time histories were correlated with analysis with excellent agreement. The effects of forward speed and some rotor design parameters on the coupled rotor/airframe stability were explored both by model and analysis. Some physical insights into the coupled stability phenomenon are suggested.

Miao, W. L.↗

Average configuration of the distant (less than 220-earth-radii) magnetotail - Initial ISEE-3 magnetic field results

Magnetic field measurements from the first two passes of the ISEE-3 GEOTAIL Mission have been used to study the structure of the trans-lunar tail. Good agreement was found between the ISEE-3 magnetopause crossings and the Explorer 33, 35 model of Howe and Binsack (1972). Neutral sheet location was well ordered by the hinged current sheet models based upon near earth measurements. Between X = -20 and -120 earth radii the radius of the tail increases by about 30 percent while the lobe field strength decreases by approximately 60 percent. Beyond X = -100 to -1200 earth radii the tail diameter and lobe field magnitude become nearly constant at terminal values of approximately 60 earth radii and 9 nT, respectively. The distance at which the tail was observed to cease flaring, 100-120 earth radii, is in close agreement with the predictions of the analytic tail model of Coroniti and Kennel (1972). Overall, the findings of this study suggest that the magnetotail retains much of its near earth structure out to X = -220 earth radii.

Slavin, J. A.↗

The Interaction of Global Biochemical Cycles

The global biosphere in an exceedingly complex system. To gain an understanding of its structure and dynamic features, it is necessary not only to increase the knowledge about the detailed processes but also to develop models of how global interactions take place. Attempts to analyze the detailed physical, chemical and biological processes in this context need to be guided by an advancement of understanding of the latter. It is necessary to develop a strategy of data gathering that severs both these purposes simultaneously. The following papers deal with critical aspects in the global cycles of carbon, nitrogen, phosphorus and sulfur in details as well as the cycle of water and the flow of energy in the Earth's environment. The objective is to set partly the foundation for the development of mathematical models that allow exploration of the coupled dynamics of the global cycles of carbon, nitrogen, phosphorus, sulfur, as well as energy and water flux.

Moore, B., III↗

Evolution of Grains in a Turbulent Solar Nebula

Planetesimal formation by gravitational instability of a dust layer requires a nonturbulent solar nebula. The assumption that the solar nebula is a turbulent, convective accretion disk is explored. Self consistent models of a convective disk depend on high opacity of the disk material, which must be provided by grains. Grain coagulation is implied by the requirement of forming planetesimals, as the turbulent velocities (approx. 1/3 sound speed) in the accretion disk would disrupt any dust layer. Collisional coagulation could form large planetesimals, simultaneously leaving a sufficient fraction of matter in small grains to maintain the nebula's opacity. Or, coagulation of grains into small (approx. cm) aggregates could lower the opacity enough for turbulence to decay. The evolution of a population of grains in a turbulent solar nebula is calculated numerically.

Weidenschilling, S. J.↗

Continental volume and freeboard through geological time

The consequences of approximately constant freeboard for continental growth are explored using a model that relates the volumes of isostatically compensated continents and oceans to the secular decline in terrestrial heat flow. It is found that a post-Archean increase in freeboard by 200 m requires continental growth of only 10 percent, while a decrease in freeboard by 200 m during this same period necessitates a crustal growth of 40 percent. Shrinkage of the continental crust since the end of the Archean can be ruled out. Changes of more than 10 percent in post-Archean crustal thickness are highly unlikely.

Schubert, G.↗

Influence of transient baroclinic eddies on planetary-scale waves

Low-order models with a mean zonal flow forced by zonally symmetric heating and one planetary-scale wave forced by topography have multiple flow equilibria. Two stable equilibria are characterized by strong zonal flow with low wave amplitude (high index circulation) and weak zonal flow with a high wave amplitude (low index circulation) fixed in phase with the topography. These two states presumably represent normal zonal circulation and a blocking configuration, respectively. When a shorter, baroclinically unstable wave is dded to this low-order model, the planetary-scale wave no longer stays in stable equilibrium states. Instead, the long wave remains in weather regimes or preferred regions in phase space. These regimes are, in general, different from the equilibria of the model with the planetary-scale wave only. Thus, the short unstable wave adds some randomness to planetary-scale circulation and changes its position with respect to the planetary-scale topography. The Reinhold and Pierrehumbert model is further explored here by adding a long-wave in the thermal forcing and exploring wider parameter space. When the symmetric thermal forcing is weak so that the short wave is stable, the planetary scale wave is fixed in amplitude and phase by the asymmetric forcing. However, when the symmetric forcing is increased to an unstable level, the planetary-scale wave becomes less organized. With asymmetric thermal forcing only (i.e., no topography) the long-wave is randomly distributed through phase space. Thermal forcing seems to be less effective in organizing weather regimes than topographic forcing.

Branscome, L. E.↗

Grain dynamics in zero gravity

The dynamics of granular materials has proved difficult to model, primarily because of the complications arising from inelastic losses, friction, packing, and the effect of many grains being in contact simultaneously. The kinetic model of granular systems is similar to the kinetic theory of gases, except that collisional energy losses are always present in the former and must be treated explicity. Few granular materials on Earth are describable by this limiting model, since gravity tends to collapse the grains into a high density state where Coulombic friction effects are dominant. The planned Space Station offers an unusual opportunity to test the kinetic grain model and to explore its predictions. Without gravity, the regime of low interparticle velocities (where an elastic description of the collision is still valid) can be investigated. This will allow for direct interpretation by dynamical computer simulations as well as by the kinetic theory. The dynamics of spherical grains inside a clear box would be examined. Results would be compared with the predictions of the kinetic theory and computer simulations.

Werner, B. T.↗

Clark Lake microbursts - On a lower limit to type III burst brightness temperatures

Further observations of solar microbursts by the Clark Lake radioheliograph are reported. The microbursts have properties consistent with weak type III bursts, with the implication that type III's can have brightness temperatures as low as 1 million K. The importance of this result is explored. A single model to explain the stronger type III bursts and the weaker microbursts is sought. It is shown that none of the models for stabilizing the strongest type III electron streams can explain the observed microbursts: these models have threshold levels of Langmuir waves which imply emission (due to spontaneous scattering off ions) with brightness temperatures in excess of those observed. It appears that either some vital physics is still missing from models for type III bursts, or that microbursts should have properties significantly different from those of type III bursts. In the latter case further observations should allow important tests of type III models.

White, S. M.↗

Large molecules in diffuse interstellar clouds

The effects of the presence of a substantial component of large molecules on the chemistry of diffuse molecular clouds are explored, and detailed models of the zeta Persei and zeta Ophiuchi clouds are constructed. The major consequence is a reduction in the abundances of singly charged atomic species. The long-standing discrepancy between cloud densities inferred from rotational and fine-structure level populations and from the ionization balance can be resolved by postulating a fractional abundance of large molecules of 1 x 10 to the -7th for zeta Persei and 6 x 10 to the -7th for zeta Ophiuchi. If the large molecules are polycyclic aromatic hydrocarbons (PAH) containing about 50 carbon atoms, they contain 1 percent of the carbon in zeta Persei and 7 percent in zeta Ophiuchi. Other consequences of the possible presence of PAH molecules are discussed.

Lepp, S.↗

Grain dynamics in zero gravity

The dynamics of granular materials has proved difficult to model, primarily because of the complications arising from inelastic losses, friction, packing, and the effect of many grains being in contact simultaneously. One interesting limit for which it was recently possible to construct a theory is that where the grain-grain interactions are dominated by binary collisions. The kinetic model of granular systems if similar to the kinetic theory of gases, except that collisional energy losses are always present in the former and must be treated explicitly. Few granular materials on Earth are describable by this limiting model, since gravity tends to collapse the grains into a high-density state where Coulombic friction effects are dominant. The planned Space Station offers an unusual opportunity to test the kinetic grain model and to explore its predictions. Without gravity, the regime of low interparticle velocities, where an elastic description of the collision is still valid, is investigated. This will allow direct interpretation by dynamical computer simulations as well as by kinetic theory.

Werner, B. T.↗

A model of auroral potential structures based on Dynamics Explorer plasma data

Dynamics Explorer 1 hot plasma data are used to investigate three major features of the mid-altitude auroral electron distribution -- the hole, the bump (at large pitch angles), and the loss cone. The results of a computer simulation show that these features can be approximately reproduced by a model involving an initial plasma sheet electron distribution and two potential drop regions that are widely separated in altitude. The observed distributions could not be reproduced, even qualitatively, by any of a wide range of distributed potential drops involving parallel electric fields at the point of observation.

Burch, J. L.↗

Relativistic electrons near geostationary orbit - Evidence for internal magnetospheric acceleration

The possibility of an internal magnetospheric acceleration mechanism as the source of relativistic electron fluxes in earth's outer magnetosphere is explored. Such a model includes the substorm generation of a spectrally soft electron component, with subsequent inward radial diffusion. At low L values, an outward transport of energetic electrons occurs which leads to a return of the accelerated population to the outer magnetosphere. Data obtained concurrently at geostationary orbit at three widely spaced local times during a relativistic electron event provide support for acceleration by a recirculation process.

Baker, D. N.↗

First results in terrain mapping for a roving planetary explorer

To perform planetary exploration without human supervision, a complete autonomous rover must be able to model its environment while exploring its surroundings. Researchers present a new algorithm to construct a geometric terrain representation from a single range image. The form of the representation is an elevation map that includes uncertainty, unknown areas, and local features. By virtue of working in spherical-polar space, the algorithm is independent of the desired map resolution and the orientation of the sensor, unlike other algorithms that work in Cartesian space. They also describe new methods to evaluate regions of the constructed elevation maps to support legged locomotion over rough terrain.

Krotkov, E.↗

Exobiology site selection for future Mars missions: Martian paleolake sediments and terrestrial analogs

This research was conducted to establish the scientific framework for the exobiological study of sediments on Mars and to encourage the selection of these sedimentary deposits as sampling sites for future Mars missions. A study was completed on the Antarctic Dry Valley Lakes (terrestrial analogs of the purported Martian paleolakes) and their sediments that allowed the development of quantitative models relating environmental factors to the nature of the biological community and sediment forming processes. The publications presented include: (1) Diversity of micro-fungi isolated in an Antarctic dry valley; (2) Lake Hoare, Antarctica--sedimentation through a thick perennial ice cover; (3) The possibility of life on Mars during a water-rich past; (4) An Antarctic research outpost as a model for planetary exploration; (5) Early Martian environments--the Antarctic and other terrestrial analogs; (6) Lipophilic pigments from the benthos of a perennially ice-covered Antarctic lake; and (7) Perennially ice-covered Lake Hoare, Antarctica--physical environment, biology, and sedimentation.

Wharton, Robert A., Jr.↗

Empirical studies of software design: Implications for SSEs

Implications for Software Engineering Environments (SEEs) are presented in viewgraph format for characteristics of projects studied; significant problems and crucial problem areas in software design for large systems; layered behavioral model of software processes; implications of field study results; software project as an ecological system; results of the LIFT study; information model of design exploration; software design strategies; results of the team design study; and a list of publications.

Krasner, Herb↗